SOLUTIONS – IIT-JEE-2011: CODE: 2

CHEMISTRY PAPER – 1

1. (B)
[Ni Cl4]2- ⇒ sp3 hybridisation ⇒ Tetrahedran
[Ni (CN)4]2- ⇒ dsp2 hybridisation ⇒ square planar
[Ni (H2O)6]2+ ⇒ sp3d2 hybridisation ⇒ octahedron
2. (A)
27 30 27 30 30 30
13 Al (α, P) 14 Si; 13 Al (α, n) 15 P; 15 P (γ, +1 β) 14 Si
3. (C)
Wurea 1000
Molarity = x
(Mol. Mass)urea Vsolution
120 1000 Wsolution
= x Vsolution =
6 Vsolution (density)solution
120 1000 x 1.15
M= x = 2.05
6 1120
4. (D)
AgNO3 (aq) + KCl (aq) → AgCl (s) + KNO3 (aq)
In the beginning ionic mobility of Cl- and NO3- being comparables conductivity tends to remain
constant. The gradual increase in conductivity is due to the excess AgNO 3 present towards the
end.
5. (C)
o-Hydroxy benzoic acid is more acidic due to ORTHO effect
6. (A)

O O
Br CH2 Cl

KOH N K (A)
NH

O O

Nucleophilic substitution occurs on alkyl chloride. It is checked in aryl bromide due to the
double bond character of C – Br bond.
7. (D)
Metallic azides on heating deposit solid metal leaving N2 gas
Ba (N3)2 → Ba (↓) + 3N2 (↑)
8. (A, B, D)
Low temperature favours PHYSISORPTION
9. (A, C, D)
SnO2 + 2C → Sn + 2CO
(cassiterite) Purified through liquation/polling
SnO2 has Fe, W, Mn, Cu associated as impurities
10. (B, C)
Allenes (D) are not planar
Gauche conformation of 1, 3-Butadiene (A) is not planar
11. (A, D)
‘C’ is true according to Maxwell’s distribution
12. (D)
13. (B)
12 and 13 are explained in the following scheme
O CH3 OH2
dil. H2SO4 NaBH4
CH4 C C CH CH4 C C CH3 + H3C C C CH3
3 HgSO4 3 H
CH3 H

H3C CH3 H3C

1,2-methylshift O3
2 O
(-H2O) Zn/H2O
14. (B) H3C CH3 H3C
15. (A)
16. (C)
14, 15 and 16 are as explained
Cu (s)  AgNO (aq)
 3   → Cu (NO3)2 (aq) + 2Ag + AgNO3 (remaining unreacted)
Ag+ + Cl- → AgCl  NH3 → [Ag (NH3)2]+
Cu2+  NH3 → [Cu (NH3)4]2+ (Deep Blue)
17. 5
3Br2 + 3Na2CO3 → 5NaBr + NaBrO3 + 3CO2
18. 6
Net weight of hydrolysed products (Wnet) = Wt. of decapeptide + wt. of H2O needed
Decapeptide ⇒ 10 – 1 = 9 bonds to be hydrolysed
⇒ 9H2O needed per molecule
∴ Wnet = 796 + 9 x 18 = 958 g
47
wt. of glycine = x 958 = 450 g
100
450
∴ No. of glycine = =6
75
19. 5

Br

+ +

(1) (2) (2)

cis and trans cis and trans

1+2+2=5

20. 7
PHe = Pext – VP = 1 – 0.068 = 0.32 atm
nRT 0.1 x 0.0821 x 273
PV = nRT ⇒ V = = =7
P 0.32
21. 4
o
300 nm = 3000 A ⇒ 4.1 eV
All metals with φ < 4.1 eV (Li, Na, K, Mg) would show photoelectric effect
22. 9
n = 3 ⇒ NO. of orbitals = n2 – 9 3s; (3PX, 3PY, 3PZ), (3dxy, 3dyz, 3dxz, 3dx2 – y2, 3dz2)
one electron in each of these orbitals can have the same value for spin quantum number.
Hence, 9 electrons
23. O O

Na O S S S S O Na
+5 and 0 oxidation states are shown by sulphur
O O
+5 zero

SOLUTIONS – IIT-JEE-2011: CODE: 2

CHEMISTRY PAPER – 2

1. (C)
Diamagnetic complexes have all paired electrons
2. (A)
Acidic medium limits the amount of S2- and those salts with low Ksp precipitate out
3. (D)
Nernst Equation
0.059 0.059 [O2 ] [H + ]4
1.67 - log [Fe2+]2 + log = 1.55 V
4 4 H2 O
4. (A)
WB 1000
∆Tf = Tsolvent – Tsolution = i x Kf x x (B → solute, A → solvent)
MB WA
i = 1 + (n – 1) α = 1 + (4 – 1) = 4
0.1 1000
∴ 0oC – Tsolution = 4 x 1.86 x x = 0.0226
329 100
⇒ (FP)solution = -2.3 x 10-2 oC
5. (C)
Only aromatic 1o amines form BDC which shows AZO coupling with β-naphthol to form red
coloured dye
6. (B)
7. (B)
8. (D)
Haemetite is Fe2O3 ⇒ 2x – 6 = 0 ⇒ x = +3
FeO . Fe 2 O3
Magnetite is FeO4 ⇒  ⇒ oxidation states} = +2; +3
Mixed oxide

9. (B, C, D)
Cl-, SCN and CN- form insoluble Cu (+1) salts; thus shifting equilibrium to the LHS direction.
10. (A, B, D)
0.693 2.303 100
= x log ⇒ [At] = 0.4
t 50% 8 x t 50% [At]
⇒ 99.6% completion of reaction
11. (B, C, D)
In (A) polyester is formed while in B, C and D Polyamides are formed
12. (A, C, D)
Acid medium changes (Mn+7O4)- to (Mn2+) ∆=5
Alkaline medium changes (Mn O4) to MnO2
+7 -
∆=3
Neutral medium changes (Mn+7O4) to MnO2 ∆=3
13. 6
No. of equivalents of AgNO3 = No. of equivalents of [Cr (H2O)5Cl] Cl2
⇒ (V x 0.1) AgNO3 = [30 x 0.01 x 2][Cr (H2O)5 Cl] Cl2
⇒ VAgNO3 = 6 mL
14. 7
Cl- is sourced from AgCl and CuCl
∴ [Cl-] = [Ag+] + [Cu+]
Also {[Ag+] [Cl-] = 1.6 x 10-10} w.r.to AgCl
And {[Cu+] [Cl-] = 1.0 x 10-6} w.r.to CuCl
15. 8
Truncated octahedron has 8 hexagonal and 6 square faces
16. 8 Cl Cl
Cl

+ CH3 + CH3
+ CH3
Cl

No chiral centre one chiral centre Two chiral centres No chiral centre
⇒ 1 isoemr ⇒ 2’ = 2 isomers ⇒ 22 = 4 isomers ⇒ 1 isomer
17. 6

H3C CH2CH3

6α hydrogens ⇒ 6 hyperconjugative structures

18. 4
2 PCl5 + H2SO4 → 2POCl3 + SO2Cl2 + 2HCl
PCl5 + H2O → POCl3 + 2HCl
PCl5 + SO2 → POCl3 + SOCl3
6PCl5 + P4O10 → 10 POCl3
19. A → r, s, t

B → s, p

CH2Cl O
O OH
CH2
CH3MgI Nucleophilic
CH 2-CH 2-CH 2-Cl CH3
CH3 CH2 Substitution
 C → s, r

OH OH2
O

CH C
18 CH3MgI CH2
CH 2-CH 2-CH 2-OH O
O 18
H dehydration
CH2 18
H2C

Nucleophilic addition

D → r, q
H2SO4 Electrophilic
CH2 CH2 CH2 C (CH3)2
dehydration Substitution
OH2 H

20. A → PRS Phase change from (s) to (g) (P)

Energy is absorbed (R)
Entropy increases (S)
B → RS Energy is absorbed (R)
Entropy increases (S)
C→T Bond forms and entropy decreases (T)
D → Q, R, T Allotropic change occurs (Q)
White P on heating forms red P i.e., heat is absorbed (R)
Red P is less reactive and stable than white P (T)