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    Peng-Robinson EOS (1976) : Home Course Outline Cubic EOS and Their Behavior (III) Peng-Robinson EOS (1976)

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    Valeria Shakarova
    The Peng-Robinson equation of state (PR EOS) was developed in 1976 by Peng and Robinson to model natural gas systems. It is based on modifying the van der Waals equation of state and introduces new parameters to better describe the behavior near the critical point, making it well-suited for modeling gas/condensate systems. The PR EOS incorporates mixing rules to calculate properties for multi-component systems and uses binary interaction parameters fitted to experimental data.

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    Peng-Robinson EOS (1976) : Home Course Outline Cubic EOS and Their Behavior (III) Peng-Robinson EOS (1976)

    Uploaded by

    Valeria Shakarova
    85 views2 pages
    The Peng-Robinson equation of state (PR EOS) was developed in 1976 by Peng and Robinson to model natural gas systems. It is based on modifying the van der Waals equation of state and introduces new parameters to better describe the behavior near the critical point, making it well-suited for modeling gas/condensate systems. The PR EOS incorporates mixing rules to calculate properties for multi-component systems and uses binary interaction parameters fitted to experimental data.

    Original Description:

    small guide on Peng Robinson EOS

    Original Title

    Peng Robinson EOS

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    The Peng-Robinson equation of state (PR EOS) was developed in 1976 by Peng and Robinson to model natural gas systems. It is based on modifying the van der Waals equation of state and introduces new parameters to better describe the behavior near the critical point, making it well-suited for modeling gas/condensate systems. The PR EOS incorporates mixing rules to calculate properties for multi-component systems and uses binary interaction parameters fitted to experimental data.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    85 views2 pages

    Peng-Robinson EOS (1976) : Home Course Outline Cubic EOS and Their Behavior (III) Peng-Robinson EOS (1976)

    Uploaded by

    Valeria Shakarova
    The Peng-Robinson equation of state (PR EOS) was developed in 1976 by Peng and Robinson to model natural gas systems. It is based on modifying the van der Waals equation of state and introduces new parameters to better describe the behavior near the critical point, making it well-suited for modeling gas/condensate systems. The PR EOS incorporates mixing rules to calculate properties for multi-component systems and uses binary interaction parameters fitted to experimental data.

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    © All Rights Reserved
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    Peng-Robinson EOS (1976) https://www.e-education.psu.

    edu/png520/print/book/export/html/1933

    Published on PNG 520: Phase Behavior of Natural Gas and Condensate Fluids (https://www.e-
    education.psu.edu/png520)
    Home > Course Outline > Cubic EOS and Their Behavior (III) > Peng-Robinson EOS (1976)

    Peng-Robinson EOS (1976)


    The Peng-Robinson EOS has become the most popular equation of state for natural gas systems in the
    petroleum industry. During the decade of the 1970’s, D. Peng was a PhD student of Prof. D.B. Robinson
    at the University of University of Alberta (Edmonton, Canada). The Canadian Energy Board sponsored
    them to develop an EOS specifically focused on natural gas systems. When you compare the
    performance of the PR EOS and the SRK EOS, they are pretty close to a tie; they are “neck to neck,”
    except for a slightly better behavior by the PR EOS at the critical point. A slightly better performance
    around critical conditions makes the PR EOS somewhat better suited to gas/condensate systems.

    Peng and Robinson introduced the following modified vdW EOS:

    + (˜ − ) =
    ˜ +2 ˜−
    (11.1a)

    or, explicitly in pressure,

    = −
    ˜− ˜ +2 ˜−
    (11.1b)

    where:

    Peng and Robinson conserved the temperature dependency of the attractive term and the acentric factor
    introduced by Soave. However, they presented different fitting parameters to describe this dependency
    (equation 4.11c), and further manipulated the denominator of the pressure correction (attractive) term.
    As we have seen before, coefficients “a” and “b” are made functions of the critical properties by imposing
    the criticality conditions. This yields:

    = 1 + (0.37464 + 1.54226 − 0.26992 ) 1− !


    (11.1c)

    "
    = 0.45724
    "
    (11.2a)

    The PR cubic expression in Z becomes:

    "
    = 0.07780
    "
    (11.2b)

    where:

    $ % − (1 − &)$ + ' − 2& − 3& $ − '& − & − & % = 0


    (11.3a)

    1 of 2 08/10/2018, 19:01
    Peng-Robinson EOS (1976) https://www.e-education.psu.edu/png520/print/book/export/html/1933

    '=
    (11.3b)

    &=
    (11.3c)

    Similar to SRK, the PR mixing rules are:

    ( )( = ) ) *+ *, ( )+, ; ( )+, = /( )+ ( ), 1 − 0+,

    (11.4a)

    ( = ) *+ +

    +
    (11.4b)

    where binary interaction parameters (kij) again play the important empirical role of helping to better fit
    experimental data. Due to the empirical character of these interaction parameters, kij’s calculated for PR
    EOS are unlikely to be the same as the kij’s calculated for SRK EOS for the same pair of molecules.

    Source URL: https://www.e-education.psu.edu/png520/m11_p2.html

    2 of 2 08/10/2018, 19:01

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