January 2002

P/N 81-CO2MAN-002

CO2
Carbon Dioxide
Fire Suppression
Systems

Owner’s Manual

Fire Systems
 January 2002
P/N 81-CO2MAN-002

CO2
Carbon Dioxide
Fire Suppression
Systems

Owner’s Manual

Fire Systems
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 FOREWORD

This Manual is written for those who fill Kidde Carbon Dioxide (CO2) Suppression System Cylinders.

IMPORTANT
Kidde assumes no responsibility for application of any systems other than those addressed in this manual. The technical data
contained herein is limited strictly for information purposes only. Kidde believes this data to be accurate, but it is published and
presented without any guarantee or warranty whatsoever. Kidde disclaims any liability for any use that may be made of the data and
information contained herein by any and all other parties.
Kidde Carbon Dioxide Engineered Fire Suppression Systems are to be designed, installed, inspected, maintained, tested and re-
charged by qualified, trained personnel in accordance with the following:
• Standard of the National Fire Protection Association No. 12, titled “Carbon Dioxide Extinguishing systems.” (Latest Edition)
• All instructions, limitations, etc., contained in the manual, P/N 81-CO2MAN-002.
• All information contained on the system nameplate(s).
Storage, handling, Transportation, service, maintenance, recharge and test of agent storage containers shall be performed only by
qualified, trained personnel in accordance with the information in the manual and Compressed Gas Association* pamphlets C-1, C-
6, G-6, G-6.3 and P-1.
• C-1, “Methods for Hydrostatic Testing of Compressed Gas Cylinders”
• C-6, “Standards for Visual Inspection of Steel Compressed Gas Cylinders”
• G-6, “Carbon Dioxide”
• G-6.3, “Carbon Dioxide Cylinder Filling and Handling Procedures”
• P-1, “Safe Handling of Compressed Gas In Containers”
*CGA pamphlets are available from:
Compressed Gas Association
Crystal Square Two
1725 Jefferson Davis Highway
Arlington, VA 22202-4102
Any questions concerning the information presented in the manual should be addressed to:
Kidde-Fenwal, Inc.
400 Main Street
Ashland, MA 01721
Phone: (508) 881-2000
Fax: (508) 881-8920

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ii
 TABLE OF CONTENTS
Foreword ....................................................................................................................................................... i
List of Tables ................................................................................................................................................. iv

Paragraph Title Page

1 General Information ................................................................................................................................. 1-1

1-1 Introduction ................................................................................................................................................. 1-1
1-2 Moving of Containers .................................................................................................................................. 1-1
1-2.1 Moving by Trucks ........................................................................................................................................ 1-1
1-2.2 Rough Handling .......................................................................................................................................... 1-1
1-2.3 Storage ........................................................................................................................................................ 1-1
1-3 Protection Cap ............................................................................................................................................ 1-1
1-4 About the System ....................................................................................................................................... 1-2
1-5 Carbon Dioxide (CO2) Overview ................................................................................................................. 1-2

2 Installation, Operation and Maintenance ............................................................................................... 2-1

2-1 Introduction ................................................................................................................................................. 2-1
2-2 Installation ................................................................................................................................................... 2-1
2-3 Instructions in Case of Fire ........................................................................................................................ 2-1
2-3.1 CO2 System Operation Procedures ........................................................................................................... 2-2
2-3.1.1 Automatic Operation ................................................................................................................................... 2-2
2-3.1.2 Cable Actuator and Electric System Operation ......................................................................................... 2-2
2-3.1.3 Remote Nitrogen Actuator Operation (Pneumatic) .................................................................................... 2-2
2-3.1.4 Local Manual Operation–All Systems ........................................................................................................ 2-2
2-3.1.5 Hose Reel or Rack System Manual Operation .......................................................................................... 2-3
2-3.1.5.1 Surface Fires .............................................................................................................................................. 2-3
2-3.1.5.2 Electrical Fires–Switchboards, Motors, etc. ............................................................................................... 2-3
2-4 Post-Operation Instructions ........................................................................................................................ 2-3
2-5 Inspection and Maintenance of the System ............................................................................................... 2-3
2-5.1 Monthly Inspection ...................................................................................................................................... 2-4
2-5.2 Semi-Annual Inspection ............................................................................................................................. 2-5
2-5.3 Annual Inspection ....................................................................................................................................... 2-5
2-5.4 5 Year and 12 Year Inspection and Test Guidelines .................................................................................. 2-5
2-6 Additional Requirements ............................................................................................................................ 2-5
2-7 Additional Specifications and Documentation ........................................................................................... 2-5

iii
 LIST OF TABLES

Table Title Page

2-1 Inspection and Maintenance Schedule ..................................................................................................... 2-4

LIST OF APPENDICES

Appendix Title Page

A MSDS Sheets ............................................................................................................................................. A-1

B Component Descriptions ............................................................................................................................ B-1

iv
 ATTENTION INSTALLER

This form must be signed by the system owner indicating that he/she has received a copy of this Owner’s Manual
P/N 81-CO2MAN-002. Have the system installer fill-out this form.

Note: Retain a copy of this form for your records.

1. System Installed:
__________________________________________________________________
__________________________________________________________________
__________________________________________________________________
__________________________________________________________________
__________________________________________________________________

2. Listing of Major System Components:

__________________________________________________________________
__________________________________________________________________
__________________________________________________________________
__________________________________________________________________
__________________________________________________________________
__________________________________________________________________

3. Description of Hazard Protected by System:

__________________________________________________________________
__________________________________________________________________
__________________________________________________________________
__________________________________________________________________
__________________________________________________________________

____________________________________________ _____________
Owner or Authorized Representative Date

____________________________________________
Title

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vi
 SAFETY SUMMARY
Safety precautions are essential whenever electrical or mechanical equipment is involved. Take precautions when handling, servic-
ing, and charging CO2 fire suppression systems cylinders. Using this equipment with the respect and caution demanded will consid-
erably lessen the possibility of personal injury. If safety precautions are overlooked or ignored, personal injury or property damage
may occur.
The following symbols are used throughout this manual. Always heed these precautions. They are essential to the safe use of the
equipment described in this manual.

! WARNING
The warning symbol identifies immediate hazards and provides specific instructions or procedures which if not
correctly followed may result in severe personal injury or death.

! CAUTION
This caution symbol identifies specific instructions or procedures which if not correctly followed could result in
equipment or property damage.
The following safety precautions should always be followed:

! WARNING
Pressurized (charged) cylinders are extremely hazardous and if not handled properly are capable of causing bodily
injury, death or property damage.
1. Read and understand this manual and the other documents referenced herein.
2. The valve cylinder safety cap MUST be installed on the cylinder at all times and only removed when performing charging,
testing, or salvaging operations in accordance with the procedures contained in this manual.
3. Wear safety glasses when working with pressurized cylinders and charging equipment
4. Make sure that all control heads, pressure operated control heads, or other type of actuation devices have been removed from
the cylinder valves. Ensure the protection caps are installed before performing any charging, leak tests or salvage operations.
Don’t get careless. Never assume a cylinder is empty. Treat all cylinders as if they are fully charged.
Smoking is prohibited in carbon dioxide fill and charging areas.

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viii
 CO2 Fire Suppression Systems

CHAPTER 1
GENERAL INFORMATION

and connection of other critical devices, such as solenoids,

1-1 INTRODUCTION cable assemblies, pressure switches and safety caps.
This document is provided to instruct and familiarize the READ, UNDERSTAND and ALWAYS FOLLOW the opera-
owner with the Kidde Carbon Dioxide (CO2) Fire Suppres- tion and maintenance manuals, owner’s manuals, service
sion System. This manual covers: manuals, etc., that are provided with the individual systems.

• Information about the system ! WARNING

• How the CO2 system operates
Pressurized (charged) containers are extremely
• How CO2 works hazardous and if not handled properly, are
• Installation of the system capable of violent discharge. This may result
• Instructions in case of fire in serious bodily injury, death and property
damage.
• Post-operation instructions
• Inspection and maintenance of the system
• Responsibilities and related equipment requirements 1-2 MOVING OF CONTAINERS
• Additional specifications and documentation 1-2.1 Moving by Trucks
Note: This owner’s manual does not cover every detail All CO2 cylinders over 40 lb. are to be laid horizontally on
of step-by-step installation procedures for Kidde the pallet in pyramidal form and securely strapped during
Carbon Dioxide (CO2) Fire Suppression System. shipment. No more than 10 CO2 cylinders may be shipped
on a single pallet. Containers must not be rolled, dragged,
The system consists of components tested within
slid or allowed to be slid from tailgates of vehicles. A suit-
the limitations defined in the detailed design, in-
able hand truck, fork truck, roll platform or similar device
stallation, operation and maintenance manual
must be used.
(P/N 81-CO2MAN-001) which is available from
Kidde. The system designer must be consulted 1-2.2 Rough Handling
whenever changes are planned for the system
Containers must not be dropped or permitted to strike vio-
or area of protection.
lently against each other or other surfaces.
A certified Kidde distributor must be consulted af-
1-2.3 Storage
ter the system has been discharged.
Containers must be stored upright and secured in place.
The technical data contained herein is limited strictly
for informational purposes only.
1-3 PROTECTION CAP
! CAUTION
It is the owner’s responsibility to read this ! WARNING
manual and to ensure proper system operation The 35 lb. through 100 lb. size cylinders are
and personnel safety. factory-equipped with a protection cap
Follow the instructions in this manual and on the CO2 cylin- threaded securely over the valve assembly. This
der nameplates. Review this information semi-annually, or device is a safety feature and provides
as needed. Place this manual in an accessible place near protection during shipment and handling. This
the CO2 system for ready reference. cap must be installed at all times, except when
the cylinders are connected into the system
Kidde believes this data to be accurate, however, it is pub- piping or being filled. Do not move or handle a
lished and presented without any guarantee or warranty carbon dioxide cylinder unless the protection
whatsoever. Kidde disclaims any liability for the informa- cap is installed.
tion contained herein by any, and all, other parties.
The 35 through 100 lb. containers are shipped with a pro-
Before handling Kidde products, all personnel must be thor- tective safety cap. This device is a safety feature that will
oughly trained in the safe handling of the containers as well protect the discharge valve from damage or rupture in a
as in the proper procedures for installation, removal, filling case where the container is mishandled.

January 2002 1-1 81-CO2MAN-002

CO2 Fire Suppression Systems

The safety cap must be installed on the container at all

! WARNING
times except when the container is attached to the system
piping; i.e., when the discharge head is connected to the Because carbon dioxide reduces the available
container discharge valve. oxygen in the atmosphere, it will not support
life. Care must be taken, and appropriate alarms
The safety cap must remain in close proximity to the con-
shall be used, to ensure that all personnel are
tainer to prevent loss while in service. Do not move or handle
evacuated from the protected space prior to
cylinders without the cap installed.
discharging the system. A suitable warning sign
For additional information on safe handling of compressed must be prominently displayed, in clear view
gas containers, see CGA Pamphlet P1 titled “Safe Han- at the point of entry into the protected area, to
dling of Compressed Gases in Containers.” (CGA pam- alert people to the asphyxiation properties of
phlets may be purchased from the Compressed Gas carbon dioxide.
Association, Crystal Square Two, 1725 Jefferson Davis
The discharge of carbon dioxide in fire suppression con-
Highway, Arlington, VA, 22202).
centrations can create a serious threat to people. Carbon
dioxide should not be used for spaces normally occupied if
1-4 ABOUT THE SYSTEM sufficient safeguards cannot be taken to ensure that all
personnel can evacuate the space before discharge.
The Kidde CO2 Fire Suppression System is an engineered,
special-hazard system utilizing a fixed pipe and nozzle dis-
tribution network, hose reels, or a combination of both. 1-5 CARBON DIOXIDE (CO2) OVERVIEW
These systems provide fire protection, using carbon diox-
Carbon dioxide is a colorless, odorless, electrically non-
ide as the extinguishant, designed in accordance with the
conductive gas with a density approximately 50% greater
National Fire Protection Association (NFPA) 12, “Standard
than air. When applied to a fire, it provides a blanket of
on Carbon Dioxide Extinguishing Systems”, (latest edition).
heavy gas which reduces the oxygen content of the atmo-
Kidde CO2 Fire Suppression Systems are designed for sup- sphere to a point in which combustion can not be sustained.
pression of Class A (wood, paper, and other cellulosic ma- In general, a reduction in oxygen concentration in the com-
terials), Class B (flammable liquids and gases), and bustion zone to 15% or less by volume is sufficient to extin-
Class C (electrical equipment) hazards. Carbon dioxide guish most diffusion-flame fires in flammable liquids.
must be applied with due consideration of the hazard being
Carbon dioxide is stored as a liquid under its own vapor
protected and its contents. Carbon dioxide should not be
pressure of 850 psi at 70° F (58.6 bar at 21° C). This pres-
used on Class D (reactive metals, metal hydrides and
sure propels the agent through the valve and subsequent
chemicals containing their own oxygen supply) hazards,
pipe network to the nozzle or nozzles. Upon discharge from
such as magnesium, potassium, sodium, and cellulose ni-
the nozzle the CO2 undergoes a rapid expansion and sub-
trate.
sequent phase change from liquid to gas. The large volu-
Examples of typical carbon dioxide system applications in- metric expansion ratio, from liquid to gas, allows for the
clude: storage of a large quantity of agent in a small cylinder.
• Industrial
• Dip tanks
• Mixing tanks
• Spray booths
• Ovens and dryers
• Quench tanks
• Coating machines
• Marine
• Dry cargo spaces
• Machinery spaces
• Paint lockers

81-CO2MAN-002 1-2 January 2002

 CO2 Fire Suppression Systems

CHAPTER 2
INSTALLATION, OPERATION AND MAINTENANCE

• All areas requiring protection are adequately covered.

2-1 INTRODUCTION • A means of manually discharging the CO2 system is
The Kidde CO2 Fire Suppression System is designed to provided in a readily accessible location where it can
discharge a specific amount of CO2 through nozzles lo- be operated while leaving the vicinity of the hazard area.
cated within the hazard area as either a local application or The manual control must be clearly labeled.
total flooding application. The amount of CO2 necessary • The installer of the CO2 system should answer any
for the system has been carefully calculated to meet strict questions regarding the components, coverage and
requirements set by Underwriters Laboratories, Factory operation of the system.
Mutual Research and the National Fire Protection Associa- • The installer has demonstrated that the installed sys-
tion. Additional requirements may apply depending upon tem conforms to the requirements of the Kidde Carbon
the application, design specifications and the Authority Dioxide (CO2) Fire Suppression Systems Design, In-
Having Jurisdiction. stallation, Operation and Maintenance Manual, (P/N 81-
The Kidde Carbon Dioxide Fire Suppression System con- CO2MAN-001), the requirements of the insurance
sists of: carrier and the Authorities Having Jurisdiction in the
area.
• CO2 container(s), discharge piping and nozzles
• Manual and/or automatic actuation devices–electric,
pneumatic, cable or local manual 2-3 INSTRUCTIONS IN CASE OF FIRE
• Detection devices, alarm devices and control panel. In case of fire, take the following steps:
The system must be provided with a means for operation 1. Direct all occupants to leave the fire area immediately.
using either an automatic or manual control. However, a
Note: Once all occupants have exited the fire area and
manual control of actuation must accompany an automatic
protected enclosure, operate the system manually
means of actuation as a redundant control. Automatic sys-
using the manual release if necessary. (Do not wait
tem operation (if provided) can be electric using UL Listed
for the system to actuate automatically.)
heat detectors, photoelectric smoke detectors, ionization
smoke detectors or optical flame detectors. 2. Suspend all operations in the fire area.
A control head (electric, pneumatic, cable or local manual) 3. Contact the fire department and local fire brigade (if
is used to operate the CO2 agent container. Pressure from applicable) immediately, no matter how small the fire
the discharge may be used to open the container valves on appears to be. Post the street address of the building
additional containers. containing the protected area and the fire department’s
telephone number beside each phone. Familiarize your-
If the system has a control panel, refer to the appropriate self with the location of the nearest telephone box or
Kidde control panel manual as applicable. pay-phone outside the building, in the event that the
fire department must be notified from outside the facil-
ity.
2-2 INSTALLATION
4. Make sure all persons have evacuated the fire area in
Kidde CO2 Fire Suppression Systems must be installed by accordance with building management emergency pro-
authorized Kidde distributors only. Each system must be cedures.
installed using genuine Kidde components and installation
5. To operate the extinguishing system, follow the instruc-
materials in accordance with the Design, Installation, Op-
tions on the manual release device, i. e., “LIFT COVER,
eration and Maintenance Manual (P/N 81-CO2MAN-001).
PULL DOWN,” etc. The remote manual release is a
Note: The installer must have a current Kidde training device, which works electrically and/or mechanically.
certificate. Exit the vicinity of the hazard immediately following ac-
tuation of the manual release device.
Check your system before acceptance. Do not accept poor
workmanship, missing system parts or substitute system 6. Do not re-enter the fire area until the fire department
components. The following items must be checked after gives approval.
the system is installed:

January 2002 2-1 81-CO2MAN-002

CO2 Fire Suppression Systems

2-3.1 CO2 System Operation Procedures 1. Immediately evacuate all personnel from the hazard
area. Close all doors.
The following operation procedures are based on the CO2
system being used in normally occupied areas or where 2. Proceed to cable pull station or manual electric station,
occupancy is possible. In these instances a pressure oper- (whichever applies) for the appropriate hazard.
ated time delay and a pressure operated siren are required, 3. Operate the station as directed on the device to actu-
to ensure that personnel are alerted and afforded the time ate the CO2 cylinders.
to evacuate the hazard area prior to system discharge, re- 4. For multiple hazard systems, operate the cable pull sta-
gardless of the actuation mode. In addition, a lock-out valve tion for the appropriate stop valve.
should be installed if the hazard is occupied by people not
5. Call the fire department immediately.
familiar with the system operation. During a lock-out pe-
riod, a trained employee should be assigned as a “fire watch” 6. If the system is provided with a reserve cylinder(s), see
with a suitable portable device, to maintain protection of Paragraph 6.4 of the Design, Installation, Operation and
the hazard until the CO2 system is restored. Maintenance Manual.
7. Contact a Kidde distributor for service.
Note: In occupied protected spaces, particularly those oc-
cupied by personnel unfamiliar with the presence 2-3.1.3 REMOTE NITROGEN ACTUATOR
of, or operational procedure of the Kidde CO2 sys- OPERATION (PNEUMATIC)
tem, Kidde recommends a lock-out valve be pro- 1. Immediately evacuate all personnel from the hazard
vided per Section 1-5.1.7 of NFPA 12, “Standard area. Close all doors.
on Carbon Dioxide Extinguishing Systems.”
2. Proceed to the remote nitrogen actuator station for the
These procedures are for reference to the system owner. appropriate hazard.
For additional information, refer to the Kidde Carbon Diox- 3. Operate the control head mounted on the nitrogen ac-
ide (CO2) Fire Suppression Systems Design, Installation, tuation cylinder.
Operation and Maintenance Manual, (P/N 81-CO2MAN-
4. Move the ball valve, installed in the actuation piping
001). Appendix B includes component descriptions of typi-
downstream of the nitrogen cylinder to the OPEN posi-
cal equipment that the personnel in charge of the equipment
tion.
should be aware of in the event of system actuation.
5. Call the fire department immediately.
Note: Be sure the Kidde distributor installing the system
6. If the system is provided with a reserve cylinder(s), see
provides a written description of the CO2 system
Paragraph 6.4 of the Design, Installation, Operation and
procedure of operation at the time the system is
Maintenance Manual.
commissioned.
7. Contact a Kidde distributor for service.
! WARNING 2-3.1.4 LOCAL MANUAL OPERATION–ALL
If the pressure operated time delay fails to SYSTEMS
operate, actuate the manual control head lever
installed on the time delay to immediately ! CAUTION
discharge the system once personnel have This manual control is not part of the normal
evacuated the area. system actuation mode and should only be
used in a last resort, emergency condition.
2-3.1.1 AUTOMATIC OPERATION
1. Immediately evacuate the hazard area. Close all doors.
When a system is operated automatically by the electric or
pneumatic detection system, proceed as follows: 2. Proceed to the cylinder(s) for the hazard.
3. Remove the locking pin from the cylinder control
1. All personnel must evacuate the hazard area promptly.
head(s).
Close all doors.
4. Rotate the local manual release lever to the RELEASED
2. Call the fire department immediately.
or OPEN position.
3. If the system is provided with a reserve cylinder(s), see
5. Proceed to hazard area stop (directional) valve if one
Paragraph 6.4 of the Design, Installation, Operation and
is installed. Remove the locking pin from the stop (di-
Maintenance Manual.
rectional) valve control head. Rotate the local manual
4. Contact a Kidde distributor for service. release lever to the RELEASED or OPEN position.
2-3.1.2 CABLE ACTUATOR AND ELECTRIC 6. Proceed to the system lock-out valve and be sure it is
SYSTEM OPERATION in the OPEN position.
Operate the system using the controls as follows: 7. Call the fire department immediately.
8. Contact a Kidde distributor for service.

81-CO2MAN-002 2-2 January 2002

 CO2 Fire Suppression Systems

2-3.1.5 HOSE REEL OR RACK SYSTEM MANUAL 2. The protected space has been thoroughly ventilated,
OPERATION ensuring that all products of combustion and carbon
1. Proceed to the carbon dioxide cylinder(s). dioxide are discharged into the atmosphere external of
the building. Forced ventilation may need to be required.
2. Remove the locking pin from the cylinder control head,
and rotate the local manual release lever to the RE- 3. In order to remove all traces of combustion products,
LEASED or OPEN position. arrange for all affected equipment to be cleaned at the
first available opportunity.
3. Unwind hose from reel or rack. Approach fire carefully.
Do not allow hose to lie in the path of the flames. 4. Contact the Kidde distributor to reset and recharge the
system. The system must be recharged immediately
4. Point horn at hazard. Open horn valve by pushing stir- and with the proper type and quantity of agent to en-
rup handle forward. sure continued protection.
5. Direct carbon dioxide discharge at base of the flames.
As flames recede, follow slowly. Follow detailed instruc-
tions below. 2-5 INSPECTION AND MAINTENANCE OF
THE SYSTEM
2-3.1.5.1 Surface Fires
1. Direct carbon dioxide discharge close to the edge of ! WARNING
the fire nearest you. DO NOT point the horn at the cen-
ter of the flame. If the hose horn must be aimed into an The owner of the Kidde Carbon Dioxide (CO2)
inaccessible fire, the horn must be in the OPEN posi- Fire Suppression System must comply with
tion. these instructions. Failure to do so may result
in inadequate system performance, property
2. Sweep the horn slowly back and forth across the base damage and personal injury.
of the flames. Chase flames slowly as the fire is extin-
guished. For bulkhead fires arising in Marine (ship- ! CAUTION
board) applications, direct the discharge at the bottom
and gradually work upward as the fire recedes. CO2 and nitrogen cylinder assemblies must be
stored, handled, transported, serviced,
3. Continue discharging carbon dioxide until all smolder-
maintained, tested and installed only by trained
ing material is covered with carbon dioxide “snow”.
personnel and in accordance with the
2-3.1.5.2 Electrical Fires–Switchboards, Motors, etc. instructions contained in the Kidde Carbon
1. Discharge carbon dioxide into all openings on burning Dioxide (CO 2 ) Fire Suppression Systems
substances. Design, Installation, Operation and
2. Continue to discharge carbon dioxide until flames have Maintenance Manual, (P/N 81-CO2MAN-001),
been extinguished and the burned material is coated NFPA-12, and CGA pamphlets C-1, C-6, G-6, G-
with carbon dioxide “snow”. This will prevent any in- 6.3 and P-1. CGA pamphlets may be obtained
candescent material from re-igniting. from the Compressed Gas Association, 1725
Jefferson Davis Highway, Arlington, VA 22202-
! CAUTION 4102. Before performing maintenance
procedures, refer to the material safety data
While it is not necessary to de-energize
sheets and safety bulletins in this manual and
equipment before discharging carbon dioxide
in the Appendix of the Kidde Carbon Dioxide
onto electrical fires, equipment must be de-
(CO 2 ) Fire Suppression Systems Design,
energized as soon as possible after system
Installation, Operation and Maintenance
discharge to prevent the fire from spreading.
Manual, (P/N 81-CO2MAN-001).
6. After the fire has been extinguished, leave the horn
valve open to relieve all pressure from the hose. ! WARNING
7. Perform post-fire maintenance. All actuation devices (control heads, discharge
8. Contact a Kidde distributor for service. heads, etc.) must be removed from the system
cylinders prior to performing system
maintenance. Observe all safety precautions
2-4 POST-OPERATION INSTRUCTIONS
applicable to handling pressurized equipment.
After the system has discharged and the fire has been ex- Recharge of CO 2 and nitrogen cylinder
tinguished, do not attempt to resume operations in the pro- assemblies must be performed by personnel
tected area containing the fire until the following steps have trained in Kidde CO 2 systems equipment.
been completed: Failure to do so may result in property damage
1. The fire department has given authorization to re-oc- or personal injury.
cupy the area.

January 2002 2-3 81-CO2MAN-002

CO2 Fire Suppression Systems

Fire suppression systems require proper care to ensure 1. Check that all personnel who may have to operate the
normal operation at all times. Periodic inspections must be system are properly trained and authorized to do so. In
made to determine the exact condition of the system equip- particular, check that all new employees have been in-
ment. structed in the use of the system.
A regular program of systematic maintenance is essential 2. Make a general inspection survey of all cylinders and
for proper operation of the carbon dioxide system. A peri- equipment for damaged or missing parts. If any equip-
odic maintenance schedule must be followed and an in- ment requires replacement, contact a Kidde distribu-
spection log maintained for ready reference. As a minimum, tor.
the log should record inspection interval, inspection proce- 3. Ensure that access to hazard areas, remote nitrogen
dure performed, maintenance performed, if any, as a re- or cable pull stations, discharge nozzles, and cylinders
sult of inspection, and name of inspector performing task. are unobstructed and there are no obstructions that
If inspection indicates areas of rust or corrosion, immedi- would hinder the operation of the equipment or distri-
ately clean and repaint the area. bution of carbon dioxide.
Perform inspections and preventative maintenance in ac- 4. Inspect flexible actuation hoses for loose fittings, dam-
cordance to the schedule in Table 2.1. The inspection pro- aged threads, cracks, distortion, cuts, dirt and frayed
cedures and intervals are recommended and may be wire braid. Inspect flexible actuation hose adapters for
modified to fit into normal facility schedules providing the stripped threads and damage. Inspect couplings and
intervals do not exceed the time periods indicated. A draw- tees for tightness. If any of these defects are present,
ing of the major CO2 Fire Suppression System components contact a Kidde distributor to replace, tighten, or clean
is included with appropriate part numbers in Appendix B of system parts.
this manual. The component drawings are for owner refer- 5. Inspect control heads attached to CO2 cylinders, nitro-
ence only. gen cylinders, stop valves and time delays for physical
damage, deterioration, corrosion, distortion, cracks, dirt,
Table 2-1. Inspection and Maintenance Schedule
and loose couplings. If a defect is found, contact a Kidde
distributor; a replacement may be necessary. Ensure
S ch ed u le R eq u iremen t that all control heads, actuation devices, etc., are all in
Inspect hazard area system components the SET or CLOSED position with the locking pin in-
Monthly stalled and seal wire intact.
Check ni trogen cylinder pressure 6. Inspect carbon dioxide cylinder and valve assembly for
Check CO2 cylinder weight leakage, physical damage such as cracks, dents, dis-
tortion, and worn parts.
Semi-Annually Test electric control head 7. Inspect cylinder straps, cradles, and attaching hard-
Test pressure switch ware for loose, damaged, or broken parts. Check straps
and associated parts for corrosion, oil, grease, grime,
Check nitrogen cylinder pressure etc.
Check CO2 cylinder weight 8. Inspect CO2 system discharge heads for cracks, cor-
rosion, grime, etc.
Annually Blow out distribution pipi ng
9. Inspect flexible discharge hoses for loose fittings, dam-
Perform complete system function aged threads, cracks, rust, kinks, distortion, dirt, and
frayed wire braid.
Test pneumatic detection system
10. Inspect discharge manifold for physical damage, cor-
Hydrostatic test all CO2 and nitrogen rosion, and dirt. Inspect manifold support brackets and
Every 5 years
system hoses and flexible connectors. clamps for looseness and damage. Inspect check and
stop valves, where applicable, for deformation, leak-
Every 5 or CO2 cylinder hydrostatic test age, cracks, wear, corrosion, and dirt.
12 years
N2 cylinder hydrostatic test
! CAUTION
2-5.1 Monthly Inspection Do not paint nozzle orifices. The part number
The following monthly inspection program should be con- of each nozzle is stamped on the nozzle.
ducted visually only. If any defects are apparent as described Nozzles must be replaced by nozzles of the
below, SUSPEND ALL OPERATIONS IN THE PRO- same part number. Nozzles must never be
TECTED AREA, and immediately contact a Kidde Distribu- interchanged, since random interchanging of
tor. In addition, Kidde recommends that all inspections, nozzles will adversely affect proper CO 2
including the monthly inspection, be conducted by an au- distribution within a hazard area.
thorized Kidde distributor.

81-CO2MAN-002 2-4 January 2002

 CO2 Fire Suppression Systems

11. Inspect discharge nozzles for dirt, clogs and physical The flexible hoses must undergo hydrostatic testing every
damage. Where flangible discs are used, ensure they 5 years in accordance with NFPA12. Testing must be con-
are intact and clean. Look for holes or cuts. Broken ducted by a certified Kidde distributor ONLY. A detailed
discs will allow vapors, oils, etc., to enter into the nozzles description of the 5 and 12 year inspection can be found in
and system piping from the hazard, and seriously af- the Design, Installation, Operation and Maintenance
fect or block system discharge. Manual, Paragraph 7.9.
12. Inspect pressure switches for deformations, cracks, dirt
or other damage.
2-6 ADDITIONAL REQUIREMENTS
13. Check nitrogen cylinder pressure gauge for proper op-
erating pressure. If pressure loss (adjusted for tem- In addition to the CO2 system and for areas not protected
perature) exceeds 10%, recharge with nitrogen to 1800 by the system, portable fire extinguishers are required. Con-
psig at 70°F. See Figure 7.18.2 of the Kidde Carbon sult with the insurance carrier, local Authorities Having Ju-
Dioxide (CO2) Fire Suppression Systems Design, In- risdiction and a portable fire extinguisher distributor for sizes,
stallation, Operation and Maintenance Manual, (P/N 81- types, spacing and location requirements.
CO2MAN-001), for the pressure-temperature Read, understand and follow the instructions in this manual
relationship. and on the container nameplates. Review these instruc-
14. Inspect the lock-out valve. The valve must be secured tions with employees semi-annually, or more frequently.
and locked in the OPEN position. Place this manual in an accessible area near the CO2 sys-
15. Visually inspect control panel and detection system. tem for ready reference. Post the name, phone number
Ensure that the system is in “Normal” status and free and address of the Kidde distributor near all telephones.
from any “Alarm” or “Trouble” signals. Also, post the emergency telephone number of the fire de-
partment and the building street address near all telephones.
16. If any defects are found during the monthly inspection,
immediately contact a Kidde Distributor to service the If any condition exists which would render the CO2 sys-
systems. tems inoperative or ineffective, SUSPEND ALL OPERA-
TIONS IN THE PROTECTED AREA IMMEDIATELY. Have
2-5.2 Semi-Annual Inspection
the condition corrected by a Kidde distributor before re-
The system must be thoroughly inspected on a semi-an- suming operations.
nual basis by a certified Kidde distributor ONLY. The semi-
annual inspection includes a weighing of the agent cylinders,
an electric control head test, and a pressure switch test. A 2-7 ADDITIONAL SPECIFICATIONS AND
detailed description of the semi-annual inspection can be DOCUMENTATION
found in the Design, Installation, Operation and Maintenance The system must be designed, installed, operated and
Manual, Paragraphs 7.4, 7.5 and 7.6. maintained only in accordance with the following documents
2-5.3 Annual Inspection and specifications:

The system must be thoroughly inspected on an annual • Kidde Carbon Dioxide (CO2) Design, Installation, Op-
basis by a certified Kidde distributor ONLY. The annual in- eration and Maintenance Manual (P/N 81-CO2MAN-
spection includes a check of the CO2 cylinder weight, a 001), available from Kidde Distributors or from Kidde
check of the nitrogen cylinder pressure, a blowout proce- at:
dure for the distribution piping, a complete system perfor- Kidde-Fenwal, Inc.
mance function test, and a pneumatic detection system test. 400 Main Street
A detailed description of the annual inspection can be found Ashland, MA 01721
in the Design, Installation, Operation and Maintenance Phone: 508-881-2000
Manual, Paragraphs 7.7 and 7.8. Fax: 508-881-8920
2-5.4 5 Year and 12 Year Inspection and Test • National Fire Protection Association Standard No. 12,
Guidelines current edition, available from:
The carbon dioxide and nitrogen cylinders must undergo National Fire Protection Association
hydrostatic testing and be marked in accordance with DOT 1 Batterymarch Park
CFR 49 Section 173.34 every 5 years after a cylinder is Quincy, MA 02269
discharged or, if no discharge has occurred, every 12 years. • Copies of the Material Safety Data Sheet (MSDS) for
The cylinders must undergo hydrostatic testing immedi- Carbon Dioxide are available in the back of this manual
ately if they show evidence of distortion, damage, cracks, (Appendix A).
corrosion, or mechanical damage. Testing must be con-
ducted by a certified Kidde distributor ONLY.

January 2002 2-5 81-CO2MAN-002

CO2 Fire Suppression Systems

THIS PAGE INTENTIONALLY LEFT BLANK.

81-CO2MAN-002 2-6 January 2002

 CO2 Fire Suppression Systems

APPENDIX A
MATERIAL SAFETY DATASHEETS

January 2002 A-1 81-CO2MAN-002

Product: Liquid Carbon Dioxide P-4573-A Date: May 1999

Praxair Material Safety Data Sheet

1. Chemical Product and Company Identification

Product Name: Carbon dioxide, refrigerated liquid Trade Name: LIQUIFLOW

(MSDS No. P-4573-A)
Chemical Name: Carbon dioxide Synonyms: Carbon dioxide (cryogenic
liquid), LCO2, liquefied CO2
Formula: CO2 Chemical Family: Acid anhydrides
Telephone: Emergencies: 1-800-645-4633* Company Name: Praxair, Inc.
CHEMTREC: 1-800-424-9300* 39 Old Ridgebury Road
Routine: 1-800-PRAXAIR Danbury, CT 06810-5113
* Call emergency numbers 24 hours a day only for spills, leaks, fire, exposure, or accidents involving this
product. For routine information, contact your supplier, Praxair sales representative, or call
1-800-PRAXAIR (1-800-772-9247).

2. Composition/Information on Ingredients
This section covers materials of manufacture only. See sections 3, 8, 10, 11, 15, and 16 for
information on by-products generated during use, especially use in welding and cutting.
For custom mixtures of this product, request an MSDS for each component. See section 16 for
important information about mixtures.
INGREDIENT CAS NUMBER CONCENTRATION OSHA PEL ACGIH TLV-TWA
Carbon Dioxide 124-38-9 >99% 5,000 ppm* 5,000 ppm**
* The symbol > means “greater than”; the symbol <, “less than.”
** See section 3.

3. Hazards Identification

EMERGENCY OVERVIEW
WARNING! Cold liquid and gas under pressure.
Can cause rapid suffocation.
Can cause frostbite.
Can increase respiration and heart rate.
May cause nervous system damage.
May cause dizziness and drowsiness.
Self-contained breathing apparatus may be required by rescue workers.
Odor: None to slightly pungent
THRESHOLD LIMIT VALUE: TLV-TWA, 5,000 ppm (ACGIH, 1998). TLV-TWA, 15 min STEL,
30,000 ppm. ACGIH recommends a TLV-TWA of 5 mg/m3 for welding fumes not otherwise classified
(NOC) that may be generated during welding with this product.TLV-TWAs should be used as a guide in
the control of health hazards and not as fine lines between safe and dangerous concentrations.

Copyright © 1997, 1999, Praxair Technology, Inc. Page 1 of 10

All rights reserved.
Revised
Product: Liquid Carbon Dioxide P-4573-A Date: May 1999

EFFECTS OF A SINGLE (ACUTE) OVEREXPOSURE:

INHALATION–Carbon dioxide gas is an asphyxiant with effects due to lack of oxygen. It is also
physiologically active, affecting circulation and breathing. Moderate concentrations may cause
headache, drowsiness, dizziness, stinging of the nose and throat, excitation, rapid breathing and heart
rate, excess salivation, vomiting, and unconsciousness. Lack of oxygen can kill.
SKIN CONTACT–No harm expected from vapor. Prolonged contact with carbon dioxide crystals
(snow) could cause frostbite. Cold gas, or liquid or solid carbon dioxide may cause severe frostbite.
SWALLOWING–An unlikely route of exposure. This product is a gas at normal temperature and
pressure. But severe frostbite of the lips and mouth may result from contact with the liquid or solid.
EYE CONTACT–No harm expected from vapor. Cold gas, or liquid or solid carbon dioxide may
cause severe frostbite.
EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: No harm expected to healthy
individuals. Where competent medical authority deems that such illness would be aggravated by exposure
to carbon dioxide, persons in ill health should be restricted from working with or handling this product.
OTHER EFFECTS OF OVEREXPOSURE: Damage to retinal or ganglion cells and central nervous
system may occur.
MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: The toxicology and the
physical and chemical properties of carbon dioxide suggest that overexposure is unlikely to aggravate
existing medical conditions.
SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH
HAZARD EVALUATION: A single study has shown an increase in heart defects in rats exposed to 6%
carbon dioxide in air for 24 hours at different times during gestation. There is no evidence that carbon
dioxide is teratogenic in humans.
CARCINOGENICITY: Carbon dioxide is not listed by NTP, OSHA, or IARC.

4. First Aid Measures

INHALATION: Immediately remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, qualified personnel may give oxygen. Call a physician.
SKIN CONTACT: For exposure to cold liquid, vapor, or solid, immediately warm frostbite area with
warm water not to exceed 105°F (41°C). In case of massive exposure, remove contaminated clothing
while showering with warm water. Call a physician.
SWALLOWING: An unlikely route of exposure. This product is a gas at normal temperature and
pressure.
EYE CONTACT: For exposure to cold liquid, vapor, or solid, immediately flush eyes thoroughly with
warm water for at least 15 minutes. Hold the eyelids open and away from the eyeballs to ensure that all
surfaces are flushed thoroughly. See a physician, preferably an ophthalmologist, immediately.
NOTES TO PHYSICIAN: There is no specific antidote. Treatment of overexposure should be directed
at the control of symptoms and the clinical condition of the patient.

Page 2 of 10
Product: Liquid Carbon Dioxide P-4573-A Date: May 1999

5. Fire Fighting Measures

FLASH POINT Not applicable AUTOIGNITION Not applicable
(test method) TEMPERATURE
FLAMMABLE LIMITS LOWER Not applicable UPPER Not applicable
IN AIR, % by volume
EXTINGUISHING MEDIA: Carbon dioxide cannot catch fire. Use media appropriate for surrounding
fire.
SPECIAL FIRE FIGHTING PROCEDURES: WARNING! Cold liquid and gas under pressure.
Evacuate all personnel from danger area. Immediately spray containers with water from maximum
distance until cool, taking care not to direct spray onto vents on top of container.Do not discharge sprays
into liquid carbon dioxide, which will freeze water rapidly. When containers have cooled, move them
away from fire area if without risk. Self-contained breathing apparatus may be required by rescue
workers. On-site fire brigades must comply with OSHA 29 CFR 1910.156.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Heat of fire can build pressure in cylinder and
cause it to rupture. No part of container should be subjected to a temperature higher than 125°F (52°C).
Liquid carbon dioxide containers are equipped with pressure relief devices.
HAZARDOUS COMBUSTION PRODUCTS: None known.

6. Accidental Release Measures

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: WARNING! Cold liquid
and gas under pressure. Carbon dioxide is an asphyxiant. Lack of oxygen can kill. Evacuate all
personnel from danger area. Use self-contained breathing apparatus where needed.Liquid carbon dioxide
will not "spill." Flakes of solid carbon dioxide will form at pressures below 67 psig (461.95 kPa) and fall
as snow. Shut off leak if you can do so without risk. Ventilate area or move container to a well-ventilated
area. Test for sufficient oxygen, especially in confined spaces, before allowing reentry.
WASTE DISPOSAL METHOD: Prevent waste from contaminating the surrounding environment.
Keep personnel away. Discard any product, residue, disposable container, or liner in an environmentally
acceptable manner, in full compliance with federal, state, and local regulations. If necessary, call your
local supplier for assistance.

7. Handling and Storage

PRECAUTIONS TO BE TAKEN IN STORAGE: Store and use with adequate ventilation. Do not
store in a confined space. Storage areas should be clean and dry, free of oils and dust, which collect on
condensing coils and impair their efficiency. Temperatures should not exceed 125 °F (51.1°C). Cryogenic
containers are equipped with a pressure relief device and a pressure-controlling valve. Under normal
conditions these containers will periodically vent product to control internal pressure. Use adequate
pressure relief devices in systems and piping to prevent pressure buildup; entrapped liquid can generate
extremely high pressures.
PRECAUTIONS TO BE TAKEN IN HANDLING: Never allow any unprotected part of your body to
touch uninsulated pipes or vessels containing cryogenic fluids. Flesh will stick to the extremely cold
metal and will tear when you try to pull free.
Use a suitable hand truck to move containers. Cryogenic containers must be handled and stored in an
upright position. Do not drop or tip containers, or roll them on their sides. If valve is hard to open,
discontinue use and contact your supplier. For other precautions in using carbon dioxide, see section 16.

Page 3 of 10
Product: Liquid Carbon Dioxide P-4573-A Date: May 1999

8. Exposure Controls/Personal Protection

VENTILATION/ENGINEERING CONTROLS:
LOCAL EXHAUST–Use a local exhaust system, if necessary, to control the concentration of carbon
dioxide in the worker's breathing zone.
MECHANICAL (general)–Under certain conditions, general exhaust ventilation may be acceptable
to keep carbon dioxide below the exposure limit.
SPECIAL–None
OTHER–None
RESPIRATORY PROTECTION: None required under normal use. An air-supplied respirator must be
used in confined spaces. Respiratory protection must conform to OSHA rules as specified in 29 CFR
1910.134.
SKIN PROTECTION: Wear insulated neoprene gloves for cylinder handling.
EYE PROTECTION: Select in accordance with OSHA 29 CFR 1910.133.
OTHER PROTECTIVE EQUIPMENT: Metatarsal shoes for cylinder handling. Protective clothing
where needed. Cuffless trousers should be worn outside shoes. Select in accordance with OSHA 29 CFR
1910.132 and 1910.133. When using carbon dioxide or carbon dioxide mixtures in welding and cutting,
see Praxair MSDS P-4574, gaseous carbon dioxide, for requirements.Regardless of protective equipment,
never touch live electrical parts.

9. Physical and Chemical Properties

MOLECULAR WEIGHT: 44.01

SPECIFIC GRAVITY (Air = 1) at 70°F (21.1°C) and 1 atm: 1.522
GAS DENSITY at 70°F (21.1°C) and 1 atm: 0.1444 lb/ft 3 (1.833 kg/m3)
LIQUID DENSITY (saturated) at 70°F (21.1°C) and 1 atm: 47.6 lb/ft 3 (762 kg/m3)
VAPOR PRESSURE at 70°F (21.1°C): 838 psig (5778 kPa)
SOLUBILITY IN WATER, vol/vol at 68°F (20°C) and 1 atm: 0.90
PERCENT VOLATILES BY VOLUME: 100
EVAPORATION RATE (Butyl Acetate = 1): High
pH: 3.7 (for carbonic acid)
SUBLIMATION POINT at 1 atm: -109.3°F (-78.5°C)
APPEARANCE, ODOR, AND STATE: Colorless, odorless, liquid. Converts to white crystalline
particles when discharged from container. The gas is slightly acid and is felt by some to have a
slight, pungent odor and biting taste.

Page 4 of 10
Product: Liquid Carbon Dioxide P-4573-A Date: May 1999

10. Stability and Reactivity

STABILITY: Unstable Stable
INCOMPATIBILITY (materials to avoid): Alkali metals, alkaline earth metals, metal acetylides,
chromium, titanium above 1022°F (550°C), uranium above 1382°F (750°C), magnesium above 1427°F
(775°C)
HAZARDOUS DECOMPOSITION PRODUCTS: Electrical discharges and high temperatures
decompose carbon dioxide into carbon monoxide and oxygen.
HAZARDOUS POLYMERIZATION: May Occur Will Not Occur
CONDITIONS TO AVOID: None known.

11. Toxicological Information

The welding process may generate hazardous fumes and gases. If using carbon dioxide for welding and
cutting, see Praxair MSDS P-4574, gaseous carbon dioxide.
Carbon dioxide is an asphyxiant. It initially stimulates respiration and then causes respiratory depression.
High concentrations result in narcosis. Symptoms in humans are as follows:

EFFECT: CONCENTRATION:

Breathing rate increases slightly. 1%

Breathing rate increases to 50% above normal level. Prolonged 2%

exposure can cause headache, tiredness.

Breathing increases to twice normal rate and becomes labored. Weak 3%

narcotic effect. Impaired hearing, headache, increased blood pressure
and pulse rate.

Breathing increases to approximately four times normal rate, symptoms 4 - 5%

of intoxication become evident, and slight choking may be felt.

Characteristic sharp odor noticeable. Very labored breathing, 5 - 10%

headache, visual impairment, and ringing in the ears. Judgment may be
impaired, followed within minutes by loss of consciousness.

Unconsciousness occurs more rapidly above 10% level. Prolonged 50 - 100%

exposure to high concentrations may eventually result in death from
asphyxiation.

12. Ecological Information

No adverse ecological effects expected. Carbon dioxide does not contain any Class I or Class II ozone-
depleting chemicals. Carbon dioxide is not listed as a marine pollutant by DOT.

13. Disposal Considerations

WASTE DISPOSAL METHOD: Do not attempt to dispose of residual or unused quantities. Return
cylinder to supplier.

Page 5 of 10
Product: Liquid Carbon Dioxide P-4573-A Date: May 1999

14. Transport Information

DOT/IMO SHIPPING NAME: Carbon dioxide, refrigerated liquid

HAZARD IDENTIFICATION PRODUCT
CLASS: 2.2 NUMBER: UN 2187 RQ: Not applicable
SHIPPING LABEL(s): NONFLAMMABLE GAS
PLACARD (when required): NONFLAMMABLE GAS
SPECIAL SHIPPING INFORMATION: Cylinders should be transported in a secure position, in a
well-ventilated vehicle. Cylinders transported in an enclosed, nonventilated compartment of a vehicle can
present serious safety hazards.
Shipment of compressed gas cylinders that have been filled without the owner's consent is a violation of
federal law [49 CFR 173.301(b)].

15. Regulatory Information

The following selected regulatory requirements may apply to this product. Not all such requirements are
identified. Users of this product are solely responsible for compliance with all applicable federal, state,
and local regulations.
U.S. FEDERAL REGULATIONS:
EPA (ENVIRONMENTAL PROTECTION AGENCY)
CERCLA: COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND
LIABILITY ACT OF 1980 (40 CFR Parts 117 and 302):
Reportable Quantity (RQ): None
SARA: SUPERFUND AMENDMENT AND REAUTHORIZATION ACT:
SECTIONS 302/304: Require emergency planning based on Threshold Planning Quantity
(TPQ) and release reporting based on Reportable Quantities (RQ) of extremely hazardous
substances (40 CFR Part 355):
Threshold Planning Quantity (TPQ): None
Extremely Hazardous Substances (40 CFR 355): None
SECTIONS 311/312: Require submission of MSDSs and reporting of chemical inventories
with identification of EPA hazard categories. The hazard categories for this product are as
follows:
IMMEDIATE: Yes PRESSURE: Yes
DELAYED: No REACTIVITY: No
FIRE: No
SECTION 313: Requires submission of annual reports of release of toxic chemicals that
appear in 40 CFR Part 372.
Carbon dioxide does not require reporting under Section 313.
40 CFR 68: RISK MANAGEMENT PROGRAM FOR CHEMICAL ACCIDENTAL
RELEASE PREVENTION: Requires development and implementation of risk management
programs at facilities that manufacture, use, store, or otherwise handle regulated substances in
quantities that exceed specified thresholds.
Carbon dioxide is not listed as a regulated substance.

Page 6 of 10
Product: Liquid Carbon Dioxide P-4573-A Date: May 1999

TSCA: TOXIC SUBSTANCES CONTROL ACT: Carbon dioxide is listed on the TSCA
inventory.
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION:
29 CFR 1910.119: PROCESS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS
CHEMICALS: Requires facilities to develop a process safety management program based on
Threshold Quantities (TQ) of highly hazardous chemicals.
Carbon dioxide is not listed in Appendix A as a highly hazardous chemical.
STATE REGULATIONS:
CALIFORNIA: Carbon dioxide is not listed by California under the SAFE DRINKING WATER
AND TOXIC ENFORCEMENT ACT OF 1986 (Proposition 65).
WARNING: The combustion of this gas produces carbon monoxide— a chemical known to the
State of California to cause birth defects or other reproductive harm.
(California Health and Safety Code §25249.5 et seq.)
PENNSYLVANIA: Carbon dioxide is subject to the PENNSYLVANIA WORKER AND
COMMUNITY RIGHT-TO-KNOW ACT (35 P.S. Sections 7301-7320).

16. Other Information

Be sure to read and understand all labels and instructions supplied with all containers of this product.
ADDITIONAL SAFETY AND HEALTH HAZARDS: The welding process may generate hazardous
fumes and gases. If using carbon dioxide for welding and cutting, see Praxair MSDS P-4574, gaseous
carbon dioxide.
OTHER HAZARDOUS CONDITIONS OF HANDLING, STORAGE, AND USE: Cold liquid and
gas under pressure. Contact may cause frostbite. Use piping and equipment adequately designed to
withstand pressures to be encountered. Avoid materials incompatible with cryogenic use; some metals
such as carbon steel may fracture easily at low temperature. Gas can cause rapid suffocation due to
oxygen deficiency. Store and use with adequate ventilation. Carbon dioxide is heavier than air. It tends to
accumulate near the floor of an enclosed space, displacing air and pushing it upward. This creates an
oxygen-deficient atmosphere near the floor. Ventilate space before entry. Verify sufficient oxygen
concentration. Close cylinder valve after each use; keep closed even when empty.Prevent reverse flow.
Reverse flow into container may cause rupture. Use a check valve or other protective device in any line or
piping from the cylinder.Never work on a pressurized system. If there is a leak, close the container valve.
Blow the system down in a safe and environmentally sound manner in compliance with all federal, state,
and local laws; then repair the leak. Never place a compressed gas cylinder where it may become part of
an electrical circuit.
MIXTURES: When you mix two or more gases or liquefied gases, you can create additional,
unexpected hazards. Obtain and evaluate the safety information for each component before you produce
the mixture. Consult an industrial hygienist or other trained person when you evaluate the end product.
Remember, gases and liquids have properties that can cause serious injury or death.

Page 7 of 10
Product: Liquid Carbon Dioxide P-4573-A Date: May 1999

HAZARD RATING SYSTEMS:

NFPA RATINGS: HMIS RATINGS:

HEALTH =3 HEALTH =3
FLAMMABILITY =0 FLAMMABILITY = 0
REACTIVITY =0 REACTIVITY =0
SPECIAL = SA (CGA recommends this to designate Simple Asphyxiant.)

STANDARD VALVE CONNECTIONS FOR U.S. AND CANADA:

THREADED: CGA-320
CGA-622 for withdrawal of refrigerated liquid
PIN-INDEXED YOKE: Not applicable
ULTRA-HIGH-INTEGRITY CONNECTION: Not applicable
Use the proper CGA connections. DO NOT USE ADAPTERS. Additional limited-standard
connections may apply. See CGA pamphlet V-1 listed below.
Ask your supplier about free Praxair safety literature as referred to in this MSDS and on the label for this
product. Further information about this product can be found in the following pamphlets published by the
Compressed Gas Association, Inc. (CGA), 1725 Jefferson Davis Highway, Arlington, VA 22202-4102,
Telephone (703) 412-0900.
AV-1 Safe Handling and Storage of Compressed Gases
G-6 Carbon Dioxide
G-6.1 Standard for Low Pressure Carbon Dioxide Systems at Customer Sites
G-6.2 Commodity Specification for Carbon Dioxide
P-1 Safe Handling of Compressed Gases in Containers
P-14 Accident Prevention in Oxygen-Rich, Oxygen-Deficient Atmospheres
SB-2 Oxygen-Deficient Atmospheres
V-1 Compressed Gas Cylinder Valve Inlet and Outlet Connections
— Handbook of Compressed Gases, Third Edition

Page 8 of 10
Product: Liquid Carbon Dioxide P-4573-A Date: May 1999

Praxair asks users of this product to study this MSDS and become aware of product hazards and safety
information. To promote safe use of this product, a user should (1) notify employees, agents, and
contractors of the information in this MSDS and of any other known product hazards and safety
information, (2) furnish this information to each purchaser of the product, and (3) ask each purchaser to
notify its employees and customers of the product hazards and safety information.

Page 9 of 10
Product: Liquid Carbon Dioxide P-4573-A Date: May 1999

The opinions expressed herein are those of qualified experts within Praxair, Inc. We
believe that the information contained herein is current as of the date of this Material
Safety Data Sheet. Since the use of this information and the conditions of use of the
product are not within the control of Praxair, Inc., it is the user’s obligation to
determine the conditions of safe use of the product.

Praxair MSDSs are furnished on sale or delivery by Praxair or the independent distributors and suppliers
who package and sell our products. To obtain current Praxair MSDSs for these products, contact your
Praxair sales representative or local distributor or supplier. If you have questions regarding Praxair
MSDSs, would like the form number and date of the latest MSDS, or would like the names of the Praxair
suppliers in your area, phone or write the Praxair Call Center ( Phone: 1-800-PRAXAIR; Address:
Praxair Call Center, Praxair, Inc., PO Box 44, Tonawanda, NY 14150-7891).
PRAXAIR, the FLOWING AIRSTREAM design, and LIQUIFLOW are trademarks or registered trademarks of
Praxair Technology, Inc. in the United States and other countries.

Praxair, Inc.
39 Old Ridgebury Road
Danbury, CT 06810-5113

Printed in USA Page 10 of 10

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81-CO2MAN-002 A-2 January 2002

 CO2 Fire Suppression Systems

APPENDIX B
COMPONENT DESCRIPTIONS

LIST OF ILLUSTRATIONS
APPENDIX B

Figure Title Page

B-1 25 lb. thru 50 lb.Carbon Dioxide Cylinders, Bent Siphon Tube .................................................. 1-2
B-2 75 lb. and 100 lb.Carbon Dioxide Cylinders ............................................................................... 1-3
B-3 Discharge Head, Plain Nut ........................................................................................................ 1-4
B-4 Flex Hose - 3/4" and 1/2" ........................................................................................................... 1-4
B-5 Nozzle Part Numbers ................................................................................................................ 1-5
B-6 Multijet Nozzle, Type "S" ............................................................................................................ 1-6
B-7 Multijet Nozzle, Type "S" Flanged .............................................................................................. 1-6
B-8 Multijet Nozzle, Type "M" ........................................................................................................... 1-7
B-9 Multijet Nozzle, Type "L" ............................................................................................................ 1-7
B-10 Lever or Pressure Operated Control Head ................................................................................ 1-8
B-11 Nitrogen Pilot Cylinder and Bracket ........................................................................................... 1-8
B-12 Ball Valve 1/4" ............................................................................................................................ 1-9
B-13 Stop (Directional) Valves, 1/2" thru 2" ........................................................................................ 1-9
B-14 Stop (Directional) Valves, 2-1/2" and 3" ..................................................................................... 1-10
B-15 4" Stop (Directional) Valve ......................................................................................................... 1-10
B-16 Valve, CO2 Lock Out w/Limit Switch ......................................................................................... 1-11
B-17 Safety Outlets ............................................................................................................................ 1-11
B-18 Pressure Operated Switch ......................................................................................................... 1-12
B-19 Pressure Operated Switch, Explosion Proof ............................................................................. 1-12
B-20 Discharge Delay with Manual Operated Control Head .............................................................. 1-13
B-21 Pull Box, Break Glass ................................................................................................................ 1-13

January 2002 B-1 81-CO2MAN-002

CO2 Fire Suppression Systems

TYPE "I" CYLINDER

CONTROL VALVE
PORT
THREAD FOR
DISCHARGE HEAD
SAFETY DISC
ASSEMBLY
NAMEPLATE

THREAD FOR
PROTECTION
CAP (35 LB, AND
50 LB CYL INDERS ONLY)

PART VALVE
CYLINDER A B
NUMBER TYPE

870486 25 lb. 30.0" 8.50"

982547 35 lb. 1/2" 40.0" 8.50"

982548 50 lb. 55.0 8.50

Figure B-1. 25 lb. thru 50 lb. Carbon Dioxide Cylinders, Bent Siphon Tube

81-CO2MAN-002 B-2 January 2002

 CO2 Fire Suppression Systems

TYPE "I" CYLINDER

VALVE
THREAD FOR
CONTROL DISCHARGE HEAD
PORT
SAFETY DISC
ASSEMBLY

THREAD FOR
PROTECTION CAP

Pressure Ratings: PART VALVE

CYLINDER A B
NUMBER TYPE
Working Pressure = 1800 psig
Maximum Pressure at T = 130°F = 2250 psig 870287 75 lb. 60.0" 9.25"
5/8"
Hydrostatic Test Pressure = 3000 psig 870269 100 lb. 62.0" 10.50"

Figure B-2. 75 lb. and 100 lb. Carbon Dioxide Cylinders

January 2002 B-3 81-CO2MAN-002

CO2 Fire Suppression Systems

3.81"
(97mm)

3.94"
(100mm)

SWIVEL NUT
(FOR CONNECTION P/N: 872450
TO CYLINDER VALVE)

P/N 872450
Figure B-3. Discharge Head, Plain Nut

HOSE

S iz e P /N L

1/2" 252184 14.5"

3/4" 251821 16.4"

Figure B-4. Flex Hose - 3/4" and 1/2"

81-CO2MAN-002 B-4 January 2002

 CO2 Fire Suppression Systems

SIZE V S S-ZINC S-FLANGED M L

1+ 930067 X X X X X

2 919309 803381 803897 802290 X X

2+ 803327 803365 803881 802974 X X

3 929242 803366 803882 802975 X X

3+ 803328 803369 803883 802976 X 842334

4 915876 803368 803884 802977 842319 842335

4+ 803329 803369 803885 802978 842320 242336

5 214721 803370 803886 802979 842321 842337

5+ 214722 803371 803887 802980 842322 242338

6 214723 803372 803888 802981 842323 842339

6+ 214724 803373 803889 802982 842324 242340

7 214725 803374 803890 802983 842325 842341

7+ 214726 803375 803891 802984 X 842342

8 214727 803376 803892 802985 842326 842343

8+ 214728 803377 803893 802986 X 842344

9 214729 803378 803894 802987 842327 842345

9+ X 803379 803895 802988 X 842346

10 X 803380 803896 802989 842328 842347

11 X X X X 842329 X

12 X X X X 842330 X
13 X X X X 842331 X

14 X X X X 842332 X
15 X X X X 842333 X

Figure B-5. Nozzle Part Numbers

January 2002 B-5 81-CO2MAN-002

CO2 Fire Suppression Systems

1.12"
(29mm)
HEX

5.00"
(127mm)

3.50"
(89mm) For P/N, refer to Table
in Figure B-5.

Figure B-6. Multijet Nozzle, Type "S"

1.12"
(29mm)
HEX

5.00"
(127mm)

4.25"
(108mm)

Available Finishes (nozzle only):

For P/N, refer to Table
1. Red Paint in Figure B-5.
2. Zinc Plated

Figure B-7. Multijet Nozzle, Type "S" Flanged

81-CO2MAN-002 B-6 January 2002

 CO2 Fire Suppression Systems

1.38"
(35mm)
HEX

9.50"
(241mm)

5.13" For P/N, refer to Table

(130mm)
in Figure B-5.

Available Finishes (nozzle only):

1. Red Paint
2. Zinc Plated
Figure B-8. Multijet Nozzle, Type "M"

152.4mm

3.625
(92.1 MM)
Available Finishes (nozzle only): For P/N, refer to Table
1. Red Paint in Figure B-5.

Figure B-9. Multijet Nozzle, Type "L"

January 2002 B-7 81-CO2MAN-002

CO2 Fire Suppression Systems

LEVER ALLOW APPROX. 2"

CLEARANCE FOR
SAFETY PIN OPERATION OF LEVER

CLOSED

SEAL WIRE

OPEN

TO OPEN

4.50"

SET
OPERATED
MATERIAL
Lever: Stainless Steel 3.00"
P/N 878751
Body and Piston: Brass

Figure B-10. Lever or Pressure Operated Control Head

CYLINDER P/N WK-877940-000

BRACKET P/N WK-877845-000

16"
(406mm)

SPECIFICATIONS
MATERIAL
Cylinder Capacity:
Cylinder: Steel, Painted Black 108 in3 (1770 cm3)
Valve: Brass 3.56" Safety Outlet Burst Range:
(90mm) 2650-3000 psi (183-207 bars) at 70°F (20°C)
Bracket: Steel, Painted Black
Nitrogen-BB-n-411b, Grade A, Type 1 1800 psi
Adapter: Brass
(124 bars at 70°F (20°C)

Figure B-11. Nitrogen Pilot Cylinder and Bracket

81-CO2MAN-002 B-8 January 2002

 CO2 Fire Suppression Systems

SEAL WIRE
SEPARATE

MATERIAL
Stainless Steel, Type 316
Operating Pressure:
3000 psig @ 170°F (77°C)
Minimum Bursting Pressure:
P/N 283888
10000psi (680 bars) 2.57

Figure B-12. Ball Valve 1/4"

A B

PART VALVE SIZE A B C

NUMBER NPT
IN MM IN MM IN MM
Operating Pressure @ 70°F (20°C):
850 psi (58 bar)
870023 1/2" 3.75 95 2.5 64 4.68 119
Test Pressure: 870022 3/4" 4.25 108 2.81 71 5.68 144
2250 psi (155 bar) 870122 1" 5.5 140 3.62 92 6.87 175
870032 1-1/4" 5.5 140 3.62 92 6.87 175
Burst Pressure: 870123 1-1/2" 7.5 191 4.75 121 8.43 214
6000 psi (413 bar) 870049 2" 7.5 191 4.75 121 8.43 214

Figure B-13. Stop (Directional) Valves, 1/2" thru 2"

January 2002 B-9 81-CO2MAN-002

CO2 Fire Suppression Systems

10.5"
(267mm)

9.81"
INLET
(249mm)

SIDE VIEW
WITHOUT
ASSEMBLED FLANGE
Operating Pressure @ 70°F (20°C):
850 psi (58 bar)
Test Pressure:
2250 psi (155 bar) P/N 890010
Burst Pressure:
6000 psi (413 bar)

Figure B-14. Stop (Directional) Valves, 2-1/2" and 3"

12.12"
(308mm)

11.06"
INLET
(281mm)

SIDE VIEW
WITHOUT
ASSEMBLED FLANGE
Operating Pressure @ 70°F (20°C):
850 psi (58 bar)
Test Pressure: P/N 890208
2250 psi (155 bar)
Burst Pressure:
6000 psi (413 bar)

Figure B-15. 4" Stop (Directional) Valve

81-CO2MAN-002 B-10 January 2002

 CO2 Fire Suppression Systems

GENERAL DIMENSIONS - FOR REFERENCE ONLY

ASSY. PART NO. SIZE: IN. A B C D E F G

81-934711-000 1/2 .660 3.939 1.938 2.250 5.500 2.800 2.500

81-934712-000 3/4 .810 4.500 2.188 2.600 5.500 2.800 2.500

81-934713-000 1 1.000 4.938 2.375 2.990 6.500 2.800 2.500

81-934714-000 1 1/2 1.440 5.875 2.750 3.870 8.500 2.800 2.750

81-934715-000 2 1.720 6.875 3.375 4.500 8.500 2.800 2.750

E
G

D
A

Figure B-16. Valve, CO2 Lock Out w/Limit Switch

RETAINING NUT
SEAL WIRE

PRESSURE RELIEF
PART OPERATES AT
AGENT
NUMBER
1.78" BODY PSI BARS
(45mm)
803242 N2/CO2 2400-2800 166-193

Figure B-17. Safety Outlets

January 2002 B-11 81-CO2MAN-002

CO2 Fire Suppression Systems

4.00"
OPERATED

SET

R
Kidde
PRESSURE OPERATED SWITCH
3P.D.T.

4.00"
UL

FM

P/N: 486536

Figure B-18. Pressure Operated Switch

4.37"

SET POSITION

3 POLE

PRESSURE
OPERATED
EXPLOSION
PROOF
SWITCH

9.00"
INLET

GAS

P/N: 981332

Figure B-19. Pressure Operated Switch, Explosion Proof

81-CO2MAN-002 B-12 January 2002

 CO2 Fire Suppression Systems

N
PE
3 O
1
4 TO

CLOSED
LOCAL CONTROL LEVER
(OPERATED POSITION)
TO OPEN

Finish: Red Paint

11
5
16

N o min al D elay
P /N
T ime

OUT
871071 30
IN

897636 60

1
15
8

9
3
16 DIA.

Figure B-20. Discharge Delay with Manual Operated Control Head

OPTIONAL
NAMEPLATE
(BY INSTALLER)

FOR FIRE
BREAK GLASS PULL HANDLE

R
Kidde

PULL
5.87" HANDLE
(149mm) PULL HARD

400 Main Street - Ashland, MA 01721-2150

Tel.(508)881-2000 FAX (508)881-8920

HAMMER
P/N 928103

5.00"
(127mm)

P/N: 871403

Figure B-21. Pull Box, Break Glass

January 2002 B-13 81-CO2MAN-002

CO2 Fire Suppression Systems

THIS PAGE INTENTIONALLY LEFT BLANK.

81-CO2MAN-002 B-14 January 2002

 TECHNICAL MANUAL USER FEEDBACK FORM

(Use this report to indicate deficiencies, user remarks and recommendations relating to the publication. Fold on dotted line, tape and mail to
KIDDE-FENWAL, Inc., 400 Main Street, Ashland, MA 01721, Attn. Documentation Manager or FAX to 508-881-8920)

DATE:

1. PART NUMBER 2. VOLUME NO. 3. TITLE (NOMENCLATURE)

4. CHANGE NO. OR REV. DATE 5. SYSTEM/EQUIPMENT 6. PRIORITY OF COMMENT

7. USER EVALUATION

MANUAL IS: q EXCELLENT q GOOD q FAIR q POOR q COMPLETE qINCOMPLETE

8. q PROBLEM q QUESTION q SUGGESTION qCOMMENT: (check one)

9. RECOMMENDED CHANGE TO PUBLICATION

PAGE PARAGRAPH LINE FIGURE TABLE RECOMMENDED CHANGES AND REASON

NO. NO. NO. NO. NO. (Use Blank Continuation Sheets as Required)

10. ORIGINATOR 11. COMPANY NAME

12. ADDRESS

13. KIDDE-FENWAL USE ONLY

a. Received b. Action Necessity c. Priority d. Comments

FOLD

Place
Stamp
Here

KIDDE-FENWAL, Inc.
400 Main Street
Ashland, MA 01721

Attn. Documentation Manager

FOLD
 LIMITED WARRANTY STATEMENT
Kidde-Fenwal, Inc. represents that this product is free from defects in material and workmanship, and it will repair or replace
any product or part thereof which proves to be defective in workmanship or material for a period of twelve (12) months from
the date of purchase but not to exceed eighteen (18) months after shipment by Kidde-Fenwal Inc. For a full description of
Kidde-Fenwal’s LIMITED WARRANTY, which, among other things, EXCLUDES warranties of MERCHANTABILITY and FIT-
NESS FOR A PARTICULAR PURPOSE and liability for CONSEQUENTIAL DAMAGES, please read the entire LIMITED WAR-
RANTY on the Kidde-Fenwal Quotation, Acceptance of Order and/or Original Invoice which will become part of your sales
agreement. Please contact Kidde-Fenwal directly for a return material authorization (RMA) number before returning material
to the factory at Ashland, Massachusetts, shipment prepaid. Kidde-Fenwal will repair or replace and ship prepaid.

Kidde is a registered trademark of Kidde-Fenwal, Inc.

These instructions do not purport to cover all the details or variations in the equipment
described, nor do they provide for every possible contingency to be met in connection
with installation, operation and maintenance. All specifications subject to change without

Fire Systems
notice. Should further information be desired or should particular problems arise which
are not covered sufficiently for the purchaser’s purposes, the matter should be referred
to Kidde-Fenwal, Inc., Ashland, Masssachusetts
Kidde-Fenwal Inc.
400 Main Street, Ashland, MA 01721 06-236177-001 Rev. AA ©2002 Kidde-Fenwal, Inc. Printed in USA
Tel: (508) 881-2000 Fax: (508) 881-8920
http://www.kiddefiresystems.com