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Aits 2017-18 Full Test 10 Paper 2 Jee Adv

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FIITJEE JEE (Advanced)-2018

FULL TEST – X

Paper 2

Time Allotted: 3 Hours Maximum Marks: 231


 Pl ea s e r ea d t h e i n s t r u c t i o n s c a r ef u ll y . Yo u a r e a l l o t t ed 5 m i n u t es
s p ec i f i c a ll y f o r t h i s p u r p o s e.
ALL INDIA TEST SERIES

 Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f
t h e t es t .

INSTRUCTIONS
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into three sections: Section-A, Section-C & Section-D.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers
on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with black pen for each character of your
Enrolment No. and write your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.
1. Section-A (01 – 03, 24 – 26, 47 – 49) contains 9 multiple choice questions which have only one
correct answer. Each question carries +3 marks for correct answer and –1 mark for wrong
answer.
Section-A (04 – 08, 27 – 31, 50 – 54) contains 15 multiple choice questions which have one or
more than one correct answer. Each question carries +4 marks for correct answer and –2
marks for wrong answer.
Partial Marks +1 for each correct option provided no incorrect options is selected.
Section-A (09 – 10, 32 – 33, 55 – 56) contains 3 paragraphs. Based upon paragraph, 2 multiple
choice questions have to be answered. Each question has only one correct answer and carries
+3 marks for correct answer. There is no negative marking.
2. Section-C (11 – 20, 34 – 43, 57 – 66) contains 30 Numerical based questions with answer as
numerical value from 0 to 9 and each question carries +3 marks for correct answer. There is no
negative marking.

3. Section-D (21 – 23, 44 – 46, 67 – 69) contains 9 Numerical answer type questions with answer
XXXXX.XX and each question carries +4 marks for correct answer and –1 mark for wrong
answer.

Name of the Candidate

Enrolment No.

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AITS-FT-X (Paper-2)-PCM-JEE(Advanced)/18 2

Useful Data

PHYSICS

Acceleration due to gravity g = 10 m/s2


Planck constant h = 6.6 1034 J-s
Charge of electron e = 1.6  1019 C
Mass of electron me = 9.1  1031 kg
Permittivity of free space 0 = 8.85  1012 C2/N-m2
Density of water water = 103 kg/m3
Atmospheric pressure Pa = 105 N/m2
Gas constant R = 8.314 J K1 mol1

CHEMISTRY

Gas Constant R = 8.314 J K1 mol1


= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Avogadro's Number Na = 6.023  1023
Planck’s constant h = 6.625  1034 Js
= 6.625  10–27 ergs
1 Faraday = 96500 coulomb
1 calorie = 4.2 joule
1 amu = 1.66  10–27 kg
1 eV = 1.6  10–19 J

Atomic No: H=1, He = 2, Li=3, Be=4, B=5, C=6, N=7, O=8,


N=9, Na=11, Mg=12, Si=14, Al=13, P=15, S=16,
Cl=17, Ar=18, K =19, Ca=20, Cr=24, Mn=25,
Fe=26, Co=27, Ni=28, Cu = 29, Zn=30, As=33,
Br=35, Ag=47, Sn=50, I=53, Xe=54, Ba=56,
Pb=82, U=92.

Atomic masses: H=1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16,
F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,
Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,
Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.

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PART – I (Physics), PART – II (Chemistry), PART – III (Mathematics):


(SECTION – D)

For questions 21 to 23, 44 to 46, 67 to 69.


Numerical answer type questions with answer XXXXX. XX
If answer is 348.4 / 251.37 / 213

Correct Method :
0 0 3 4 8 . 4 0
0 0 2 5 1 . 3 7
0 0 2 1 3 . 0 0

Wrong Method :
3 4 8 . 4
3 4 8 . 4
3 4 8 . 4
3 4 8 . 4
2 5 1 . 3 7
2 1 3 .
2 1 3 . 0
2 1 3 . 0
3 4 8 . 4 0
2 5 1 . 3 7
2 1 3 . 0 0

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Physics PART – I

SECTION – A

Straight Objective Type

This section contains 3 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D),
out of which only ONE is correct

1. The escape velocity at the poles of a planet is v e. If the effect of rotation of a planet makes the
weight of a body at the equator 10% less than the weight at pole, the peripheral velocity of a point
on the equator of the planet is (assume the planet to be a uniform solid sphere)
v ve
(A) e (B)
5 2 5
5v e 2v e
(C) (D)
2 5

2. Current I flowing along edges of one face of a cube as shown in figure-I, produces magnetic field

B  B0 kˆ at the centre of the cube. Consider another identical cube, where current I flows along
the path as shown in the figure-II. What magnetic field is produced at the centre of the second
cube?
I I

Figure – (i) Figure – (ii)

(A) Zero 
(B) B0 ˆj  kˆ  ˆi 

(C) B0 ˆj  kˆ  ˆi  (D) B0  ˆj  kˆ  ˆi 
Space for Rough work

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3. One end of a non-conducting spring of force


×××××××××××××× ×
constant k is connected to the mid-point of a
×××××××××××××× ×
conducting rod of mass m and length  , which can
×××××××××××××× ×
slide freely on a pair of parallel and smooth
×××××××××××××× ×
horizontal conducting rails. The other end of the C
×××××××××××××× × k
spring is connected to a rigid wall. There exists a
×××××××××××××× ×
uniform magnetic field B normal to the plane of
×××××××××××××× ×
paper and into it. Electrical resistance of the rails
×××××××××××××× ×
and rod are negligible. The rails are connected to a
capacitor of capacitance C. If the wire is pushed
towards left and released, the time period of its
oscillation will be  Given m  2CB2 2  .

m  3m m
(A) T  2 (B) T     
k  2k 2k 

3m  3m m
(C) T  2 (D) T     
2k  2k k 

Multiple Correct Choice Type

This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out of which only ONE OR MORE THAN ONE is/are correct

4. In the figure shown, the friction between the wedge and the m
horizontal surface is sufficient to prevent the wedge from sliding.
The mass of the wedge is M and its inclination is . A particle of
mass m is held motionless on the top of the wedge. Friction
M
coefficient between particle and wedge is . Now the particle and
the wedge are released from rest. Then 
(A) If  > tan , wedge will not topple for any value of m.
M
(B) If  > tan , wedge will topple for m 
3 sin   sin    cos  
M
(C) If  < tan , wedge will topple for m 
3 sin   sin    cos  
M
(D) If  < tan , wedge will topple for m 
6 sin   sin    cos  

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5. A charged fixed annular disc of uniform positive charge density  has


inner and outer radii R and 2R respectively. A negatively charged 
particle of mass m and charge – q is released on the axis of the disc R –q
from a distance x from the centre. Then
(A) The speed of the particle when reaches the centre of ring, m

q 2R
v
m 0

R  R2  x 2  4R2  x 2 
(B) The speed of the particle when it reaches the centre of ring,
q
v
m 0

R  4R2  x2  R2  x 2 
(C) Work done by electrostatic force till the particle reaches the centre of ring
q
=
20

R  R2  x 2  4R 2  x 2 
1 q
(D) If x << R, the frequency of oscillation of the particle is f 
2 40 mR

6. An artificial satellite of mass m revolves in a circular orbit of radius 4R around the centre of the
moon (where R is the radius of the moon). Suddenly it starts experiencing a slight resistance due
to cosmic dust. The resistance force depends on the speed of satellite as F = kv where k is a
constant. If the radius of the moon is R and acceleration due to gravity on the moon’s surface is
g, then (assume that at every moment the satellite follows a circular path)
m
(A) The satellite will hit the moon’s surface after time t  ln2
k
2m
(B) The satellite will hit the moon’s surface after time t  ln 2
k
3
(C) The work done by the resistance force on the satellite till it hits the moon surface   mgR .
8
3
(D) Work done by gravitational force till the satellite hits the moon’s surface = mgR .
4

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7. A block of mass m = 2 kg rests on a rough horizontal F


surface. The coefficient of friction between block and 30N

surface is  = 0.5. The block is acted upon by a


horizontal time varying force as shown. Then
(A) The block starts moving at time t = 1s
(B) The maximum velocity acquired by the block is
3 6 t(s)
25 m/s
(C) The maximum velocity attained by the block is
20 m/s
(D) Velocity of block at t = 6 sec is 12.5 m/s

8. Two identical dumbbells are formed by welding two m


small identical particles each of mass m at the ends of u
massless rod each of length  . The dumbbells are
moving in free space with equal speed u without
rotation towards each other as shown in the figure. 
Collision between the particles are elastic. Then
(A) Angular velocity of each dumbbell just after first m
u u u
collision is m

(B) Angular velocity of each dumbbell just after first 
2u
collision is
 m
(C) Speed of centre of mass of any one of the dumbbell u
just after collision is zero.
(D) Speed of centre of mass of any one of the dumbbell just after collision is u.

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Comprehension Type

This section contains 1 group of questions. The group has 2 multiple choice question based on a
paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which only ONE is
correct

Paragraph for Question Nos. 9 and 10

A pendulum is suspended from a fixed point. The mass of the bob of the pendulum is m and the length of
m
string is . It is initially at rest at its lowest position. A particle of mass moving horizontally along
2
negative x-direction with velocity 2g collides with the bob and comes to rest. When the bob comes to
rest, another particle Q of mass m moving horizontally along y-direction collides with the bob and sticks to
it. It is observed that the bob now moves along a horizontal circle. There is horizontal floor 2 distance
below the point of suspension of the pendulum.

9. Which of the following is possible value of speed of particle Q just before its collision with the
bob?
7 g 3g
(A) (B)
3 4
7g 4 g
(C) (D)
4 3

10. If string breaks during the circular motion, the bob will hit the floor after a time equal to
4 4
(A) (B)
g 2g
5 
(C) (D)
2g 2g

Space for Rough work

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SECTION – C

(One Integer Value Correct Type)

This section contains 10 questions. Each question, when worked out will result in one integer from 0 to
9 (both inclusive).

11. A ray of light travelling in air is incident at grazing angle air


y
(incident angle  90°) on a long rectangular slab of a B
transparent medium of thickness d. The point of
incidence is the origin A (0, 0). The medium has a
variable index of refraction   1  e x/ d . Determine the d 
slab
x coordinate (in meter) of the point B, where the ray
meets the upper surface of slab air boundary (Take d =
(25/7) m and ln2 = 0.7).
A x
air

12. A wedge of mass 3 kg is lying at rest on a frictionless


horizontal surface. A block of mass m is released from rest
on the wedge. If the path of block (with respect to the
ground) makes an angle 60° with horizontal after it is
released, the mass of block (in kg) is

30° 60°

13. A solid object of uniform cross section area and relative density 0.2 is pressed down and held at
rest inside water surface so that its upper surface is in level with the water surface. Length of the
object is   1.2m . When released the object jumps out of water moving vertically. The velocity of
the object (in m/s) when it just comes out completely from the water is (Take g = 10 m /s2).

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14. The bottom of a container is made of an equi-convex lens. object


The focal length of the lens in air is 60 cm. Now its lower
surface is silvered. The refractive index of the material of the
lens is 1.5. Water is filled in the container to a depth 30 cm.
27
When an object is placed at a distance cm above the
n
water surface on the principle axis of lens, the final image of
the object coincides with the object. Find the value of n. 30 cm
(given water = 4/3)

15. A conducting light string is wound on the rim of a metal ××××××××××××××××


ring of radius r and mass m. The free end of the string is × × × × ×B× × × × × × × × × × ×
fixed to the ceiling. A vertical infinite conducting smooth × × × × × × ×R× × × × × × × × ×
××××××××××××××××
plane is always tangent to the ring. The ring is released ××××××××××××××××
and simultaneously a uniform magnetic field of strength B ××××××××××××××××
perpendicular to the plane of the ring is switched on. The ××××××××××××××××
string and the plane are connected by a resistance R. The ××××××××××××××××
××××××××××××××××
ring is always immersed in the magnetic field. If the × × × × × × × × × × × × ×plane
×××
mgR ××××××××××××××××
terminal velocity of the ring is , find the value of n. ××××××××××××××××
nB2r 2
××××××××××××××××
××××××××××××××××
××××××××××××××××

16. A square current carrying loop of side length  and carrying a y


current I is hinged about its horizontal side PQ (Parallel to y
 Q
axis). There is a uniform magnetic field B  B0 ˆi  kˆ in the   z I

region. The linear mass density of loop is  and acceleration


due to gravity is g. The loop remains in equilibrium when it’s P
plane makes an angle  = 37 with the vertical (z-axis). If the
n g  R
value of B0 is , find the value of n. (given sin 37= 3/5)
7I

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17. When the potential difference applied to an x-ray tube is 10 kV the minimum wavelength of
continuous x-ray spectrum is 0. Further when the potential difference applied is increased from
10 kV to 20 kV the difference of wavelengths of K line and minimum wavelength of continuous x-
ray increases to twice of its initial value. Atomic number of anode material of x-ray tube is z. If the
n
value of z – 1 equals , then find the value of n.
9 0R

18. The radiation emitted when an electron jumps from n = 4 to n = 3 in a Li++ ion (atomic no.
z = 3) falls on a metal surface to produce photoelectron. When the photoelectron with maximum
kinetic energy are made to move perpendicular to a uniform magnetic field of 2  104 T, it follows
9.1
a circular path of radius cm. The work function of metal (in eV) to the nearest integer is
1.6
(given mass of electron m = 9.1  1031 kg and charge on electron = 1.6  1019 C)

19. A car begins to move at time t = 0 and then accelerates along a straight horizontal track with a
velocity given by v = 2t2 for 0  t  2, where t is time in second. After the end of acceleration, the
car continues to move at constant speed. A small block initially at rest on the floor of the car
begins to slip at t = 1 sec and stops sliding at t = 3 sec. If the coefficient of static and kinetic
3 S
friction between the block and the floor are S and K respectively, find the value of .
K

20. A uniform ring of mass m and radius R is placed freely in a E


gravity free region. Half of the ring is positively charged with
uniform linear charge density + and other half is negatively
charged with uniform charged density . A uniform electric field
E is switched on along the normal to the plane of the ring. If the
angular speed of the ring when it turns through an angle 90 is
O
 E 
n , find the value of n.
 m 
 

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SECTION – D

(Numerical Answer Type)

This section contains 3 questions. Each question, when worked out will result in numerical answer type
(XXXXX.XX)

21. In a hydrogen like atom, an electron is revolving in an orbit having quantum number n. Its
frequency of revolution is found to be 13.2  1015 Hz. Energy required to completely remove this
electron to infinity from the above orbit of atom is 54.4 eV. In a time interval of 7 nanosecond the
electron jumps back to orbit having quantum number n/2. If the average torque acting on the
electron during the above process is  Nm, then find the value of   1026.
h
(given  2.1 10 34 J  s , frequency of revolution of electron in the ground state of

H-atom = 6.6  1015 Hz)

22. A screw gauge with a pitch of 0.5 mm and a circular scale with 50 divisions is used to measure
the diameter of a uniform wire. Before starting the measurement, it is found that when the two
jaws of the screw gauge are brought in contact, the 47th division of the circular scale coincides
with the main scale line and that the zero of the main scale is barely visible. When the diameter of
wire is measured by this screw gauge the main scale reads 1.10 cm and the 12th division of the
circular scale coincides with the main scale line. Find the diameter (in mm) of the cylinder.

23. A uniform chain of length L has one of its end attached to a


3L
vertical wall at point A, while of the length of the chain is A
4
lying on table as shown in figure. Tangent to the chain at A
makes an angle 37 with the wall. Find the minimum coefficient 37
of friction between table and chain so that chain remains in
equilibrium.

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Chemistry PART – II

SECTION – A

Straight Objective Type

This section contains 3 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D),
out of which only ONE is correct

24. KMnO4 in neutral/weakly alkaline medium oxidizes thiosulphate to:


(A) SO32 (B) S2 O42 
(C) SO 24 (D) S4 O62 

25. O

COCH3 i KBrO,


ii H
iiii 
 A, A is
CH3

(A) O (B) COOH

COOH
OH
CH3
(C) O (D) COOH
CH3
CH3 OH

26. A red hot sample of atomic hydrogen in a tube was subjected to electrical discharge. The
approximate voltage at which the first indication of current flow was observed:
(A) 13.6 V (B) 10.2 V
(C) 1.51 V (D) 1.89 V

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Multiple Correct Choice Type

This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out of which only ONE OR MORE THAN ONE is/are correct

27. Which of the following pairs of compound could be separated by recrystallization?


(A) meso-tarteric acid and (  )-tartaric acid.
(B) O CH2 CH3
CH CH 2 3
O C O C H
H3C O C
and H3C C OH CH3
CH3 H OH
CH3
CH3
(C)
and

O Br Br
O
Br Br
(D) CH3 CH3
COOH COOH
C H OH C H OH
H and NH 3
CH 2 HO H CH2 HO H
NH 3 H
Ph Ph COO
COO
(an acid-base salt)

Ph =

28. Select reaction/s in which anion of main ionic product do not have -bond.
(A) Li + O2 (excess)  (B) Na (excess) + O2 
(C) Ca + F2 (excess)  (D) NaOH (cold) + Cl2 

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29. In the following conversion


MeNO2 H2 SO 4 H2 /Ni
D  glucopyrano s e 
EtONa  ?   ?  Product  s 
Which of the following is/are correct about final product(s)?
(A) optically active (B) optically inactive
(C) optically active as well as optically inactive (D) all are correct

30. Which of the following is incorrect statement for an ideal gas?


(A) When temperature increases at constant pressure, collision frequency increases.
(B) Mean free path decreases by increasing temperature at constant pressure.
(C) If all gas molecules are assumed to be rigid sphere of negligible volume, the only possible
molecular motion is translation.
(D) Kinetic energy decreases by increasing pressure at constant temperature.

31. There are process which are used to determine some important properties of colloidal solution.
By which of the following processes, the nature of electrical charge on colloidal particles can be
determined?
(A) ultramicroscopic (B) electrophoresis
(C) dialysis (D) electroosmosis

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Comprehension Type

This section contains 1 group of questions. The group has 2 multiple choice question based on a
paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which only ONE is
correct

Paragraph for Question Nos. 32 to 33

When a sample of an ideal gas is changed from an initial state to a final state. Various curves can be
plotted for the process like P – V curve, V – T curve, P – T curve etc. For example P – V curve for a fixed
amount of an ideal gas at constant temperature is a rectangular, V – T curve for a fixed amount of an
ideal gas at constant pressure is straight line and P – T curve for a fixed amount of an ideal gas is again
straight line. However, the shapes may vary if the constant parameters are also changed.

32. At constant P of 0.0821 atm, logV v/s log T graph is plotted for 3 samples of ideal gas as shown.
Value of number of moles of gas in these three samples is respectively:
[log2 = 0.3010, log3 = 0.4771]
1

logV
3

0.4771

0.3010 logT

1 1
(A) 3,1, (B) ,1,3
2 2
1 1
(C) 1, ,3 (D) ,3,1
2 2

33. Two moles of an ideal gas is changed from its initial state (16 atm, 6L) to final state (4 atm, 15 L)
in such a way that this change can be represented by a straight line in P – V curve. The
maximum temperature attained by the gas during the above change is: (take
1
R L atm K 1 mol1 )
12
(A) 324 K (B) 648 K
(C) 1296 K (D) 972 K

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SECTION – C

(One Integer Value Correct Type)

This section contains 10 questions. Each question, when worked out will result in one integer from 0 to
9 (both inclusive).

34. Compound(x) (C8H7N) on treatment with cold SnCl2/dil.HCl (aqueous), produces y(C8H8O). y on
heating with sodium acetate in acetic anhydride followed by acidification forms (z) (C10H10O2). All
these compounds (x, y, z) on oxidation under severe conditions form a diacid which gives only
one mononitro isomer in nitrating mixture, how many products will be formed on reductive
ozonlysis of (z)?

35. How many of the following can give aldehyde by the oxidation with Jones reagent?
(a) CH2 OH (b) CH2 = CH – CH2OH

OH
(c) CH3 (d) CH 2 OH

H3C C CH2 OH
CH3

NH2
(e) OH

36. From the following the complex that is expected to show optical isomerism is/are:
(1) [Ni(en)3]2+ (2) [Fe(ox)Cl4]3-
(3) [Cr(NH3)3Cl2(NO3)] (4) [Zn(NO3)2(NH3)(CO)]

37. At 263 K a solid compound A(H2O)8 show following equilibria (Assume 263 K is sublimation point
of H2O(s) under given condition):


A  H2 O 8  s  
 A  g  8H2 O  g ; K p1


A  H2 O 8  s  
 A  g  8H2 O  s ; K p2
If equilibrium partial pressures of two gases A and H2O are 0.2 bar and 0.001 bar respectively.
And the vapour pressure of ice is 10-x bar. What is value of ‘x’?

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38. How many of the following is/are correct structure(s) for any oxide of nitrogen?

(I) O (II) O O
O
+ + +
N O N N O N
O O O
(III) O (IV)
+
-2
+
O N N N O N
O
(V) (VI) O
N O +
O N O
O

39. In 2nd order reaction: 2A  A 2 , the rate of formation of A2 is 10-5 M sec-1 at 0.01 M
concentration of A, and the rate of disappearance of A is x × 10-1, find out the value of x?

40. How many of the following reaction(s) is/are neither stereospecific nor regiospecific?
HCl
(i) trans  2  pentene  
Br
(ii) 1  pentene  2
NaCl Excess

H O
(iii) Cyclobutene 
2
Br  2
D /Pt
(iv) 1  ethylcyclopropene  2
 
Hg OAc 
(v) trans  2  pentene  2
NaBH4 /H O  2

H /H2O
(vi) trans  2  pentene 
Br /CCl
(vii) trans  2  pentene 
2 4

NaH I I
CH3 OH     Product ?
41.
Excess
How many of ‘C’ atoms are there in one molecule of the product?

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42. How many ‘H’ atoms are there in the final product of the following reaction sequence?

conc. HNO /conc.H SO 


3 2 4 H /
  A 
Et/ AcOH B  C

43. How many of the following option(s) is/are incorrect?


(i) The order of rate of E2 reaction is

Et < Et

Et Cl Et Cl
(ii) The poorest leaving group among the – SH, – NH2, – OAc, – OH is – OH.

(iii) N
is stronger nucleophile as compared to Et3N.

(iv) In the reaction


Ph
H C Br 
EtOH

Ph
Rate of reaction is unaffected, if the concentration of Ph2CHBr is tripled and the concentration of
ethanol is doubled.
(v) The order of SN2 mechanism in the following alkyl halide is:

Br
> Br > Br

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SECTION – D

(Numerical Answer Type)

This section contains 3 questions. Each question, when worked out will result in numerical answer type
(XXXXX.XX)

44. There are five solutions


Solution 1 – 0.2 M HCl
Solution 2 – 0.2 M BOH (Kb = 10-2M)
Solution 3 – 0.2 M, 1 lit HCl + 0.2 M, 1 lit BOH
Solution 4 – 0.2 M, K4[Fe(CN)6]
Solution 5 – 0.2 M, Na3PO4
What is the correct code of solution numbers in increasing order of their respective freezing
points?

45. At 298 K, the emf of the cell


Hg | 0.01 mol dm3 kcl | 1 mol dm 3 KNO3 | 0.01 mol dm3 KOH | Hg
saturated with Hg2 Cl2 saturated with HgO
is found to be 0.1634 v. What is the free energy change of the cell reaction? (Given 1F = 96500
C)

46. The density of a sodium chloride sample is found to be 2.16801 gm/cm 3, instead of 2.18 gm/cm3.
What is the percentage of unoccupied sites in the sample?

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Mathematics PART – III

SECTION – A

Straight Objective Type

This section contains 3 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D),
out of which only ONE is correct

47. A circle C1 with radius 5 touches x-axis and another circle C2 with radius 4 touches y-axis. The
two circles touches each other externally so that their point of contact lies in the first quadrant, let
the locus of their point of contact be the curve S. Two tangents are drawn to the curve S from
point P(9, 5) to meet the curve at Q and R. The area of PQR is
29 27
(A) (B)
4 5
13 25
(C) (D)
2 3

48. In a ABC, internal angle bisectors AI, BI and CI are produced to meet opposite sides in A, B
AI  BI  CI
and C respectively, then the maximum value of is
AA   BB  CC
27 13
(A) (B)
2 4
8 27
(C) (D)
27 256

49. Point ‘O’ is the centre of ellipse with major axis AB and minor axis CD. Point F is one focus of
ellipse. If OF = 6 and the diameter of the inscribed circle of OCF is 2, then the product AB.CD
equals
(A) 65 (B) 72
(C) 78 (D) 92

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Multiple Correct Choice Type

This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out of which only ONE OR MORE THAN ONE is/are correct

50. Vertices A, B and C of a tetrahedron ABCD are (1, 1, 1), (1, 0, 0), (3, 0, 0) respectively. The
altitude from vertex D to the opposite face ABC meets the median line through A of the ABC at a
2 2
point E. If the length of side AD is 4 and volume of the tetrahedron is , then the correct
3
statements is/are
(A) the altitude from vertex D is 2 (B) there is exactly one position for the point E
(C) there can be two position for the point E (D) vector ˆj  kˆ is normal to the plane ABC

i
51. Let   e 2017 , then
2016
 2016 
(A)   r

  r  2 (B) Re   r   0
r 1  r 1 
2016 2016
(C)    r   r   0 (D)   r    r   1
r 1 r 1

 1
52. Let P  ,  , (0 <  < 1) be any point on the hyperbola xy = 1. Tangent to the hyperbola at P
 
intersect the coordinate axes at Q and R & normal at P intersects the coordinate axes at M and N
(Q and M lie on x-axis). If OQR and OMN have equal area, then
(A) area of OMN = 2 (B)   2  1
(C) QR = 27/4 (D) MN = 27/4

53. The roots of equation x5 – 40x4 + x3 + x2 + x +  = 0 are real and in G.P. If the sum of their
reciprocal is 10, then  can be
1
(A) –32 (B)
32
1
(C)  (D) 32
32

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dy sin2 x
54. A function y = f(x) satisfying the differential equation  sin x  y cos x   0 is such that
dx x2
y  0 as x  , then
 /2

(A) lim f  x   1
x 0
(B)  f  x  dx is less than
2
0
 /2
(C)  f  x  dx is greater than unity (D) f(x) is an odd function
0

Comprehension Type

This section contains 1 group of questions. The group has 2 multiple choice question based on a
paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which only ONE is
correct

Paragraph for Question Nos. 55 to 56

Read the following write up carefully and answer the following questions:
Consider the following three sets of complex roots of unity. A = {z: z18 = 1}, B = {: 48 = 1} and
C = {z: z  A and   B}, then

55. The number of distinct elements in the set C is


(A) 864 (B) 48
(C) 66 (D) 144

56. Let the set C has n distinct elements C1, C2, ....., Cn, then the value of
|C2 – C1| + |C3 – C1| + ..... + |Cn – C1| is
º º
5 5
(A) 2cot   (B) cot  
8 4
º º
 15   15 
(C) 2cot   (D) cot  
 11   8 

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AITS-FT-X (Paper-2)-PCM-JEE(Advanced)/18 24

SECTION – C

(One Integer Value Correct Type)

This section contains 10 questions. Each question, when worked out will result in one integer from 0 to
9 (both inclusive).

1 2 1
 f x  1  1
57. f: R  R is a continuous function satisfying   x  dx  2  f  x  dx  3 , then 256 f  8  is equal
0 0
to _____

58. There are seven letters L1, L2, L3, L4, L5, L6 and L7 and six envelopes E1, E2, E3, E4, E5, E6
corresponding to first six letters. The total number of ways if none of the letters goes to its correct
envelope, even letters goes to even envelopes. Odd letters goes to envelopes other that E4 and
E6 and all the envelopes except E2 contains exactly one letter is, N. If N = 2 + 4, where   z,
then  is equal to _____

 z  z1 
59. Let A(z1), B(z2) and C  z1  2  are vertices of a triangle. If |z2 + iz1| = |z1| + |z2|, z1  7
 1 i 
and |z2| = 3, then area of ABC is _____

1 1 1   A 
60. Let A    .....  , then find   _____ (where [.] denotes the greatest integer
2 3 10000  50 
function)

61. The possible number of ordered triplets (m, n, p) where m, n, p  N is (6250)k. Such that
1  m  100, 1  n  50, 1  p  25 and 2m + 2n + 2p is divisible by 3, then k is _____

2 p2
62. Number of integral values of p for which the system of equations cos1 x  sin1 y   
4
and

2 4
 cos x  sin y 
1 1

16
has real solutions is _____

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63. Let f: R+  R+ be a differentiable function satisfying f(x)·f(yf(x)) = f(x + y)  x, y  R+ and


f  x
f(0) = –1, and f(0) = 1 then area of the region bounded by the curve y  and the coordinate
x 1
axes is _____

ln 2
2e3x  e2x  1
64. Let I   dx , then 11e–I is equal to _____
0 e  e2x  e x  1
3x

65. The number of different hyperbolas, which can be represented by the equation
1  x 2  y 2  nCr x is _____ (where n and r are integers satisfying 1  r  n  5)

 3 r  3r 2r 
1  4 3 
66. Let A   2  , B   and C    be given matrices. If
   2 2  r
 0
r
r  1 3 
1 2 
50
ab
 tr   AB  
r
Cr  3  a  3b _____ (where tr(A) denotes trace of matrix A), then value of is
r 1 20
(where a, b  I and a is not divisible by 3)

SECTION – D

(Numerical Answer Type)

This section contains 3 questions. Each question, when worked out will result in numerical answer type
(XXXXX.XX)

67. The equation a8x8 + a7x7 + a6x6 + ..... + a0 = 0 has all roots positive and real and a8 = 1, a7 = –4
1 a a
and a0 = 8 , then the value of 2 6 is equal to _____
2 a4

68. Coordinate of any point P are (4, 5). If A and B are variable points on straight lines y = x and
y = 2x respectively. Then find minimum value of (PA + PB + AB)2 _____

69. If the length of the largest interval in which the function f(x) = sin–1|sin x| + cos–1(cos x) is
constant is 2, then the value of  is _____ where ( > 0)

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