Material Safety Data Sheet

Benzyl alcohol

Section 1 - Chemical Product and Company Identification

MSDS Name: Benzyl alcohol
Catalog 10584-0000, 10584-5000, 14839-0000, 14839-0010, 14839-0025, 14839-
Numbers: 0050, 37809-0000
Synonyms: Phenylmethanol
Acros Organics BVBA
Company Identification: Janssen Pharmaceuticalaan 3a
2440 Geel, Belgium
Acros Organics
Company Identification: (USA) One Reagent Lane
Fair Lawn, NJ 07410
For information in the US, call: 800-ACROS-01
For information in Europe, call: +32 14 57 52 11
Emergency Number, Europe: +32 14 57 52 99
Emergency Number US: 201-796-7100
CHEMTREC Phone Number, US: 800-424-9300
CHEMTREC Phone Number, Europe: 703-527-3887
Section 2 - Composition, Information on Ingredients
CAS# Chemical Name: % EINECS#
100-51-6 Benzyl alcohol >98.5% 202-859-9
Hazard Symbols: XN

Risk Phrases: 20/22

Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed.Hygroscopic (absorbs moisture from the air).Air
sensitive.
Potential Health Effects
Eye: May cause moderate eye irritation. Causes redness and pain.
 Causes moderate skin irritation. Prolonged and/or repeated contact may cause
Skin: defatting of the skin and dermatitis. Causes redness and pain. May be harmful if
absorbed through the skin.
Harmful if swallowed. May cause severe gastrointestinal tract irritation with
Ingestion:
nausea, vomiting and possible burns.
Harmful if inhaled. Inhalation of high concentrations may cause central nervous
Inhalation: system effects characterized by nausea, headache, dizziness, unconsciousness and
coma. May cause respiratory tract irritation.
Chronic: Prolonged or repeated skin contact may cause dermatitis.
Section 4 - First Aid Measures
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting
Eyes:
the upper and lower eyelids. Get medical aid.
Get medical aid. Flush skin with plenty of water for at least 15 minutes while
Skin:
removing contaminated clothing and shoes.
Ingestion: Get medical aid. Wash mouth out with water.
Remove from exposure and move to fresh air immediately. If not breathing,
Inhalation: give artificial respiration. If breathing is difficult, give oxygen. Get medical
aid.
Notes to
Physician:
Section 5 - Fire Fighting Measures
As in any fire, wear a self-contained breathing apparatus in pressure-
General
demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Information:
Will burn if involved in a fire.
Extinguishing
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Media:
Section 6 - Accidental Release Measures
General
Use proper personal protective equipment as indicated in Section 8.
Information:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then
Spills/Leaks:
place in suitable container.
Section 7 - Handling and Storage
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use
Handling:
only in a chemical fume hood.
Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly
Storage:
closed container. Store protected from light. Store under nitrogen.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an
eyewash facility and a safety shower. Use adequate general or local exhaust
ventilation to keep airborne concentrations below the permissible exposure
 limits.
Exposure Limits
CAS# 100-51-6:

Personal Protective Equipment

Eyes: Wear chemical splash goggles.
Skin: Wear appropriate gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European
Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149
Respirators: approved respirator if exposure limits are exceeded or if irritation or other
symptoms are experienced.

Section 9 - Physical and Chemical Properties

Physical State: Clear liquid

Color: colorless to pale yellow
Odor: aromatic odor - faint odor
pH: Not available
Vapor Pressure: 0.13 mbar @ 20 deg C
Viscosity: 6.6 mPa.s @ 20 deg C
Boiling Point: 205 deg C ( 401.00°F)
Freezing/Melting Point: -15 deg C ( 5.00°F)
Autoignition Temperature: 435 deg C ( 815.00 deg F)
Flash Point: 93 deg C ( 199.40 deg F)
Explosion Limits: Lower: 1.3 Vol %
Explosion Limits: Upper: 13 Vol %
Decomposition Temperature: Not available
Solubility in water: 40 g/l (20°C)
 Specific Gravity/Density: 1.044
Molecular Formula: C7H8O
Molecular Weight: 108.14
Section 10 - Stability and Reactivity
Chemical Stability: Slowly oxidized by atmospheric oxygen.
Incompatible materials, light, exposure to air, exposure to moist air
Conditions to Avoid:
or water, heat.
Strong oxidizing agents, acids, aluminum, coatings, iron, plastics,
Incompatibilities with
sulfuric acid, nonmetal halides (e.g. diselenium dichloride, disulfur
Other Materials
dichloride, phosphorus trichloride).
Hazardous
Decomposition Carbon monoxide, carbon dioxide.
Products
Hazardous
May occur.
Polymerization
Section 11 - Toxicological Information
CAS# 100-51-6: DN3150000
RTECS#:
RTECS:
CAS# 100-51-6: Draize test, rabbit, skin: 100 mg/24H Moderate;
Inhalation, mouse: LC50 = >500 mg/m3;
Inhalation, rat: LC50 = >500 mg/m3;
Oral, mouse: LD50 = 1360 mg/kg;
Oral, mouse: LD50 = 1360 mg/kg;
Oral, rabbit: LD50 = 1040 mg/kg;
LD50/LC50:
Oral, rabbit: LD50 = 1040 mg/kg;
Oral, rat: LD50 = 1230 mg/kg;
Oral, rat: LD50 = 1660 mg/kg;
Skin, rabbit: LD50 = 2000 mg/kg;
Skin, rat: LD50 = 100 pph/90M;
.
Other:
Benzyl alcohol - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA
Carcinogenicity: Prop 65.

Other: See actual entry in RTECS for complete information.

Section 12 - Ecological Information
Fish: Fathead Minnow: LC50: 770-460 mg/l; 48-96 h; .
Daphnia: Water Flea: EC50: 400 mg/l; 48h; .
Ecotoxicity:
Fish: Leuciscus idus: LC50: 646 mg/l; 48h; .

Other: Readily biodegradable.

 Log Pow: 1.1BOD5: 70%
Section 13 - Disposal Considerations
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - Transport Information
IATA IMO RID/ADR
Shipping Not regulated as a Not regulated as a Not regulated as a
Name: hazardous material hazardous material hazardous material
Hazard
Class:
UN
Number:
Packing
Group:
Section 15 - Regulatory Information
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
WGK (Water Danger/Protection)
CAS# 100-51-6: 1
Canada
CAS# 100-51-6 is listed on Canada's DSL List
</ TD>
US Federal
TSCA
CAS# 100-51-6 is listed on the TSCA Inventory.
Section 16 - Other Information
MSDS Creation Date: 7/16/1996
Revision #3 Date 2/09/2004
Revisions were made in Sections: General revision.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantibility or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall the company be
liable for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential, or exemplary damages
howsoever arising, even if the company has been advised of the possibility of
such damages.
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