SAFETY DATA SHEET

Prepared in accordance with the Thai Classification System and Revision date: 11-Jun-2018
Communication of the Hazards of the Hazardous Substance 2555 BC (2012)

According to the Thai Classification System and Communication of the Hazards of the Hazardous Substance 2555 BC (2012),
(SDS) must be provided for hazardous substances or mixtures. This product does not meet the classification criteria of the
standard. Therefore such document is outside the scope of the standard and the requirements for content in each section do
not apply.

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product name: CAB-O-SILÒTS-622 Fumed Silica

Product code: TS622

Synonyms: Silicon Dioxide, Synthetic Amorphous Silica, Pyrogenic (Fumed) Amorphous Silica

Recommended use: Various, Rheological control, Flow agent, Thickening agent, Reinforcing agent in: Coatings,
Adhesives and/or sealants, Inks and toners, Silicone Elastomer, Rubber products,
Suspension, Dispersion, Paints, Cosmetics, Hygiene and sanitary products, Other

Restrictions on use: Not Applicable.

Supplier:

Cabot Corporation
157 Concord Road
Billerica, MA 01821
UNITED STATES
Tel: 1-978-663-3455
Fax: 1-978-670-6955

Asia Pacific Regional Headquarters

Cabot China Ltd
558 Shuangbai Road
Minhang District
Shanghai 201108, China
Tel: +86 21 5175 8800
Fax: +86 216434 5532

Emergency Telephone Number: 24H/7d service

CHEMTREC Thailand : 001-800-13-203-9987
International CHEMTREC: +1 703-741-5970 or +1-703-527-3887
CHINA: CHEMTREC 4001 - 204937
GERMANY: CHEMTREC 0800-181-7059
UK: CHEMTREC: (+44)-870-8200418
US: CHEMTREC: 1-800-424-9300 or 1-703-527-3887

2. HAZARDS IDENTIFICATION

Classification
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Product code: TS622 Product name: CAB-O-SILÒTS-622 Fumed Silica Revision date: 11-Jun-2018
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This substance/mixture is considered not hazardous according to the Thailand Classification System and Communication of the
Hazards of the Hazardous Substance 2555 BC (2012).

Pictogram:
None

Signal Word:
None

Hazard statements:
None

Precautionary statements:
None

Hazards not otherwise classified

(HNOC)

Do not expose to temperatures above 150°C. Hazardous products of combustion can include carbon monoxide and carbon
dioxide.

Potential health effects

Principle Routes of Exposure: Inhalation, Skin Contact, Eye contact

Eye Contact: May cause mechanical irritation. Avoid contact with eyes.

Skin Contact: May cause mechanical irritation and skin drying. Avoid contact with skin. No cases of
sensitization in humans have been reported.

Inhalation: Dust may be irritating to respiratory tract. Provide appropriate exhaust ventilation at
machinery and at places where dust can be generated. See also Section 8.

Ingestion: Adverse health effects are not expected. See Section 11.

Carcinogenicity: Does not contain any substances greater than 0.1% listed by IARC (International Agency
for Research on Cancer), NTP (National Toxicology Program), OSHA (Occupational Safety
and Health Administration), ACGIH (American Conference for Governmental Industrial
Hygienists) or EU (European Union). See also Section 11.

Target Organ Effects: Lungs, See Section 11

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Product code: TS622 Product name: CAB-O-SILÒTS-622 Fumed Silica Revision date: 11-Jun-2018
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Medical Conditions Aggravated by Asthma, Respiratory disorder

Exposure:

Potential Environmental Effects: None known. See Section 12.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Synonyms: Silicon Dioxide, Synthetic Amorphous Silica, Pyrogenic (Fumed) Amorphous Silica.

Chemical name CAS No weight-% Trade secret

Silane, dichlorodimethyl-, reaction products with 68611-44-9 100 -
silica

The hyphen (-) means "not applicable"

4. FIRST AID MEASURES

FIRST AID MEASURES

Skin Contact Wash thoroughly with soap and water. Seek medical attention if symptoms develop.

Eye contact Flush eyes immediately with large amounts of water for 15 minutes. Seek medical
attention if symptoms develop.

Inhalation If cough, shortness of breath or other breathing problems occur, move to fresh air. Seek
medical attention if symptoms persist. If necessary, restore normal breathing through
standard first aid measures.

Ingestion Do not induce vomiting. If conscious, give several glasses of water. Never give anything
by mouth to an unconscious person.

Most important symptoms and effects, both acute and delayed

Symptoms: The most important known symptoms and effects are described in Section 2 and/or in
Section 11.

Indication of any immediate medical attention and special treatment needed

Note to physicians: Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment. Water. Dry chemical. Carbon dioxide (CO2). Foam.

Unsuitable Extinguishing Media: None.

Specific hazards arising from the None.

chemical:

Hazardous combustion products: Carbon monoxide (CO). Carbon dioxide (CO2).

Protective equipment and Wear suitable protective equipment. In the event of fire, wear self-contained breathing
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precautions for firefighters: apparatus.

Risk of Dust Explosion: Not Applicable: Will not cause dust explosion.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions: Avoid dust formation. Ensure adequate ventilation. Use personal protective equipment.
See also Section 8.

For emergency responders: Use personal protection recommended in Section 8.

Environmental Precautions:

Environmental Precautions: Contain spilled product on land, if possible. Local authorities should be advised if
significant spillages cannot be contained.

Methods and material for containment and cleaning up

Methods for containment: Prevent further leakage or spillage if safe to do so.

Methods for cleaning up: Clean up promptly by vacuum. Use of a vacuum with high efficiency particulate air (HEPA)
filtration is recommended. Do not create a dust cloud by using a brush or compressed air.
Pick up and transfer to properly labelled containers. See Section 13.

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling: Avoid contact with skin and eyes. Avoid dust formation. Do not breathe dust. Provide
appropriate exhaust ventilation at machinery and at places where dust can be generated.
Do not create a dust cloud by using a brush or compressed air.

Take precautionary measures against static discharges. All metal parts of the mixing and
processing equipment must be earthed/grounded. Ensure all equipment is electrically
earthed/grounded before beginning transfer operations. Fine dust is capable of
penetrating electrical equipment and may cause electrical shorts.

General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice

Conditions for safe storage, including any incompatibilities

Storage Conditions: Keep containers tightly closed in a dry and well-ventilated place. Do not store together
with volatile chemicals as they may be adsorbed onto product. Store at ambient
conditions. Keep in properly labeled containers.

Incompatible materials: None known.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure guidelines: The table below is a summary. Please see the specific legislation for complete
information.

Amorphous Silica, The regulatory Australia: 2 mg/m³, TWA, Respirable

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exposure limits are found under the Austria MAK 4 mg/m³, TWA, Inhalable fraction
general silica, CAS RN 7631-86-9: Finland: 5 mg/m³
Germany TRGS 900: 4 mg/m³, TWA, Inhalable fraction
India: 10 mg/m³, TWA
Ireland: 2.4 mg/m³, TWA, Respirable dust
Norway: 1.5 mg/m³, TWA, Respirable dust
Switzerland: 4 mg/m³, TWA
UK WEL: 6 mg/m³, TWA, Inhalable fraction
2.4 mg/m³, TWA, Respirable fraction
US OSHA PEL: 6mg/m³ (54 FR2701)

Dust, or Particulates Not Otherwise Belgium: 10 mg/m³, TWA, Inhalable

Specified: 3 mg/m³ TWA, Respirable

China: 8 mg/m³, TWA

10 mg/m³, STEL

France: 10 mg/m³, TWA Inhalable dust

5 mg/m³, TWA Respirable dust

Italy: 10 mg/m³, TWA, Inhalable

3 mg/m³, TWA, Respirable

Malaysia: 10 mg/m³, TWA, Inhalable

3 mg/m³, TWA, Respirable

Spain: 10 mg/m³, VLA, Inhalable

3 mg/m³, VLA, Respirable

US ACGIH - PNOS: 10 mg/m³, TWA, Inhalable

3 mg/m³, TWA, Respirable

US OSHA - PEL: 15 mg/m³, TWA, Total dust

5 mg/m³, TWA, Respirable

NOTE:

In its facilities globally, Cabot Corporation manages silica to the Germany TRGS 900 occupational exposure limit of 4 mg/m³,
TWA, Inhalable fraction

MAK: Maximale Arbeitsplatzkonzentration (Maximum Workplace Concentration)

PEL: Permissible Exposure Limit
PNOS: Particulate Not Otherwise Specified
STEL: Short Term Exposure Limit
TRGS: Technische Regeln für Gefahrstoffe (Technical Rule for Hazardous Materials)
TWA: Time Weighted Average
US ACGIH: United States American Conference of Governmental Industrial Hygienists
US OSHA: United States Occupational Safety and Health Administration
VLA: Valore Límite Ambientales (Environmental Limit Value)
WEL: Workplace Exposure Limit

Engineering Controls: Ensure adequate ventilation to maintain exposures below occupational limits. Provide
appropriate local exhaust ventilation at machinery and at places where dust can be
generated.

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Personal protective equipment [PPE]

Respiratory Protection: Approved respirator may be necessary if local exhaust ventilation is not adequate.

Hand Protection: Wear protective gloves to prevent skin drying. Use protective barrier cream before
handling the product. Wash hands and other exposed skin with mild soap and water.

Eye/face Protection: Wear eye/face protection. Wear safety glasses with side shields (or goggles).

Skin and Body Protection: Wear suitable protective clothing. Wash clothing daily. Work clothing should not be
allowed out of the workplace.

Other: Handle in accordance with good industrial hygiene and safety practice. Emergency
eyewash and safety shower should be located nearby.

Environmental exposure controls: In accordance with all local legislation and permit requirements as applicable for dusts.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information given is based on data obtained from this product and similar products.

Physical State: Solid Odor: None.

Appearance: Powder Odor threshold: Not Applicable
Color: White

Property Values Rema rks•Met hod

pH: 4.0-5.0 In-house testing
Melting point/freezing point: 1700 °C NIOSH Pocket Guide to Chemical Hazards
Boiling point / boiling range: 2230 °C NIOSH Pocket Guide to Chemical Hazards
Evaporation Rate: Not Applicable
Vapor pressure: Not Applicable
Vapor Density: Not Applicable
Density: 2.2-2.3 g/cm3 @ 20 °C
Bulk Density: <4 lbs/ft3 DIN/ISO 787:11

Specific Gravity at 20°C: 2.2-2.3 No information available

Water solubility: No information available
Solubility(ies): No information available
Partition Coefficient Not Applicable
(n-octanol/water):
Decomposition temperature: >400 °C Bulk Powder test- Diffusion cell
Viscosity: Not Applicable
Kinematic viscosity: Not Applicable
Dynamic viscosity: Not Applicable
Oxidizing Properties: No oxidizing properties
Softening point: Not Applicable
VOC content (%): Not Applicable
% Volatile (by Volume): Not Applicable
% Volatile (by Weight): Not Applicable

Surface Tension: Not Applicable

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Explosive properties: Non-explosible

Flash Point: Not Applicable

Flammability (solid, gas): Not flammable. Product resists ignition and does not promote
flame spread. Not readily combustible (Class 4.1) according to
EU Method A10
Flammability Limit in Air: No information available
Explosion Limits in Air - Upper (g/m3): No information available
Explosion Limits in Air - Lower (g/m3): No information available
Autoignition Temperature: Unlikely to ignite
Minimum Ignition Temperature: >790 °C ASTM E-1491 Dust cloud

Minimum Ignition Energy: >10 J BS 5958 (Part 1, 1991)

Ignition Energy: No information available
Maximum Absolute Explosion Pressure: Not Applicable
Maximum Rate of Pressure Rise: Not Applicable
Burn Velocity: No information available
Kst Value: Not Applicable
Dust Explosion Classification: Not Applicable
End point is listed "not applicable" due to the inherent properties of the substance
"No information available" indicates testing has not been performed

10. STABILITY AND REACTIVITY

Reactivity: Not reactive. Substance is an inert inorganic solid.

Stability: Stable under recommended handling and storage conditions.

Stable up to 400° C. No exotherm (BulkPowder test - Diffusion cell).

Possibility of hazardous reactions: None under normal processing.

Hazardous polymerization: Hazardous polymerization does not occur.

Conditions to avoid: Do not expose to temperatures above 150°C. Keep away from heat and sources of
ignition. Avoid dust formation.

Incompatible materials: None known.

Explosion data Will not cause dust explosion. See also Section 9.

Sensitivity to Mechanical Impact: None.

Sensitivity to Static Discharge: This material will not create nor support conditions that would result in a dust explosion
or fire. Take precautionary measures against static discharges. Avoid dust formation. All
metal parts of the mixing and processing equipment must be earthed/grounded. Ensure
all equipment is electrically earthed/grounded before beginning transfer operations.

Hazardous decomposition products: Carbon monoxide (CO). Carbon dioxide (CO2).

11. TOXICOLOGICAL INFORMATION

Information given is based on data obtained from this substance or from similar substances.

Acute toxicity
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Oral LD50: LD50/oral/rat = > 5000 mg/kg. No deaths occurred and no signs of toxicity were seen
during the observation periods after single oral administration of the substance. (OECD
423).

Inhalation LC50: Due to the product's physical characteristics, no suitable testing procedure is available

Dermal LD50: No data are available on the product itself.

Synthetic Amorphous Silica: LD50/dermal/rabbit = > 2000 mg/kg. Very slight transient
erythema in one animal. No signs of systemic or organ toxicity (OECD 402).

Skin corrosion/irritation: Primary irritation index = 0.0 @ 24 hr. Not classified as an irritant (OECD 404)

Serious eye damage/eye irritation: Not classified as an irritant in rabbit studies (OECD 405). High dust concentrations may
cause mechanical irritation.

Sensitization: No experimental animal data are available. No cases of sensitization in humans have been
reported.

Mutagenicity: Not mutagenic in Ames test. Negative in the chromosome aberration test in Chinese
hamster ovary (CHO) cells.

Carcinogenicity: No evidence of cancer in rats exposed for 24 months at 100 mg/kg/d (diet). (ECETOC JACC
Report 051 - Synthetic Amorphous Silica, September 2006).

Synthetic Amorphous Silica: No evidence of carcinogenicity was observed in multiple

animal species following repeated oral or inhalation exposure to amorphous silica.
Similarly, epidemiology studies show no evidence of carcinogenicity in workers who
manufacture amorphous silica.

Reproductive and Developmental No effects on reproductive organs have been reported in animal toxicity studies. No
Toxicity: developmental effects observed on progeny in dietary study (doses of 0 or 500 mg/kg/d).
(ECETOC JACC Report 051 - Synthetic Amorphous Silica, September 2006).

STOT - single exposure: Specific target organ toxicity is not expected after single oral, single inhalation, or single
dermal exposure.

STOT - repeated exposure: Repeated dose toxicity: oral (rat) , 5 to 8 weeks, no significant treatment-related adverse
effects at doses of up to 2000 mg/kg/d. (ECETOC JACC Report 051 - Synthetic Amorphous
Silica, September 2006).

Synthetic Amorphous Silica. Repeated dose toxicity: oral (rat), 2 weeks to 6 months, no
significant treatment-related adverse effects at doses of up to 8% silica in the diet.
Repeated dose toxicity: inhalation (rat), 13 weeks, Lowest Observed Effect Level (LOEL) =
1.3 mg/m3 based on mild reversible effects in the lungs.
Repeated dose toxicity: inhalation (rat), 90 days, LOEL = 1 mg/m3 based on reversible
effects in the lungs and effects in the nasal cavity.

Based on available data, a STOT-RE classification is not warranted.

Aspiration Hazard: Based on industrial experience and available data, no aspiration hazard is expected.

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12. ECOLOGICAL INFORMATION

Information given is based on data from similar substances.

Aquatic Toxicity: Fish (Brachydanio rerio) LC50 (96 h): > 10,000 mg/l; (Method: OECD 203)
No acute toxicity to Daphnia with EL and EL50 ranging from >1000 to 10,000 mg/L (OECD
202)

ENVIRONMENTAL FATE
Persistence and degradability The methods for determining biodegradability are not applicable to inorganic substances

Bioaccumulation Not expected due to physicochemical properties of the substance.

Mobility: Not expected to migrate.

Distribution to Environmental No information available.

Compartments:

Other adverse effects: No information available.

13. DISPOSAL CONSIDERATIONS

Disclaimer: Information in this section pertains to the product as shipped in its intended composition as described in Section 3
of this SDS. Contamination or processing may change waste characteristics and requirements. Regulations may also apply to
empty containers, liners or rinsate. State/provincial and local regulations may be different from federal regulations.

Unused and Uncontaminated Product, as supplied, should be disposed of in accordance with the regulations issued by
Product: the appropriate federal, state and local authorities. Same consideration should be given
to containers and packaging.

14. TRANSPORT INFORMATION

Not self-heating solids (Class 4.2). per UN Transporation of Dangerous Goods.

DOT

UN/ID no Not regulated

Proper Shipping Name Not regulated
Hazard Class Not regulated
Packing group Not regulated

ICAO (air)

UN/ID no Not regulated

Proper Shipping Name Not regulated
Hazard Class Not regulated
Packing group Not regulated

IATA

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UN/ID no Not regulated

Proper Shipping Name Not regulated
Hazard Class Not regulated
Packing group Not regulated

IMDG

UN/ID no Not regulated

Proper Shipping Name Not regulated
Hazard Class Not regulated
Packing group Not regulated

RID

UN/ID no Not regulated

Proper Shipping Name Not regulated
Hazard Class Not regulated
Packing group Not regulated

ADR

UN/ID no Not regulated

Proper Shipping Name Not regulated
Hazard Class Not regulated
Packing group Not regulated

15. REGULATORY INFORMATION

International Inventories

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory Complies
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List Complies
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Complies
Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances Complies
IECSC - China Inventory of Existing Chemical Substances Complies
KECL - Korean Existing and Evaluated Chemical Substances Complies
PICCS - Philippines Inventory of Chemicals and Chemical Substances Complies
AICS - Australian Inventory of Chemical Substances Complies
NZIoC - New Zealand Inventory of Chemicals Complies
TCSI - Taiwan Chemical Substance Inventory Complies

16. OTHER INFORMATION

Pharmaceutical Use:
Not permitted

Food Additive Use:

Not permitted

References:

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NIOSH Pocket Guide to Chemical Hazards, September 2005. "Silica, amorphous". DHHS (NIOSH) Publication No. 2005-149.
National Technical Information Service, Springfield, VA. p. 277

Contacts:

Cabot Corporation Cabot GmbH Cabot Carbon, Ltd.

157 Concord Road Kronenstrasse 2 Sully Moors Road
Billerica, MA 01821 79618 Rheinfelden Sully, Glamorgan CF64 5RP
UNITED STATES GERMANY Wales, UNITED KINGDOM
Tel: 1-978-663-3455 Tel (+49) 7623.707.0 Tel: (+44) 1446.736999 Fax: (+44)1446.737123
Fax: 1-978-670-6955 Fax: (+49) 7623.707.530

Cabot Corporation Cabot Bluestar Ltd. Cabot Corporation

700 E U.S. Highway 36 Xinghuo Industrial Garden 3603 South Saginaw Road
Tuscola, IL 61953-9643 Yongxiu County, Jiujiang City Midland, MI 48640
UNITED STATES 330319 UNITED STATES
Tel:1-217-253-3370 Jiangxi Province, CHINA Tel: 1-989-495-0030
Fax: 1-217-253-5530 Tel: (86-792) 3171616 Fax: 1-989-495-2139
Fax: (86-792) 3170320
Disclaimer:
The information set forth is based on information that Cabot Corporation believes to be accurate. No warranty, expressed or
implied, is intended. The information is provided solely for your information and consideration and Cabot assumes no legal
responsibility for use or reliance thereon. In the event of a discrepancy between the information on the non-English document
and its English counterpart, the English version shall supersede.

Prepared by: Cabot Corporation - Safety, Health and Environmental Affairs

Revision date: 11-Jun-2018

All names annotated with the Òor Ô symbol are trademarks of the Cabot Corporation or its affiliates.

End of Safety Data Sheet

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