New 6xxx Aluminum Alloy PDF
New 6xxx Aluminum Alloy PDF
New 6xxx Aluminum Alloy PDF
SAE TECHNICAL
PAPER SERIES
S. J. Murtha
Aluminum Company of America
SAE
MAR 0 7 1995
LIBRARY
**
-l.and
=For
The Engineering Society
Advancing Mobility
Sea Air and S ~ a c e -
International Congress and Exposition
Detroit, Michigan
. 27 March 2,1995
Februarv -
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ISSN 0148-7191
Copyright 1995 Society of Automotive Engineers, Inc.
Positions and opinions advanced in this paper are those of the author(s) and not
necessarily those of SAE. The author is solely responsible for the content of the
paper. A process is available by which discussions will be printed with the paper if
it is published in SAE transactions. For permission to publish this paper in full or in
part, contact the SAE Publications Group.
The panels were rated for degree of filiform corrosion this way, effects of Mg and Si can be graphically
(i.e., number of sites on duplicate panels and average depicted for easier interpretation. Effects of Cu can be
length of sites). seen by comparing separate figures showing the same
parameter (i.e., transverse yield strength for 0.0% Cu
-
EXPERIMENTAL RESULTS LABORATORY STUDY alloys in Figure 2a compared to identical data for 0.2%
Cu alloys in Figure 2b). Highlights of the mechanical
-T4 MECHANICAL PROPERTIES (EFFECT OF Mg property data are summarized below.
-
AND Si) Figures 2-6 illustrate composition effects on Low solute alloys in the bottom left-hand corner of the
transverse -T4 temper mechanical properties. A number composition box exhibit strengths which are well below
of mechanical property parameters are shown on the those of standard alloys [I]. At these strength levels,
schematic Mg and Si composition boxes for handling damage could potentially be a concern. If slight
experimental alloys containing 0.0% Cu as well as 0.2% strength improvements were made, then these
Cu. Transverse yield strengths in Figure 2a are shown compositions could possibly provide adequate damage
within the corner and center points of the Mg/Si resistance (during handling). The remaining alloys
composition box for alloys containing 0.0% Cu (at exhibit strengths which should be acceptable in the -T4
corners of box) and 0.1 % Cu (at center of box). This temper. Assuming adequate formability, the composition
illustration has been repeated in Figure 2b for alloys with the highest strength would be the most desirable.
containing 0.2% Cu at the corners of the Mg/Si box. In This was achieved by the alloys in the upper right-hand
corner of the Mg/Si composition box. This was not
unexpected since these materials contained the greatest
amounts of Mg and Si.
0% C u O corners of box & 0.1% 8 center
The higher Si samples generally exhibited the best
overall values of tensile elongation as shown in
Figures 3a and 3b.
The strain hardening exponent (n), which is an
indicator of necking resistance, has been used to predict
plane strain stretching ability. Although the data is not
consistent when comparing the 0% and 0.2% Cu
containing samples, the lower Mg bearing compositions
(left side of experimental composition box) do show the
best overall n values (Figures 4a and 4b). Although the
lncreasing %Mg
GA 34628.4a
0% Cu 8 corners of box 6 0.l0A 8 center 0°' Cu 8 corners of box & 0.1% 8 center
lncreasing %Mg
0.2% Cu 63 corners of box & 0.1% 8 center 0.2% Cu 8 corners of box & 0.1% 8 center
lncreasing %Mg
The r-bar values plotted in Figures 6a and 6b for most stretching performance. Even though the higher solute
of the experimental compositions do not vary alloys (upper right-hand corner compositions)
significantly due to composition changes. Values only demonstrated high strengths, they also exhibited very
range from 0.66 to 0.72 and are similar to those high LDH values as well.
previously published for standard aluminum auto body The data implies that all compositions would have
sheet alloys [I]. This data suggests that composition good bendability since minimum rlt values in the guided
does not significantly affect r values in aluminum alloys bend test range from 0 to 0.5 (Figures 8a and 8b).
over the composition range studied here. Figure 9 illustrates that high Si compositions (upper
-T4 SIMULATIVE FORMABILITY (EFFECT OF Mg half of box) exhibit the best performance (highest strains
-
AND Si) Plots illustrating composition effects on at the point of maximum stress) in the hydraulic bulge
simulative formability test indicators are shown in test for compositions containing no copper. However,
Figures 7-9. These are similar to schematic plots when 0.2% copper is added, the low Si, high Mg
depicting the -T4 mechanical properties which were composition (bottom right-hand corner) also performs
discussed above. well. Conversely, compositions near the bottom left-
As suggested by the uniform elongation hand corner of the box are inferior in this test. As in the
measurements, the high Si samples exhibited superior dome height tests, Si additions appear to improve
LDH values (Figures 7a and 7b). Compositions near the formability. In order to determine the reasons for this
upper left-hand corner showed the best plane strain behavior, instantaneous strain hardening values were
0% Cu O corners of box & 0.1% 8 center 0% Cu @ corners of box & 0.1% @ center
lncreasing %Mg -
Figure 6a: Experimental Results
lncreasing %Mg
GA 34628.7b
0.2% Cu O corners of box & 0.10/0 O center 0.2% Cu @ corners of box & 0.1% @ center
lncreasing %Mg
0.2% Cu 8 corners of box & 0.1% 8 center 0.2% Cu O corners of box 6 0.1% 8 center
lncreasing %Mg
calculated (from the measured stress-strain data) and evaluated in this study. These include practices
plotted as a function of strain for compositions containing conducted at 60 min1204"C (no pre-stretch) and
constant amounts of all elements except for Si. These 20 mid185°C (2% pre-stretch).
plots are shown in Figures 10 and 11. When Si The highest strengths were achieved with the alloys
increases in these samples, strain hardening is retained in the upper right-hand corner of the composition box.
even after very high deformation strains (>30-35O/0). This was not unexpected since these compositions did
This suggests that the higher Si alloys resist strain contain the greatest amount of solute compared to the
localization more readily compared to samples others which were studied. The strengths of samples
containing lower amounts. This can be important during from the left side of the experimental composition box
stamping where strain values can sometimes be quite were well below those at the center or on the right-hand
large. Even though some materials exhibit good strain side of the box. The compositions near the lower left-
hardening behavior at low strains, rapid strain hand corner were not given further consideration due to
localization often occurs. These materials cannot be a combination of low -T4 strengths, low -T62 strengths,
deformed as readily as those which retain their strain and low formability.
hardening ability over a larger range of strains. -T62 CORROSION RESISTANCE (EFFECT OF
-T62 TYPE MECHANICAL PROPERTIES (EFFECT MgISilCu) - All experimental compositions performed
OF Mg AND Si) - Plots are shown in Figures 12 and 13 similarly in filiform corrosion tests. Although the new
which demonstrate composition effects on artificially 6XXX alloy (high Mg and Si; low Cu) exhibited the same
aged strengths. Two -T62 type aging conditions were 36 number of corrosion sites (seven total sites for each
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- -
- -
-
Low Si
...
. . ..
-
High Si
.. -
Increasing %Mg
I I I I I
- -
- ,\
-
-
Increasing %Mg
-
EFFECTS OF COPPER ADDITIONS ON
PERFORMANCE ( LABORATORY STUDY) - Many
Low Si
properties were not significantly affected by the 0.2%
copper additions studied here (i.e., elongations, strain
0.0 I I I I I hardening exponent (n), and LDH values). Copper did
0.0 0.1 0.2 0.3 0.4 0.5 0.6
appear to be somewhat beneficial to -T4 and -T62
True thickness strain
strengths as well as formability performance in biaxial
stress states (bulge).
Figure 11: Strain Hardening Behavior SUMMARY OF PERFORMANCE IN LABORATORY
for High Mg Samples
EXPERIMENTS - Based on the experimental results, the
highest solute compositions (upper right-handcorner
compositions) exhibited the best overall combination of
alloy) as the 6016 alloy in filiform corrosion evaluations,
properties. Not only did these alloys show excellent
the average length of sites within the new alloy
stretchability in LDH and hydraulic bulge tests, but they
(1.02 mm) was about 112 of the value measured for the
were also able to attain yield strengths following artificial
6016 alloy (2.03 mm). This suggests that the rate of
aging practices which were approximately 20-25%
attack for the new 6XXX alloy was not as great as that of
higher than any other experimental alloy. In addition to
AA 6016, even though the initiation rate might have been
its forming and strength capabilities, the low copper
similar.
37 version of this alloy exhibited similar or better filiform
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ratio (r), and LDH values as well. The height which it
attained prior to failure in LDH tests was higher than all
other alloys including AA 2008 and AA 61 11. This data
Increasing %Mg
again illustrates the good forming capabilities of this new
material.
Figure 13b: Experimental Results -T6 STRENGTHS (AFTER ARTIFICIAL AGING) -
of Laboratory Fabricated Sheet Strengths after artificial aging were evaluated since
> Tran. TYS @ 2% Str.+20min/185C (MPa) < - automotive manufacturers often require certain minimum
strength levels for dent resistance and/oi structural
purposes. These strengths have to be attained from the
corrosion resistance than AA 6016. Therefore, the upper brief thermal practices which are already in place in
right-hand corner composition was the basis for the alloy automotive assembly plants (i.e., paint bake operations).
fabricated at an Alcoa rolling mill facility. The target Mg, In rare cases, auxiliary thermal practices are also utilized
Si, Fe, and Mn levels for this material were the same as (in addition to paint bake practices) as a means to
those used for the original laboratory study. However, improve strengths through artificial aging.
copper levels were controlled between 0.02% and 0.10% Two thermal practices were chosen for evaluation.
in order to minimize corrosion susceptibility while First, the 20 min.lI85"C (without pre-strain) aging
maximizing the benefit to formability and strength. practice was chosen to simulate strengths which could
be attained during a typical paint bake operation.
EXPERIMENTAL RESULTS - PLANT TRIAL Second, the 60 mid204"C aging practice was chosen to
simulate strengths which could be achieved assuming an
As described in the previous section, one GXXX alloy auxiliary thermal operation was added to existing paint
from the laboratory study was chosen for a plant trial. bake practices.
The alloy chosen showed the best overall The new GXXX alloy is not quite as strong as
formability/strength/corrosion resistance performance AA 61 11 following an artificial aging practice of
within the laboratory experiments. The intent of the plant 60 min1204"C (which is near peak strength), however, it
trial was to verify the performance observed in laboratory is stronger than 61 11 after a simulated paint bake
experiments. operation. Although the new alloy may not be able to
38
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..
lative Formabll~tvcT43
1Hl204C 20min/185C
Yield Yield
Strength Strength Filiform **
Alloy Temper (MPa) (MPa) (Ranking)
reach the same peak strengths as AA 6111, the aging Is more resistant to filiform corrosion compared to the
kinetics of the new alloy are more rapid (compared to 2008-T6,2036-T6,6009-T6,6016-T6,and 6111-T6 body
611I ) , enabling it to reach higher strengths during sheet alloys.
shorter time periods. Since aluminum ABS alloys most
often have only brief paint bake thermal operations Based on the data determined in this program and
(15-30 minutes at high temperatures) as a means to the performance of the newly developed alloy, the
achieve artificial aging, it would follow that alloys which following additional conclusions are justified:
attain higher strengths after relatively short periods of
time would be most desirable. Si additions provide simultaneous increases in
-
-T6 DURABILITY The relative filiform rankings listed stretchability and strength of 6 X M aluminum alloys.
for the various alloys in Table 1 show that, in general,
the lower copper alloys are more resistant to filiform Mg additions increase the strength of 6 X M aluminum
attack. It is not surprising that the low copper 6XXX automotive sheet alloys but can also decrease
alloys which were tested in the laboratory phase of this formability in certain cases.
program exhibited the best filiform corrosion resistance.
Their resistances would perhaps be expected to be Uniform elongation predicts plane strain stretching
similar to those of 5XXX alloys which normally are performance more effectively than strain hardening
considered to be excellent. exponent (n).
Results from this study and from studies conducted
previously suggest that alloys containing higher amounts REFERENCES
of copper might be more susceptible to filiform corrosion
attack [5]. This is not to say that filiform corrosion attack [ I ] Story, J. M., Jarvis, G. W., Zonker, H. R. and
could not be prevented in alloys containing higher Murtha, S. J., "Issues and Trends in Aluminum
amounts of copper. Rather, other studies have shown Automotive Sheet Forming," SAE Paper No. 930277.
that a proper coating system (coating + sample [2] Fuhrer, P., "Aluminum Car Body Sheets A -
preparation) can prevent filiforrn corrosion from occurring Continuing Optimization Process,"l?ASELM '91' [Proc.
[5,8]. Previous observations have shown that when the Conf.], Tokyo, Japan, 1991 October, Japan Institute of
coating does not provide adequate protection, filiform Light Metals, Nihonbashi, Asahiseimei Bldg.,
attack can occur 151. When the coating system is not 1-3 Nihonbashi 2-chome, Chuo-ku, Tokyo 100, Japan,
optimum, then the resistance of the parent material 1991, pp. 1171-1178.
would presumably become more important. Overall, [3] Decaillet, C., Millet, P. and Saur, E., "Recent
robust coating systems in combination with the new Developments in Aluminium Manufacture for Car Body
6XXX alloy are expected to provide excellent resistance Panels," Int. J. of Vehicle Design, Vol. 11, No. 3, 1990.
to filiform corrosion. [4] Fortin, P. E., Bull, M. J. and Moore, D. M., "An
Optimized Aluminum Alloy (X6111) for Auto Body Sheet
CONCLUSIONS Applications," SAE Paper No. 830096.
[5] Powers, John H.," Filiform Corrosion Resistance
An experimental program was conducted to study the of Painted Automotive Body Sheet," SAE Paper
effects of certain alloy additions on the properties and No. 910556.
characteristics of 6XXX auto body sheet alloys. As a [6] Youngsuk, K. and Park, K., "A Plane Strain Punch
result, a new 6XXX-T4 automotive body sheet alloy Stretching Test for Evaluating Stamping Formability of
(patent pending) has been developed which has a better Steel Sheets," Metallurgical and Materials Transactions
combination of formability, strength, and corrosion A, Vol. 25A, 1994 October, pp. 2199-2205.
resistance compared to all other aluminum alloys [7] Sachdev, A. K., "Development of an Aluminum
currently available. Specifically, the alloy: Sheet Alloy With Improved Formability," Met Trans.,
Vol. 21A, 1990 January, p. 165.
Is more formable than most heat treatable alloys (81 Bloeck, M. and Timm, J., "Aluminum Auto Body
available today including 2008-T4, 2036-T4,6009-T4, Sheet of the AlMgSi Alloy Family," Aluminium, Vol. 70,
6016-T4, and 6111-T4. NO. 1/2 (1994), pp. 87-93.