Chapter 15
Chapter 15
Chapter 15
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CHAPTER (15)
CHEMISTRY IN SOCIETY
( )
1. Chemistry In Moderm Agriculture ( )
- The world population is increasing day by day and year by year.
- There is an urgent need for increasing food production to need the increasing
population.
* Chemistry In Moderm Agriculture ( fertilizer
( soil reaction insecticides growth
of substance
* Fertilizer Elements
* Photosynthesis reaction (
- In the presence of sunlight the green part of the plants can bring about a chemical
reacton that combines carbon dioxide and water to form sugar which is futher con-
verted to other food forms and stored in the plants . This chemical reaction is known
as photosynthesis reaction.
* What is an photosynthesis reaction?
sunlight
6CO2(g) + 6H2O →
greenpart
C6H12O6(s) + 6O2(g)
sunlight
carbon dioxide + water →
greenpart
glucose + oxygen
* Write down the equation for photosynthesis reaction.
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*Fertilizers (
- Fertilizers are substances that supply nutrients to plants.
Fertilizers
↓ ↓
Natural fertilizers Chemical fertilizers
(
↓ ↓ ( salt and other chemical compounds
Manure Humus ( containing elements necessary
( is obtained by the ( comes from plant residues) for plant growth)
decomposition of animal
dung and urine)
↓ ↓ ↓
Nitrogen fertilizers(N) Phosphorus fertilizers(P) Potassium fretilizers(K)
(i) Urea, CO(NH2)2 (i) Super phosphate, (i) Potassium chloride,KCl
Ca(H2PO4)2.2CaSO4
(ii) Ammonium sulphate, (ii) Bone meal, (ii) Potassium sulphate,
(NH4)2SO4 (3% of N2 and 22%H3PO4) K2SO4
(iii) Ammonium nitrate, NH4NO3 ( prepared by crushing defatted bone)
(iv) Sodium nitrate , NaNO3 ( not chemical fertilizers)
(v) Calcium nitrate,Ca(NO3)2
Urea
- Urea, CO(NH2)2 contains 46% of nitrogen.The application of urea to soil increases
the acidity of the siol.
Production of urea
- Urea is manufactured on a very large scale by heating ammonia and carbon dioxide
uder pressure with a suitable catalyst.
Δ , pressure
CO2(g) + 2NH3(g) →
catalyst
CO(NH2)2 (s) + H2O(g)
Δ , pressure
carbon + ammonia →
catalyst
urea + water
Reaction in the soil with urea
CO(NH2)2 (s) + H2O(l) → CO2(g) + 2NH3(g)
urea + water → carbon + ammonia
Cement
- Cement is the substance used in teh construction of building. It is a grey powder. It
is composed of lime, alumina , sillica and irom (III) oxide.
The chief compounds present in cement
- The chief compounds present in cement are lime, alumina, silica and haematite
(iron(III) oxide) as; (i) tetracalcium alumino-ferrate , 4CaO.Al2O3.Fe2O3
(ii) dicalcium silicate , 2CaO.SiO2 (iii) tricalcium silicate , 3CaO.SiO2
(iv) tricalcium aluminate , 3CaO.Al2O3
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Raw materials for making cement
(i) Haematite, Fe2O3 (ii) Clay , SiO2 and Al2O3
(ii) Limestone , CaCO3 (iv) Gypsum , CaSO4.2H2O
Main stages in manufacturing process of cement
- The four main stages of manufacturing process of cemnent are;
(i) Mixing (ii) Cooling
(iii) Heating (iv) Grinding
Salt production
- Sea water contains about 3.5% of salts by weight out of which 2.7% by weight of
common salt,NaCl is dissolved.
The undissolved and dissolved substances in sea water as follows;
1. Suspensions
undissolved 2. Al2O3
substances 3. CaCO3
4. CaSO4
1. NaCl
dissolved 2. KCl
substances 3. MgSO4 increasing solubilities
4. MgBr2
Common salt
- Common salt becomes damp due to the presence of magnesium chloride
(hydroscopic substance) . It can absorb moisture from the air.
Bittern
- The water that flows out from the fith solar pond consists of dissolved MgSO4 ,
MgCl2 and MgBr2 . This water is called bittern.
Disadavantages of the Traditional Method of production of NaCl
(1) The persentages of the different impurities are high in the common salt.
(2) Forest are destroyed because of the falling of trees for firewood. That makes
forest depletion.
(1) Solar energy is free and therefore salt produced by this method is relatively
cheap. In addition,forests are conserved because no firewood is required.
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Effect of N P K on plants NPK
Nature of plants N P K
- Root crops (sweet potatoes) very little fair amount good amount
Insecticides
- Insecticides are chemicals that kill insects.
Some insecticides are ;
-BHC ( benzene hexa chloride,C6H6Cl6 of Gammaxene) Endrin, Aldrin and Dieldrin.
-Aldrin and Dieldrin are used as soil fumigant .
-BHC is used for spraying or dusting of plants,especially cotton.
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Growth substances or Plant hormone
- IAA (Indoleacetic acid ) is a chemical that uses for growth of plants. It activates the
growth of leaves, stems, roots, flowers, fruits and seeds.
- NAA ( Naphthalene acetic acid) can be produced more cheaply, shows similar
activites to IAA.
Acidity or Alkalinity of the soil
- Acidity or Alkalinity of the soil is one of the important factors because the plants do
not grow well on the soil of high acidity or high alkalinity.
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Plastic and Polymer
* Polymer
- Polymer are large organic macromolecules.They are made up of small repeating
units known as monomers.
e.g - protein, carbonhydrate, wood and natural rubber are all ploymers.
* What is meant by the term Polymer? Give any two examples of natural polymers.
* Homopolymer
- Some polymers are homopolymer, containing just one monomer.
* Copolymer
- Copolymers are polymers made up of two or more different types of monomer.
* Condensation polymerization
Nylon ( polyamide or polypeptide)
- Nylon is the condensation polymer formed from two different monomers, a diamine
and a dicarboxylic acid . From the two monomers,element of water is eliminated from
the condensation reaction producing a polymer containig a peptide linkage.Thus nylon
is known as a polyamide.
polyamide
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* Polyester(
- Polyster are condensation copolymers made from two monomers. One monomer has
an alcohol group(–OH) at each end. The other monomer has a carboxylic acid group
(– COOH) at each end. When the monomers react, an ester link is formed, with water
being lost each time.
(–OH)
O
(–COOH) (–C–O–)
(b) What type of polymerization can udergo by using the following compound? Write
down the equation.
* Addition polymerization
- Alkenes such as ethene contains a double bond, C = C. These molecules can taken
part in addition reaction. The double bond is broken and other atoms attach to the
carbons. Many ethene molecules enables to join in each other to form a large molecule
poly(ethene).
ethene alkene
addition reaction atom
ethene molecules
polyethene polythene
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Addition polymerization
* Polyethene (PE)
H H high prssure H H
n C=C C – C
H H Δ , catalyst H H n
ethene polyethene(polyethylene)
* Polypropylene (PP)
H H high prssure H H
n C=C C – C
H CH3 Δ , catalyst H CH3 n
peopene(propylene) polypropene(polypropylene)
H H high prssure H H
n C=C C – C
H Cl Δ , catalyst H Cl n
vinyl chloride polyvinyl chloride
* Polytetrafluoroethene (PTFE)
F F high prssure F F
n C=C C – C
F F Δ , catalyst F F n
tetrafluoroethene Polytetrafluoroethene
* Polystyrene (PS)
H H high prssure H H
n C=C C – C
H C6H5 Δ , catalyst H C6H5 n
styrene Polystyrene
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* Thermoplastic polymers
- They are polymers. They can be softened on heating and melted. They set again
when cooled and can be re-moulded. eg ; poly(ethene),poly(chloro ethene) ,(PVC ).
* Thermosetting polymers
- They are polymers. They can be heated and moulded only once. eg; melamine.
The chains in these polymers are cross-linked to each other and are permanend
chemical bonds.
*Recycling of thermoplastic polymers
(i) heat at low temperature
(ii) obtain molten or softened polymer
(iii) re-mould into new thermoplastic product(s).
*Recycling of Thermosetting polymers
(i) heat at high temperature (700 � C )in the absence of air
(ii) obtain new monomers and other chemicals
(iii) re-polymerise into new product(s).
*Chemical from coal
- The chemicals which can be obtained from coal are ammonia,coal gas, coal tar and
coke.
* What are the methods for recycling platic wastes?
* The methods for recycling platic wastes.
*Soap
- Soap is the sodium salt of fatty acid formed from the chemical reaction of oil or fat
molecule with caustic soda .
H35C17-COOCH2 HO–CH2
glyceryl + sodium → sodium + glycerol
tristearate hydroxide stearate
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Soapless detergent
- Soapless detergents do not form scum with hard water since they do not react with
Ca2+ and Mg2+ present in such water. The soapless detergents are designed so that they
are biodegradable. Bactria readily break down these new molecules so that they do not
persist in the enviroment.
CHAPTER 15
QUESTION AND PROBLEM
1. What are the long forms of BHC and POP, NPK, IAA, NAA?
6. A field of rice needs 15 kg nitrogen per acre. How many kilograms of ammonium
nitrate are required for 10 acres? (N = 14, H = 1, O = 16)
7. A field of rice needs 20 kg nitrogen per acre. How many kilograms of ammonium
nitrate are required for 100 acres? (N = 14, H = 1, O = 16)
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11. How many types of fertilizers are there? What are they?
13. What are fertilizers? Give relevant explanation for the addition of lime and also
of gypsum to the soil.
14. Discuss the natural fertilizers. What are the natural fertilizers?
15. What are chemical fertilizers? Name the two elements that are essential for plants
growth?
16. What are chemical fertilizers? Name the elements that are essential for the growth
of plants.
19. How many amount of N, P and K are required for root crops?
20. Which element (s), N or P or K is most suitable for seed bearing plants and for
leaf crops?
21. Which element, N or P or K is most suitable for growing cabbage? Give reason.
22. Which element, N or P or K is most suitable for fruting and for Leaf crops?
24. Write the names and formulae of two important nitrogen fertilizers.
25. Write equation in words and symbols for the production of urea.
27. What is the reason for the addition of urea to the soil? Illustrate and equation for
the reaction of urea in the soil?
28. What is the reason for the addition of urea to the soil? Illustrate an equation for
the manufacturing of urea?
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29. Write an equation for the reaction of soil urea with water.
30. What are chemical fertilizers? What is the reason for the addition of urea to the
soil?
36.(i) How would you prepare the bone meal? Is it a chemical fertilizers?
(ii) Describe the substances contained in the bone meal.
38. Explain why acidity and alkalinity of the soil is one of the important fators.
39. How can you test the soil reaction? Explain it.
40. Describe how would you neutralize the acidity and alkalinity of soil.
41. Give relevant explanaitons for the addition of lime and gypsum to the soil.
48. What are the raw materials for the production of cement?
49. What are the four important stages in the manufacture of cement?
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50. Why is gypsum mixed withclinker and ground in the final state cement produc-
tion?
51. Describe the preparation of plaster or paris from gypsum.
52. Write down the chemical composition of POP. Illustrate its uses.
55. Arrange the substances that dissolve in sea water according to their increasing
solubilities.
56. Describe the substances that remain in solution after the crystallization of sodium
chloride from sea water.
57. Describe the substances that separate out from sea water before the crystalliza-
tion of sodium chloride.
58. Why does common salt become damp when it is exposed to the air?
60. What are the disadvantages for the production of common salt by the traditional
method?
61. Write down the advantages of salt production by solar evaporation. (any two)
64. What is meant by terms “polymers”? Give any two examples of natural polymers?
67. What are the long terms of the following substances? PTEE, PVC, PP, PS?
68. What is the long form of PS and PVC? Mention its uses?
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1.Write TRUE or FALSE for the following statements.
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12. Bone meal is a [natural; chemical; physical] fertilizer.
13. Bone meal is used as [nitrogen; phosphate; potassium] fertilizer.
14. The urea fertilizer is produced as [grey; brown; white] pellets.
15. Natural fertilizers are more preferrable than [chemical; neutral; physical] fertilizers.
16. An important nitrogen fertilizer is [urea; ammonium sulphate; ammonium nitrate].
17. The function of soil batteria is to convert ammonia to [nitrate; sulphat; chloride].
18. Over use of [human; manure; chemical] fertilizer changes the acidity of soil.
19. [Gypsum; Lime; Urea] is used to neutralize the soil acid.
20. [Roots; Branches; Stems] of plants absorb the food from the soil in the form of soluble
salts.
21. [Flowering plants; Seed bearing plants; Root crops] require good amount of
phosphorus.
22. [Urea; Ammonium nitrate; Ammonium sulphate] is manufactured on a very large scale by
heating ammonia and carbon dioxide under pressure with a suitable catalyst.
23. Leaf crops require abundant [phosphorus; nitrogen; potassium].
24. Application of urea to the soil increases the [basicity; neutrality; acidity] of the soil.
25. [Nitrogen; Potassium; Phosphorous] is not a constituent element of the plant body.
26. Leaf crops like cabbage require a fair amount of [nitrogen; phosphorus; potassium].
27. The percentage of nitrogen in urea is [46%; 64%; 32%].
28. Root crops require a good amount of [nitrogen; potassium; phosphorous].
29. [NPK; IAA; Aldrin] is toxic to mammals and should be used with caution.
30. [Nitrogen; Hydrogen; Oxygen] is an essential and important constituent of the plant's body.
31. Soil supplies [carbon dioxide; urea; water] and other elements to plants.
32. Gypsum used in cement is to [improve the building capacity; increase the bulk
volume; regulate the setting time].
33. Gypsum is [CaSO4.H2O; 2CaSO4.H2O; CaSO4.2H2O].
34. Plaster of Paris is a fine white powder having the molecular formula [CaSO4.H2O;
CaSO4.2H2O; 2CaSO4.H2O].
35. [Lime stone; Cement; Plaster of Paris] is substance which is more widely used in the
construction of buildings.
36. Terylene clotheing is generally soft than that made from [nylon; teflon; PVC].
37. Monomer of polystyrene is [CH3CH=CH2; C6H5CH=CH2; CF2=CF2].
38. [CH3CH=CH2; CH3CHCl; CH3COOH] will undergo addition polymerization.
39. [CH2=CH2; CH3CH2Cl; HOCH2CH2OH] will undergo addition polymerization.
40. [Vinyl chloride; ethyl chloride; ethanoic acid] will undergo addition reaction.
41. All living things contain [polymers; monomers; copolymers].
42. [Polystyrene; Polyester; Polyethene] is copolymer.
43. Synthetic polymers, often called [platics; biogas; biomass].
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44. Polymers are large organic [macromolecules; large molecules; big molecules].
45. Polymers are made up of small repeating units known as [monomers; so ap;
detergents].
46. Alkenes molucules can take part in [addition reaction; substitution reaction;
displacement reaction].
47. The trade name for polyamide is [nylon; teflon; PVC].
48. Fats and oils are [mono; di; tri] glycerides.
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4.Match each of the items given in List A with the appropriate items given in List B.
List A List B
1. (a) Alternative fuels (ii) other than crude oil, coal and
natural gas
(b) Petrol (iv) gasoline
(c) Kerosene (vi) paraffin
(d) Petroleum (i) crude oil
(e) CNG (vii) compressed natural gas
(f) LPG (iii) liquid petroleum gas
(g) A fraction (v) hydrocarbons of closed boiling
points
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2. Fill in the blanks with correct word or words of following statements.