Applied Energy: Eoghan Mckenna, Marcelle Mcmanus, Sam Cooper, Murray Thomson
Applied Energy: Eoghan Mckenna, Marcelle Mcmanus, Sam Cooper, Murray Thomson
Applied Energy: Eoghan Mckenna, Marcelle Mcmanus, Sam Cooper, Murray Thomson
Applied Energy
journal homepage: www.elsevier.com/locate/apenergy
h i g h l i g h t s
" No business case for lossless lead-acid batteries for PV with UK feed-in tariff.
" Business case considerably worse with realistic battery.
" Battery’s negative environmental impact further strengthens argument against use.
a r t i c l e i n f o a b s t r a c t
Article history: Occupants of dwellings with grid-connected photovoltaic (PV) systems can often benefit financially from
Received 1 October 2012 exporting electricity to the grid. When export prices are lower than import prices, however, occupants are
Received in revised form 6 November 2012 incentivised to time-shift demand in order to avoid exports and reduce imports. To maximise this poten-
Accepted 7 November 2012
tial financial benefit, the addition of batteries to the PV system has been proposed to take advantage of
the specific commercial opportunity presented to the occupant of trading exported power during the day
for imported power during the evening. This paper therefore assesses the economic and environmental
Keywords:
impact of the use of lead-acid batteries in grid-connected PV systems under current feed-in tariff arrange-
Lead-acid battery
PV system
ments in the UK. The development of a lead-acid battery model is described, which is used to simulate
Feed-in tariff hypothetical power flows using measured data on domestic PV systems in the UK. The simulation results
Environmental impact indicate that the net benefit of the battery is negative, even when considering an idealised lossless
battery. When realistic energy losses and lifetimes are accounted for, the financial loss for the systems
considered here can approach £1000/year. The environmental impact of the use and production of the
lead-acid battery is also described, and also found to be negative, further strengthening the argument
against the use of lead-acid batteries in domestic grid-connected PV systems.
Ó 2012 Elsevier Ltd. All rights reserved.
0306-2619/$ - see front matter Ó 2012 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.apenergy.2012.11.016
240 E. McKenna et al. / Applied Energy 104 (2013) 239–249
mental impact of battery production [7], by also considering the in- mised for grid-connected systems, nonetheless it is assumed that
use environmental impacts of the battery for such applications. batteries for these two applications will have broadly similar char-
The approach taken in this paper is to develop a model of a lead- acteristics. Three battery sizes from the PVStor range are consid-
acid battery, which is applied to recorded data from UK dwellings ered, detailed in Table 1. A 48 V battery system has been chosen,
with PV systems. The model is used to simulate hypothetical as this is the voltage level specified for the chosen inverter (de-
power flows for the PV system with battery. Section 3 describes scribed in Section 3.7).
the development of the battery model, and the method used to cal-
culate the simulated power flows, cost benefits, and environmental 3.1. Battery charge and discharge voltage
impacts associated with the battery. Section 4 then presents and
discusses the results of the economic and environmental analysis, Fig. 1A has been adapted from the manufacturer’s data sheet
with Section 5 providing the concluding remarks. and shows battery cell voltage as a function of state of charge for
varying rates of charge and discharge. The top four lines represent
the charge voltages, while the bottom four represent discharge
2. Feed-in tariffs and the financial benefits in time-shifting
voltages. The different currents are indicated by ‘C’ values. C100 re-
demand
fers to a constant current that would fully discharge the battery
over a period of 100 h. For a 430 A h battery, C100 is equal to
This paper considers domestic grid-connected PV systems on a
4.3 A, and C10 is equal to 43 A. For a 210 A h battery, C100 is
current UK feed-in tariff, which consists of a generation price
2.1 A, and so on. C values have the same magnitude for both charg-
(21.0 p/kW h at the time of writing) paid for generated units, and
ing and discharging. The general relationship is as follows:
an export price of 3.2 p/kW h paid for exported units [8]. An import
price of 11.8 p/kW h has been assumed, which is a typical value for C nominal
Cn ¼ ð1Þ
a domestic consumer on a ‘standard’ flat-rate demand tariff [9]. n
In this context, occupants with PV systems can benefit finan-
where n is the discharge time (h), Cn the ‘C’ value for a discharge
cially by using electricity generated by their PV rather than export-
time n (A), and Cnominal is the nominal capacity of the battery.
ing it to the grid [10]. Occupants could typically achieve this by
changing their behaviour or routines in order to shift their demand
3.2. Voltage efficiency
to the middle of the day when their PV is generating [11], for
example by eating a hot meal at lunch rather than dinner, or with
It can be seen from Fig. 1A that, for a given state of charge, the
the help of technology such as timers, that can delay when appli-
rate of discharge has less effect on the voltage compared to the rate
ances are switched on.
of charge. As a result, in the model, the voltage efficiency is applied
A further option available to the occupants, considered here, is
to the charge phase and not the discharge phase. The model there-
the use of battery storage [12]. In the UK context, the battery is
fore estimates the voltage efficiency as a function of the state of
charged during the day using cheap surplus PV generation, and dis-
charge and rate of charge. Fig. 1B shows the voltage efficiency
charged during the evening and night, to avoid the expensive im-
which is estimated here as the ratio of the discharge voltage over
ports from the grid [3]. Note that battery systems of this type are
the charge voltage, taken at the same rate of charge and discharge.
commercially available for this purpose in the UK [13,14].
As expected, efficiencies tend to be lower at high state of charge,
and high currents.
3. Method
3.3. Coulombic efficiency
This section describes a novel method for developing a realistic
lead-acid battery model. The battery model is empirical, using The effect of state of charge on coulombic efficiency is esti-
existing work as input data – the novelty lies in how this data is mated from Stevens [19], which gives empirical data for coulombic
combined in order to create a realistic model. The authors note that efficiency at different states of charge for a valve regulated lead-
there are numerous other approaches to modelling lead-acid bat- acid battery used in PV applications. Coulombic efficiency is de-
teries in PV systems and refer interested readers to [3,15–17]. fined here as amp-hours output over amp-hours input. This data
The model estimates the battery efficiency under varying rates is reproduced in Fig. 2A, and shows the reduction in coulombic effi-
of charge and discharge, as well as varying states of charge. Oper- ciency associated with incremental changes in battery state of
ational energy losses are quantified using the concepts of voltage charge. Stevens only gives data for states of charge above 70%,
efficiency and coulombic, or charge, efficiency. The overall energy though this is sufficient for this battery model because a minimum
efficiency of the battery can be viewed as the product of the bat- state of charge of 60% is used.
tery’s voltage and coulombic efficiencies. Fig. 2A shows that, while coulombic efficiency is high for states
The voltage efficiency reflects the fact that charge is removed of charge below 70%, it decreases considerably as the battery
from a battery at low voltage, while charge is added to it at a higher reaches a fully charged state. Intuitively, this reflects the fact that,
voltage. This difference in charging and discharging voltage inevi- as the battery is charged, it becomes increasingly difficult to charge
tably results in energy losses. it further. Note that Stevens’ experiment only tested a single rate of
Coulombic efficiency reflects the fact that more charge has to be charge and discharge, in this case a value close to the battery’s
put into the battery than it is possible to subsequently remove. nominal discharge rate. In the model, as a matter of choice, the
Coulombic efficiency, in particular, is adversely affected by rapid coulombic efficiency as a function of state of charge is applied to
charging and rapid discharging. Due to the ‘peaky’ nature of the battery charging cycle, though it could equally have been ap-
domestic dwelling demand [18], losses associated with rapid dis- plied on the discharge cycle.
charging will be particularly significant for the application consid- The effect of the rate of discharge is considered independently.
ered in this paper. Finally, both voltage and coulombic efficiency This is estimated from data from the manufacturer describing the
are also reduced at high states of charge [19]. available battery capacity (in A h) as a function of varying rates
The model is based on the data sheet of a BP Solar ‘PVstor’ of discharge [20]. Table 2 reproduces the data for the 430 A h bat-
valve-regulated lead-acid battery [20], which is designed for use tery. This shows that the capacity available is decreased if the bat-
in stand-alone PV systems. While these batteries may not be opti- tery is discharged at higher currents. A second, independent
E. McKenna et al. / Applied Energy 104 (2013) 239–249 241
Table 1
Details of the batteries used in the study.
voltages and separate converters are more likely to be ‘off the shelf’
components, as well as to avoid losses in the battery before the
units generated by the PV are metered by the generation meter.
Note that a technical comparison of different system configura-
tions is out of scope of this paper.
Battery power flows are then calculated as follows. The battery
is charged when the following conditions are met:
P pv > P d and SOC < SOC max
Fig. 1. Voltage efficiency used in the battery model. The battery is disconnected when either the minimum state of
charge SOCmin (60%) or maximum state of charge SOCmax (100%) is
reached. This constraint has been imposed in order to ensure max-
coulombic efficiency is therefore estimated as the ratio of the imum battery life as per the manufacturer’s recommendations
capacity available at a given discharge rate compared to the capac- [20].
ity available at nominal discharge rate (C100). This is shown as a The battery charging current is then calculated as:
function of discharge current in Fig. 2B for the three battery sizes
considered here. In the model, this coulombic efficiency is applied
ginv ðPd Ppv Þ
Ibat ¼ ð2Þ
to the discharge phase. When modelled in this way, the round trip V bat
efficiency for a full charge followed by a full discharge at C100 is Charging current is limited to C13 (33 A for a 430 A h battery),
approximately 73%. For C10, the round trip efficiency is 44%. Note based on battery manufacturer’s recommendations [20].
that these round-trip efficiencies are for illustration only – the The charge entering the battery (Qcharge) is then calculated by:
operation of the battery in the model does not use full discharge
Q charge ¼ gv oltage gSOC Ibat t ð3Þ
cycles.
The minus sign is necessary because charging currents are taken
3.4. Calculation of power flows as negative in the model.
State of charge in time interval i is then:
The battery efficiencies described above are then applied to the
SOCðiÞ ¼ SOCði 1Þ þ Q charge ð4Þ
system shown in Fig. 3. This presents a one-line diagram showing
the major electrical components of the PV system with battery The battery is discharged when the following conditions are
storage that is modelled in this paper. A description of the variables met:
used is provided in Table 3. The PV system shown here is fully me-
P pv < P d and SOC > SOC min
tered, as it includes an export meter as well as a generation meter.
Note that the battery is connected via a DC–AC converter to the In which case the battery discharge current is given by:
consumer unit (distribution board), and not connected via DC to
Pbat
the PV, as for example is proposed by Braun et al. [5]. This is for Ibat ¼ ð5Þ
ginv V bat
practical considerations, as the PV and battery have different DC
242 E. McKenna et al. / Applied Energy 104 (2013) 239–249
Table 2
Discharge characteristics of the 430 A h battery at varying rates of discharge at 25 °C.
Hours for full discharge Discharge current (A) Capacity available (A h) Coulombic efficiency (%)
C0.5 0.5 194.00 97 23
C1 1 110.00 110 26
C2 2 64.00 128 30
C3 3 50.67 152 35
C4 4 39.50 158 37
C5 5 33.20 166 39
C6 6 29.83 179 42
C7 7 27.29 191 44
C8 8 27.13 217 50
C9 9 26.11 235 55
C10 10 25.50 255 59
C25 25 12.32 308 72
C50 50 7.22 361 84
C100 100 4.30 430 100
Variable Description The operation of the battery will reduce exports and imports.
Ppv PV generation (kW)
The reduction in exports is an opportunity cost to the system own-
Pe PV output exported to grid (kW) er, while the reduction in imports is a benefit due to avoided costs.
Pi Electricity demand imported from the grid (kW) The economic benefit associated with the battery in time interval i,
Pnet = Pe Pi Dwelling’s net power flow (kW) mnet ðiÞ, is calculated by:
Pd = Ppv Pnet Consumer electricity demand (kW)
Pbat Power from battery (kW)
Ibat Current from battery (A) mnet ðiÞ ¼ DmðiÞ DcðiÞ ð8Þ
Vbat Battery voltage (V)
SOC Battery state of charge (%) where Dm(i) is the change in income to the occupant in time inter-
ginv Battery inverter efficiency
val i associated with the battery. This is the difference between the
gvoltage Battery voltage efficiency
gSOC Battery coulombic efficiency due to state of charge income to the occupant associated with generation and export pay-
gdischarge Battery coulombic efficiency due to rate of discharge ments with the battery and the equivalent income without the bat-
t Time (h) tery. For example, if the battery reduced exports in time interval i,
then Dm(i) would be negative.
Dc(i) is the change in costs to the occupant in time interval i
Discharge current is limited to C5 (86 A for a 430 A h battery), associated with the battery. This is the difference between the cost
again based on manufacturer’s recommendations. The charge leav- of electricity consumed within the dwelling with the battery com-
ing the battery (Qdischarge) is then given by: pared to the equivalent cost of electricity without the battery. For
example, if the battery reduced imports in time interval i, then
Ibat t
Q discharge ¼ ð6Þ Dc(i) would be negative, as costs would be reduced.
gdischarge The estimate of the total economic benefit of the battery (not
State of charge in time interval i is given by: including equipment costs) is then given by the sum of mnet over
the course of a whole year for the dwellings described in the fol-
SOCðiÞ ¼ SOCði 1Þ Q discharge ð7Þ lowing section.
E. McKenna et al. / Applied Energy 104 (2013) 239–249 243
3.6. Description of data used in the analysis battery. While a full Life Cycle Assessment was not undertaken, a
life cycle approach was taken, following the ISO Standards
In Fig. 3, power flows denoted with an asterisk indicate where [27,28]. This was done using SimaPro software, and was originally
recorded data on domestic dwellings with installed PV in the UK described by McManus [7]. Three environmental issues have been
has been used from the Photovoltaic Domestic Field Trial (‘‘DFT’’) assessed; the impact on greenhouse gases (GHGs), fossil fuel deple-
[21]. The battery model is used to simulate hypothetical power tion, and metal depletion. These were analysed using both IPCC
flows given the addition of a battery to the systems. In the model, data and the ‘Recipe’ LCA methodology [29]. The work has focused
the dwelling demands and PV generation are unchanged from on these three areas as previous research has shown these are
those of the DFT systems. The resolution of the data is 5 min. some of the major impact areas for battery use and production
The study uses data from two of the Domestic Field Trail’s sites. [7]. In addition, GHG and fossil fuel depletion are major policy driv-
The first site consists of data from 22 dwellings, and the second site ers within the energy arena, and the impact of metal depletion has
consists of data from 15 dwellings. Annual irradiances for the two been widely discussed as a potential area for concern associated
sites were 894.7 kW h/m2, and 892.8 kW h/m2, which are quite with the use and production of batteries [30].
typical for the UK [22]. The production impacts of lead-acid batteries per kg of battery
Note that the sizes of PV systems installed in the dwellings con- weight in terms of greenhouse gases, metal depletion, and fossil
sidered here range between 1.5 kWpeak and 3.29 kWpeak, while re- fuel depletion are 0.9 kg CO2eq, 0.4 kg Feeq, and 0.3 kg oileq respec-
cent installations in the UK are closer to 4 kWpeak. The applicability tively [7]. The contribution to greenhouse gases and fossil fuel is
of the results to more modern systems will be discussed in the predominantly associated with the extraction and processing of
results. lead and the polypropylene used in the battery production. The
contribution to metal depletion is dominated by the lead within
3.7. Battery inverter the battery. Note that this approach assumes a mix of virgin and
recycled materials is used in the battery production, based current
The battery inverter is based on the SMA Sunny Backup 5000 norms, as described by McManus [7].
[13], which includes battery charge regulator and power electronic
converter. The efficiency of the inverter is modelled on the effi-
ciency curve provided in this product’s manual. The inverter has 3.9.2. In-use impacts
a peak efficiency of 95.4% and efficiency of more than 91% through- The in-use impact of the batteries is associated with the time-
out most of its operating range. Note that this efficiency applies to varying environmental impact of grid-electricity [31]. From the
charging as well as discharging. The inverters are sized for the perspective of the national grid, the effect of adding a battery to
maximum discharge current of the batteries multiplied by the bat- a PV system (where previously there was none) is to increase de-
tery voltage, giving the inverter sizes shown in Table 1. mand during the day, when the battery is charging, and to decrease
demand during the evening, when the battery is discharging. These
3.8. Cost and lifetime of equipment changes in demand throughout the course of the day will result in
corresponding changes in generation from fossil fuel plant. More-
Costs were estimated as the cost of the equipment (battery and over, due to losses in the battery it can be expected that the in-
battery inverter) divided by its expected lifetime. Battery costs crease in daytime generation will be greater than the
have been estimated at $200/kWh from a Sandia National Labora- corresponding decrease in generation during the evening, meaning
tories Report [23]. The cost of the battery inverter has been that the battery will cause a net increase in fossil fuel generation,
estimated at £606/kW, based on lowest of three quotes for ‘SMA with a resulting negative environmental impact.
Sunny Backup systems’ produced from an internet search [24– To calculate how the changes in demand throughout the day
26]. The Sunny Backup has been chosen as it is a battery inverter associated with adding the battery to the PV system can be ex-
that is currently commercially available and designed for the pected to result in changes in generation from fossil fuel plant, data
purposes in hand. Table 1 shows the inverter sizes for the three from the UK balancing mechanism reports [32] was used to calcu-
batteries considered here. late the ‘responsiveness’ of gas and coal generation to historic
Inverter lifetime was assumed to be 10 years. Battery lifetime is changes in demand for each 5 min period in 2009–2011. Respon-
estimated from Jenkins’ design equation, which estimates the use- siveness here refers to the change in generation (in kW h) that is
ful lifetime for lead-acid batteries in grid-connected residential PV associated with a change in demand of 1 kW h.
systems as a function of the battery size and usage [6], as follows: For some time periods, a calculated responsiveness was unchar-
acteristically high or low due to operators switching from one
329:9 S plant type to another. To compensate for this effect, time periods
T¼ ð9Þ
Ee were grouped into 144 sets (one for each hour of the day for each
where T is the estimated battery lifetime (years), Ee is the annual ex- 2-month period of the year) and the weighted average responsive-
ports available from the PV system (kW h/year), and S is the battery ness of each plant type was calculated for each set. The average
capacity (kW h). was weighted by the absolute value of the change in total genera-
tion during each time period (Eq. (10)). The resulting values for the
3.9. Environmental impact responsiveness of coal and gas plant are provided for reference in
Appendix A.
The environmental impact is considered in two areas: produc- " !#
tion impacts, and in-use impacts. For both of these, the analysis DPgen X
hn
DPgen ðiÞ X
hn
¼ jDPtotal ðiÞj= jDPtotal ðiÞj ð10Þ
compares the impact associated with adding a battery to the PV Deltaptotal h i¼h1
DPtotal ðiÞ i¼1
systems considered here, compared to the same PV systems with-
out battery.
DP gen
where Deltaptotal
is the weighted average responsiveness of electric-
h
3.9.1. Production impacts ity generated by coal or gas plant to unit changes in total electrical
The production impact of lead acid batteries was determined by demand during the time periods in set h (h1 to hn), DPgen(i) the
examining the processes and materials contained within the increase in average electrical power generation from gas or coal
244 E. McKenna et al. / Applied Energy 104 (2013) 239–249
Table 4
Environmental impact of coal and gas generation.
Climate change (kg CO2eq) Metal depletion (kg Feeq) Fossil fuel depletion (kg oileq)
For 1 kW h electricity from gas generation 0.484 1.01 103 0.198
For 1 kW h electricity from coal generation 1.08 3.99 103 0.291
E. McKenna et al. / Applied Energy 104 (2013) 239–249 245
Fig. 8. Annual benefits for lossless and realistic batteries for multiple dwellings
Fig. 6. Cost benefit over the course of a single day. with PV in the UK.
Fig. 8 shows the resulting annual benefits to the occupants of of the battery inverter over the total energy into the battery inverter.
the dwellings considered here, in terms of reduced costs of elec- The mean round trip efficiency values are 39.1% for the 210 A h bat-
tricity, for the three sizes of realistic batteries (black markers). tery, 53.0% for the 430 A h battery, and 58.5% for the 570 A h battery.
The x-axis shows annual exports for the PV system without bat- Fig. 10 shows annualised equipment costs for the realistic bat-
tery, as the main purpose of the battery is to reduce these exports. tery (black markers), which can reach £1000/year for the larger
The benefits are low – for the larger systems shown here, which are systems considered here. The costs increase with available exports,
comparable to modern 4 kWpeak PV systems, the benefits of a bat- which reflects the reduction in battery lifetimes associated with
tery might amount to £30/year. battery wear, shown in Fig. 9B. Systems with high exports result
The low benefits shown in Fig. 8 are due to the battery inefficien- in greater battery wear, and shorter lifetimes. For large systems,
cies which are shown in Fig. 9A. This shows annual round-trip effi- comparable to modern 4 kWpeak PV systems, a 570 A h battery
ciencies for the different dwellings and battery size configurations. has an expected lifetime of 5.23 years, dropping to 1.93 years for
The round-trip efficiency is calculated here as the total energy out a 210 A h battery.
246 E. McKenna et al. / Applied Energy 104 (2013) 239–249
Fig. 10. Annual costs for lossless and realistic batteries for multiple UK dwellings Fig. 11. Annual net benefits for lossless and realistic batteries for multiple
with PV. dwellings with PV in the UK.
E. McKenna et al. / Applied Energy 104 (2013) 239–249 247
Table 5
– Battery weights and production impacts.
Battery Capacity Weight per cell Number of cells in Total battery weight Production impacts
(A h) (kg) battery (kg)
Climate change Metal depletion Fossil fuel depletion
(kg CO2eq) (kg Feeq) (kg oileq)
210 38 8 304 273.6 121.6 91.2
420 29 24 696 626.4 278.4 208.8
570 37 24 888 799.2 355.2 266.4
Table 6
Annual production and in-use impacts for 430 A h battery with 3.29 kWpeak PV system. Standard deviations shown in brackets.
Climate Change (kg CO2eq/year) Metal depletion (kg Feeq/year) Fossil fuel depletion (kg oileq/year)
Production impacts 127.5 (26.2) 56.6 (11.6) 42.5 (8.7)
In-use impacts 657.7 (137.3) 2.2 (0.5) 201.7 (41.9)
Total 785.1 58.8 244.2
In-use impacts (lossless battery) 5.09 (2.35) 0.0255 (0.0188) 0.79 (0.36)
248 E. McKenna et al. / Applied Energy 104 (2013) 239–249
the PV and consumed within the dwelling [34]. The result is an Western Australia [37]. These states have feed-in tariffs with ex-
‘effective export price’ of 29 c€/kW h–17 c€/kW h = 12 c€/kW h, port prices of 8 cAUD/kW h, which is 17 cAUD/kW h (10.93 p/
which is 8 c€/kW h cheaper than a typical import price of 20 c/ kW h) less than a typical import price of 25 cAUD/kW h. The im-
kW h. This results in an import export price ratio of 20/12 = 1.67. port export price ratio is therefore 3.13, which is again lower than
As described in Section 4.2, the minimum ratio needed to result the UK price ratio (3.69). The results of this paper are therefore also
in a benefit is 2.14 (for the 570 A h battery). Considering that applicable to Australian PV systems installed from late 2012
Germany has a solar resource that is not dissimilar to that of the onwards.
UK [22], it would appear that the present study’s conclusions Finally, note that this paper has only considered the economic
concerning the lack of business case for batteries in grid-connected benefit to the occupant associated with the use of the battery given
PV systems is also applicable to Germany. current feed-in tariff arrangements. It is quite possible however
The findings are also relevant to PV systems installed from late that there are additional economic benefits associated with this
2012 in the Australian states of Queensland [35], Victoria [36], and type of distributed storage, in particular to other stakeholders
Table 7
Weighted average change in electricity generated by coal to unit changes in total electrical demand in GB electricity market (data from 2009 to 2011).
Table 8
Weighted average response in electricity generated by gas (CCGT) to unit changes in total electrical demand in GB electricity market (data from 2009 to 2011).
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