Brochure - Elementrac ONH Series
Brochure - Elementrac ONH Series
Brochure - Elementrac ONH Series
NEW
Hydrogen Analyzers
ELEMENTRAC® ON-p | OH-p | ONH-p | H-500
ELEMENTRAC® ON-p | OH-p | ONH-p | H-500
ELTRA
Now argon
as
as carrier g
possible!
s
ONH Serie
NEW ELTRA® ELEMENTRAC® Series
The analyzers of ELTRA’s new ELEMENTRAC series are a combination of high functionality, elegant
design and innovative features. The user-friendly operation, robust construction and precision of the
instruments are further indicators of the high product quality.
The ELEMENTRAC ONH series is used to analyze oxygen, nitrogen and hydrogen concentrations in
inorganic sample materials reliably, accurately and safely by inert gas fusion.
2
Oxygen, Nitrogen, Hydrogen Analysis
Oxygen, nitrogen and hydrogen strongly influence the properties of metals such as steel,
titanium, copper. Brittleness, ductility and hardness are particularly influenced by the element
concentration; hence a reliable and precise measurement of these elements is an important
part of the quality control process. ELTRA supplies analyzers for the determination of the single
elements O, N, H as well as for the combinations ON, OH and ONH.
The ELEMENTRAC ONH series uses inert gas fusion. This method involves heating the sample
in a graphite crucible to 3,000 °C. Oxygen is determined by infrared cells as CO2, nitrogen and
hydrogen are measured by a thermal conductivity cell in their elemental form. Typical samples
for ONH analysis are all metal alloys (steel, copper, refractory metals) as well as ceramics and
other inorganic materials. ELTRA offers the H-500 analyzer exclusively for the determination of
hydrogen in steel based on hot extraction analysis.
Technical Details 06
Software 12
Standard-Compliant Work 13
Applications ELEMENTRAC ONH series 14
Technical Data 16
The CS-800 is ideal for the quick The CHS-580 is used for the The Thermostep analyzer
simultaneous determination of quick simultaneous determina- allows for determination of
carbon and sulfur in steel, cast tion of carbon, hydrogen and different sample parameters
iron, nonferrous metals, carbides, sulfur in samples such as coal, such as moisture, volatiles,
ceramics, glass, cement and other coke, ores, minerals, slag, and and ash in one single analysis
inorganic samples. many more. cycle.
NEW:
Closed Gas
System!
ONH Series
04
Quick results thanks to easy operation
Operation of the ELEMENTRAC ONH analyzers is easy, impulse furnaces closes. The measurement results
safe and convenient. First the sample is weighed, then are available 2 to 3 minutes later. During analysis it
logged into the sample list and finally introduced to is possible to log in more samples into the sample
the sample port system. Refractory materials such list or to search for and, if required, export previous
as titanium or ceramics need to be placed inside a measurement results. The ELEMENTRAC ONH series
nickel capsule or basket first. The next step is to requires minimum maintenance; all chemicals which
place a graphite crucible, which may contain more need to be exchanged regularly are easily accessible.
flux melting agent (e. g. tin), on the lower electrode.
The analysis is started in the software upon which the
Turning on the analyzer Weighing the sample Transferring the weight to the software
(manual or automatic)
Manual sample feed to the sample port Placing a crucible on the lower electrode Start of analysis
system
heated
catalyst
removable door (hidden) sample insert
crucible support
with graphite
crucible
moisture filter
Schuetze reagent
ON-/OFF
switch
06
Gas system
The ELEMENTRAC ONH series uses a closed gas system in overpressure to ensure that 100 % of the
released sample gas is lead to the detectors to guarantee low detection limits and good reproducibility.
The efficient economy mode during analysis breaks helps to reduce carrier gas consumption and hence
operating cost.
A powerful, controlled catalyst heats the contained copper oxide to 750 °C thus
ensuring the complete transformation of the CO formed in the graphite crucible to CO2.
Before the CO2 analysis in the infrared cells starts, water is chemically bound by a filter
to minimize interferences in IR absorption. This ensures reliable oxygen measurement
also for low concentrations. The catalyst is integrated in the analyzer and not located
at the front. To change the copper oxide it is simply popped out.
The ELEMENTRAC ONH analyzers use infrared cells to measure the oxygen concentration
via the carbon dioxide generated during the analysis process. The length of the
cuvette of such an infrared cell determines the sensitivity for measuring very low
oxygen concentrations, for example in stainless steel. Shorter cuvettes are suitable
for measuring high oxygen concentrations, for example in slag or oxides. ELTRA offers
cuvettes with various lengths to guarantee an optimum oxygen measuring range for
a variety of applications.
Options
The ELEMENTRAC ONH series may be upgraded for specific analytical requirements. The optional package
available includes gas calibration, complementing the calibration of solids included in the standard
configuration, effective carrier gas purification, an external chiller as well as a support for high-temperature
crucibles (HT crucibles) to safely analyze refractory alloys.
The impulse furnace and the sample port system are essential components of the
ELEMENTRAC ONH series. The sample port system ensures complete purging of the
sample from atmospheric gasses as well as its safe and loss-free transport to the
Impulse
furnace graphite crucible. The sample is melted in the furnace and the contained gasses are fully
and uniformly released.
The generator of the ELEMENTRAC ONH analyzers provides 8.5 kW which are reduced to 6.8 kW by the
software for safety reasons to avoid burning of the graphite crucibles. This ensures safe operation while
still providing sufficient power to analyze refractory samples.
water cooling
The funnel-shaped sample chamber allows for analysis of grains without the use of capsules which
offers some decisive advantages:
08
Sensitive thermal conductivity cell with optional
use of argon
Whereas the oxygen content of a sample is measured with infrared cells, hydrogen and nitrogen
are determined in their elemental form with the help of a robust thermal conductivity cell with
a wide measuring range. This cell was optimized for integration into the ELEMENTRAC ONH
analyzers and permits the use of cost-efficient argon as carrier gas.
analysis gas
The innovative ELEMENTRAC thermal conductivity cell is based on a micromechanical silicon chip which is coupled
to a membrane and works independently of a reference gas flow. If the thermal conductivity of the gas changes,
for example through nitrogen released from the sample, the heating capacity required for heating the membrane
changes as well. This is indicated by a measuring signal. The method is robust and sensitive and it guarantees
stable measuring results over a wide concentration range.
Beside helium and nitrogen argon is also a standard carrier gas for the ELEMENTRAC ONH analyzers. They are
equipped with connections for all three gasses so that no cumbersome hardware modifications are required.
Hydrogen Resistance
Precise determination of H2 also
in large samples
furnace
10
Operation H-500
Operation of the H-500 is easy and safe. After weighing
1
the sample, for example in a quartz boat, the weight is
transferred to the connected PC. It is also possible to
enter the weight manually in the H-500 software. The
sample is placed into the cold zone of the horizontally
positioned furnace (fig. 1). After the analysis has
started the furnace is rotated upwards (fig. 2) for the
sample to fall into the hot zone. By adding nitrogen
as carrier gas hydrogen diffuses out and is carried to
a thermal conductivity cell with up to two different
sensitivities. The typical analysis time is about 3 to 15
minutes. Detector signals and instrument parameters
2
are displayed during analysis. Evaluation of the signals
and display of the results are done automatically; the
data can be transferred to a laboratory information
management system (LIMS). The H-500 requires
minimum maintenance. The particle filters and chemicals
which need to be maintained are easily accessible.
The structure of the ELEMENTS software is based on a single central window (analysis) from which all
important functions such as calibration, sample log in and analysis, evaluation etc. can be started. Further
functionalities such as maintenance, application settings etc. are only one mouse click away from the
central window. This arrangement permits an efficient and convenient working process.
n Export functions
n Comment fields
Leakage test
12
Standard-Compliant Work
ELEMENTRAC® ON-p | OH-p | ONH-p
E-1587 Nickel Standard Test Methods for Chemical Analysis of Refined Nickel
Example:
Oxygen, nitrogen and hydrogen
in steel
The oxygen, nitrogen and hydrogen content have a strong influence on
material properties such as hardness, ductility or brittleness of steel.
Therefore, the determination of these parameters is an essential part
of the quality control of steel. The ELEMENTRAC ONH analyzers fulfill
all requirements of standards like ISO 10720 and 17053. Thanks to the
innovative sample port system it is possible to analyze grains without
capsule (e. g. CRM 281-1).
Excellent
ility!
reproducib
Sample weight approx. 1,000 mg (ELTRA samples), 500 mg (CRM 281-1), 10 measurements
* not certified
14
Applications – Inorganic
ELEMENTRAC® ON-p | OH-p | ONH-p
Example:
Oxygen in copper
Oxygen is introduced into copper during production and when tubes or
wires are drawn. Therefore measuring the oxygen content is part of an
effective quality control process and can be conveniently carried out
with the ELEMENTRAC ONH analyzers.
Oxygen
Reference material
[ppm]
ELTRA 91000-1004
7.0 ± 0.6
(Lot 113C)
Example:
Oxygen, nitrogen and hydrogen in titanium
An accurate element analysis of titanium is challenging because of its
high melting point. Therefore, a power of 6 kW is required for oxygen
and nitrogen analysis whereas 3 kW are sufficient for hydrogen analysis.
Reliable
sults!
analysis re
ELTRA 912505-1004
0.215 ± 0.008 0.0065 ± 0.0012 77 ± 8
(Lot 613B)
ELTRA 912505-1001
0.0522 ± 0.0013 0.0101 ± 0.0009 11 ±0.9
(Lot 114C)
Analysis time
Oxygen 85 seconds –
Nitrogen 90 seconds –
General data
Solid standards (one point; multi point), gas Solid standards (one point; multi point), gas
Calibration
calibration calibration
Non-dispersive IR (O2);
Detection Thermal conductivity cell
Thermal conductivity cell (N2; H2)
Magnesium perchlorate; sodium hydroxide on inert Magnesium perchlorate; sodium hydroxide on inert
Chemicals
carrier; copper oxide; Schuetze reagent carrier; Schuetze reagent
Furnace Water-cooled impulse furnace with 8.5 kW(2) Resistance furnace with quartz tube up to 1,000 °C
15 – 35 °C; 15 – 35 °C;
Working conditions
20 – 80 % humidity (not condensating) 20 – 80 % humidity (not condensating)
Dimensions (W x H x D) 57 x 77 x 63 cm 75 x 52 x 60 cm
(1)
The exact measuring range depends on the selected configuration.
(2)
Limited to 6.8 kW in applications