This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles

for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

Designation: A333/A333M − 18

Standard Specification for

Seamless and Welded Steel Pipe for Low-Temperature
Service and Other Applications with Required Notch
Toughness1
This standard is issued under the fixed designation A333/A333M; the number immediately following the designation indicates the year
of original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval.
A superscript epsilon (´) indicates an editorial change since the last revision or reapproval.

1. Scope* A999/A999M Specification for General Requirements for

2
1.1 This specification covers nominal (average) wall seam- Alloy and Stainless Steel Pipe
less and welded carbon and alloy steel pipe intended for use at A671/A671M Specification for Electric-Fusion-Welded
low temperatures and in other applications requiring notch Steel Pipe for Atmospheric and Lower Temperatures
toughness. Several grades of ferritic steel are included as listed E23 Test Methods for Notched Bar Impact Testing of Me-
in Table 1. Some product sizes may not be available under this tallic Materials
specification because heavier wall thicknesses have an adverse E165/E165M Practice for Liquid Penetrant Examination for
effect on impact properties. General Industry
E709 Guide for Magnetic Particle Testing
1.2 The values stated in either SI units or inch-pound units
are to be regarded separately as standard. Within the text, the 2.2 ASME Boiler and Pressure Vessel Code:4
SI units are shown in brackets. The values stated in each Section VIII
system may not be exact equivalents; therefore, each system Section IX
shall be used independently of the other. Combining values
from the two systems may result in non-conformance with the 3. Ordering Information
standard. The inch-pound units shall apply unless the “M” 3.1 Orders for material under this specification should
designation of this specification is specified in the order. include the following, as required, to describe the material
adequately:
NOTE 1—The dimensionless designator NPS (nominal pipe size) has
been substituted in this standard for such traditional terms as “nominal 3.1.1 Quantity (feet, centimetres, or number of lengths),
diameter,” “size,” and “nominal size.” 3.1.2 Name of material (seamless or welded pipe),
1.3 This international standard was developed in accor- 3.1.3 Grade (Table 1),
dance with internationally recognized principles on standard- 3.1.4 Size (NPS or outside diameter and schedule number of
ization established in the Decision on Principles for the average wall thickness),
Development of International Standards, Guides and Recom- 3.1.5 Lengths (specific or random) (Section 9), (see the
mendations issued by the World Trade Organization Technical Permissible Variations in Length section of Specification
Barriers to Trade (TBT) Committee. A999/A999M),
3.1.6 End finish (see the Ends section of Specification
2. Referenced Documents A999/A999M),
2.1 ASTM Standards:3 3.1.7 Optional requirements, (see the Heat Analysis require-
A370 Test Methods and Definitions for Mechanical Testing ment in the Chemical Composition section of A999/A999M,
of Steel Products the Repair by Welding section, and the section on Nondestruc-
tive Test Requirements),
1
This specification is under the jurisdiction of ASTM Committee A01 on Steel, 3.1.8 Test report required, (see the Certification section of
Stainless Steel and Related Alloys and is the direct responsibility of Subcommittee Specification A999/A999M),
A01.10 on Stainless and Alloy Steel Tubular Products. 3.1.9 Specification designation, and
Current edition approved Nov. 1, 2018. Published November 2018. Originally
approved in 1950. Last previous edition approved in 2016 as A333/A333M – 16.
3.1.10 Special requirements or exceptions to this specifica-
DOI: 10.1520/A0333_A0333M-18. tion.
2
For ASME Boiler and Pressure Vessel Code applications see related Specifi-
cation SA-333 in Section II of that Code.
3
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
4
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Available from American Society of Mechanical Engineers (ASME), ASME
Standards volume information, refer to the standard’s Document Summary page on International Headquarters, Two Park Ave., New York, NY 10016-5990, http://
the ASTM website. www.asme.org.

*A Summary of Changes section appears at the end of this standard

Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States

1
 A333/A333M − 18
TABLE 1 Chemical RequirementsB
Composition, %
Element
Grade 1 Grade 3 Grade 4 Grade 6 Grade 7 Grade 8 Grade 9 Grade 10 Grade 11
Carbon, max 0.30 0.19 0.12 0.30 0.19 0.13 0.20 0.20 0.10
Manganese 0.40–1.06A 0.31–0.64 0.50–1.05 0.29–1.06A 0.90 max 0.90 max 0.40–1.06 1.15–1.50 0.60 max
Phosphorus, 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.035 0.025
max
Sulfur, max 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.015 0.025
Silicon ... 0.18–0.37 0.08–0.37 0.10 min 0.13–0.32 0.13–0.32 ... 0.10–0.35 0.35 max
Nickel ... 3.18–3.82 0.47–0.98 0.40 max 2.03–2.57 8.40–9.60 1.60–2.24 0.25 max 35.0–37.0
Chromium ... ... 0.44–1.01 0.30 max ... ... ... 0.15 max 0.50 max
Copper ... ... 0.40–0.75 0.40 max ... ... 0.75–1.25 0.15 max ...
Aluminum ... ... 0.04–0.30 ... ... ... ... 0.06 max ...
Vanadium, max ... ... ... 0.08 ... ... ... 0.12 ...
NiobiumD , max ... ... ... 0.02C ... ... ... 0.05 ...
Molybdenum, ... ... ... 0.12 ... ... ... 0.05 0.50 max
max
Cobalt ... ... ... ... ... ... ... ... 0.50 max
A
For each reduction of 0.01 % carbon below 0.30 %, an increase of 0.05 % manganese above 1.06 % would be permitted to a maximum of 1.35 % manganese.
B
Where an ellipsis (...) appears in this table, there is no requirement and analysis for the element need not to be determined or reported.
C
By agreement between the manufacturer and the purchaser, the limit for niobium may be increased up to 0.05 % on heat analysis and 0.06 % on product analysis.
D
The terms Niobium (Nb) and Columbium (Cb) are alternate names for the same element.

3.1.11 Supplementary requirements, if any (subsize impact into the plate surface. No concavity of contour is permitted
specimens, pipe for hydrofluoric acid alkylation service). unless the resulting thickness of weld metal is equal to or
greater than the minimum thickness of the adjacent base metal.
4. Materials and Manufacture 4.2.3 Radiographic Examination—All welded joints shall
4.1 Manufacture—Except as provided in paragraph 4.2, the be fully radiographed in accordance with the requirements of
pipe shall be made by the seamless or welding process with the the ASME Boiler and Pressure Vessel Code, Section VIII,
addition of no filler metal in the welding operation. Grade 4 Division 1, latest edition, paragraph UW-51.
shall be made by the seamless process. 4.2.3.1 As an alternative, the welded joints may be ultra-
sonically examined in accordance with Appendix 12 of the
NOTE 2—For electric-fusion-welded pipe, with filler metal added,
fabricated of pressure vessel quality plates, see Specification A671/ ASME Boiler and Pressure Vessel Code, Section VIII, Division
A671M. 1.
4.2 Grade 11 pipe may be produced by welding with or 4.2.4 Repair Welding—Weld metal defects shall be repaired
without the addition of filler metal. The following requirements by removal to sound metal and repair welding if approved by
shall apply for Grade 11 welded with the addition of filler the purchaser.
metal. 4.2.4.1 The repair shall be blended smoothly into the
4.2.1 The joints shall be full-penetration, full fusion double- surrounding base metal surface and examined by the magnetic
welded or single-welded butt joints employing fusion welding particle examination in accordance with Practice E709, or by
processes as defined in “Definitions,” ASME Boiler and the liquid penetrant method in accordance with Practice
Pressure Vessel Code, Section IX. This specification makes no E165/E165M.
provision for any difference in weld quality requirements 4.2.4.2 Each repair weld of a cavity where the cavity, before
regardless of the weld joint type employed (single or double) in repair welding, has a depth exceeding the lesser of 3⁄8 in. [9.5
making the weld. Where backing strips are employed, the ring mm] or 10.5 % of the nominal thickness shall be radiographi-
or strip material shall be the same as the plate being joined. cally examined as required for the original welds.
Backing rings or strips shall be completely removed after 4.2.5 Transverse Tension Test—One test shall be made to
welding, prior to any required radiography, and the exposed represent each lot (Note 3) of finished pipe. The test specimens
weld surface shall be examined visually for conformance to the shall be taken across the welded joint. The tension test results
requirements of 4.2.2. Welds made by procedures employing of the welded joints shall conform to the tensile properties for
backing strips or rings which remain in place are prohibited. Grade 11 in Table 2.
Welding procedures and welding operators shall be qualified in 4.2.5.1 The test specimens shall be taken from the end of the
accordance with ASME Boiler and Pressure Vessel Code, finished pipe. As an alternative, the tension test specimens may
Section IX. be taken from a welded prolongation of the same material as
4.2.2 The weld surface on either side of the weld may be the pipe, which is attached to the end of the pipe and welded as
flush with the base plate or may have a reasonably uniform a prolongation of the pipe longitudinal seam.
crown, not to exceed 1⁄8 in. [3 mm]. Any weld reinforcement 4.2.5.2 The test specimens shall be in accordance with
may be removed at the manufacturer’s option or by agreement Section IX, Part QW, paragraph QW-150 of the ASME Boiler
between the manufacturer and purchaser. The contour of the and Pressure Vessel Code and shall be one of the types shown
reinforcement shall be reasonably smooth and free from in QW-462.1 of that code. The tension test specimen may be
irregularities. The deposited metal shall be fused uniformly flattened cold before final machining to size.

2
 A333/A333M − 18
TABLE 2 Tensile Requirements
Grade 1 Grade 3 Grade 4 Grade 6 Grade 7 Grade 8 Grade 9 Grade 10 Grade 11
psi MPa psi MPa psi MPa psi MPa psi MPa psi MPa psi MPa psi MPa psi MPa
Tensile strength, min 55 000 380 65 000 450 60 000 415 60 000 415 65 000 450 100 000 690 63 000 435 80 000 550 65 000 450
Yield strength, min 30 000 205 35 000 240 35 000 240 35 000 240 35 000 240 75 000 515 46 000 315 65 000 450 35 000 240
Longi- Trans- Longi- Trans- Longi- Trans- Longi- Trans- Longi- Trans- Longi- Trans- Longi- Trans- Longi- Trans- Longi-
tudinal verse tudinal verse tudinal verse tudinal verse tudinal verse tudinal verse tudinal verse tudinal verse tudinal
Elongation in 2 in. or 50
mm, (or 4D), min, %:
Basic minimum 35 25 30 20 30 16.5 30 16.5 30 22 22 ... 28 ... 22 ... 18A
elongation for walls 5⁄16
in. [8 mm] and over in
thickness, strip tests,
and for all small sizes
tested in full section
When standard round 28 20 22 14 22 12 22 12 22 14 16 ... ... ... 16 ... ...
2-in. or 50-mm gage
length or proportionally
smaller size test
specimen with the gage
length equal to 4D (4
times the diameter) is
used
For strip tests, a 1.75B 1.25B 1.50B 1.00B 1.50B 1.00B 1.50B 1.00B 1.50B 1.00B 1.25B ... 1.50B ... 1.25B ... ...
deduction for each 1⁄32
in. [0.8 mm] decrease in
wall thickness below 5⁄16
in. [8 mm] from the
basic minimum
elongation of the
following percentage
Elongation in 2 in. or 50 mm, min, %C
Wall Thickness
Grade 1 Grade 3 Grade 4 Grade 6 Grade 7 Grade 8 Grade 9 Grade 10
in. mm Longi- Trans- Longi- Trans- Longi- Trans- Longi- Trans- Longi- Trans- Longi- Trans- Longi- Trans- Longi- Trans-
tudinal verse tudinal verse tudinal verse tudinal verse tudinal verse tudinal verse tudinal verse tudinal verse
⁄
5 16 (0.312) 8 35 25 30 20 30 16 30 16 30 22 22 ... 28 ... 22 ...
⁄
9 32 (0.281) 7.2 33 24 28 19 28 15 28 15 28 21 21 ... 26 ... 21 ...
1⁄4 (0.250) 6.4 32 23 27 18 27 15 27 15 27 20 20 ... 25 ... 20 ...
7⁄32 (0.219) 5.6 30 ... 26 ... 26 ... 26 ... 26 ... 18 ... 24 ... 18 ...
3⁄16 (0.188) 4.8 28 ... 24 ... 24 ... 24 ... 24 ... 17 ... 22 ... 17 ...
5⁄32 (0.156) 4 26 ... 22 ... 22 ... 22 ... 22 ... 16 ... 20 ... 16 ...
1⁄8 (0.125) 3.2 25 ... 21 ... 21 ... 21 ... 21 ... 15 ... 19 ... 15 ...
3⁄32 (0.094) 2.4 23 ... 20 ... 20 ... 20 ... 20 ... 13 ... 18 ... 13 ...
1⁄16 (0.062) 1.6 21 ... 18 ... 18 ... 18 ... 18 ... 12 ... 16 ... 12 ...
A
Elongation of Grade 11 is for all walls and small sizes tested in full section.
B
The following table gives the calculated minimum values.
C
Calculated elongation requirements shall be rounded to the nearest whole number.
Note—The preceding table gives the computed minimum elongation values for each 1⁄32-in. [0.80-mm] decrease in wall thickness. Where the wall thickness lies between
two values shown above, the minimum elongation value is determined by the following equation:

Grade Direction of Test Equation

1 Longitudinal E = 56 t + 17.50 [E = 2.19 t + 17.50]
Transverse E = 40 t + 12.50 [E = 1.56 t + 12.50]
3 Longitudinal E = 48 t + 15.00 [E = 1.87 t + 15.00]
Transverse E = 32 t + 10.00 [E = 1.25 t + 10.00]
4 Longitudinal E = 48 t + 15.00 [E = 1.87 t + 15.00]
Transverse E = 32 t + 6.50 [ E = 1.25 t+ 6.50]
6 Longitudinal E = 48 t + 15.00 [E = 1.87 t + 15.00]
Transverse E = 32 t + 6.50 [ E = 1.25 t + 6.50]
7 Longitudinal E = 48 t + 15.00 [E = 1.87 t + 15.00]
Transverse E = 32 t + 11.00 [E = 1.25 t + 11.00]
8 and 10 Longitudinal E = 40 t + 9.50 [ E = 1.56 t + 9.50]
9 Longitudinal E = 48 t + 13.00 [E = 1.87 t + 13.00]
where:
E = elongation in 2 in. or 50 mm, in %, and
t = actual thickness of specimen, in. [mm].

4.2.6 Transverse Guided-Bend Weld Test—One transverse 4.2.6.1 The two bend test specimens shall be taken from the
guided bend test (two specimens) shall be made to represent weld at the end of the finished pipe. As an alternative, by
each lot (Note 3) of finished pipe. agreement between the purchaser and the manufacturer, the test

3
 A333/A333M − 18
specimens may be taken from a test plate of the same material TABLE 4 Impact Temperature
as the pipe, the test plate being attached to the end of the pipe Impact Test Temperature
Grade
and welded as a prolongation of the pipe longitudinal seam. °F °C
4.2.6.2 The bend test shall be in accordance with QW-160 1 −50 −45
of Section IX of the ASME Boiler and Pressure Vessel Code. 3 −150 −100
4 −150 −100
4.2.7 Charpy V-notch Impact Tests—Impact tests on welded 6 −50 −45
joints shall include tests on weld metal and heat affected zones 7 −100 −75
and shall meet the same requirements as the base metal. (See 8 −320 −195
9 −100 −75
Tables 3 and 4). 10 −75 −60
4.2.7.1 Each set of weld metal impact test specimens shall 11 –320 –195
be taken across the weld with the notch in the weld metal. Each
test specimen shall be oriented so that the notch is normal to
the surface of the material and one face of the specimen shall reheating to a suitable tempering temperature, in place of any
be within 1⁄16 in. [1.5 mm] of the surface of the material. of the other heat treatments provided for in 4.3.1.
4.2.7.2 Each set of heat affected zone impact test specimens 4.3.2 Grade 8 pipe shall be heat treated by the manufacturer
shall be taken across the weld and of sufficient length to locate, by either of the following methods:
after etching, the notch in the heat affected zone. The notch 4.3.2.1 Quenched and Tempered—Heat to a uniform tem-
shall be cut approximately normal to the surface of the material perature of 1475 6 25 °F [800 6 15 °C]; hold at this
in such a manner as to include as much heat affected zone temperature for a minimum time in the ratio of 1 h/in. [2
material as possible in the resulting fracture. min/mm] of thickness, but in no case less than 15 min; quench
NOTE 3—The term “lot” applies to all pipe (may include more than one by immersion in circulating water. Reheat until the pipe attains
heat of steel) within a 3⁄16 in. [4.7 mm] range of thickness and welded to a uniform temperature within the range from 1050 to 1125 °F
the weld procedure, and when heat treated, done to the same heat-treating [565 to 605 °C]; hold at this temperature for a minimum time
procedure and in the same furnace. The maximum lot size shall be 200
linear ft [60 m] of pipe.
in the ratio of 1 h/in. [2 min/mm] of thickness, but in no case
less than 15 min; cool in air or water quench at a rate no less
4.3 Heat Treatment: than 300 °F [165 °C]/h.
4.3.1 All seamless and welded pipe, other than Grades 8 and 4.3.2.2 Double Normalized and Tempered—Heat to a uni-
11, shall be treated to control their microstructure in accor- form temperature of 1650 6 25 °F [900 6 15 °C]; hold at this
dance with one of the following methods: temperature for a minimum time in the ratio of 1 h/in. [2
4.3.1.1 Normalize by heating to a uniform temperature of min/mm] of thickness, but in no case less than 15 min; cool in
not less than 1500 °F [815 °C] and cool in air or in the cooling air. Reheat until the pipe attains a uniform temperature of 1450
chamber of an atmosphere controlled furnace. 6 25 °F [790 6 15 °C]; hold at this temperature for a
4.3.1.2 Normalize as in 4.3.1.1, and, at the discretion of the minimum time in the ratio of 1 h/in. [2 min/mm] of thickness,
manufacturer, reheat to a suitable tempering temperature. but in no case less than 15 min; cool in air. Reheat to a uniform
4.3.1.3 For the seamless process only, reheat and control hot temperature within the range from 1050 to 1125 °F [565 to 605
working and the temperature of the hot-finishing operation to a °C]; hold at this temperature for a minimum time of 1 h/in. [2
finishing temperature range from 1550 to 1750 °F [845 to 945 min/mm] of thickness but in no case less than 15 min; cool in
°C] and cool in air or in a controlled atmosphere furnace from air or water quench at a rate not less than 300 °F [165 °C]/h.
an initial temperature of not less than 1550 °F [845 °C]. 4.3.3 Whether to anneal Grade 11 pipe is per agreement
4.3.1.4 Treat as in 4.3.1.3 and, at the discretion of the between purchaser and supplier. When Grade 11 pipe is
manufacturer, reheat to a suitable tempering temperature. annealed, it shall be normalized in the range of 1400 to 1600 °F
4.3.1.5 Seamless pipe of Grades 1, 6, and 10 may be heat [760 to 870 °C].
treated by heating to a uniform temperature of not less than 4.3.4 Material from which test specimens are obtained shall
1500 °F [815 °C], followed by quenching in liquid and be in the same condition of heat treatment as the pipe
furnished. Material from which specimens are to be taken shall
be heat treated prior to preparation of the specimens.
TABLE 3 Impact Requirements for Grades 1, 3, 4, 6, 7, 9, 10, and
11 4.3.5 When specified in the order the test specimens shall be
taken from full thickness test pieces which have been stress
Minimum Average Notched Minimum Notched Bar
Bar Impact Value of Impact Value of One relieved after having been removed from the heat-treated pipe.
Size of Each Set of Three Specimen Only of The test pieces shall be gradually and uniformly heated to the
Specimen, mm SpecimensA a SetA
prescribed temperature, held at that temperature for a period of
ft·lbf J ft·lbf J
time in accordance with Table 5, and then furnace cooled at a
temperature not exceeding 600 °F [315 °C]. Grade 8 shall be
10 by 10 13 18 10 14
10 by 7.5 10 14 8 11 cooled at a minimum rate of 300 °F [165 °C]/h in air or water
10 by 6.67 9 12 7 9 to a temperature not exceeding 600 °F [315 °C].
10 by 5 7 9 5 7
10 by 3.33 5 7 3 4 5. Chemical Composition
10 by 2.5 4 5 3 4
A
Straight line interpolation for intermediate values is permitted. 5.1 The steel shall conform to the requirements as to
chemical composition prescribed in Table 1.

4
 A333/A333M − 18
TABLE 5 Stress Relieving of Test Pieces value. When an erratic result is caused by a defective
Metal TemperatureA,B Minimum Holding specimen, or there is uncertainty in test procedures, a retest will
Grades 1, 3, 6, 7, and 10 Grade 4C Time, be allowed.
h/in. [min/mm]
°F °C °F °C of Thickness 8.2 For Grade 8 each of the notched bar impact specimens
1100 600 1150 620 1 [2.4] shall display a lateral expansion opposite the notch of not less
1050 565 1100 600 2 [4.7]
1000 540 1050 565 3 [7.1]
than 0.015 in. [0.38 mm].
A
8.2.1 When the average lateral expansion value for the three
For intermediate temperatures, the holding time shall be determined by straight-
line interpolation. impact specimens equals or exceeds 0.015 in. [0.38 mm] and
B
Grade 8 shall be stress relieved at 1025 to 1085 °F, [550 to 585 °C], held for a the value for one specimen is below 0.015 in. [0.38 mm] but
minimum time of 2 h for thickness up to 1.0 in. [25.4 mm], plus a minimum of 1 h
for each additional inch [25.4 mm] of thickness and cooled at a minimum rate of
not below 0.010 in. [0.25 mm], a retest of three additional
300 °F [165 °C]/h in air or water to a temperature not exceeding 600 °F [315 °C]. specimens may be made. The lateral expansion of each of the
C
Unless otherwise specified, Grade 4 shall be stress relieved at 1150 °F [620 °C]. retest specimens must equal or exceed 0.015 in. [0.38 mm].
8.2.2 Lateral expansion values shall be determined by the
procedure in Test Methods and Definitions A370.
8.2.3 The values of absorbed energy in foot-pounds [joule]
and the fracture appearance in percentage shear shall be
5.2 When Grades 1, 6, or 10 are ordered under this
recorded for information. A record of these values shall be
specification, supplying an alloy grade that specifically re-
retained for a period of at least 2 years.
quires the addition of any element other than those listed for
the ordered grade in Table 1 is not permitted. However, the
9. Lengths
addition of elements required for the deoxidation of the steel is
permitted. 9.1 If definite lengths are not required, pipe may be ordered
either in single random lengths of 16 to 22 ft (Note 4) with
6. Product Analysis maximum 5 % of the lengths between 12 and 16 ft (Note 4), or
in double random lengths with a minimum average of 35 ft
6.1 At the request of the purchaser, an analysis of one billet
(Note 4) and an absolute minimum length of 22 ft (Note 4) with
or two samples of flat-rolled stock from each heat or of two
maximum 5 % of the lengths between 16 and 22 ft (Note 4).
pipes from each lot shall be made by the manufacturer. A lot of
pipe shall consist of the following: NOTE 4—This value(s) applies when the inch-pound designation of this
NPS Designator Length of Pipe in Lot
specification is the basis of purchase. When the “M” designation of this
Under 2 400 or fraction thereof specification is the basis of purchase, the corresponding metric value(s)
2 to 6 200 or fraction thereof shall be agreed upon between the manufacturer and purchaser.
Over 6 100 or fraction thereof
6.2 The results of these analyses shall be reported to the 10. Workmanship, Finish, and Appearance
purchaser or the purchaser’s representative and shall conform 10.1 The pipe manufacturer shall explore a sufficient num-
to the requirements specified. ber of visual surface imperfections to provide reasonable
6.3 If the analysis of one of the tests specified in 6.1 does assurance that they have been properly evaluated with respect
not conform to the requirements specified, an analysis of each to depth. Exploration of all surface imperfections is not
billet or pipe from the same heat or lot may be made, and all required but may be necessary to ensure compliance with 10.2.
billets or pipe conforming to the requirements shall be ac- 10.2 Surface imperfections that penetrate more than 12½ %
cepted. of the nominal wall thickness or encroach on the minimum
wall thickness shall be considered defects. Pipe with such
7. Tensile Requirements defects shall be given one of the following dispositions:
7.1 The material shall conform to the requirements as to 10.2.1 The defect may be removed by grinding provided
tensile properties prescribed in Table 2. that the remaining wall thickness is within specified limits.
10.2.2 Repaired in accordance with the repair welding
8. Impact Requirements provisions of 10.5.
8.1 For Grades 1, 3, 4, 6, 7, 9, 10, and 11, the notched-bar 10.2.3 The section of pipe containing the defect may be cut
impact properties of each set of three impact specimens, off within the limits of requirements on length.
including specimens for the welded joint in welded pipe with 10.2.4 The defective pipe may be rejected.
wall thicknesses of 0.120 in. [3 mm] and larger, when tested at 10.3 To provide a workmanlike finish and basis for evalu-
temperatures in conformance with 14.1 shall be not less than ating conformance with 10.2, the pipe manufacturer shall
the values prescribed in Table 3. remove by grinding the following:
8.1.1 If the impact value of one specimen is below the 10.3.1 Mechanical marks, abrasions and pits, any of which
minimum value, or the impact values of two specimens are less imperfections are deeper than 1⁄16 in. [1.6 mm], and
than the minimum average value but not below the minimum 10.3.2 Visual imperfections commonly referred to as scabs,
value permitted on a single specimen, a retest shall be allowed. seams, laps, tears, or slivers found by exploration in accor-
The retest shall consist of breaking three additional specimens dance with 10.1 to be deeper than 5 % of the nominal wall
and each specimen must equal or exceed the required average thickness.

5
 A333/A333M − 18
10.4 At the purchaser’s discretion, pipe shall be subject to 12.5 Specimens showing defects while being machined or
rejection if surface imperfections acceptable under 10.2 are not prior to testing may be discarded and replacements shall be
scattered, but appear over a large area in excess of what is considered as original specimens.
considered a workmanlike finish. Disposition of such pipe shall 12.6 Results obtained from these tests shall be reported to
be a matter of agreement between the manufacturer and the the purchaser or his representative.
purchaser.
10.5 When imperfections or defects are removed by 13. Specimens for Impact Test
grinding, a smooth curved surface shall be maintained, and the
13.1 Notched bar impact specimens shall be of the simple
wall thickness shall not be decreased below that permitted by
beam, Charpy-type, in accordance with Test Methods E23,
this specification. The outside diameter at the point of grinding
Type A with a V notch. Standard specimens 10 by 10 mm in
may be reduced by the amount so removed.
cross section shall be used unless the material to be tested is of
10.5.1 Wall thickness measurements shall be made with a
insufficient thickness, in which case the largest obtainable
mechanical caliper or with a properly calibrated nondestructive
subsize specimens shall be used. Charpy specimens of width
testing device of appropriate accuracy. In case of dispute, the
along the notch larger than 0.394 in. [10 mm] or smaller than
measurement determined by use of the mechanical caliper shall
0.099 in. [2.5 mm] are not provided for in this specification.
govern.
10.6 Weld repair shall be permitted only subject to the 13.2 Test specimens shall be obtained so that the longitudi-
approval of the purchaser and in accordance with Specification nal axis of the specimen is parallel to the longitudinal axis of
A999/A999M. the pipe while the axis of the notch shall be perpendicular to
the surface. On wall thicknesses of 1 in. [25 mm] or less, the
10.7 The finished pipe shall be reasonably straight. specimens shall be obtained with their axial plane located at the
midpoint; on wall thicknesses over 1 in. [25 mm], the speci-
11. General Requirements mens shall be obtained with their axial plane located 1⁄2 in.
11.1 Material furnished to this specification shall conform to [12.5 mm] from the outer surface.
the applicable requirements of the current edition of Specifi- 13.3 When testing welds the specimen shall be, whenever
cation A999/A999M unless otherwise provided herein. diameter and thickness permit, transverse to the longitudinal
axis of the pipe with the notch of the specimen in the welded
12. Mechanical Testing joint and perpendicular to the surface. When diameter and
12.1 Sampling—For mechanical testing, the term “lot” ap- thickness do not permit obtaining transverse specimens, longi-
plies to all pipe of the same nominal size and wall thickness (or tudinal specimens in accordance with 13.2 shall be obtained;
schedule) that is produced from the same heat of steel and the bottom of the notch shall be located at the weld joint.
subjected to the same finishing treatment in a continuous
furnace. If the final heat treatment is in a batch-type furnace, 14. Impact Test
the lot shall include only those pipes that are heat treated in the
14.1 Except when the size of the finished pipe is insufficient
same furnace charge.
to permit obtaining subsize impact specimens, all material
12.2 Transverse or Longitudinal Tensile Test and Flattening furnished to this specification and marked in accordance with
Test—For material heat treated in a batch-type furnace, tests Section 16 shall be tested for impact resistance at the tempera-
shall be made on 5 % of the pipe from each lot. If heat treated ture for the respective grades as shown in Table 4.
by the continuous process, tests shall be made on a sufficient 14.1.1 Special impact tests on individual lots of material
number of pipe to constitute 5 % of the lot, but in no case less may be made at other temperatures as agreed upon between the
than 2 pipes. manufacturer and the purchaser, provided that the test tempera-
12.3 Impact Test—One notched bar impact test, consisting ture is lower than those listed for each Grade in Table 4.
of breaking three specimens, shall be made from each heat 14.1.2 When subsize Charpy impact specimens are used and
represented in a heat-treatment load on specimens taken from the width along the notch is less than 80 % of the actual wall
the finished pipe. This test shall represent only pipe from the thickness of the original material, the specified Charpy impact
same heat and the same heat-treatment load, the wall thick- test temperature for Grades 1, 3, 4, 6, 7, 9, 10, and 11 shall be
nesses of which do not exceed by more than 1⁄4 in. [6.3 mm] the lower than the temperature shown in Table 4 for the respective
wall thicknesses of the pipe from which the test specimens are grade. Under these circumstances the temperature reduction
taken. If heat treatment is performed in continuous or batch- values shall be by an amount equal to the difference (as shown
type furnaces controlled within a 50 °F [30 °C] range and in Table 6) between the temperature reduction corresponding to
equipped with recording pyrometers so that complete records the actual material thickness and the temperature reduction
of heat treatment are available, then one test from each heat in corresponding to the Charpy specimen width actually tested.
a continuous run only shall be required instead of one test from Appendix X1 shows some examples of how the temperature
each heat in each heat-treatment load. reductions are determined.
12.4 Impact Tests (Welded Pipe)—On welded pipe, addi- 14.2 The notched bar impact test shall be made in accor-
tional impact tests of the same number as required in 12.3 shall dance with the procedure for the simple beam, Charpy-type test
be made to test the weld. of Test Methods E23.

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 A333/A333M − 18
TABLE 6 Impact Temperature Reduction 15.3.1 If the test signals were produced by visual imperfec-
Specimen Width Along Notch or Actual Temperature Reduction, tions (listed in 15.3.2), the pipe may be accepted based on
Material Thickness Degrees ColderA visual examination, provided the imperfection is less than
in. mm °F °C 0.004 in. (0.1 mm) or 12½ % of the specified wall thickness
0.394 10 (standard size) 0 0 (whichever is greater).
0.354 9 0 0
0.315 8 0 0 15.3.2 Visual Imperfections:
0.295 7.5 ( ⁄4 std. size)
3 5 3 15.3.2.1 Scratches,
0.276 7 8 4
0.262 6.67 (2⁄3 std. size) 10 5 15.3.2.2 Surface roughness,
0.236 6 15 8 15.3.2.3 Dings,
0.197 5 (1⁄2 std. size) 20 11
0.158 4 30 17 15.3.2.4 Straightener marks,
0.131 3.33 (1⁄3 std. size) 35 19
15.3.2.5 Cutting chips,
0.118 3 40 22
0.099 2.5 (1⁄4 std. size) 50 28 15.3.2.6 Steel die stamps,
A
Straight line interpolation for intermediate values is permitted. 15.3.2.7 Stop marks, or
15.3.2.8 Pipe reducer ripple.
14.3 Impact tests specified for temperatures lower than 70
16. Product Marking
°F [20 °C] should be made with the following precautions. The
impact test specimens as well as the handling tongs shall be 16.1 Except as modified in 16.1.1, in addition to the
cooled a sufficient time in a suitable container so that both marking prescribed in Specification A999/A999M, the mark-
reach the desired temperature. The temperature shall be mea- ing shall include whether hot finished, cold drawn, seamless or
sured with thermocouples, thermometers, or any other suitable welded, the schedule number and the letters “LT” followed by
devices and shall be controlled in accordance with Test the temperature at which the impact tests were made, except
Methods and Definitions A370, Section 25. The specimens when a lower test temperature is required because of reduced
shall be quickly transferred from the cooling device to the anvil specimen size, in which case, the higher impact test tempera-
of the Charpy impact testing machine and broken with a time ture applicable to a full-size specimen should be marked.
lapse of not more than 5 s. 16.1.1 When the size of the finished pipe is insufficient to
obtain subsize impact specimens, the marking shall not include
15. Hydrostatic or Nondestructive Electric Test
the letters “LT” followed by an indicated test temperature
15.1 Each pipe shall be subjected to the nondestructive unless Supplementary Requirement S1 is specified.
electric test or the hydrostatic test. The type of test to be used 16.1.2 When the pipe is furnished in the quenched and
shall be at the option of the manufacturer, unless otherwise tempered condition, the marking shall include the letters “QT,”
specified in the purchase order. and the heat treatment condition shall be reported to the
15.2 The hydrostatic test shall be in accordance with Speci- purchaser or his representative.
fication A999/A999M.
15.3 Nondestructive Electric Test—Nondestructive electric 17. Keywords
tests shall be in accordance with Specification A999/A999M, 17.1 low; low temperature service; seamless steel pipe;
with the following addition: stainless steel pipe; steel pipe; temperature service applications

SUPPLEMENTARY REQUIREMENTS

The following supplementary requirement shall apply only when specified by the purchaser in the
contract or order.

S1. Subsize Impact Specimens S2.2 The carbon equivalent shall be determined using the
S1.1 When the size of the finished pipe is insufficient to following formula:
permit obtaining subsize impact specimens, testing shall be a CE = C + Mn/6 + (Cr + Mo + V)/5 + (Ni + Cu)/15
matter of agreement between the manufacturer and the pur- S2.3 Based upon heat analysis in mass percent, the vana-
chaser. dium content shall not exceed 0.02 %, the niobium content
shall not exceed 0.02 % and the sum of the vanadium and
S2. Requirements for Pipe for Hydrofluoric Acid Alky- niobium contents shall not exceed 0.03 %.
lation Service
S2.4 Based upon heat analysis in mass percent, the sum of
S2.1 The carbon equivalent (CE), based on heat analysis, the nickel and copper contents shall not exceed 0.15 %.
shall not exceed 0.43 % if the specified wall thickness is equal
S2.5 Based upon heat analysis in mass percent, the carbon
to or less than 1 in. [25.4 mm] or 0.45 % if the specified wall
content shall not be less than 0.18 %.
thickness is greater than 1 in. [25.4 mm].

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 A333/A333M − 18
S2.6 Welding consumables for repair welds shall be of low S2.7 The designation “HF” shall be stamped or marked on
hydrogen type. E60XX electrodes shall not be used, and the each pipe to signify that the pipe complies with this supple-
resultant weld chemistry shall meet the chemical composition mentary requirement.
requirements specified for the pipe.

APPENDIX

(Nonmandatory Information)

X1. DETERMINATION OF TEMPERATURE REDUCTIONS

X1.1 Under the circumstances stated in 14.1.2, the impact required reduction in test temperature is computed by taking
test temperatures specified in Table 4 must be lowered. The the difference between the temperature reduction values shown
following examples are offered to describe the application of in Table 6 for the actual pipe thickness and the specimen width
the provisions of 14.1.2. used.
X1.1.1 When subsize specimens are used (see 10.1) and the X1.1.2.1 For example, if the pipe were 0.262 in. [6.67 mm]
width along the notch of the subsize specimen in 80 % or thick and the width along the Charpy specimen notch was 3.33
greater of the actual wall thickness of the original material, the mm (1/3 standard size), the test temperature would have to be
provisions of 14.1.2 do not apply. lowered by 25 °F [14 °C]. That is, the temperature reduction
X1.1.1.1 For example, if the actual wall thickness of pipe corresponding to the subsize specimen is 35 °F [19 °C]; the
was 0.200 in. [5.0 mm] and the width along the notch of the temperature reduction corresponding to the actual pipe thick-
largest subsize specimen obtainable is 0.160 in. [4 mm] or ness is 10 °F [5 °C]; the difference between these two values is
greater, no reduction in test temperature is required. the required reduction in test temperature.
X1.1.2 When the width along the subsize specimen notch is
less than 80 % of the actual wall thickness of the pipe, the

SUMMARY OF CHANGES

Committee A01 has identified the location of selected changes to this specification since the last issue,
A333/A333M – 16, that may impact the use of this specification. (Approved Nov. 1, 2018)

(1) Deletion of the word “minimum” from Table 4. (3) Replaced test temperature tolerance with reference to Test
(2) Deletion of the word “minimum” from 14.1 and 14.1.2, and Methods and Definitions A370, Section 25 in 14.3.
clarified special impact test temperature in 14.1.1.

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