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    Destilacion TBP

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    Carlos Andres Perez
    Here are the steps to solve this homework problem: 1. Draw the TBP curve by plotting Temp (F) vs Vol % Distilled from the given data. 2. The crude oil has an API of 43. Using the correlation that Kw=141.5/API, calculate Kw=3.3 3. Draw the EFV curve by using figures 10 and 11 from the document. Given T50% for TBP is 560F. From figure 11, ΔT is 50F. So T50% for EFV is 560-50=510F. 4. The CCR is 1.8%. Using the correlation that Vol% at 1100F = 100*(1-C

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    Destilacion TBP

    Uploaded by

    Carlos Andres Perez
    227 views9 pages
    Here are the steps to solve this homework problem: 1. Draw the TBP curve by plotting Temp (F) vs Vol % Distilled from the given data. 2. The crude oil has an API of 43. Using the correlation that Kw=141.5/API, calculate Kw=3.3 3. Draw the EFV curve by using figures 10 and 11 from the document. Given T50% for TBP is 560F. From figure 11, ΔT is 50F. So T50% for EFV is 560-50=510F. 4. The CCR is 1.8%. Using the correlation that Vol% at 1100F = 100*(1-C

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    Destilacion TBP explicación

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    Here are the steps to solve this homework problem: 1. Draw the TBP curve by plotting Temp (F) vs Vol % Distilled from the given data. 2. The crude oil has an API of 43. Using the correlation that Kw=141.5/API, calculate Kw=3.3 3. Draw the EFV curve by using figures 10 and 11 from the document. Given T50% for TBP is 560F. From figure 11, ΔT is 50F. So T50% for EFV is 560-50=510F. 4. The CCR is 1.8%. Using the correlation that Vol% at 1100F = 100*(1-C

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    227 views9 pages

    Destilacion TBP

    Uploaded by

    Carlos Andres Perez
    Here are the steps to solve this homework problem: 1. Draw the TBP curve by plotting Temp (F) vs Vol % Distilled from the given data. 2. The crude oil has an API of 43. Using the correlation that Kw=141.5/API, calculate Kw=3.3 3. Draw the EFV curve by using figures 10 and 11 from the document. Given T50% for TBP is 560F. From figure 11, ΔT is 50F. So T50% for EFV is 560-50=510F. 4. The CCR is 1.8%. Using the correlation that Vol% at 1100F = 100*(1-C

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 9

    Petroleum Refining Fourth Year Dr.Aysar T.

    Jarullah

    Types of Distillation Curve

    1- True Boiling point(TBP) Distillation


    2- ASTM Distillation
    3- Semi-fractionating Distillation
    4- Equilibrium Flash Vaporization(EFV)

    1) TBP: This type of distillation is commonly used due to the accuracy of the results obtained
    by this method which is very close to that obtained via real distillation or industrial
    distillation. In this distillation, there is a fractionation column located between the condenser
    and the flask. In general, this type of distillation is carried out by two steps: firstly, under
    atmospheric pressure until 300°C (1% distilled very 2 min), secondly under vacuum pressure
    (to prevent cracking process and to reduce the boiling point) at 40mmHg (1% distilled every
    3-5 min). In this process, the vapor press. temp. is plotted vs. distilled(%) to get TBP curve.

    2) ASTM: In this type of distillation there is on fractionation column located between the
    condenser and the flask. On the other hand, the raised vapor will not be fractionated in this
    process. This distillation is used with fractions having short range of the boiling point.

    3) Semi-fractionating distillation: In this type of distillation, their will be some


    fractionating process on the raised vapor via package located between the condenser and the
    flask.

    4) Equilibrium Flash Vaporization (EFV): Is a single stage separation technique. A liquid


    mixture feed is pumped through a heater to raise the temperature and enthalpy of the mixture.
    It then flows through a valve and the pressure is reduced, causing the liquid to partially
    vaporize. Because the vapor and liquid are in such close contact up until the "flash" occurs,
    the product liquid and vapor phases approach equilibrium.
    Petroleum Refining Fourth Year Dr.Aysar T. Jarullah

    Fig. 5. TBP cut point versus ASTM end point


    Petroleum Refining Fourth Year Dr.Aysar T. Jarullah

    Fig. 6. Crude distillation curve

    Fig. 7. TBP and gravity-mid-percent curves


    Petroleum Refining Fourth Year Dr.Aysar T. Jarullah

    Average Boiling Point


    1- Volume Average Boiling Point (VABP)

    T20%  T50%  T80%


    VABP 
    3
    Ti% = Temp. at i vol. % distilled

    For short cut Boiling Point (having short B.P)

    VABP  T50%
    2- Weight Average Boiling Point (WABP)

    T10%  T20%  T30%  ..........T90%


    WABP 
    9
    Ti% = Temp. at i weight. % distilled

    3- Molal Average Boiling Point (MABP)

    Tx1  Tx 2  Tx 3  ..........
    MABP 
    x1  x 2  x3 ................
    Tix = Temp. at i mol. x distilled, x is the no. of mole

    MABP  VABP  T

    4) Slope of Distillation Curve

    T70%  T10%
    Slope 
    60
    If the slope  2  Short Cut (T50% )  VABP  WABP  MABP

    Fig. 10 is used to convert Distillation Curve from any type to any type.

    Figure 11 is used to find T50% for EFV ( y axix  T50%( ASTM or TBP)  T50%( EFV ) )
    Petroleum Refining Fourth Year Dr.Aysar T. Jarullah

    Fig. 8. Molal average boiling point of petroleum fractions

    Fig.9. Mean average boiling point of petroleum fractions


    Petroleum Refining Fourth Year Dr.Aysar T. Jarullah

    Also, Differential (Δ) can be estimated from the following eq.

    Fig. 10. Relationships between the slopes of various distillation curves


    Petroleum Refining Fourth Year Dr.Aysar T. Jarullah

    Fig. 11. Relationships between distillation temperatures at 50% vaporized and the flash
    (E.F.V.) Temp. at 50%

    Ex) Find T100% and T0% for EFV if T 50%(TBP) = 570 and Slope = 9.4.

    Sol.: From Fig.10, the slope of EFV curve = 6.6 (at 9.4 TBP)

    From Fig. 11, ΔT = 65 (at T50%(TBP) = 570)

     T50%( EFV )  T50%( ASTM or TBP)  T  570  65  505


    y T100%  505
    slope    6.6  T100%  835
    x 50  0
    y 505  T0%
    Slope    6.6  T0%  175
    x 100  50
    Petroleum Refining Fourth Year Dr.Aysar T. Jarullah

    Fig. 12. Sulfur content of products from Middle East crude oils
    Petroleum Refining Fourth Year Dr.Aysar T. Jarullah

    Home work

    For a given crude oil; 1- Draw a TBP curve, 2- Evaluate the crude, 3- Find the value of Kw if
    API=43, 4- Draw a EFV on the same Figure, 5- Find the vol. dis. At 1100F if CCR= 1.8%
    then draw it, and 6- Find the vol. of the distilled at 1000F.

    Vol. Distilled 0 10 20 30 40 50 60 70 80
    Temp. (F) 160 270 335 400 480 560 610 680 820 1100
    Sp.gr 0 0.72 0.75 0.78 0.80 0.82 0.835 0.85 0.87

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