MATERIAL SAFETY DATA SHEET

SODIUM SULFIDE
MSDS Number: IR/VFY/02 01.06.2015

1. Product Identification
Synonyms : Sodium monosulfide
CAS No. : 1313-82-2
Chemical Formula : Na2S.9H2O
Product Codes :

2. Composition/Information on Ingredients
Composition:
Name CAS # % by Weight
Sodium sulfide 1313-82-2 100
Toxicological Data on Ingredients: Sodium sulfide LD50: Not available. LC50: Not available.

3. Hazards Identification
Potential Acute Health Effects:
Very hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of
inhalation. Corrosive to eyes and skin. The amount of tissue damage depends on length of contact. Eye
contact can result in corneal damage or blindness. Skin contact can produce inflammation and blistering.
Inhalation of dust will produce irritation to gastro-intestinal or respiratory tract, characterized by burning,
sneezing and coughing. Severe over-exposure can produce lung damage, choking, unconsciousness or death.
Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized
by itching, scaling, reddening, or, occasionally, blistering.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. Repeated exposure of the eyes to a low level of dust can
produce eye irritation.
Repeated skin exposure can produce local skin destruction, or dermatitis. Repeated inhalation of dust can
produce varying degree of respiratory irritation or lung damage.
 MATERIAL SAFETY DATA SHEET
4. First Aid Measures
Eye Contact:
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15
minutes, keeping eyelids open. Cold water may be used. Do not use an eye ointment. Seek medical
attention.
Skin Contact:
If the chemical got onto the clothed portion of the body, remove the contaminated clothes as quickly as
possible, protecting your own hands and body. Place the victim under a deluge shower. If the chemical got
on the victim's exposed skin, such
as the hands : Gently and thoroughly wash the contaminated skin with running water and non-abrasive
soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used. If
irritation persists, seek medical attention. Wash contaminated clothing before reusing.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek
medical attention.
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-
mouth resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth
resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention.
Ingestion:
Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not
breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
Serious Ingestion: Not available.

5. Fire Fighting Measures

Flammability of the Product: Flammable.
Auto-Ignition Temperature: Not available.
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: Some metallic oxides.
 MATERIAL SAFETY DATA SHEET
Fire Hazards in Presence of Various Substances:
Highly flammable in presence of open flames and sparks, of heat. Flammable in presence
of combustible materials, of moisture.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks
of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media and Instructions:
Flammable solid. Spontaneously combustible material. Do not use water or foam. SMALL
FIRE: Use DRY chemical powder.
LARGE FIRE: Use DRY chemical powder. Use water spray or fog. Cool containing vessels
with water jet in order to prevent
pressure build-up, autoignition or explosion.
Special Remarks on Fire Hazards: Refrigerate.
Special Remarks on Explosion Hazards: Not available.

6. Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Spontaneously combustible solid. Corrosive solid. Stop leak if without risk. Do not get water
inside container. Absorb with an inert material and put the spilled material in an appropriate waste
disposal. Obtain advice on use of water as spilled material may react with it. Do not touch spilled
material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas;
dike if needed. Eliminate all ignition sources. Cover with wet earth, sand or other non-combustible
material. Call for assistance on disposal.

7. Handling and Storage

Precautions:
Keep container dry. Keep away from heat. Keep away from sources of ignition. Ground
all equipment containing material.
Do not breathe dust. Never add water to this product In case of insufficient ventilation, wear
suitable respiratory equipment If you feel unwell, seek medical attention and show the label when
possible. Avoid contact with skin and eyes Keep away from incompatibles such as acids.
Storage:
 MATERIAL SAFETY DATA SHEET
Flammable materials should be stored in a separate safety storage cabinet or room. Keep away
from heat. Keep away from sources of ignition. Keep container tightly closed. Keep in a cool, well-
ventilated place. Ground all equipment containing material. Keep container dry. Keep in a cool
place.

8. Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep
airborne levels below recommended exposure limits. If user operations generate dust, fume or
mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection:
Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an
approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self-contained breathing
apparatus should be used to avoid inhalation of the product. Suggested protective clothing might
not be sufficient; consult a specialist BEFORE handling this product.
Exposure Limits: Not available.

9. Physical and Chemical Properties

Physical state and appearance: Solid. (Deliquescent crystals solid.)
Odor: Not available.
Taste: Not available.
Molecular Weight: 240.18 g/mole
Color: Yellow.
pH (1% soln/water): Not available.
Boiling Point: Decomposes.
Melting Point: 1180°C (2156°F)
Critical Temperature: Not available.
Specific Gravity: 1.86 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
 MATERIAL SAFETY DATA SHEET
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility:
Easily soluble in cold water, hot water. Very slightly soluble in methanol. Insoluble in diethyl
ether, n-octanol.

10. Stability and Reactivity

Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Highly reactive with acids.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity: Air and light sensitive.
Special Remarks on Corrosivity: Corrosive.
Polymerization: No.

11. Toxicological Information

Routes of Entry: Dermal contact. Eye contact. Inhalation. Ingestion.
Toxicity to Animals:
LD50: Not available. LC50: Not available.
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans: Very hazardous in case of skin contact (irritant, permeator), of
ingestion, of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Not available.

12. Ecological Information

Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation:
 MATERIAL SAFETY DATA SHEET
Possibly hazardous short term degradation products are not likely. However, long term degradation
products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are
not toxic.
Special Remarks on the Products of Biodegradation: Not available.

13. Disposal Considerations

Dispose in accordance with all applicable regulations. Subject to disposal
regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): P022.

14. Transport Information

DOT Classification: CLASS 8: Corrosive solid.
Identification: : Sodium sulfide, hydrated : UN1849 PG: II
Special Provisions for Transport: Not available.

15. Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Sodium sulfide
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200).
Other Classifications:
WHMIS (Canada): CLASS D-2B: Material causing other toxic effects (TOXIC).
DSCL (EEC):
R38- Irritating to skin. R41- Risk of serious damage to eyes.
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 3
Reactivity: 0
Personal Protection: j
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 1
Reactivity: 1
MATERIAL SAFETY DATA SHEET
Specific hazard:
Protective Equipment:
Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an
approved/certified respirator or equivalent. Wear appropriate respirator when

ventilation is inadequate. Splash goggles.

16. Other Information

References:
-The Sigma-Aldrich Library of Chemical Safety Data, Edition II. -Hawley,
G.G.. The Condensed Chemical Dictionary, 11e ed. New York N.Y., Van
Nostrand Reinold, 1987.
Other Special Considerations: Not available.
Created: 10/11/2005 12:37 PM
Last Updated: 05/21/2013 12:00 PM
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should
make their own investigations to determine the suitability of the information
for their particular purposes. In no event shall ScienceLab.com be liable for
any claims, losses, or damages of any third party or for lost profits or any
special, indirect, incidental, consequential or exemplary damages, howsoever
arising, even if ScienceLab.com has been advised of the possibility of such
damages.
Last Updated: 25- January-17

Disclaimer:
*****************************************************************
************
IRIL CSP.VRL provides the information contained herein in good faith but
makes no representation as to its comprehensiveness or accuracy. This
document is intended only as a guide to the appropriate precautionary
handling of the material by a properly trained person using this product.
Individuals receiving the information must exercise their independent
judgement in determining its appropriateness for a particular purpose.
IRIL
MATERIAL SAFETY DATA SHEET
SAFETY- VRL. MAKES NO REPRESENTATIONS OR WARRANTIES,
EITHER
EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY
WARRANTIES
OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE
WITH
RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE
PRODUCT TO
WHICH THE INFORMATION REFERS. ACCORDINGLY, IRIL
CSP.VRL WILL NOT
BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR
RELIANCE
UPON THIS INFORMATION.
*****************************************************************
*******
Prepared by: IRIL-SAFETY-VRL
Phone Number: (02876) 248700 (GUJARAT.INDIA.)