Solved Problems IN Quantum Physics: Dr. Ing. Valerică D. Ninulescu
Solved Problems IN Quantum Physics: Dr. Ing. Valerică D. Ninulescu
IN
QUANTUM PHYSICS
The radiant exitance (energy radiated from a body per unit area per unit
time), M , of a blackbody at temperature T grows as T 4 :
M (T ) = σT 4 , (1.1)
Wien’s displacement law states that the wavelength for maximum emis-
sive power from a blackbody is inversely proportional to its absolute temper-
ature,
λmax T = b. (1.3)
8πν 2
ρν (ν, T ) = kB T, (1.4)
c3
The spectral energy density in terms of wavelength can be derived as
8π
ρλ (λ, T ) = kB T. (1.5)
λ4
The Rayleigh–Jeans formula agrees with experimental results only at very
long wavelengths at any given temperature.
8πν 2 hν
ρν (ν, T ) = 3
. (1.6)
c exp(hν/kB T ) − 1
The spectral energy density in terms of wavelength can be derived as
8πhc 1
ρλ (λ, T ) = 5
. (1.7)
λ exp(hc/λkB T ) − 1
The spectral radiant exitance Mλ (emitted power per unit of area and
unit of wavelength) of a blackbody is
2πhc2 1
Mλ (λ, T ) = . (1.8)
λ5 exp(hc/λkB T ) − 1
2
(1/2)mvmax = hν − Φ. (1.9)
At the incidence of photons of frequency ν, the stopping voltage of the
photoelectrons is
U0 = (h/e)ν − Φ/e. (1.10)
Planck-Einstein relations
Compton effect
Given that λ is the wavelength of the incident photon and λ′ that of the
scattered photon in the direction θ (angle between the direction of incidence
and direction of scattering, see Fig. 1.1), the change in wavelength is
where
Answer. The Earth emits radiation all the time and receives radiation from the
Sun during the day only. During a clear day, the Earth surface is heated up; it
means that the flux of energy received from the Sun is greater than that emitted
by the Earth. Once the Sun goes down, less and less power is received by the
Earth. The Earth surface begins to cool and during the night the temperature is
contiuously decreasing. The Earth’s surface is coldest in the early morning hours.
1.2 Determine the energy of a photon and the number of photons emitted
per second by a P = 2 mW He–Ne laser that operates on the wavelength
λ = 632.8 nm. Interpret the results.
Solution. The energy of a photon is
c
E=h = 3.14 × 10−19 J,
λ
4 1 The experimental foundations of quantum mechanics
which is a very small energy for the macroscopic world. The appropriate energy
unit at the atomic scale is the electron volt. The energy of a photon emitted by the
He–Ne laser is
3.14 × 10−19
E = 3.14 × 10−19 J = eV = 1.96 eV.
1.6 × 10−19
The number of photons emitted per second is
P
= 6.37 × 1015 photons/s.
hc/λ
The huge number of photons explains why we do not notice the quantum nature of
the electromagnetic field in everyday life: adding or subtracting one photon does
not make a noticeable difference.
1.4 Prove that the relation between radiant exitance (emitted power per
unit area) M of a blackbody and the energy density ρ of the blackbody
cavity is
M = (1/4)cρ. (1.14)
Solution. Let us consider a small surface of the body; this can be considered as
plane. Let us denote by A the area. We choose a 3-D Cartesian coordinate system
with the origin O on the emitting surface and the Oz-axis perpendicular to the
surface and directed outward (see figure below).
z
We first write the flux of energy through the surface of area
✻ n
✕ A inside the solid angle dΩ = sin θ dθ dϕ around the direc-
A θ tion n determined by polar angles θ and ϕ. During the time
❘ O interval ∆t, the energy emitted inside the solid angle dΩ is
located inside the cylinder of generatrix paralell to n and
c ∆t length c ∆t. The energy inside this volume is ρAc ∆t cos θ
and only the fraction dΩ/4π propagates in the considered
solid angle.
The total energy emitted through the surface of area A in the time interval ∆t
is
θ=π/2Z ϕ=2π
sin θ dθ dϕ 1
Z
ρAc ∆t cos θ = cρA ∆t.
θ=0 ϕ=0 4π 4
M = (1/4)cρ.
Remark. In case we are interested in the relation between the spectral quantities
Mλ and ρλ , we restrict ourselves to the radiation in the wavelength interval (λ, λ +
dλ). The energy emitted with the wavelength in the specified interval in ∆t is
θ=π/2Z ϕ=2π
sin θ dθ dϕ 1
Z
ρλ dλ Ac ∆t cos θ = cρλ dλ A ∆t.
θ=0 ϕ=0 4π 4
The energy emitted in unit time through the unit area of surface is
Mλ dλ = (1/4)cρλ dλ
is inferred.
6 1 The experimental foundations of quantum mechanics
1.5 (a) Use Eq. (1.6) to determine the radiant energy density ρ(T ) in a
cavity whose walls are kept at the temperature T . Hint:
∞
x3 π4
Z
dx = .
0 exp x − 1 15
∞ ∞
8πh ν3
Z Z
ρ(T ) = ρν (ν) dν = 3 dν
0 c 0 exp(hν/kB T ) − 1
4Z ∞
x3 8π5 kB
4
8πh kB T
= 3 dx = T 4 ∝ T 4.
c h 0 exp x − 1 15c h3
3
1 2π5 kB4
2π5 kB4
M= cρ = T 4
= σT 4
, where σ = ≈ 5.67 × 10−8 W m−2 K−4
4 15c2 h3 15c2 h3
is Stefan–Boltzmann constant.
1 − x/5 = exp(−x),
where the shorthand notation x = hc/λkB T have been used. Besides the trivial
solution x = 0, a positive solution exists, x ≈ 4.965 (see figure below).
✻
1
The spectral energy density is maximum for the wavelength λmax given by
hc
λmax T ≈ ≈ 2.898 × 10−3 m K.
4.965 kB
1.7 Derive the form of the Planck radiation formula in the limit case:
(a) hc/λkB T ≪ 1 (large wavelengths);
(b) hc/λkB T ≫ 1 (small wavelengths).
Interpret the results.
Solution. (a)
8πhc 1
ρλ (λ, T ) = 5
λ exp(hc/λkB T ) − 1
8πhc 1
= .
λ5 hc hc 2
1+ + + ··· − 1
λkB T λkB T
8πhc 1 8πhc
ρλ (λ, T ) ≈ = exp(−hc/λkB T ).
λ5 exp(hc/λkB T ) λ5
In this case hc/λ ≫ kB T and the discreteness of the cavity energy is obvious;
the classical theory gives completely wrong predictions.
Plot the stopping voltage versus the frequency of the light and use the
graph to determine the threshold frequency, the threshold wavelength, the
work function of the metal, and the quotient h/e.
Solution. The dependence of the stopping voltage on the frequency of light is given
by Eq. (1.10). The following Matlab program determines all required physical
quantities.
Phi_over_e=-p(2) % V
h_over_e=p(1)*1e-14 % Vs
plot([nu_0 1.05*max(nu)]*1e-14,...
polyval(p,[nu_0 1.05*max(nu)]*1e-14))
set(gca,’XLim’,[4.5 8.5],’XTick’,4.5:0.5:8.5,’XTickLabel’,...
[’4.5’;’5.0’;’5.5’;’6.0’;’6.5’;’7.0’;’7.5’;’8.0’;’8.5’],...
’YLim’,[0 1.6],’YTick’,0:0.2:1.6,’YTickLabel’,...
[’0.0’;’0.2’;’0.4’;’0.6’;’0.8’;’1.0’;’1.2’;’1.4’;’1.6’])
After running the program, the sought quantities are displayed in the Matlab
Command Window: ν0 ≈ 4.81 × 1014 Hz, λ0 ≈ 624 nm, Φ ≈ 1.99 eV, and h/e ≈
4.15 × 10−15 V s. The graph is shown as ‘Figure 1’ window and is presented below.
1.6
1.4
1.2
1.0
U/V
0.8
0.6
0.4
0.2
0.0
4.5 5.0 5.5 6.0 6.5 7.0 7.5 8.0 8.5
ν/(1014 Hz)
The stopping voltage is given by Eq. (1.10), where ν = c/λ. We get U0 ≈ 0.77 V.
(b) The number of electrons extracted in unit time is
P
n=η
hc/λ
λeP
I = ne = η ≈ 1.8 µA.
hc
Let
p us denote by me the electron mass. The initial energy of the system is
pc + m2e c4 + p2 c2 , while the energy of the final state is me c2 . It is clear that
conservation of energy is violated, so the process cannot occur.
Remark. An electron participating in the photoelectric effect is not free, but
bound to either an atom, molecule, or a solid. The electron and the heavy matter
to which the electron is coupled share the energy and momentum absorbed and it is
always possible to satisfy both momentum and energy conservation. However, this
heavy matter carries only a very small fraction of the photon energy, so that it is
usually not considered at all.
Almost all of this radiation is blocked by the thick leaded glass in the screen.
1.2 Questions and problems 11
p❘
e
(b) The kinetic energy of the recoiling electron is equal to the energy loss of the
photon:
of atoms de-excite. These atoms have spent a time t in the upper energy level.
Thus, the probability that an atom remains in the upper energy level a time t is
AN (t) dt
= A exp(−At) dt.
N (0)
Fundamental physical
constants
The tables below give values of some basic physical constants recom-
mended for international use by the Committee on Data for Science and
Technology (CODATA).