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    Solubility of Organic Compounds: Answers To Questions

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    Matthew Rei De Leon
    This document discusses the solubility of various organic compounds in different solvents. It begins by explaining the intermolecular forces involved when different solutes dissolve in solvents like water, diethyl ether, sodium hydroxide, sodium bicarbonate, hydrochloric acid, and sulfuric acid. Balanced chemical equations are provided for representative solute-solvent interactions. The best solvent is identified to differentiate between several pairs of compounds based on their predicted solubility properties.

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    Solubility of Organic Compounds: Answers To Questions

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    Matthew Rei De Leon
    383 views3 pages
    This document discusses the solubility of various organic compounds in different solvents. It begins by explaining the intermolecular forces involved when different solutes dissolve in solvents like water, diethyl ether, sodium hydroxide, sodium bicarbonate, hydrochloric acid, and sulfuric acid. Balanced chemical equations are provided for representative solute-solvent interactions. The best solvent is identified to differentiate between several pairs of compounds based on their predicted solubility properties.

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    This document discusses the solubility of various organic compounds in different solvents. It begins by explaining the intermolecular forces involved when different solutes dissolve in solvents like water, diethyl ether, sodium hydroxide, sodium bicarbonate, hydrochloric acid, and sulfuric acid. Balanced chemical equations are provided for representative solute-solvent interactions. The best solvent is identified to differentiate between several pairs of compounds based on their predicted solubility properties.

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    © All Rights Reserved
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    Download as docx, pdf, or txt
    383 views3 pages

    Solubility of Organic Compounds: Answers To Questions

    Uploaded by

    Matthew Rei De Leon
    This document discusses the solubility of various organic compounds in different solvents. It begins by explaining the intermolecular forces involved when different solutes dissolve in solvents like water, diethyl ether, sodium hydroxide, sodium bicarbonate, hydrochloric acid, and sulfuric acid. Balanced chemical equations are provided for representative solute-solvent interactions. The best solvent is identified to differentiate between several pairs of compounds based on their predicted solubility properties.

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    M. De Leon / Chemistry 31.

    1 (2019) P a g e |1

    Solubility of Organic Compounds


    Matthew Rei B. De Leona, Avian Faye B. Vitalb
    aNational
    Institute of Molecular Biology and Biotechnology, University of the Philippines Diliman, Quezon City, Philippines
    bNational
    Institute of Molecular Biology and Biotechnology, University of the Philippines Diliman, Quezon City, Philippines
    Performed 15 August 2019; Submitted 22 August 2019

    ANSWERS TO QUESTIONS

    1. Account for the solutes dissolved in the given solvent by identifying the intermolecular forces of attraction
    involved.
     Hexane was not included in the table below since it is an inert compound.

    Test H2O diethyl 5.0% NaOH 5.0% 5.0% HCl Conc.


    Compound ether NaHCO3 H2SO4
    phenol - - Ion-induced - - -
    dipole, LDF
    benzoic acid - - Ion-induced Ion-induced - -
    dipole, LDF dipole, LDF
    sucrose H-bonding, - - - - -
    LDF
    aniline - - - - Ion-dipole, -
    H-bonding,
    LDF
    ethanol H-bonding, Dipole- - - - -
    LDF induced
    dipole, LDF
    benzaldehyde - - - - - Ion-
    induced
    dipole, LDF

    [1] Silberberg, M. In Chemistry: The Molecular Nature of Matter and Change; McGraw-Hill Companies, 2009; pp
    451–456.
    2. Write the balanced equations involved for solutes that dissolved with the given solvent. Draw the organic
    compounds using bond-line structures.
     phenol and NaOH: C6H5OH+ NaOH→ C6H5ONa + H2O

    Matthew Rei B. De Leon. Mobile: 09195075924


    E-mail address: mbdeleon10@up.edu.ph
    M. De Leon / Chemistry 31.1 (2019) P a g e |2

     benzoic acid and NaOH: C6H5COOH + NaOH → C6H5COONa + H2O

     benzoic acid and NaHCO3: C6H5COOH + NaHCO3 → C6H5COONa + CO2 + H2O

     sucrose and H2O: C12H22O11 + H2O → C6H12O6 + C6H12O6

     aniline and HCl: C6H5NH2 + HCl → C6H5NH3Cl

     ethanol and H2O: C2H5OH(l) + H2O(l) → C2H5OH(aq)

     ethanol and diethyl ether: C2H5OH + (C2H5)2O → C6H16O2

    Matthew Rei B. De Leon. Mobile: 09195075924


    E-mail address: mbdeleon10@up.edu.ph
    M. De Leon / Chemistry 31.1 (2019) P a g e |3

     benzaldehyde and H2SO4: C7H6O + H2SO4 → C7H6O4S + H2O

    [2] Lehman, J. W. Operational Organic Chemistry: A Problem-solving Approach to the Laboratory Course, 4th ed.;
    Pearson Prentice Hall, 2009.
    [3] Carter, J. The Effect of PH on Ethanol Preserved Muscle Tissue. Collection F 2009, 23 (1-2), 36–45.
    [4] Diethyl ether ethanol. https://pubchem.ncbi.nlm.nih.gov/compound/Diethyl-ether-ethanol (accessed Aug
    21, 2019).

    3. Determine the best solvent to differentiate the following pairs of compounds based on their predicted solubility.
     CH3NH2 and CH3(CH2)5NH2 = H2O
     phenol and CH3(CH2)5COOH = NaHCO3
     p-xylene and benzaldehyde = H2SO4
     chloroform and tert-butanol = H2SO4
     glucose and n-butanol = diethyl ether

    [5] Fieser, L. F.; Williamson, K. L. Organic Experiments, 7th ed.; D.C. Heath, 1992; pp 574.

    Matthew Rei B. De Leon. Mobile: 09195075924


    E-mail address: mbdeleon10@up.edu.ph

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