Dislocations and Strengthening Mechanisms: 7 - 1 I N T R o D U C T I o N
Dislocations and Strengthening Mechanisms: 7 - 1 I N T R o D U C T I o N
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The process by which plastic deformation is produced by dislocation is termed slip, the
crystallographic plane along which the dislocation line crosses is the slip plane (see figure above).
Macroscopic plastic deformation simply corresponds to permanent deformation that results from
the movement of dislocations, or slips, in response to shear stress (see figure). Part (a) shows an
edge dislocation where the dislocation line moves
parallel in the direction of the applied shear. Part (b)
shows a screw dislocation where the dislocation line
motion is perpendicular to the stress direction. However,
the net plastic deformation for the motion of both
dislocation types is the same.
The direction of motion of the mixed dislocation line is
neither perpendicular nor parallel to the applied stress,
but lies somewhat in between.
All metals and alloys contain some dislocations that were
introduced during solidification, during plastic
deformation, and as a consequence of thermal stresses
that result from rapid cooling.
Dislocation density in a material is expressed as the total dislocation length per unit volume, or
equivalently, the number of dislocations that intersect a unit area of a random section. The units of
dislocation density are mm of dislocation /mm^3 or just 1/mm^2.
Dislocation densities as low as 103 / mm2 are typically found in carefully solidified metal crystals.
For heavily deformed metals, the density may run as high as 109 – 1010 /mm2. Heat treating a
deformed metal specimen can diminish the density to on the order of 105 – 106 /mm2.
For ceramic materials, dislocation density is between 10^2 – 10^4 /mm2. For silicon single
crystals (used in IC) the value lies between 0.1 – 1 /mm^2.
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7.3 Characteristics of Dislocations
Strain fields (important dislocation characteristic) exist
around dislocations which are influential in determining the
mobility of the dislocations, as well as their ability to
multiply.
When metals are plastically deformed, some fraction of the
deformation energy (approx. 5%) is retained internally; the
remainder is dissipated as heat. The major portion of this
stored energy is strain energy associated with dislocations.
Consider the edge dislocation shown in the figure. Some
atomic lattice distortion exists around the dislocation line. Consequently, there are regions in which
compressive, tensile, and shear lattice strains are imposed in the neighboring atoms.
Atoms immediately above and adjacent to the dislocation line are squeezed together; may be
thought of as experiencing a compressive strain relative to atoms positioned far in the perfect
crystal.
Directly below the half-plane, lattice atoms sustain an imposed tensile strain
Shear strains also exist in the vicinity of the edge dislocation. However, for a screw dislocation,
lattice strains are pure shear only.
Lattice distortions may be considered as
strain fields that radiate from the dislocation
line. The strains extend into the surrounding
atoms with magnitude decreasing with radial
distance from dislocation.
Strain fields surrounding two (or more)
adjacent dislocations may interact such that
forces are imposed on each dislocation by
the combined interactions of all its
neighboring dislocations.
For example, consider two edge dislocations
that have the same sign and the same slip
plane (part a of the figure). The strain field
interaction is such there exists between these
two isolated dislocations a mutual repulsive
force that tends to move them apart.
Part (b) shows that two edge dislocations with the same slip plane but opposite sign will be
attracted to one another and dislocation annihilation will occur when they meet. The two extra half-
planes of atoms will align and become a complete plane.
Dislocation interactions are possible between edge, screw,, and/or mixed dislocations. Resulting
stain field are important in the strengthening mechanisms of metals.
During plastic deformation, the number of dislocations increases dramatically. Dislocation density
of highly deformed may be as high as 10^10 /mm^2. One important source of such increase is
existing dislocations which multiply. Also, grain boundaries as well as internal defects and surface
irregularities (scratches and nicks - stress concentrations) may serve as dislocation formation sites
during deformation.
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7.4 Slip Systems
Dislocations do not move with the same degree of ease on all crystallographic planes of atoms and
in all crystallographic directions.
Ordinarily there is a preferred plane and in that plane there are specific directions along which
dislocation motion occurs. This plane is called the slip plane and the direction of movement is
called the slip direction. The combination of the slip plane and the slip direction is called the slip
system.
The slip system depends on the crystal structure of the metal and is such that the atomic distortion
(which accompanies the motion of a dislocation) is a minimum.
For a particular crystal structure, the slip plane is the plane that has the most dense atomic
packing; the greatest planar density. Also, the slip direction corresponds to the direction (in the slip
plane) that is most closely packed with atoms; the highest linear density. (see section 3.11). How
do we explain this?????
Since the distance between atoms is shorter than the average, the distance perpendicular to the
plane has to be longer than average. Being relatively far apart, the atoms can move more easily
with respect to the atoms of the adjacent plane.
Example: consider the FCC crystal structure, part
(a) shows a unit cell. There is a set of planes, the
{111} family, all of which are closely packed. A
{111}-type plane is indicated in the unit cell (part b).
Slip occurs along <110>-type direction within the
{111} planes as indicated in the figure. Hence,
{111} <110> represents the slip plane and direction
combination, or the slip system for FCC.
Several slip systems may exist for a particular crystal structure, the number of independent slip
systems represents the different possible combinations of slip planes and directions. For FCC, there
are 12 slip systems: 4 unique {111} planes and (within each plane) 3 independent <110>
directions.
Table below list the possible slip systems for FCC, BCC, and HCP crystal structures. For BCC and
HCP, slip is possible on more than one family of planes which are operable at elevated
temperatures.
Metals with FCC and BCC crystal structures have a relatively large number of slip systems (at least
12). These metals are quite ductile because extensive plastic deformation is possible along the
various systems. Conversely, HCP metals having few slip systems are normally quit brittle.
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7.5 Slip in Single Crystals
As discussed previously, edge, screw, and mixed dislocations move in response to shear stresses
applied along a slip plane and in a slip direction.
Also, as noted in section 6.2, even though an applied stress may be pure tensile
(or compressive), shear components exist at all but parallel or perpendicular
alignments to the stress direction. These shear components are called resolved
shear stresses, and their magnitudes depend not only on the applied stress, but
also on the orientation of the both the slip plane and direction within that plane.
Let (see figure)
φ = angle between applied stress direction and the normal to slip plane.
λ = angle between applied stress direction and slip direction.
It can be shown that the resolved shear stress is
τ R = σ cos φ cos λ (7.1)
In response to an applied tensile (or compressive) stress, slip in a single crystal specimen starts on
the most favorably oriented slip system when the resolved shear stress reaches some critical value,
called the critical resolved shear stress λ crss ; it represents the minimum shear stress required to
initiate slip and hence when yielding occurs.
Therefore, the single crystal plastically deforms or yields when τ R )max = τ crss and the magnitude
of the applied stress required to initiate yielding (yield strength) is
τ crss
σy = (7.3)
(cos φ cos λ )max
The minimum stress necessary to introduce yielding occurs when a single crystal is oriented such
that φ = λ = 45 o , under these conditions
σ y = 2 τ crss (7.4)
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On the surface of a polished single crystal specimen, these steps appear as lines, which
are called slip lines. A zinc single crystal that has been plastically deformed to the degree
that theses slip markings are noticeable as shown.
As extension of a single crystal continues, both the number of slip lines and slip step
width will increase.
φ = 45 o , λ = tan −1 ( a 2 / a ) = 54.7 o
a) τ R = σ cos φ cos λ = ( 52 )(cos 45 o )(cos 54.7 o ) = 21.3 MPa
τ crss 30 MPa
b) σy = = = 73.4 MPa
(cos φ cos λ )max (cos 45 o )(cos 54.7 o )
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7.7 Deformation By Twinning (not covered)
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9 Since the two grains are of different orientations, a dislocation passing into grain B will have to
change its direction of motion; this becomes more difficult as crystallographic misorientation
increases.
9 The atomic disorder within a grain boundary region will result in a discontinuity of slip planes
from one grain into the other.
It should be mentioned that for high-angle grain boundaries, dislocations may not cross grain
boundaries during deformation; rather, a stress concentration ahead of a slip plane in one grain may
activate sources of new dislocations in an adjacent grain.
A fine-grained material (one that has small grains) is harder and stronger than one that is coarse
grained. The former has a greater total grain boundary area to impede dislocation motion. For
many materials, the yield strength σ y varies with grain size according to Hall-Petch equation:
σ y = σ o + k y d −1 / 2 (7.5)
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7.9 Solid-Solution Strengthening (see CD)
Alloying metals with impurity atoms (substitutional or interstitial) into solid solution (section 4.3)
is another technique to strengthen and harden metals. This is called solid-solution strengthening.
High-purity metals are almost always softer and weaker than alloys composed of the same base
metal. Increasing the concentration of impurity results in an attendant increase in tensile and yield
strengths. Figure shown indicates variation of tensile strength, yield strength, and ductility (%EL)
with nickel content for copper-nickel alloy.
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To accomplish this, a smaller impurity atom is located where its tensile strain will partially cancel
some of the dislocation’s compressive strain; adjacent to the dislocation line and above the slip
plane (see part b). A larger impurity atom wonders and diffuses through the lattice where its
compressive strain will partially cancel some of the dislocation’s tensile strain; below the
dislocation line (see part d).
An interstitial impurity atom (imposes compressive stains in its vicinity) wonders and diffuses
through the lattice where its compressive strain will partially cancel some of the dislocation’s
tensile strain; just below the dislocation line
For both cases, the resistance to slip is greater when impurity atoms are present. Also, the same
lattice strain interactions will exist between impurity atoms and dislocations that are in motion
during plastic deformation. Thus, a greater applied stress is necessary to first initiate and then
continue plastic deformation for solid-solution alloys, as opposed to pure metals; thus,
enhancement of strength and hardness.
The price paid for the enhancement of strength and hardness is a reduction in the ductility (%EL)
of the metal as %CW increases.
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Strain hardening is demonstrated in a stress-strain
diagram shown (section 6.8) – see figure repeated.
It can be explained: the dislocation density in a metal
increases with cold work (deformation) due to dislocation
multiplication or formation of new dislocations. Thus, the
average distance of separation between dislocations
decreases-dislocation are positioned closer together. One
the average, dislocation-dislocation strain interactions are
repulsive. The net result is that the motion of a
dislocation is hindered by the presence of other
dislocations. As the dislocation density increases,
resistance to dislocation motion becomes more
pronounced. Thus, stress needed to deform a metal
increases with increasing cold work.
Figure shown demonstrates the influence of cold work on the
stress-strain behavior for low-carbon steel.
Stress
Strain hardening is often utilized commercially to enhance the
mechanical properties of metals during fabrication procedures.
The effects of strain hardening may be removed by annealing heat
treatment (chapter 11).
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7.11 Recovery
With no applied external stress, heating and holding at elevated temperature Æincreases atomic
diffusion Æ enhances dislocation motion Æ relieves some of the stored internal strain energy.
There is some reduction in the number of dislocations, and dislocations with low internal strain
energy are produced.
Also, physical properties such as electrical and thermal conductivities and the like are recovered to
the values existed before cold working.
7.12 Recrystallization
Even after recovery is complete, the grains are still in relatively high strain energy state.
Recrystallization is the formation of a new set of strain-free and equiaxed grains (approx. equal
dims. in all dirs.) that have low dislocation densities and are characteristic of the precold-worked
condition.
The difference in internal energy between the strain and the unstrained material is the driving force
to produce this new grain structure.
The new grains form as very small nuclei and grow until they completely consume the parent
material, processes that involve short-range diffusion (Temp. and Time are important parameters.)
The photomicrographs below show several stages of recrystallization and grain growth of brass:
a) Cold-worked grain structure (33%CW) (70X).
b) Initial stage of recrystallization after 3s at 580o C, the very small grains are those that have recrystallized.
c) Partial replacement of cold-worked grains by recrystallized ones after 4s at 580o C.
d) Complete recrystalization after 8s at 580o C. All called-worked crystals are consumed.
e) Grain growth after 15 min. at 580o C. f) Grain growth after 10 min. at 700o C.
a) 33% cold
b) New crystals
worked
nucleate after c)After 4
brass 3 sec. at 580C. seconds
0.6 mm
0.6 mm
e)After 15 min
d)After 8 at 580 C
seconds
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Above figures show that recrystallization depends on time. Next figure shows that recrystallization
also depends on temperature: the influence of annealing temperature on the tensile strength and
ductility of a brass alloy (heat treatment for 1 h). Grain size as a function of annealing temperature
is indicated. Grain structures during recovery, recrystallization, and grain growth stages are shown.
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Recrystallization precedes more rapidly in pure metals than alloys. For pure metals,
recrystallization temperature is normally (0.3 Tm) where Tm is the absolute melting temperature.
For some commercial alloys it may run as high as (0.7 Tm). See table below for recrystallization
and melting temperatures for a number metals and alloys.
From Fig.(a) 20% CW gives σ y = 345 MPa . But part (c) shows that greater than 20% EL are
possible for deformation of 23% CW or less.
Thus during the final drawing operation, deformation must be between 20%CW and 23%CW.
Take the average 21.5%CW, and then calculate the final diameter for the first drawing do', which
becomes the original for the second drawing. So,
π (d o' / 2) 2 − π (5.1 / 2) 2
21.5% CW = X 100
π (d o' / 2) 2
Or d o' = 5.8 mm
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7.13 Grain Growth
After recrystallization is complete, the strain-free grains will
continue to grow if the metal specimen is held at the elevated
temperature. See part (e) of figure above: grain growth after 15 min
at 580o C. This phenomenon is called grain growth. Grain growth
does not have to be preceded by recovery and recrystallization.
An energy is associated with grain boundaries. As grains increase in
size, the total boundary area decreases, yielding an attendant
reduction in the total energy which is the driving force for grain
growth. Big grains grow at the expense of the small ones that shrink.
Thus the average grain size increases with time.
The growth of grain size with temperature can occur in all
polycrystalline materials. It occurs by migration of atoms at grain
boundaries by diffusion, thus grain growth is faster at higher
temperatures. The directions of boundary movement and atomic
motion are opposite to each other as shown in the figure.
For many polycrystalline materials, the grain diameter d varies with
time t according to the empirical relation:
d n − don = K t (7.7)
Where d = grain diameter at time t, do = initial grain diameter at time t = 0.
K = coefficient dependent on material and temperature T.
n = constant equals to greater than 2.
t = elapsed time.
The dependence of grain size on time and temperature is demonstrated in the figure shown. A plot
of the logarithm of grain size as a function of the logarithm of time for brass alloy at several
temperatures. The curves are linear at
lower temperature. Grain growth
proceeds more rapidly as temperature
increases; the curves are displaced
upward to larger grain sizes. This is
explained by enhancement of diffusion
rate with rising temperature.
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Notes:
1) Fabrication of metals: forming operations, casting, powder metallurgy & welding.
2) Thermal processing of metals: Annealing processes, quenching, and tempering.
3) Plastic deformation is usually achieved by forming operations, where some external stress is
used with magnitude exceeding the
yield strength of the material.
Examples of forming techniques are:
a) forging, b) rolling, c) extrusion,
and d) drawing.
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