DPP EXERCISE

NEET
INORGANIC CHEMISTRY

BY
JITENDRA HIRWANI

PERIODIC TABLE
&
PERIODICITY

ETOOSINDIA
INDIA’S NO. 1 ONLINE COACHING

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DPP -1
1. Modern periodic law is
(1) The physical and chemical properties of the elements are periodic function of their atomic numbers.
(2) The physical and chemical properties of the elements depend upon the energy of the electrons.
(3) The physical and chemical properties of the elements depend upon atomic weight.
(4) None of these.
Ans. (1)
2. Which of the following statements about modern periodic table is incorrect ?
(1) The p-block has 6 columns because a maximum of 6 electrons can occupy all the orbitals in the p-subshell.

A
(2) The d-block has 8 columns because a maximum of 8 electrons can occupy all the orbitals in the d-subshell.

I
(3) Each block contains a number of columns equal to number of electrons that can occupy the subshell.
(4) The block indicates the value of azimuthal quantum number for the last subshell which received electrons.
Ans. (2)
3.

Ans.
(1) Metalloids
(2)
(2) Transition elements (3) Non-metals

N D
Elements which generally exhibit multiple oxidation states and whose ions are usually coloured are
(4) Gases

I
4. IUPAC name of the element having atomic number 108 is
(1) Unniloctium (2) Ununoctium (3) Nilniloctinium (4) Ununoctinium

S
Ans. (1)
5. Which of the following is a representative element ?
(1) Zn (2) Sr (3) Cu (4) Fe

O
Ans. (2)
6. The electronic configuration of an element is 1s2 2s2 2p6 3s2 3p3. What is the atomic number of the element, which is just
below the above element in the periodic table ?

Ans.
7.
(3)

TO
(1) 36 (2) 49 (3) 33

The valence shell electronic configuration of transition elements is

(1) ns1 (2) ns2np5 (3) ns0–2(n–1)d1–10
(4) 34

(4) ns2(n–1)d10

E
Ans. (3)
8. Eka-aluminium and Eka-silicon are known as
(1) Gallium and Germanium (2) Aluminium and Silicon
(3) Iron and Sulphur (4) Boron and Technitium
Ans. (1)
9. Which is mismatched regarding the position of the element as given below ?
(1) X(Z = 89) - f block, 6th period (2) Y(Z = 100) - f block, 7th period
(3) Z(Z = 115) - d block, 7th period (4) Both (1) & (3)
Ans. (4)
10. Which set does not show correct matching ?
(1) SC3+ [Ne]3s2 3p6 zero group (2) Fe2+ [Ar]3d6 VIII group
5 1
(3) Cr[Ar] 3d 4s VIB group (4) All of the above
Ans. (1)

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11. 4d35s2 configuration belongs to which group :-

(1) IIA (2) IIB (3) V B (4) III B
Ans. 3
12. An ion M+3 has electronic configuration [Ar] 3d10 4s2 element M belongs to :-
(1) s-block (2) p-block (3) d-block (4) f-block
Ans. (2)

I A
N D
S I
O O
E T

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DPP - 2
1. When a neutral atom is converted into a cation its
(1) Atomic weight increases (2) Atomic weight decreases
(3) Size increases (4) Size decreases
Ans. (4)
2. Of the following, which one is a correct statement ?
(1) Ionic radius of a metal is same as its atomic radius
(2) The ionic radius of a metal is greater than its atomic radius
(3) The atomic radius of a non-metal is more than its ionic radius

A
(4) The ionic radius of a metal is less than its atomic radius

I
Ans. (4)
3. Which of the following N3–, O2–, F– is largest in size ?
(1) N3– (2) O2– (3) F– (4) All of these

D
Ans. (1)
4. Which of the following is not correct for iso-electronic ions?

N
(1) They have the same number of electrons around their nuclei.

I
(2) Higher the atomic number, higher will be positive charge in a series of isoelectronic ions of same period.
(3) Isoelectronic ions have same electric charge

S
(4) An isoelectronic series may have both positively and negatively charged ions.
Ans. (3)
5. The radii of F, F–, O and O2– are in the order

O
(1) O2– > O > F– > F (2) F– > O2– > O > F (3) O2– > F– > O > F (4) O2– > F– > F > O
Ans. (3)
6. Which of the following is correct?

Ans. (3)

TO
(1) rionic  Z (2) rionic  Zeff (3) rionic  Z
1
eff
2
(4) rionic  Z eff

E
7. Which ion has the largest radius ?
(1) Se2– (2) F– (3) O2– (4) Rb+
Ans. (1)
8. Which one of the following is correct order of the size of iodine species ?
(1) I+ > I– > I (2) I– >I > I+ (3) I > I– > I+ (4) I > I+ > I–
Ans. (2)
9. According to Slater rule, which of the following has the highest screening constant for last electron ?
(1) Fluorine (F) (2) Oxygen (O) (3) Carbon (C) (4) Nitrogen (N)
Ans. (1)
10. The ionic sizes decreases in the order :
(1) K+ > S2– > Sc3+ < V5+ < Mn7+ (2) S2– < K+ > Sc3+ > V5+ > Mn7+
(3) Mn7+ > V5+ < Sc3+ > K+ > S2– (4) Mn7+ < V5+ < Sc3+ < S2– > K+
Ans. (2)

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11. The set representing the correct order of ionic radius is :

(1) Li+ > Be2+ > Na+ > Mg2+ (2) Na+ > Li+ > Mg2+ > Be2+
(3) Li+ > Na+ > Mg2+ > Be2+ (4) Mg2+ > Be2+ > Li+ > Na+
Ans. (2)
12. Crystal radius of three ions have 100 pm, 81 pm and 75 pm respectively. If all the three ions have same number of
protons, then select the correct statement.
(1) All the three ions are isoelectronic
(2) All the three ions have same charge
(3) All the three ions have different charge but metal is same
(4) All are correct
Ans. (3)

A
13. Which of the following has largest radius :-

I
(1) 1s2, 2s2, 2p6, 3s2 (2) 1s2, 2s2, 2p6, 3s2, 3p1 (3) 1s2, 2s2, 2p6, 3s2, 3p3 (4) 1s2, 2s2, 2p6, 3s2, 3p5
Ans. 1

D
14. Ionic radii of :-
(1) Ti4+ < Mn7+ (2) 37Cl– < 35Cl– (3) K+ > Cl– (4) P3+ > P5+
Ans. 4

N
15. In an anion :-

I
(1) Number of proton decreases (2) Protons are more than electrons
(3) Effective nuclear charge is more (4) radius is larger than neutral atom

S
Ans. 4

O O
E T

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DPP - 3
1. Which of the following processes involves absorption of energy ?
(1) Cl(g) + e–  Cl– (g) (2) O–(g) + e–  O2– (g)
(3) O(g) + e–  O– (g) (4) S(g) + e–  S– (g)
Ans. (2)
2. Energy required for the ionisation of 0.02 gram atom of magnesium is x kJ. The amount of energy required to ionise 1
atom of magnesium is

x x  103
J
(1) x kJ (2) 0.02N J (3) 0.02N A (4) xNA kJ
A

A
Ans. (3)

I
3. Which systematic diagram is correct about ionisation energy of coinage metals ?

D
Au Au
Remain
Increase Decrease Decrease
almost same
(1) (2)

N
Cu Decrease Ag Cu Increase Ag

(3)
Decrease

Cu
Au

Decrease
Remain
almost same

Ag

S I
(4)
Decrease

Cu
Au

Decrease
Increase

Ag

Ans.
4.
(4)

O O
Assign true (T) or false (F) for the following statements and select correct option for your answer.
(I) I.P. of O(g) is less than I.P. of O–(g)
(III) E.A. of Ne(g) is greater than E.A. of O(g)
(II) I.P. of Ne(g) is greater than I.P. of Ne+(g)
(IV) I.P. of N(g) is greater than I.P. of N+(g)

T
(1) F, F, T. T (2) T, T, T, T (3) T, T, T, F (4) F, T, F, T
Ans. (1)

E
5. Process Na+ 
I II
 Na(g)   Na(s) :
(1) In (I) energy released, (II) energy absorbed (2) In both (I) & (II) energy is absorbed
(3) In both (I) & (II) energy is released (4) In (I) energy absorbed, (II) energy released
Ans. (3)
6. Arrange the elements with the following electronic configuration of valence electron in decreasing order of egH(–)
(A) 3s2 3p4 (B) 2s2 2p4 (C) 2s2 2p3 (D) 2s2 2p5
(1) C > A > B > D (2) C > B > A > D (3) b > C > D > A (4) A > B > C > D
Ans. (2)
7. Be and Mg have zero value of electron affinity, because :
(1) Be and Mg have [He] 2s2 and [Ne] 3s2 configuration respectively
(2) 2s and 3s orbitals are filled to their capacity
(3) Be and Mg are unable to accept electron
(4) All the above are correct
Ans. (4)

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8. Compared to the first ionisation potential, the value of second ionisation potential of an element is :-
(1) Negligible (2) Smaller (3) Greater (4) Double
Ans. 3
9. Least ionisation potential will be of :-
(1) Be3+ (2) H (3) Li +2 (4) He+
Ans. 2
10. Select the correct order of I.E. :-
(1) Cl– > Cl > Cl+ (2) Cl+ > Cl > Cl– (3) Cl > Cl+ > Cl– (4) Cl– > Cl+ > Cl
Ans. 2

A
11. Least electronegative element is :-

I
(1) I (2) Br (3) C (4) Fr
Ans. 4

N D
S I
O O
E T

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DPP - 4
1. Which of the following oxide is expected to react readily with NaOH ?
(1) Na2O (2) CaO (3) NO (4) Cl2O7
Ans. (4)
2. Match the following, regarding nature of the oxides
Column-I Column-II
a. N2O (i) Basic
b. BaO (ii) Amphoteric
c. As2O3 (iii) Acidic

A
d. Cl2O7 (iv) Neutral

I
(1) a(ii), b(i), c(iii), d(iv) (2) a(iv), b(i), c(iii), d(ii) (3) a(iv), b(i), c(ii), d(iii) (4) a(ii), b(i), c(iv), d(iii)
Ans. (3)
3. Valence electrons in the element A are 3 and that in element B are 6. Most probable compound formed from A and B is

D
(1) A2B (2) AB2 (3) A6B3 (4) A2B3
Ans. (4)
4. Select correct diagram about the acidic strength of oxides :

CO2
Increase N2O5

I CO2

N
Decrease N2O5

S
Increase Decrease Decrease Decrease
(1) (2)

O
Decrease P4O10 Increase P4O10
SiO2 SiO2

(3)

TO
CO2

Decrease
Increase
N2O5

Decrease
(4)
CO2
Decrease

Increase
N2O5

Decrease

Ans.
5.

Ans.
(1) E SiO2
Decrease P4O10

Which of the following elements will form alkaline oxide ?

(1) K
(1)
(2) P (3) S
SiO2
Decrease P4O10

(4) Cl

6. Identify the correct order of acidic strength of CO2, CuO, CaO, H2O -
(1) CaO < CuO < H2O < CO2 (2) H2O < CuO < CaO < CO2
(3) CaO < H2O < CuO < CO2 (4) H2O < CO2 < CaO < CuO
Ans. (1)
7. In which of the following sets of oxides, all are amphoteric oxide ?
(1) ZnO, K2O, SO3 (2) ZnO, P2O5, Cl2O7 (3) SnO2, Al2O3, ZnO (4) PbO2, SnO2, SO3
Ans. (3)

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8. The most acidic oxide among the following is :

(1) Cl2O5 (2) Cl2O (3) Cl2O3 (4) Cl2O7
Ans. (4)
9. The decreasing order of the acidic properties of oxides :
(1) P2O5 > KO2 > ZnO > MgO (2) P2O5 > ZnO > MgO > KO2
(3) KO2 > P2O5 > ZnO > MgO (4) KO2 > MgO > ZnO > KO2
Ans. (2)
10. The decreasing order of the basic properties of oxides
(1) Tl2O > Tlo3 > Ga2O3 > Al2O3 (2) Ga2O3 > Tl2O > Tl2O3 > Al2O3
(3) Al2O3 > Tl2O > Tl2O3 > Ga2O3 (4) Tl2O > Ga2O3 > Al2O3 > Tl2O3

A
Ans. (1)

D I
I N
O S
TO
E

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