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JEE Advance Mock 03 Afternoon QP

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Shiv Chhatrapati Shikshan Sanstha, Latur.

CET– CELL A
Sections : (A) Physics (B) Chemistry (C) Mathematics
Qu estio ns : 22 22 22
Marks : 76 76 76
Roll No.
IIT–JEE Date : 16 May, 2019
00 Afternoon Session Mock-03 Time : 2.00 pm To 5.00 pm

This is to certify that, the entry of Roll No. has been correctly written and verified.

Candidate's Signature JEE Advance Invigilator's Signature

Note : i) All questions are compulsory.


ii) Darken ( l ) the appropriate circle (  ) of the most correct option/response with black ball point pen.
Physics - Full Syllabus
SECTION – 1 : (One or More options Correct Type) (Marks : + 4,–2,+2)
01. An object is taken from a point P to another point Q in a gravitational field
a) assuming the earth to be spherical, if both P and Q lie on the earth's surface, the work
done is zero
b) if P is on the earth's surface and Q above it, the work done is minimum when it is taken
along the straight line PQ
c) the work done depends only on the position of P and Q and is independent of the path
along which the particle is taken
d) there is no work done if the object is taken from P to Q and then brought back to P along
any path
02. A thin cylindrical metal rod is bent into a ring with a small gap as shown in figure. On heating
the system

a)  decreases, r and d increase c) d and r increase


b)  increases d) is constant
03. A hollow and a solid sphere of same material and identical outer surface are heated to the
same temperature
a) In the beginning both will emit equal amount of radiation per unit line
b) In the beginning both will absorb equal amount of radiation per unit time
c) Both spheres will have same rate of fall of temperature (dT/dt)
d) Both spheres will have equal temperature at any moment
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04. One mole of an ideal monatomic gas has initial temperature T0, is made to go through the
cycle abca shown in the given figure. If U denotes the internal energy, then choose the correct
alternative

9RT0
a) Uc > Ub > Ua c) U c  Ua 
2
3RT0
b) Uc – Ub = 3 RT0 d) U c  Ua 
2
05. A gas is enclosed in a cylinder with a movable frictionless piston. Its initial thermodynamic
105
state at pressure Pi = 105 Pa and volume Vi = 10–3 m3 changes to a final state at Pf  Pa and
32
Vf  8  10 3 m3 in a quasi- static pro ces s, such that P 3 V 5 = co nstant. co nsider another
thermodynamic process that brings the system from the same initial state to the same final
state in two steps : an isobaric expansion at Pi followed by an isochoric (isovolumentric) process
at volume V f. The amount of he at supplie d to the syste m in the two-step process is
approximately
a) 112 J c) 588 J
b) 294 J d) 813 J
06. A sinusoidal wave y1 = asin(t – kx) is reflected from a right support and the reflected wave
superpose with the incident wave y1. Assume the rigid support to be at x = 0
a) Stationary waves are obtained with antinodes at the rigid support
b) Stationary waves are obtained with nodes at the rigid support
c) Stationary waves are obtained with intensity varying periodically with distance
d) Stationary waves are obtained with intensity varying periodically with time.
07. A sonic source, located in a uniform medium, emits waves of frequency n. If intensity, energy
density (energy per unit volume of the medium) and maximum speed of oscillations of medium
particle are, respectively, I, E and u0 at a point, then which of the following graphs are correct?

a) c)

b) d)

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08. Consider Gauss' law

Then, for the situation shown in figure at the Gaussian surface


a) E due to q2 would be zero

b) E due to both q1 and q2 would not be zero
c)  due to both q1 and q2 would not be zero
d)  due to q2 would be zero

SECTION – 2 : (Integer value correct Type) (+ 3, –1)


09. A block of mass M is tied to one end of a massless rope. The other end of the rope is in the
hands of a man of mass 2 M as shown in figure. The block and the man are resting on a rough
wedge of mass M. The whole system is resting on a smooth horizontal surface. The man starts
walking towards right while holding the rope in his hands. Pulley is massless and frictionless.
1
The displacement of the wedge when the block meets the pulley, can be m towards left,
x
then 'x' is
(Assume wedge is sufficiently long so that man does not fall down)

10. A rope ladder of length L is attached to a balloon of mass M. As the man of mass m climbs the
ladder into the balloon basket, the balloon comes down by a vertical distance s. Then the
increase in potential energy of man divided by the increase in potential energy of balloon is
L  xs
then 'x' is
xs

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11. Three blocks A, B and C of equal mass m are placed one over the other on a frictionless surface
(table) as shown in figure. The coefficient of friction between any blocks A, B and C is . The
maximum value of mass of block D so that the blocks A, B and C move without slipping over
xm 
each other is , then 'x' is
1 

12. A fixed U-shaped smooth wire has a semi-circular bending between A and B as shown in figure.
A bead of mass m moving with uniform speed v through the wire enters the semicircular bend
at A and leaves at B. The average force exerted by the bead on the part AB of the wire is
xmv 2
, then 'x' is
d

SECTION – 3 : (Column - Matching Type) (+4, –1)


13. An object O is kept perpendicular to the principal axis of a spherical mirror. Each situation
(a, b, c and d) gives object coordinate u in centimeter with sign, the type of mirror, and then
the distance (centimeters with sign) between the focal point and the pole of the mirror. ON
the right side information, regarding the image is given.
Correctly, match the situation on the left side with the images described on the right side.

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14. The spectral lines of hydrogen-like atom fall within the wavelength range from 950A0 to 1350 A0.
Then, match the following
C o lumn- I C o lumn- II
A. If it is atomic hydrogen atom and p.  = 1212 A0 and it corresponds to transition
energy E = – 0.85 eV from 2 to 1
B. If it is atomic hydrogen atom and q.  = 134 A0 and it corresponds to transition
energy E = – 3.4 eV from 2 to 1
C. If it is double ionized lithium atom, r.  = 303 A0 and it corresponds to transition
then from 2 to 1
D. If it is singly ionized helium atom, s.  = 970 A0 and it corresponds to transition
then from 4 to 1

SECTION – 4 : (Single options Correct Type) (Marks : + 4,–2)

15. Charge Q is uniformly distributed on a thin insulating ring of mass m which is initially at rest.
Two what angular velocity will the ring be accelerated when a magnetic field B, perpendicular
to the plane of the ring, is switched on?
QB QB
a) c)
m 2m
QB QB
b)  d) 
m 2m
16. For a resistance R and capacitance C in series, the impedance is twice of a parallel combination
of the same elements. What is the frequency of applied emf?
1 1
a) c)
2RC RC
2 1
b) d)
RC 4 RC
17. In a Young's double slit experiment with wavelength 5890A 0 there are 60 fringes in the field
of vision. How many fringes will be obsereved in the same field of vision if wavelength used is
5460A0.
a) approximately 60 c) approximately 65
b) approximately 62 d) approximately 67

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18. A spinni ng cylinder of mas M and r adiu s R is lower ed on a r ough incl ined plane of angle 30 0
with the horizontal and   1 / 3 . The cylinder is released at a height of 3R from horizontal.
Find thetotal time taken by the cylinder to reach the bottom of the incline.

  0R R   0R R
a)  4  c)  4 
 g g   g g 

  0R R   0R R
b)  6  d)  6 
 g g   g g 

SECTION – 5 : (Comprehension Type) (+2, –1)


Passage - 1
For the system shown in figure, capacitance is C. The left plate is given a charge Q1 and the
right plate is uncharged. Now, the switch is closed

19. Find the amount of charge that will flow through the battery before the steady state is achieved.
Q1
a) CV c) CV 
2
Q1
b) CV – Q1 d) CV 
2
20. Find the charge appearing on the inner face of the left plate
Q1 Q1
a) CV  c) CV 
2 2
b) CV + Q1 d) CV

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Passage - 2
A resistor circuit is constructed such that 12 resistors are arranged to form a cube as shown in
figure. Each resistor has a resistance of 2 . The potential difference of 30 V is applied across two
of the opposing points as shown

21. The points having the same potential are


i. B, D, E ii. C, F, H
iii. C, E
a) Only i is correct c) Only ii is correct
b) i, ii and iii are correct d) i and ii both are correct
22. If we replace resistors between A and B and resistors between G and H by wires of zero
resistance, then the points having the same potential are
i. D, E, C, F ii. A, B
iii. G, H
a) Only i is correct c) Only iii is correct
b) Only ii is correct d) i, ii and iii are correct

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Chemistry – Full Syllabus


SECTION – 1 : (One or More options Correct Type) (Marks : + 4,–2,+2)
23. Following three planes (P1, P2, P3) in an FCC unit cell of an element are shown

Choose the correct option


a) P1 contains no centre of voids of three dimensions
b) P2 contains only centre of Octahedral voids
c) P3 contains Both centre of Octahedral and Tetrahedral voids
d) Area of Plane P1 is minimum
24. Solubility product of AgCl(s) in water at 250C is 12 × 10–10 M2 then select the correct options
a) Solubility of AgCl in presence of 10–5 M AgNO3 is 3 × 10–5 moles/L
b) Solubility of AgCl in presence of excess of KCl will increase due to formation of complex
AgCl 2 (aq.)
c) Solubility of AgCl in presence of 2M NH3 is greater than that in pure water
d) Solubility of AgCl remains unaffected on adding any amount of NaBr solution because
there is no common ion effect.

25.

Which statement is/are true for compound C


a) Compound C with -naphthol produces orange red dye
b) Compound C react with B in alkaline medium and form aniline yellow
c) Compound C with NaBF4/ produces fluorobenzene
d) Compound C can undergo coupling reaction with anisole
26. In which of the following reactions alcohol obtained as major product

a)

b)

c)

d)

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27.

then compound A, compound B and compound C in the reaction are

a) c) Compound A = EtOOC–CH2–HC(COOEt)2

b) d)

28. To accomplish the following conversion which set of reagents can be used
C6 H5CH  CH  CH2OH 
 C6 H5CH  CH  CHO
a) O 3/H 2O 2 c) KMnO4, H+

b) d) MnO2

29. In which of the following conversions an increase in bond order is observed>?


a) O2  O2 c) N 2  N 2
b) O2  O2 d) C22  C2
30. Which of the following reaction(s) is (are) not an example of redox reaction?
a) Hydrolysis of XeF2 c) Reaction of XeF4 with O2F2
b) Hydrolysis of XeF6 d) Reaction of XeF2 with PF5

SECTION – 2 : (Integer value correct Type) (+ 3, –1)


31. The quantitative oxidation of hypo with potassim permangnate in faintly alkaline or neutral
medium, the equivalent weight of hypo is
32. The complex compound having general formula CrCl3.6H2O when treated with silver nitrate
produced two moles of AgCl precipitate. What will be the percent loss of weight of this
compound on treating with concentrated sulphuric acid?
(At. wt. of Cr = 52, Cl = 35.5, O = 15, H = 1).
33. Assume that th ereaction MeMgBr with ethylacetate proceeds with 100% conversion to give
tert-butano. The volume of 0.2 M solution of MeMgBr required to convert 10 ml of a 0.025 M
solution of ethylacetate to tert-butanol is
34. (R)-2-methyl-1-butanol has a specific rotation of + 13.50. The specific rotation 2-methyl-1-butanol
containing 40% of the (S)-enantiomer is ______ 0. (Round off to one decimal place)

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SECTION – 3 : (Column - Matching Type) (+4, –1)


35. Match the following
C o lumn- I C o lumn- II
(Sign of H and S re spctively) ( Nature of re action)
A. –&– p. Spontaneous only at low temperature
B. –&+ q. Spontaneous only at high temperature
C. +&+ r. Spontaneous at all temperature
D. +&– s. Non-spontaneous at all temperature

36. Match the following


C o lumn- I C o lumn- II
A. The radial node of 5s atomic orbital is p. 1
B. The angular node of 3dyz atomic orbital is q. 4
C. The sum of angular node and radial node of 4dxy atomic r. 2
orbital
D. The angular node of 3p atomic orbital s. 3

SECTION – 4 : (Single options Correct Type) (Marks : + 4,–2)


37. S1 : Diborane (B2H6) reacts with excess NH3 at low temperature to form the adduct B2 H6  2NH3
which is ionic in nature.
S2 : B2 H6  2NH3 comprises [H3N  BH2  NH3 ] [BH4 ] and on heating forms borazine.
a) Statement-1 is true, Statement-2 is true, Statement-2 is a correct explanation for
Statement-1
b) Statement-1 is true, Statement-2 is true, Statement-2 is not a correct explanation for
Statement-1
c) Statement-1 is true, Statement-2 is false
d) Statement-1 is false, Statement-2 is true.
38. S1 : Al has great affinity for oxygen and forms Al2O3 with evolution of excessive amount of
heat.
S2 : Al2O3 has very high Lattice energy & finally divided Al powder has larger surface area
and thus reacts vigorously with air and is hazardous.
a) Statement-1 is true, Statement-2 is true, Statement-2 is a correct explanation for
Statement-1
b) Statement-1 is true, Statement-2 is true, Statement-2 is not a correct explanation for
Statement-1
c) Statement-1 is true, Statement-2 is false
d) Statement-1 is false, Statement-2 is true.

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39. S1 : Aniline does not undergo friedal craft reaction
S2 : NH2 groups of aniline react with lewis acid AlCl3 to give acid base reaction.
a) Statement-1 is true, Statement-2 is true, Statement-2 is a correct explanation for
Statement-1
b) Statement-1 is true, Statement-2 is true, Statement-2 is not a correct explanation for
Statement-1
c) Statement-1 is true, Statement-2 is false
d) Statement-1 is false, Statement-2 is true.
40. S1 : The major products formed by heating C6H5CH2OCH3 and HI are C6H5CH2I and CH3OH.
S2 : Benzyl cation is more stable than methyl cation.
a) Statement-1 is true, Statement-2 is true, Statement-2 is a correct explanation for
Statement-1
b) Statement-1 is true, Statement-2 is true, Statement-2 is not a correct explanation for
Statement-1
c) Statement-1 is true, Statement-2 is false
d) Statement-1 is false, Statement-2 is true.

SECTION – 5 : (Comprehension Type) (+2, –1)


Passage - 1
The potential of an electrode when each species involved in it exists in the standard state is
called its standard electrode potential. The standard reduction potential of a couple is the
measure of its tendency to get reduced. A series obtained by arranging the couples in order of
their decreasing standard potentials is called electrochemical series. Any of the two couples
of this series joined together gives an electrochemical cell in which reduction occurs at the
electrode which occupies at the higher position. The standard potential of hydrogen electrode
is taken to be zero convention. Given below are the sequence of half-reactions (acidic media)
wit h r el evant E 0 values in volt at 298 K.

Also given some more E0298 data are :

41. The E0 for is equal to


a) 1.05 V c) 5.27 V
b) 1.506 V d) 7.53 V
42. For the cell mixed with 50 mL

is equal to

a) – 0.15 V c) – 0.44 V
b) + 0.185 V d) + 0.145 V

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Passage - 2
On an industrial scale, H2O2 can be prepared by hydrolysis of Peroxodisulphuric acid obtained by
electrolysis of 50% H2SO4 or an equimolar mixture of H2SO4 and ammonium Sulphate. The strength
of H2O2 solution can be expressed in a number of ways namely normality, molarity, percentage
strength and volume strength, H2O2 acts as an oxidising as well as a reducing agent both in acidic
and basic media.
43. In acidic medium, H2O2 acts as reducing agent in its reaction with
a) FeSO 4 c) H2S
b) KMnO 4 d) K4[Fe(CN)6 ]
44. A dilute solution of H2O2 is labelled as 20 volumes. Its percentage strength is
a) 10% c) 30%
b) 6% d) 3%

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Mathematics - Full Syllabus
SECTION – 1 : (One or More options Correct Type) (Marks : + 4,–2,+2)
45. The vertices of the triangle ABC lie on x, y, z axes respectively. Which of the following CANNOT
be the ratio of sides of the triangle
a) 6 :7 :8 c) 3 :4 :6
b) 2 :5 :6 d) 3 :4 :5
2
46. PQ is a double ordinate of the parabola y = 4ax. If the normal at P intersect the line passing
through Q and parallel to x-axis at G; then locus of G is a parabola with
a) Vertex at (4a, 0) c) Directrix as the line x – 3a = 0
b) Focus at (5a, 0) d) Length of latus rectum equal to 4a
47. Which of the following is true
a) x 2000  3x2  3x  1  0x  R
ab  bc  ca
b)  c 2 , if a, b are legs of a right triangle and c is hypotenuse
2
c) x 2001  3x 2  3x  1  0x  R 
ab  bc  ca
d)  c 2 if a, b, c are sides of obtuse ABC with c being largest side
2
48. Which of the following is correct
a) a, b, c are real numbers greater than 2 then a + b + c < abc
3

b)  (sin x  sin 2x  sin 4 x)dx  0


0

2
2
c) x
0
sin xdx  0

3
d) sin1  sin 2  sin3  sin 4  sin 5 
8
 n C0  nC2  nC4 ..... 
49. Number of values  2n/2
 can take is k, then k is factor of
 
a) 5120 c) 25600
b) 480 d) 81
50. a  7C0  7C3  7C6
b  7C1  7C4  7C7
c  7C2  7C5 then a3 + b3 + c3 – 3abc is a factor of
a) 5120 c) 25600
b) 480 d) 81
2 2
51. Let   cos  i sin the number of sequence of a1, a2, a3, a4, a5 (ordered) ( a i  {0,1,2} for i = 1,
5 5
2, 3, ..., 5) such that a1   a 22  a3 3 ...a 55  0 is m. m is a factor of
a) 5120 c) 25600
b) 480 d) 81
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52. A is a 3 × 3 matrix with element a ij |i  j| i, j . (Det A) is a factor of


a) 5120 c) 25600
b) 480 d) 81

SECTION – 2 : (Integer value correct Type) (+ 3, –1)


53. A square ABCD has all its vertices on the curves x2y2 = 1. The midpoints of its sides also lie on
the same curve. The square of area of the square is k, then k/10 =
54. A point E is taken inside a square ABCD, (A(0, 0), B(10, 0)) foot of perpendicular from E to AB
is T and DT, AE ; CT, BE intersect at K(x1, y1) M(x2, y2) respectively. If E is at (6, 6) then
|x2 – x1| + |y1 – y2| + 2|y1| +|y2| = L then L – 10 =
55. Number of ordered pairs of (x, y), |x||y| < 2002, satisfying 2y – x = sin x – sin2y and cosx +
5siny = 4 is k, then k/5 =
56. In ABC, (A(2,5), B(2, – 33)) G is centroid and midpoint of GB is E. If 2.AG = AC then CE = L,
then L – 30 =

SECTION – 3 : (Column - Matching Type) (+4, –1)


57. Match the following
C o lumn- I C o lumn- II
A. Sum of digits of a natural number is 12, the number p. –1
of divisors of the number can be

 x 1 
   ln[x]   
 lim  ln 1  sin   
B.  x     q. 1
 x   
   

where [ ] is GIF
C. Let f(x) be cubic polynomial such that r. 2
sin 3 x  sin 2 x 1
lim 
x 0 f (x) 2
x 2[x]  x  1 1
lim  then f(1) =
x 0 f (x) 2
D. Number of solution of s. 4
sin4(cos43x) + cos4(cos43x) = 1 in [0, 1] is

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58. Match the following


C o lumn- I C o lumn- II
A. f(x) = |1 – 4x2|, x < 1 p. Continuous x  R
 x 2  2x,x  1
{x 2 }  1 2
B. f (x)  x 1 q. Discontinuous at exactly on point
x2 1
=0 x2 = 1
C. f (x)  max{2x ,xn2  n2  3} r. Discontinous at exactly 2 points
sin [x2  1]
D. f (x)  sin(x|x|)  s. Discontinous at more than 2 points
x2  1
(Where [.], {.} denotes greatest integer function and fractional part function)

SECTION – 4 : (Single options Correct Type) (Marks : + 4,–2)


59. Nine delegates, three each from three different countries, randomly select chairs at a round
table that seats nine people. Let the probability that each delegate sits next to atleast one
m
delegate from another country be . Where m and n are relatively prime then n – m =
n
a) 13 c) 15
b) 14 d) 16
60. Let A adn B be 2 × 2 non singular skew symmetric matrices such that AB = BA. If PT denotes
transpose of P then (B2A2)2((BTA)–1)2((BA–1)T)2 is equal to
a) A4 c) B2
b) B4 d) A2 B 2

  
  2
cos  x   dx

2 cos  x   dx I   4
I1  
2
 4
,
2   
2 sin  x 
61.  
0
  4  then the correct relation is
0
sin  x  1 
1   4 2

a) I1 = I2 c) I1 2  I2

b) I1  I2 2 d) 2I1 = I2
62. Three different planes given by y = 0, x + z = 1 and ax + by + cz = d, intersect in same line.
Distances from points (0, 1, 0) and (, , ) to the plane ax + by + cz = d are 1 unit and 2 units
respectively then which can be the correct relation?
a) 2    2   4 c) 2    2   8
b) 2    2  8 d) 2    2  8

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SECTION – 5 : (Comprehension Type) (+2, –1)


Passage - 1
Consider the set A = {1, 2, 3, 4, .... n}. Let S be the set of all one-one function f from A to A such
that |f(1) – 1| = |f(2) – 2|= ...... |f(n) – n| then
63. The number of elements of S is 1 if n =
a) 5 c) 9
b) 6 d) 8
64. The number of elements of S if n = 4 is less than or equal to
a) 1 c) 3
b) 2 d) 0

Passage - 2
x
2 1
Consider the function, f (x)   (5ln(1  t )  10t tan  16sin t)dt
0

65. Which of the following is true for f(x)?


a) negative for all x  (0,1) c) decreasing for all x  (0,1)
b) increasing for all x  (0,1) d) non-monotonic function for x  (0,1)
66. Which of the following is/are true of f '(x) ?
a) positive for all x  (0,1) c) negative for all x  (0,1)
b) decreasing for all x  (0,1) d) neither increasing nor decreasing x  (0,1)

16/05/2019 (16) MOCK–03


(JEE-ADVANCED–2019) KEY TO THE QUESTION BOOKLET 16/05/2019
MOCK-03 (Afternoon Session)
PHYSICS CHEMISTRY MATHEMATICS
1 acd C–q 23 abcd C–q 45 bc C–s
2 cd D–q 24 abc D–s 46 abcd D–q
3 ab 14 A–s 25 acd 36 A–q 47 abcd 58 A–q
4 abcd B–p 26 acd B–r 48 ab B–s
5 c C–q 27 acd C–s 49 abc C–p
6 a D–r 28 bd D–p 50 ac D–p
7 acd 15 d 29 ac 37 a 51 bd 59 c
8 bd 16 a 30 bd 38 a 52 abc 60 b
9 (2) 17 c 31 (31) 39 a 53 (8) 61 b
10 (1) 18 b 32 (6.75) 40 a 54 (5) 62 c
11 (3) 19 d 33 (2.5) 41 b 55 (2) 63 a
12 (4) 20 d 34 (2.7) 42 d 56 (8) 64 c
13 A–r 21 d 35 A–p 43 b 57 A–s 65 b
B–s 22 d B–r 44 b B–p 66 a

(JEE-ADVANCED–2019) KEY TO THE QUESTION BOOKLET 16/05/2019


MOCK-03 (Afternoon Session)
PHYSICS CHEMISTRY MATHEMATICS
1 acd C–q 23 abcd C–q 45 bc C–s
2 cd D–q 24 abc D–s 46 abcd D–q
3 ab 14 A–s 25 acd 36 A–q 47 abcd 58 A–q
4 abcd B–p 26 acd B–r 48 ab B–s
5 c C–q 27 acd C–s 49 abc C–p
6 a D–r 28 bd D–p 50 ac D–p
7 acd 15 d 29 ac 37 a 51 bd 59 c
8 bd 16 a 30 bd 38 a 52 abc 60 b
9 (2) 17 c 31 (31) 39 a 53 (8) 61 b
10 (1) 18 b 32 (6.75) 40 a 54 (5) 62 c
11 (3) 19 d 33 (2.5) 41 b 55 (2) 63 a
12 (4) 20 d 34 (2.7) 42 d 56 (8) 64 c
13 A–r 21 d 35 A–p 43 b 57 A–s 65 b
B–s 22 d B–r 44 b B–p 66 a

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