LPG Chemical Composition

% Gas Volume % Liquid Volume

C2 Ethane 0.18 0.15
C3 Propane 18.35 16.27
iC4 Iso – Butane 19.85 20.90
nC4 Normal – Butane 60.75 61.65
iC5 Iso - Pentane 0.87 1.03
Total 100.00 100.00

Heating Value
Net Value Btu/Ft3 2886.87
Gross Value Btu/Ft3 3129.39
Net Value K. Cal/M3 25690.27
Gross Value K. Cal/M3 27848.41
Mol. Wt. 55.67
Ethyl Mercaptan injected into LPG at 1-2 LBS./10000 US Gals(12-24g/m3)
liquid volume would provide sufficient odorization for LPG to be detected in Air
at less then 20% lel.
ICSC 0232 - BUTANE

BUTANE ICSC: 0232

November 2003
CAS #: 106-97-8 n-Butane
UN #: 1011
EINECS #: 203-448-7

ACUTE HAZARDS PREVENTION FIRE FIGHTING

NO open flames, NO sparks and NO Shut off supply; if not possible and no
smoking. Closed system, ventilation, risk to surroundings, let the fire burn
FIRE & explosion-proof electrical equipment itself out. In other cases extinguish
Extremely flammable. Gas/air
and lighting. Prevent build-up of with powder, carbon dioxide. In case
EXPLOSION mixtures are explosive. electrostatic charges (e.g., by of fire: keep cylinder cool by spraying
grounding) if in liquid state. Use non- with water. Combat fire from a
sparking handtools. sheltered position.

SYMPTOMS ACUTE HAZARDS FIRST AID

Fresh air, rest. Artificial respiration
Inhalation Drowsiness. Unconsciousness. Use closed system or ventilation. may be needed. Refer for medical
attention.
ON FROSTBITE: rinse with plenty of
ON CONTACT WITH LIQUID: Cold-insulating gloves. Protective
Skin FROSTBITE. clothing.
water, do NOT remove clothes. Refer
for medical attention .
First rinse with plenty of water for
ON CONTACT WITH LIQUID: several minutes (remove contact
Eyes FROSTBITE.
Wear face shield.
lenses if easily possible), then refer
for medical attention.
Ingestion

SPILLAGE DISPOSAL CLASSIFICATION & LABELLING

Evacuate danger area! Consult an expert! Personal protection:
self-contained breathing apparatus. Ventilation. Remove all ignition According to UN GHS Criteria
sources. NEVER direct water jet on liquid.
STORAGE
Transportation
Fireproof. Cool. UN Classification
UN Hazard Class: 2.1
PACKAGING

Prepared by an international group of experts on behalf of ILO and WHO, with

the financial assistance of the European Commission.
© ILO and WHO 2017

1/2
ICSC 0232 - BUTANE

BUTANE ICSC: 0232

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance Formula: C4H10

ODOURLESS COLOURLESS COMPRESSED LIQUEFIED GAS. Molecular mass: 58.1
Boiling point: -0.5°C
Physical dangers Melting point: -138°C
The gas is heavier than air and may travel along the ground; distant Relative density (water = 1): 0.6
ignition possible. The gas is heavier than air and may accumulate in Solubility in water, g/100ml at 20°C: 0.0061
lowered spaces causing a deficiency of oxygen. As a result of flow, Vapour pressure, kPa at 21.1°C: 213.7
agitation, etc., electrostatic charges can be generated. Relative vapour density (air = 1): 2.1
Flash point: -60°C
Chemical dangers
Auto-ignition temperature: 365°C
Explosive limits, vol% in air: 1.8-8.4
Octanol/water partition coefficient as log Pow: 2.89

EXPOSURE & HEALTH EFFECTS

Routes of exposure Inhalation risk

The substance can be absorbed into the body by inhalation. On loss of containment this substance can cause suffocation by lowering
the oxygen content of the air in confined areas.
Effects of short-term exposure
Rapid evaporation of the liquid may cause frostbite. The substance may Effects of long-term or repeated exposure
cause effects on the central nervous system.

Occupational exposure limits

TLV: 1000 ppm as STEL.
MAK: 2400 mg/m3, 1000 ppm; peak limitation category: II(4); pregnancy risk group: D

ENVIRONMENT

NOTES
Check oxygen content before entering area.
Turn leaking cylinder with the leak up to prevent escape of gas in liquid state.
Information except physical properties also apply for Isobutane (CAS 75-28-5).
High concentrations in the air cause a deficiency of oxygen with the risk of unconsciousness or death.

ADDITIONAL INFORMATION
EC Classification
Symbol: F+; R: 12; S: (2)-9-16-33; Note: C

All rights reserved. The published material is being distributed without warranty of any kind, either
expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the
interpretation and use of the information contained in this material.

2/2
ICSC 0319 - PROPANE

PROPANE ICSC: 0319

November 2003
CAS #: 74-98-6 n-Propane
UN #: 1978
EINECS #: 200-827-9

ACUTE HAZARDS PREVENTION FIRE FIGHTING

NO open flames, NO sparks and NO Shut off supply; if not possible and no
smoking. Closed system, ventilation, risk to surroundings, let the fire burn
FIRE & explosion-proof electrical equipment itself out. In other cases extinguish
Extremely flammable. Gas/air
and lighting. Prevent build-up of with powder, carbon dioxide. In case
EXPLOSION mixtures are explosive. electrostatic charges (e.g., by of fire: keep cylinder cool by spraying
grounding) if in liquid state. Use non- with water. Combat fire from a
sparking handtools. sheltered position.

SYMPTOMS ACUTE HAZARDS FIRST AID

Fresh air, rest. Artificial respiration
Inhalation Drowsiness. Unconsciousness. Use closed system or ventilation. may be needed. Refer for medical
attention.
ON FROSTBITE: rinse with plenty of
ON CONTACT WITH LIQUID: Cold-insulating gloves. Protective
Skin FROSTBITE. clothing.
water, do NOT remove clothes. Refer
for medical attention .
First rinse with plenty of water for
ON CONTACT WITH LIQUID: several minutes (remove contact
Eyes FROSTBITE.
Wear face shield.
lenses if easily possible), then refer
for medical attention.
Ingestion

SPILLAGE DISPOSAL CLASSIFICATION & LABELLING

Evacuate danger area! Consult an expert! Personal protection:
self-contained breathing apparatus. Remove all ignition sources. According to UN GHS Criteria
Ventilation. NEVER direct water jet on liquid.
STORAGE
Transportation
Fireproof. Cool. UN Classification
UN Hazard Class: 2.1
PACKAGING

Prepared by an international group of experts on behalf of ILO and WHO, with

the financial assistance of the European Commission.
© ILO and WHO 2017

1/2
ICSC 0319 - PROPANE

PROPANE ICSC: 0319

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance Formula: C3H8 / CH3CH2CH3

ODOURLESS COLOURLESS COMPRESSED LIQUEFIED GAS. Molecular mass: 44.1
Boiling point: -42°C
Physical dangers Melting point: -189.7°C
The gas is heavier than air and may travel along the ground; distant Relative density (water = 1): 0.5
ignition possible. The gas is heavier than air and may accumulate in Solubility in water, g/100ml at 20°C: 0.007
lowered spaces causing a deficiency of oxygen. As a result of flow, Vapour pressure, kPa at 20°C: 840
agitation, etc., electrostatic charges can be generated. Relative vapour density (air = 1): 1.6
Flash point: -104°C
Chemical dangers
Auto-ignition temperature: 450°C
Explosive limits, vol% in air: 2.1-9.5
Octanol/water partition coefficient as log Pow: 2.36

EXPOSURE & HEALTH EFFECTS

Routes of exposure Inhalation risk

The substance can be absorbed into the body by inhalation. On loss of containment this substance can cause suffocation by lowering
the oxygen content of the air in confined areas.
Effects of short-term exposure
Rapid evaporation of the liquid may cause frostbite. The substance may Effects of long-term or repeated exposure
cause effects on the central nervous system.

Occupational exposure limits

MAK: 1800 mg/m3, 1000 ppm; peak limitation category: II(4); pregnancy risk group: D

ENVIRONMENT

NOTES
Check oxygen content before entering area.
Turn leaking cylinder with the leak up to prevent escape of gas in liquid state.
High concentrations in the air cause a deficiency of oxygen with the risk of unconsciousness or death.

ADDITIONAL INFORMATION
EC Classification
Symbol: F+; R: 12; S: (2)-9-16

All rights reserved. The published material is being distributed without warranty of any kind, either
expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the
interpretation and use of the information contained in this material.

2/2
ICSC 0901 - ISOBUTANE

ISOBUTANE ICSC: 0901

November 1998
CAS #: 75-28-5 2-Methylpropane
UN #: 1969 1,1-Dimethylethane
EINECS #: 200-857-2 Trimethylmethane

ACUTE HAZARDS PREVENTION FIRE FIGHTING

Shut off supply; if not possible and no
NO open flames, NO sparks and NO
risk to surroundings, let the fire burn
smoking. Closed system, ventilation,
FIRE & itself out. In other cases extinguish
Extremely flammable. Gas/air explosion-proof electrical equipment
with water spray. In case of fire: keep
EXPLOSION mixtures are explosive. and lighting. Prevent build-up of
cylinder cool by spraying with water.
electrostatic charges (e.g., by
Combat fire from a sheltered
grounding) if in liquid state.
position.

SYMPTOMS ACUTE HAZARDS FIRST AID

Use ventilation, local exhaust or Fresh air, rest. Refer for medical
Inhalation Shortness of breath. Suffocation.
breathing protection. attention.
ON FROSTBITE: rinse with plenty of
ON CONTACT WITH LIQUID: Cold-insulating gloves. Protective
Skin water, do NOT remove clothes. Refer
FROSTBITE. clothing.
for medical attention .
First rinse with plenty of water for
several minutes (remove contact
Eyes Wear safety goggles or face shield.
lenses if easily possible), then refer
for medical attention.
Do not eat, drink, or smoke during
Ingestion work.

SPILLAGE DISPOSAL CLASSIFICATION & LABELLING

Evacuate danger area! Consult an expert! Ventilation. Remove all
ignition sources. NEVER direct water jet on liquid. Personal According to UN GHS Criteria
protection: filter respirator for organic vapours of low boiling point
adapted to the airborne concentration of the substance.
STORAGE Transportation
UN Classification
Fireproof. Cool. UN Hazard Class: 2.1
PACKAGING

Prepared by an international group of experts on behalf of ILO and WHO, with

the financial assistance of the European Commission.
© ILO and WHO 2017

1/2
ICSC 0901 - ISOBUTANE

ISOBUTANE ICSC: 0901

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance Formula: C4H10 / (CH3)2CHCH3

COLOURLESS COMPRESSED LIQUEFIED GAS WITH Molecular mass: 58.1
CHARACTERISTIC ODOUR. Boiling point: -12°C
Melting point: -160°C
Physical dangers Relative density (water = 1): 0.6 (liquid)
The gas is heavier than air and may travel along the ground; distant Solubility in water at 20°C: none
ignition possible. As a result of flow, agitation, etc., electrostatic charges Vapour pressure, kPa at 20°C: 304
can be generated. Relative vapour density (air = 1): 2
Flash point: Flammable gas
Chemical dangers
Auto-ignition temperature: 460°C
Reacts with strong oxidants, acetylene, halogens and nitrogen oxides.
Explosive limits, vol% in air: 1.8-8.4
This generates fire and explosion hazard.
Octanol/water partition coefficient as log Pow: 2.8

EXPOSURE & HEALTH EFFECTS

Routes of exposure Inhalation risk

The substance can be absorbed into the body by inhalation. A harmful concentration of this gas in the air will be reached very quickly
on loss of containment.
Effects of short-term exposure
Rapid evaporation of the liquid may cause frostbite. The substance may Effects of long-term or repeated exposure
cause effects on the cardiovascular system. This may result in impaired
functions and respiratory failure. Exposure at high levels could cause
death.

Occupational exposure limits

TLV: 1000 ppm as STEL.
MAK: 2400 mg/m3, 1000 ppm; peak limitation category: II(4); pregnancy risk group: D

ENVIRONMENT

NOTES
Turn leaking cylinder with the leak up to prevent escape of gas in liquid state.
The measures mentioned in section PREVENTION are applicable to production, filling of cylinders, and storage of the gas.

ADDITIONAL INFORMATION
EC Classification
Symbol: F+; R: 12; S: (2)-9-16; Note: C

All rights reserved. The published material is being distributed without warranty of any kind, either
expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the
interpretation and use of the information contained in this material.

2/2