TSA
TSA
a Spray Applications
Armelle M. Vardelle
chais
36.26 · University of Limoges
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ications
rojects
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40 Citations SUL PACCHETTO
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91 References SOGGIORNO*
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duction
s have historically been developed to provide protection against corrosion and
that is to protect the material from chemical and physical interaction with its
ment. Corrosion and wear problems are still of great relevance in a wide range of
al applications and products as they result in the degradation and eventual failure of
ents and systems both in the processing and manufacturing industries and in the
life of many components. Various technologies can be used to deposit the
iate surface protection that can resist under specific conditions. They are usually
ished by coating thickness: deposition of thin films (below 10 to 20 µm according to
and deposition of thick films. The latter, mostly produced at atmospheric pressure
hickness over 30 µm, up to several millimeters and are used when the functional
ance and life of component depend on the protective layer thickness. Both coating
ogy can also be divided into two distinct categories: ”wet” and ” dry ” coating
s, the crucial difference being the medium in which the deposited material is
ed. The former group mainly involves electroplating, electroless plating and hot-dip
zing while the second includes, among others methods, vapor deposition, thermal
chniques, brazing, or weld overlays. This chapter deals with coatings deposited by
spraying. It is defined by Hermanek (2001) as follows , “Thermal spraying
es a group of coating processes in which finely divided metallic or non-metallic
s are deposited in a molten or semi-molten condition to form a coating”. The
d in air at atmospheric pressure will be considered, except when the coating material
expensive, such as platinum that must be sprayed in a chamber to recover the over-
ting material may be in the form of powder, ceramic rod, wire or molten materials.
tral part of the system is a torch converting the supplied energy (chemical energy for
tion or electrical energy for plasma- and arc-based processes), into a stream of hot
he coating material is heated, eventually melted, and accelerated by this high-
ture, high-velocity gas stream towards a substrate. It impacts on the substrate in the
a stream of droplets that are generated by the melting of powders or of the tips of
rods in the high-energy gas stream. The droplets flatten or deform on the substrate
erate lamellae called “splats”. The piling up of multiple layered splats forms the
spray processes are now widely used to spray coatings against, wear and corrosion
against heat (thermal barrier coating) and for functional purposes. The choice of the
on process depends strongly on the expected coating properties for the application
ting deposition cost. Coating properties are determined by the coating material, the
which it is provided, and by the set of parameters used to operate the deposition
Thermal spray coatings are generally characterized by a lamellar structure and the
ntact between the splats and the substrate or the previously deposited layers
ne to a large extent the coating properties, such as thermal conductivity, Young’s
s, etc. The real contact area ranges generally between 20 to 60 % of the coating
parallel to the substrate. It increases with impact velocities of particles provided that
r are not either too much superheated or below their melting temperature. That is
ghly the density of coatings increases from flame, wire arc, plasma, HVOF or HVAF
lly D-gun spraying and self-fluxing alloys flame sprayed and then re-fused.
ermal spray coatings contain some defects as pores, often globular, formed during
neration, un-molten or partially melted particles that create the worst defects,
d particles, and cracks formed during residual stress relaxation. The cracks appear
-cracks within splats and macro-cracks running through layered splats especially at
terfaces and tending to initiate inter-connected porosities. Moreover, when the
g process is operated in air, oxidation of hot or fully melted particles can occur in
s well as that of splats and successive passes during coating formation. Thus,
ng on the spray conditions and materials sprayed, the coatings are more or less
and for certain applications must be sealed by appropriate means.
pter will present successively:
following thermal spra processes flame High Velocit Ox Fuel (HVOF) D gun
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following
See all ›
thermalSee
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all ›
processes: See
flame,
all ›
High Velocity Oxy-Fuel (HVOF), D-gun,
sma,40wire arc and Plasma Transferred Download citation Share Download full-text PDF
Citations 91 References 10 Figures(PTA)). The possibility to use them to
Arc
nufacture coatings on site will also be mentioned. The coating structures (lamellar or
nular) with their void content and the inter-connected porosities and crack networks
be linked to their corrosion resistance. The different sealing processes will also be
ussed according to service temperature of coatings.
hort introduction to the main modes of wear (abrasion, erosion and adhesion) linked
orrosion.
tings used against atmospheric or marine corrosion (sacrificial coatings).
mal spray
ollowing, we will only present the processes that are used in air at atmospheric
e. Figure 1 shows the general concept of thermal spray, Fauchais et al (2012). The
material can be fed in the hot gas stream a s p ow der or wi re or rod. C oa ti ng s a re
the flattening and solidification of droplets impacting onto the part to be covered.
roplets can be partially or totally melted when they are issued from powders or
melted when they result from the atomization of melting wires or rods. The
ucture of the coating formed by the piling up of these particles depends on (i)
impact parameters (particle temperature, molten state, velocity and size), (ii)
e conditions (shape, roughness, surface chemistry…), (iii) the temperature control of
e and coating before (preheating) during and after (cooling) spraying and (iv) the
attern.
neral remarks can be expressed:
erent materials require different deposit conditions,
cific coating properties (high density or desired porosity) may require specific
ticle velocity/temperature characteristics,
heat fluxes to the substrate depend on the coating method and for some substrate
erials they have to be minimized,
strate preheating and temperature control during spraying strongly affect coating
perties and in particular residual stresses,
d frequently a trade-off exists between coating quality and process economics.
ance, if the plasma spray process can offer a high-temperature and high-velocity
ment for the injected powders, it will bring about a strong heating of the substrate,
powder material may undergo chemical change during the deposition due to
e heating, e.g. WC-Co powders may decompose.
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spraying: instead of using solid electrodes, the arc strikes between two continuously
ng consumable conductive wires, one being the cathode and the other the anode.
ted tips of the wires are fragmented into tiny droplets, a few tens of µm in diameter,
tomizing gas blown between both wires. The latter is generally compressed air but
dizing gas as nitrogen or argon is also sometimes used. The droplet high
tures at impact produce metallurgical interactions or diffusion zones or both
the impinging droplets and the substrate or previously deposited layers. The wires
ssarily made of ductile material, or of a ductile envelope filled with a non-ductile or
material. They are, then, called cored wires. All particles issuing from the ductile
e fully melted at impact and their impact velocity can be as high as 120 m.s-1.
ximum arc current that can vary from 200 up to 1500 A characterizes the different arc
uns. This process has higher spray rates (5 to 30 kg.h-1) than other spray processes
deposition efficiency is about 80 %; it is the most economical for materials that can be
ed in form of wires or cored wires. The oxide content of coatings depends strongly
prayed materials and the atomization gas; it is generally rather high, e.g. over 25%
minum coatings. Using nitrogen instead of air as atomizing gas can reduce it, but
ng to the high gas flow rates (around 1m3.mn-1 or more), the process becomes
ve. Coating porosity is usually over 10% and its adhesion is medium in the 40-MPa
An advantage of this process is the little heating of the substrate while the divergence
pray pattern is a disadvantage. As other spray processes it is noisy and dusty.
s can be used against abrasion and adhesion (friction) under low load but their main
protection against atmospheric or marine corrosion and electrical applications.
ransferred arc (PTA) deposition process: PTA is different from the other thermal spray
es because the substrate serves as one electrode, usually the anode, for the arc that
he process gases and the sprayed material. Therefore, it requires electrically-
ive substrates. The transferred arc induces a local melting of the substrate and the
, heated in the plasma column, stick to the molten pool and are melted by the
red arc. The process is a combination of welding and thermal spraying processes.
ture allows the attainment of excellent bonding between the substrate and the
and very high coating densities. The feedstock is either powders with particle sizes
ne hundred micrometer range or wires. Metals, alloys and cermets can be sprayed
s technique. The PTA guns differ in maximum arc current varying from 200 to 600A.
tings are thicker than those manufactured by other thermal spray processes, their
s can reach centimeters, and they are metallurgically bonded to the substrate that
k th i t l l t it d i i C ti d t h it d
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kept
Seehorizontal
all › orSee
close
all › to it during spraying.
See all › Coatings do not show porosity and
ess40
d eposition
Citations e fficien cy is
91 References over 90 %. Powde
10 Figures r flow ra te c an b eDownload
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or even Share Download full-text PDF
th hi gh -p owe r P TA de vi ce s. The co at in g r es ist an ce to we ar is ex ce lle nt as we ll as
orrosion at high temperature.
ombustion-based processes
ainly comprise flame spraying, High Velocity Oxy-fuel Flame (HVOF) or High
Air-fuel Flame (HVAF) and Detonation gun (D-gun).
shown in Figure 2. Sprayed materials are mainly metals or polymers and many
s are commercially available, which are very easy to spray. Flame-sprayed
generally present a high porosity (> 10%), low adhesion (< 30MPa) and oxide
between 6 and 12%. The deposition efficiency is around 50%. The particle flow
etween 3 and 7 kg.h1. Substrate and coating must be cooled during spraying.
praying can be used to deposit self-fluxing alloys ; the coating process is then
d by a fusing process. Self-fluxing alloys contain Si and B (e.g. CrBFeSiCNi) which
deoxidizers. Rather dense coatings can be observed when spraying self-fluxing
ontaining Si and B with a reaction of the type:
(FeCr)xOx+y + 2 B + 2 Si → x Fe + x Cr + B2Ox.SiOy
B2Ox.SiOy is a borosilicate. This process requires a thermal post treatment of the
This “fusing” step is commonly carried out with oxy-acetylene torches very well
o reheat the coating over the minimum of 1040°C. During reheating oxide diffuses
the coating surface where it is mechanically removed (turning, milling…). The
results in rather dense and hard coatings Lin and Han (1998). These self-fluxing
an be reinforced with hard ceramic particles such as WC, Harsha et al (2007).
ated coatings have almost no porosity and exhibit an excellent adhesion thanks to
n at the substrate-coating interface. Self-fluxing alloys can also be deposited by
and HVOF spraying. These materials of brazing type are very easy to deposit.
er, these coatings are limited to substrates that can tolerate the fusing temperature
sible induced distortion. So, this process can be used for steel substrates but not
minum alloys! Such coatings are used against abrasion (friction, erosion) and
n (cold or hot).
he coating material is in the form of wire (metallic and ductile) or cored wires
ramics or non-ductile materials), rod or cord (for ceramics), a compressed gas jet
to atomize the melted tip and the noise level of the process is not negligible.
er, compared to powders the variety of sprayed materials is larger. Wires of self-
alloys can be sprayed. Oxides are of course generated during the spray process
than with powders and the coating oxide content is generally about 4 to 8%; the
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p g g y ;
on See all ›
efficiency See better
is also all › See achieved
than that all › with powders; Download
it is around 70%.
citation Share Download full-text PDF
ed 40
to Citations
powders the 91 material
References 10 Figures
flow rate varies from 5 to 15 kg.h-1. With wires the
adhesion is slightly better than that obtained with powders. The porosity is
to that obtained with powders except for ceramic materials that are more porous
sent an excellent wear resistance. Generally these coatings are used against
n or adhesion under low load and against atmospheric corrosion.
elocity Oxy-fuel Flame (HVOF) and high velocity air-fuel flame (HVAF). These
es use significantly higher upstream pressures than flame spray processes and a de
ozzle; they are characterized by supersonic speeds of gas flow. The combustion of
carbon molecule (CxHy) either as gas or liquid (kerosene) is achieved with an
, either oxygen or air, in a chamber at pressures between 0.24 and 0.82 MPa or
more for high-power guns. A convergent-divergent de Laval nozzle follows the
tion chamber achieving very high gas velocities (up to 2000 m/s). The last trend is
nitrogen (up to 2000 slm) in the combustion chamber to increase the gas velocity
rease its temperature. Mostly powders are used, which are injected either axially
lly or both, depending on the gun design. Few guns have been designed to use
r cored wires. Also, recently liquid feedstock injection (suspensions or solutions)
n developed, mainly for axial injection. The particle velocities and temperatures
d with different guns (Top gun, Jet Kote,DJ standard, DJ 2700, DJ 2800 and JP 5000
e presented in Figure 2. Substrate and coating must be cooled during spraying.
evels for HVOF guns working with gases is about 100-120 kW, while they can reach
for guns working with liquid. Globally this process, working mainly with metals,
nd cermets (one of the most successful applications) has deposition efficiencies of
0% for powder flow rates up to 7.2 kg.h-1 for gas-fuel guns and up to 12 kg.h-1 for
uel guns. Resulting coating porosities are a few %, with a good adhesion to substrate
y 60 to 80 MPa) and low oxygen content (between 0.5 and a few %). The process is
oisy, dusty with large quantities of explosive gases. As for detonation-gun (see
the main applications of coatings are protection against abrasion and adhesion
) under low load as well as protection against corrosion.
on gun (D-gun). The detonation is mainly generated in acetylene- or hydrogen-
mixtures (with some nitrogen to modify the detonation parameters) contained in a
sed at one of its ends. The shock wave created by the combustion in the highly
sed explosive medium results in a high pressure wave (about 2 MPa) pushing
heated by the combustion gases. Gas velocities of more than 2000 m/s are
d. Contrary to the flame and HVOF devices where combustible gases and powders
tinuously fed within the gun, combustible gases and powder are fed in cycles
d at a frequency of 3 to 100 Hz.
ulting deposits are dense and tightly bonded to the substrate. The process is the
of all the thermal spray processes (more than 150 dBA). Coating porosity is low
1 %) and its oxygen content is between 0.1-0.5%. The deposition efficiency is about
powder flow rates of 1 to 2 kg.h-1. The sprayed materials are mainly powders of
alloys and cermets; some oxides can be sprayed but with particle sizes in the 20-μm
r below Substrate and coating must be cooled during spra ing The main
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r below.
See all ›
Substrate and coating See
See all ›
must be cooled during spraying. The main
all ›
ions40are coatings against abrasion and adhesion Download
(friction) under low citation
load as well as Share Download full-text PDF
Citations 91 References 10 Figures
against corrosion.
praying: Many applications, especially those on big parts, e.g. a bridge, require that
g is performed on site. This is feasible with wire arc, flame and in certain cases
ting formation
ed to many other material processes, coatings produced by thermal spraying
y contain many defects. (i) The real contact area between the splat and the substrate
reviously deposited layers determines the coating properties. Inter-lamellar pores
ween layered splats, or first splats and substrate; their thickness is between a few
dths to a few tenths of micrometers. The real contact between splats increases from
0 to 60 % with particle impact velocities, provided that particles are not either too
uperheated or below their melting temperature. (ii) Splashing of the melted particles
lattening upon impact can significantly affect the coating properties Gawne (1995).
deposited on splashed material exhibit lower adhesion and this effect is more
nt when spraying metals because the splashed material is oxidized rather fast due
mall droplet sizes. (iii) Substrate geometry may affect the flow of impacting and
g particles Racek (2010). (iv) Pores, often called globular, are formed during coating
on because of shadowing effect, narrow holes in valleys between splats not
ely filled, un-molten or partially melted particles and exploded particles. These
r pores are distributed more or less homogeneously through the coating and their
l to deteriorate coating properties is proportional to their size, Ctibor et al (2006).
re, to reduce the coating porosity, the incorporation in the coating of large un-
particles, which are sufficiently heated to stick on the substrate, or of partially
particles, must be avoided. This can be done by choosing carefully the particle size
tion and optimizing the particle injection. However, sometimes a compromise has
ound between having most particles fully melted but with rather high oxide
and more un-melted particles with lower oxide content. (v) Coatings also contain
ormed during residual stress relaxation and that often contribute to the open
y of coatings. The micro-cracks within splats result from quenching stress
on and are observed in ceramic materials. The macro-cracks are often due to the
on of an expansion mismatch stress; they run through layered splats especially at
erfaces and, so, tend to initiate inter-connected porosities. Other stress relaxations
ur but they can be avoided by optimizing spray or service conditions. (vi) At last,
source of defects is the particle impact angle that reduces the normal impact
, resulting in elongated splats. Spraying with an angle above a certain value,
ng on particle and substrate materials, will promote splashing even on substrates
ed above the so called “transition temperature”. Above this temperature, the
xhibit a regular disk shape on a smooth substrate while below they have an
r shape. Typically, depending on the spray process used and the material sprayed
rosity varies between 0 5 and 15 % It does not mean necessarily that porosities are
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rosity varies between 0.5 and 15 %. It does not mean necessarily that porosities are
See all › See all › See all ›
nnected, but it can happen. Download citation Share Download full-text PDF
40 Citations 91 References 10 Figures
3 illustrates schematically the structure of a thermal-sprayed coating. Figure 4a
the cross section of a stainless steel coating (304L) deposited by air plasma spraying
w carbon (1040) steel substrate and Figure 4b that of an yttria partially stabilized
(Y-PSZ). Figure 4a and Figure 4b show all the coating characteristics presented in
matic cross section in Figure 3, except that the Y-PSZ coating (Figure 4b) does not
of course, oxidation and its lamellar structure is more pronounced.
d be noticed that microstructural homogeneity, process reproducibility and precise
onal tolerances are indispensable requirements in manufacturing of coatings. Net
nd high precision dimensional deposition of coatings are essential for cost efficiency,
ly in the case of hard coatings that require machining and finishing. The movement
ocity of the robot-guided torch has a crucial importance, especially for net-shaped
on complex 3D geometries, on the final properties of coating: thickness, roughness,
n, porosity, thermal stress distribution, etc. It is thus mandatory to develop software
for the off-line generation, simulation and implementation of movement (position
ntation) of the spray torches Candel and Gadow (2006).
.
chematic cross section of a thermally-sprayed coating
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) Stainless steel coating (304L) deposited by air plasma spraying on a low carbon
eel substrate, (b) Y-PSZ (8wt%) coating deposited by air plasma spraying on a super
a variety of metal alkoxides, nitrates, or hydroxides. Molten metals are also used
ng and strengthening purposes. The metal-coating wetting is, then, a key issue. For
zirconia is completely wetted by liquid pure manganese. Electroplating or glazing
deposition) can also be used.
olutions can be used to improve coating density and two examples are presented
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olutions can be used to improve coating density and two examples are presented
See all › See all › See all ›
Download citation Share Download full-text PDF
40 Citations 91 References 10 Figures
ting properties can be improved by annealing. By definition annealing corresponds
a heat treatment that alters the microstructure of a material causing change in
perties such as strength, hardness, ductility, etc. For thermally-sprayed coatings,
ealing or heat-treating is performed Davis (2004) at high temperatures, but well
ow the coating melting temperature, Tm. It takes place at atmospheric pressure in air
more generally in a controlled atmosphere or under vacuum and may induce
nges in coating microstructure and thermo-mechanical properties. Annealing may
ult in the formation of amorphous phase, the relaxation of residual stress
mperature must be over that of recovery ≈ 0.4xTm), diffusion between substrate and
ting improving the bond strength, the coating densification by increasing inter-splat
esion. It also may lead to recrystallization and grain growth occurring through
ering, reduction of coating oxide content when heated in hydrogen atmosphere or
mplete oxidation when heated in oxygen atmosphere, carbide precipitation from
d solutions with cobalt, thus enhancing the coating toughness.
other means to promote diffusion at the substrate and coating interface and to
apse the internal pores is to use some austempering process that consists of
nching the part directly into a liquid salt bath . For example Lenling et al (1991) used
process for plasma–sprayed composite coatings consisting of WC-Co and Ni-base,
ut 250-μm thick deposited onto AISI 5150 steel substrates. The samples were
mersed in a 870°C neutral salt for 30 min, quenched in a neutral salt bath at 315°C for
min and finally cooled and rinsed with room temperature water. After this
tment, the samples showed an increase in the percentage of WC phase and less
irable carbide phases formed during plasma spraying were eliminated. The bonding
ubstrate was improved, the coating hardness increased and residual compressive
sses appeared.
advantage of laser heat treating and glazing is that the amount of thermal energy
lied to the surface and the location on the surface to be treated are well controlled
is (2004). For treated surfaces, the intensity of the hemispherical reflection
fficient, R of the coating, must be considered, the energy or power absorbed by the
face being proportional to (1-R). Using a wide range of energy densities makes it
sible to get accurate temperature profiles at precise locations at different depths in
coating. The treatment enables the heat treating or melting of the surface (laser
zing). It must be kept in mind that coatings with low thermal conductivities (below
40 W.m-1.K-1) may exhibit high temperature gradients that induce important stresses.
latter are generally relaxed by macro-cracks orthogonal to the coating.
erent types of corrosive attack, especially for coatings can be classified as (i) general
n, corresponding to about 30% of failure, where the average rate of corrosion on the
is uniform and as (ii) localized corrosion, corresponding to about 70% of failures.
er comprises: (i) galvanic corrosion occurring when two dissimilar metals are in
with each other in a conductive solution (electrolyte), the more anodic metal being
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( y ) g
See all
d, while › more cathodic
the See all › one is unaffected.
See all › The electrolyte plays a key role, as well
Download citation Share Download full-text PDF
40 Citations
lative 91 References
surface contact 10 Figures
area; the smaller the anodic to cathodic area ratio is, the more
s the anodic metal corrosion. For example the protectection of low-carbon iron part
mospheric corrosion by a coating may use either an anodic coating (nickel) or
one (aluminum or zinc). In the first case no discontinuity in the coating can be
d, while it has no importance with cathodic coating, as illustrated in Figure 5, (ii)
anular corrosion, occurring when a chemical element is depleted during the coating
material manufacturing, e.g. during heat treatment, (iii) pitting, which is a localized
n characterized by depression or pit formation on the surface. It occurs for example
tainless steel is corroded by chloride-containing solutions, (iv) transgranular
n is mainly due to high static tensile stress in the presence of a corrosive
ment. It can be intergranular but also transgranular when cracking occurs. The
material and its microstructure play an important role in this type of corrosion.
xamples of protective coatings: a). Anodic (no discontinuity possible in the coating) ,
odic (discontinuity possible in the coating, resulting in no corrosion of iron).
ey were disposed in the marine atmosphere zone, seawater splash zone, tidal zone
-immersion zone. The tests included marine atmospheric outdoor exposure test,
r exposure corrosion test and coating adhesion test. It was found that the
nce of coated panels was as fine as original but with a little sea species adhering to
when they were immersed in tidal zone and full-immersion zone. Basically no
in the morphology, bond strength and no visible coating crack, blister, rust and
f was observed.
on-sacrificial coatings
tic stainless steels, aluminum bronze, nickel-base alloys, super-alloys MCrAlY where
, Co or Ni-Co, cermets (metal matrix re-enforced with WC, Cr2C3, and matrices
ng chromium or nickel or both are used against corrosion, often when it is
ed with wear. However such coatings, presenting no galvanic protection, will never
the substrate if connected porosities and oxide networks exist, which is the case in
thermal-sprayed coatings. Therefore, the substrate protection requires using a
ve bond coat or producing dense coatings, or sealing them. The latter operation is
ays possible if the service temperature is over a few hundreds of Celsius degrees. A
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y p p g
Seewill
mples all › be presented
See all ›below. According
See all › to Moskowitz (1993), the use of vacuum
Download citation Share Download full-text PDF
40post-treatments
rs or Citations 91 References
can eliminate 10 Figures
most defects, but these methods are costly and
cal on a large scale. Thus, he proposed using modified HVOF process with unique
s shrouding to achieve highly-dense, low-oxide coatings of metallic alloys. Coatings
sion-resistant alloys for severe petroleum industry corrosion applications, such as
6L stainless steel and Hastelloy C-276, were shown to act as true corrosion barriers.
de content also plays a role. For example 316L stainless steel coatings formed by
nd HVOF where applied on carbon steel panels and their resistance to salt spray
ed as sprayed or sealed Zeng et al (2008). When coatings were sealed, corrosion was
he HVAF coatings than that on the sealed HVOF coating, and almost no corrosion was
d on the sealed coating sprayed with powder of the largest particles (highest porosity)
en 500 h of salt spray testing. While the amount of through pores dominates the
n resistance of as-sprayed coatings, the degree of oxidation of the coatings (much less
VAF) determines the corrosion resistance when sealing is applied.
lications in oil and gas industry on parts subjected to severe wear, cermets are used,
wever some problems for offshore installations. According to Meng (2010) the choice
the wide varieties of tungsten carbides with different alloying binders is not
The corrosion resistance of coatings can be improved by the proper choice of binder.
mple, Souza and Neville (2003) have shown that WC-CrNi exhibits passive behavior,
less steel, and would be compatible for use as a coating/substrate system when
to seawater, which is not the case for WC-CrC-CoCr. As previously mentioned the
porosity and its oxide content must be as low as possible. It is why HVOF guns are
used as they result in higher impact velocities (and so low coating porosity), and
article temperatures (and so less particle oxidation) as shown by Ishikawa et al (2005).
ed a commercial HVOF gun with a gas shroud attachment (GS-HVOF) to prepare
C-Ni coatings. Results of corrosion test indicate that through porosity was eliminated
ities above 770 m/s with a lower degree of WC Degradation, wear resistance and
s of coatings prepared by GS-HVOF were superior to those prepared by the
ional HVOF. Fedrizzi et al (2007) showed that Cr3C2–NiCr coatings, in sodium
solution under sliding wear, presented good barrier properties and substrate
n was never observed. Moreover, when chromium was added to the metal matrix of
based systems, tribo-corrosion behavior was enhanced and the lower tribo-
n rates were measured. Plasma sprayed Cr2O3-8 wt.%TiO2 coatings were used on
ic cylinder piston rods and rolls but the substrate was rapidly corroded by the
n of the corrosive solution through pores: the bond coating was destroyed by the
ve solution and ceramic coating flakes dropped off. Zhang et al (2011) have sealed
with epoxy and silicone resins. The sealing treatment improved significantly the
n resistance of coatings by blocking the open pores and cracks of the coating. Sealed
ne resin, the coating gained remarkable anti-corrosion properties and after 1200-h
y test, no rust was observed on the silicone resin sealed coating.
ction of bulk materials and coatings of valve components is an important factor for
omic success of oil and gas production activities in the petrochemical field. Particle
and surface wear are associated to corrosion by hydrogen sulphide during oil and
F h li ti S i i t l (2001) h h t i d th f ll i HVOF
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. For such
See all › applications,
See allScrivani
› et alSee all › have characterized the following HVOF -
(2001)
: NiAl and composite material WC/intermetallic DownloadNi,
compounds containing citation
Cr, Co Share Download full-text PDF
40 Citations 91 References 10 Figures
WC–CoCr carbide coatings showed high erosion resistance due to their elevated
ardness. Also WC/Mo compound, because of its carbide content, showed fairly
ehavior in an erosive environment while WC/Mo compound showed an higher
resistance than Inconel 625 and NiAl.
s find increasingly large industrial use, in accordance to their high strength-to-
ratio and elastic modulus-to-density ratio. These alloys depending on their
tion, besides their poor tribological behavior, can be prone to localized corrosion
ting) in some particularly aggressive environments (e.g. seacoast atmosphere). To
these drawbacks, protective coatings or surface treatments are often employed.
et al (2010) have studied the resistance of WC-CoCr coatings HVOF-sprayed onto
T6 substrates. Coatings with thickness ranging between 50 and 150 µm were
d by stepwise increase of the number of torch scans. An increase in coating
s came along with an increase in coating density because of peening effect and
ations of the splat formation mechanism. Thanks to coating densification, the
s, wear and impact resistance, and corrosion protectiveness of the layers increased
number of torch scans. The largest improvement occurred from 2 to 3 torch scans.
ompared to anodized films these coatings had superior wear and impact resistance
red less corrosion protection.
industry, polymer coatings replace paints on the wall because they have a much
esistance to the chemical products used for cleaning (about one week for paint
about four for the polymer coating). They are even used on the floors where
coatings doped with alumina particles provide an excellent anti-slip lining, the
particles rippling out when people walk on it.
leum industry, the protection of external steel structures, pipes, tanks… is achieved
Zn or Zn-Al wire arc sprayed Davis (2004), as well as polymers sprayed by using
HVOF or plasma according to the polymer melting temperature Petrovica et al (2002).
lp and paper
e producing paper and cardboard comprise many parts that can have large
ons (e.g. rolls over one meter in diameter and ten meters in length) and are
d to high wear and corrosion problems. Coatings are used for several types of rolls
inders, including for instance, center press rolls, dryer cylinders, calender rolls,
rolls, and Yankee cylinders Vuoristo and Nylen, (2007). Coating materials used are
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d nickel-base
See all › alloys,
See nickel-chromium
all › self-fluxing
See all › alloy, carbides, oxide ceramics,
Download citation
ious40multi-layers
Citations 91 Referenceson the
depending 10application.
Figures Figure 8 shows a roll coated by Share Download full-text PDF
praying of NiCrBSi and Figure 9 another roll coated by HVOF spraying of WC-Co,
ze is underlined by the person next to it.
aper machine roll coated by NiCrBSi (self fluxing alloy)Vuoristo and Nylen, (2007).
xide coatings are used to protect such rolls, one of the problems is the expansion
h between the ceramic coating and the metal (for example 5-6 10-6K-1 for iron and
). Functionally graded (FG) coatings help to increase the compatibility between
coatings and metallic substrates as coating properties such as coefficient of thermal
on (CTE) and elastic modulus gradually change in order to reduce the thermal
within the coating Hannula et al (2009). Post-treatments, such as the deposition of
with fluoro-polymers or the sealing of coatings to protect them against corrosive
ment, are also used. Few examples are presented below:
ss rolls are used to remove water from the sheet using mechanical forces. First they
e made of granite rock and were very expensive with limited rotation velocity. Now
iron or steel roll bodies with coatings are used. The coatings are application-specific
tailored to perform optimally under production conditions of various types of
er. Factors such as wear and corrosion resistances, and the functionality of the roll
site and all the coating process stages (surface preparation, coating, surface finish)
carried out in the paper factory Vuoristo and Nylen, (2007). Figure 9 represents
OF WC-Co coating of a paper machine after finishing.
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tings are generally top-coated with a fluoro-polymer layer to improve the release
es of the roll surfaces Vuoristo and Nylen, (2007). Steels with high molybdenum
(better corrosion resistance and thermal conductivity) HVOF sprayed are also used
004).
Fiber-Reinforced Plastics rolls (CFRP roll) exhibiting excellent characteristics
g lightweight, high-stiffness, and low-flexure have been increasingly employed in
cturing industrial fields. Compared to conventional metal rolls, CFRP rolls are
and stiffer, and exhibit lower inertia moment Nagai et al (2009). Unfortunately
cermet coatings failed because of their poor thermal shock resistance on CFPR rolls.
composite porous coating including ceramics particles developed by Nagai et al
howed high thermal-shock resistance. Five coated rolls were installed in the actual
aking line. They achieved successful results with 10% improvement of the line
whereby outstanding performance and maintenance-free has been confirmed even
years of use. Yoshiya et al (2009) have developed a 5.4-m length thermal sprayed
roller, installed in a paper slitter/winder, that is moving stably at ultrahigh speed,
min-1, with no abrasive wear. The roller has a three-layer structure: a tungsten
cermet layer on grooved metal sleeve, which covers the CFRP substrate roller shell.
rmal spay process is the finishing process as no grinding is performed after cermet
deposition.
inting industry
ng to Döering et al (2008) who made an extensive review of thermal spray processes
ng: “the printing processes need all an ink transferring unit, a print form and an
ion cylinder”. The requirements for an appropriate coating in terms of the function
the requirements for the grinding and finishing steps after the coating process are
igh, as illustrated with few examples:
ink transporting systems in offset printing machines consist of several different
ers providing a homogenous film of ink for the print form For example the ductor
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ers, providing a homogenous film of ink for the print form. For example the ductor-
See all › See all › See all ›
er elevates the ink from the ink box to the ink conditioning system.DownloadIts
citation
surface Share Download full-text PDF
40 Citations 91 References 10 Figures
ghness Rz must be better than 2 µm and tolerances must be better than 2/1000 mm
oncentricity. Such conditions are achieved with chromia rich coating consisting of a
al bond coat (Ni, NiCr, NiAl) and a ceramic topcoat Döering et al (2008).
ontrast to common offset inking units, the anilox unit consists of a laser-engraved
er, taking the ink from a chamber doctor blade system Döering et al (2008).The
vure procedure is performed after finishing the roller surface. Producing pure
omia coatings implies using carefully adapted plasma spray conditions and adapted
wders, for more details see the paper of Pawlowski (1996).
ny other rolls are used in printing machines Döering et al (2008) with plasma sprayed
de coatings (chromia, alumina-titania (3 or 13 wt %)). Recently Lima and Marple
05) have proposed to replace the alumina-titania coatings that are conventionally
sma sprayed, by HVOF-sprayed nanostructure titania coating exhibiting a very
se (nearly pore free) and uniform isotropic microstructure with an excellent wear
corrosion resistance.
er rolls such as blanket cylinders are coated with Hastelloy C by either APS or
OF and at last draw rolls are coated with nickel-chromium Davis (2004).
h temperature coatings
rosion degradation of metals and alloys is a serious problem for many high
ture applications in aggressive environment, such as boilers, internal combustion
gas turbines, fluidized bed combustion, industrial waste incinerator. The depletion
grade fuels and use of residual fuel or oil in energy generation systems contribute to
e degradation. Residual fuel oil contains sodium, vanadium, and sulfur as
es. The latter react together to form low melting point compounds, known as ash,
ettle on the surface of materials and induce accelerated oxidation (hot corrosion).
on occurs when these molten compounds dissolve the protective oxide layers that
y form on materials during boiler/gas turbine operation. In the following a few
s will be presented according to industries. However it must be underlined that the
ating can be used for example against corrosion in gas turbines, internal combustion
and boilers and industrial waste incinerators. Solutions were found in the use of
cated materials, that are resistant to oxidation and corrosion at high and low
tures and exhibit high-strength, e.g. nickel- base superalloy Inconel 625. However
of these materials on cheaper metals would be cheaper than bulk super-alloy.
ents of furnaces: A wide variety of components associated with electric arc furnace
nd Basic Oxygen Furnace (BOF) are subjected to severe attack from heat, particulate
dic gases. Water-cooled components, in the off-gas duct systems such as pans, roofs,
nd panels, are subjected to high-velocity combustion gases that contain a number of
es chemicals that condense and attack the heat transfer surfaces. Coatings used are
veloped for high-temperature wear and corrosion resistance (see the articles of Wang
tak (1999), Higuera Hidalgo et al (2001), Sidhu et al (2005),(2006), Kaushal et al (2011)).
n continuous casting the cast shell in the lower half of the mold abrades and wears
om of the mold. The diffusion of the copper substrate from the mold into the surface
st product leads to a quality defect called "star cracking". Chrome- and nickel-based
protect copper molds from wear, and also enhance caster product quality by
reducing cast product contamination and star cracking problems. Thermal barrier
are also used to control the heat flow and retard rapid chilling Sanz (2001), Davis
For very corrosive melts, pure yttria is used instead of zirconia partially stabilized
ria. They are deposited onto a metal bond coat. Multi-layer coatings can also be used
ve a good compliance between the expansion coefficients of mold and topcoat. Sanz
as studied different coatings to protect the mold wall. Gibbons and Hansell (2006)
own that Cr2C3-25(Ni-20Cr) and WC-10Co-4Cr coatings deposited using JP5000
hardware, offer properties that could enable low-cost, low-volume production
m injection mold tooling to be upgraded to higher volume production tooling.
salvage is also achieved by filling the voids of porosity or wear zones, after
g, with plasma or wire-arc sprayed coatings that are then re-machined Davis (2004).
ng: Hot dipping rolls: MoB/CoCr, a novel cermet material for thermal spraying,
gh durability in molten alloys has been developed for aluminum die-casting parts,
hot continuous dipping rolls in Zn and Al-Zn plating lines, Mizuno and Kitamura
The tests revealed that the MoB/CoCr coating has a high durability without
ion in the molten Al-45wt.%Zn alloy. Using undercoat is effective to reduce the
f large difference in thermal expansion between the MoB/CoCr topcoat and
e of stainless steel of AISI 316L, widely used for the hot continuous dipping Mizuno
amura (2007). MoB-based cermet powders (MoB/NiCr and MoB/CoCr) were
d on SKD61 (AISI H-13) substrates used as a preferred die (mold) material Khan et al
The durability of these coatings on cylindrical specimens against soldering has also
vestigated by immersing them in molten aluminum alloy (ADC-12) for 25 h at 670
comparison with the durability of NiCr and CoMoCr coatings under the same
n showed that both types of MoB-based cermet coatings have high soldering
ce as negligible intermetallic formation occurred during the immersion test.
l( )h d d lf d l h dd f
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and exit rolls of steel processing line: when tungsten carbide coatings are used on
nd accumulator rolls in entrance and exit ends of a steel processing line damage of
surface is eliminated, proper grip provided and slippage prevented. The surface
is properly textured to provide the required characteristics or profile on the strip
Multi-component white cast iron is a new alloy that belongs to system Fe-C-Cr-W-
seems promising for rolls when deposited by HVOF spraying Maranho et al (2009).
ed and aluminized steel sheets: They require very high surface quality, particularly in
panels. In continuous galvanizing and aluminizing, the steel strip is dipped in the
bath through a series of rolls, which control the speed and tension of the strip and
e steel strip through the molten metal bath. The rolls operating in the molten Zn-Al
e subjected to severe corrosive environment and require frequent change and repair.
t al (2001) have shown that WC-Co coatings are not very good with molten Zn-Al.
ng the sink rolls and stabilizer rolls with molybdenum boride, tungsten carbide and
aterials, the rolls remain smoother and produce an improved strip surface.
tal forming dies: Conventionally mold and dies are manufactured by machining from
tallic materials. Tooling by using arc spray process to spray metal directly onto a 3D
pattern is an alternative method to manufacture mold and dies for plastic injection
g and other applications, Seong (2009).
hemical industry
s in chemical industry are used for pressure and storage vessels with Hastelloy B or
nel 600. In heat-affected zones, the solutions used in gas turbines (see section 4.4.6)
n employed. In some chemical reactors dealing with strong acids in combination
ganic solvents, glass lining are used and can be repaired by APS sprayed tantalum
, bonding well to the glass with an overlay of chromium oxide Davis (2004). For oil,
d petrochemical industries the following components are protected with thermal
coatings : mud drill rotors, pump impellers, plunger, turbine, rotor shaft of
gal compressor/pump, pump shafts, boiler tube, mixing screw, mandrels, actuator
nd housings, housings and valves, valve gates and seats, ball valve with large
r, progressive cavity mud motor rotors, rock drill bits, riser tensioner rods, impeller
drilling and production risers, sub-sea piping, wellhead connectors, fasteners,
sor rods, mechanical seals, pump impellers, tank linings, external pipe coatings,
al steel coating….
ectrical utilities
s against corrosion and wear (C-W) are used in fluidized-bed combustor (FBC) and
ional coal-fired boilers:
d-bed combustor boilers: the problem is linked to the finely divided mixtures of coal
estone particles eroding and corroding steam pipes and boiler walls, as well as the
lfur content of coals or low grade combustibles resulting in corrosion at high-
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ture.
SeeDifferent
all › coatings
See allare
› used: See all ›
Download citation Share Download full-text PDF
40 Citations 91 References 10 Figures
O3 (20 wt %)-Al2O3 on Ni Cr Al Y b on d co at th at pr otects against corrosion through
porous ceramic coating, Davis (2004). The addition of approximately 20 wt %
omia results in the formation of one solid solution of (Al-Cr)2O3 in the α-phase
dification; working temperatures can reach 1000 °C and the transformation of γ
se starts around 900 °C.
OF sprayed Cr3C2-NiCr coatings with high compactness and fine grain size, Wang
96). The wear resistance is due to the particles of hard carbide homogeneously
ributed within the coating, the ductile matrix being corrosive-resistant.
d boilers: Plasma-sprayed stellite-6 coating has been found to be effective in
ng the erosion-corrosion resistance of boiler steels in the coal-fired boiler
ment. A less porous structure obtained after laser re-melting was found to be
for increasing erosion-corrosion resistance, Sidhu and Prakash (2006). Inconel
or high chromium alloys or chromium-nickel alloys coatings, presenting a good
ce to sulfur have also been used, sprayed with plasma, wire-arc or HVOF Davis
Notomi and Sakakibara (2009) have proposed low cost plasma-sprayed coatings with
dness, developed by adding carbon and hardening elements to high chromium cast
Si-Mn-Cr-Mo-V-other-Fe) used for wear resistant material. Nitrogen gas atomization
lied to manufacture the powder in order to prevent the oxidation of particles. These
showed the same or better erosion resistance than Cr3C2-NiCr cermet coating, and
her reliability for long period operation and higher practicality.
ture-transition-glasses, steel molds with a nickel alloy coating can be used, e.g. self-
alloy NiCrBSi flame-sprayed and refused. For higher transition temperatures NiCr-
TiC cermets are used.
rospace
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Seein
trated allFigure
› See
10, all › parts (hundreds
many See all › of components) are covered by thermal
Download citation Share Download full-text PDF
40 Citations
coatings in aircraft91engine.
References
If, at the10 Figures coatings were APS and VPS sprayed,
beginning
spraying has been rapidly adapted to needs and twin-arc spray process is now
d. Coatings are used against fretting wear, for friction, reduction, for clearance
and for high temperature protection (thermal barrier coatings, TBC). They are also
seals and to replace hard chromium in landing gear Davis (2004).
ere first successfully tested in the turbine section of a research gas turbine engine in
-1970s. By the early 1980s they had entered revenue service on the vane platforms of
gas turbine engines, Miller (1997), Bose and de Masi-Marsin (1997), and today they are
n revenue service on vane and blade surfaces, Golosnoy et al (2009). Thermal
on benefits provided by TBCs and the resulting impact on component creep and
mechanical fatigue life have made them enablers of high-thrust gas turbine engines.
erlined by Pratt and Whiteny, of particular importance are the TBCs elaborated by
(Electron beam physical vapor deposition) that present an excellent compliance
ermal cycles and can improve blade life by a factor of three Bose and de Masi-Marsin
The aging of TBC’s topcoat depends strongly upon the spray conditions and powder
logies used to spray or deposit it, conditions acting on its sintering Golosnoy et al
Cipitria et al (2009), Markocsan et al (2009). The second problem is the oxidation of
at with the formation of Thermally Grown Oxide (TGO) Feuerstein et al (2008) as well
bond coat corrosion with oxides such as CMAS (calcium-magnesium-alumino-
nd-based turbine
ed to aero engines, land-based turbines work under different conditions: the
environment might range from cold (- 40 °C) to high temperature (55-60 °C) and
e and erosive contaminants due to the environment and fuel are present. Coatings
ied onto bearing journals, bearing seals, sub shaft journal, labyrinth seals, blades, tip
let and exhausts and housing Davis (2004). A detailed description of the different
her industries
iously described, thermal spray coatings provide superior wear (abrasive, erosive,
…) resistance and corrosion protection with coatings having low porosity, high
s, good toughness for cermets, and great flexibility of composition. Thus they are
d in:
industry: the use of cobalt-based alloys (stellites or cermets matrix) is limited, thus
against wear and corrosion rely on nickel alloy based coatings (NiCr-WC or NiCr -
Cermets with hafnium-carbide that present a large neutron cross-section have been
ed. However, thermal sprayed coatings are essentially used in pumps, turbines, heat
ers, vanes… For example Figure 11 presents a spherical vane that was HVOF
ment,See all ›
particularly See all encountered
those › Seeinallthe
› processing of nuclear wastes, metallic
Download citation Share Download full-text PDF
ents40are
Citations
subjected91toReferences 10 Figures in service, in terms, for example, of
extreme environments
at moderated temperature (several months at about 300 °C) coupled to thermal
numerous cycles up to 850 °C for a few seconds and a few ones up to 1500 °C) under
ve environment made of a complex mixture of acid vapors in the presence of an
ield of a few hundred volts and a radioactive activity Berard et al (2008). The authors
sted alumina plasma-sprayed coatings manufactured with feedstock of different
size distributions, graded alumina-titania coatings, and phosphate-sealed alumina
to improve the properties of metallic substrates operating in such extreme
ments. The effects of particle size distribution, phosphate sealant, and graded titania
ns on the dielectric strength of the as-sprayed, thermally cycled and thermally aged
were investigated. Thermal ageing test was realized in furnace at 350 °C for 400 h
rmal shocks tests resulted from cycling the coating between 850 and 150 °C using
ylene flame and compressed air-cooling. Aluminum phosphate impregnation
d to be an efficient post-treatment to fill the connected porosity of coatings. Alumina
ed coatings manufactured with +22 -45 µm and +5 -20 µm particle size distributions
d good dielectric strengths after thermal solicitations compared to coatings
ctured with bigger size distributions or to graded titania coatings.
ment industry: Again the main role of sprayed coatings is wear and corrosion
tection of mechanical seal, sleeve, burner tip, boiler tube, thermo-well, kiln support
pinion shaft, coating for cement preheat tower, impeller blade, calender roll, cone
sher and hydraulic rams with acid resistant coatings…
wing Machine: guide roller and ceramic disc, rod breakdown drawing machine, fine
wing machine and other accessories
te treatment: The oxidation of steel tubes causes an important problem in Municipal
d Waste Incinerator (MSWI) plants due to burned wastes containing high
centrations of chemically active compounds of alkali, sulfur, phosphorus and
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Ad d Pl S A li i
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See all › See all › See all › Advanced Plasma Spray Applications
Download citation Share Download full-text PDF
40 Citations 91 References 10 Figures
of stress and corrosion. At high temperatures reactions with oxygen, carbon,
n, sulfur or flux result in the formation of oxidized, carburized, nitrided, sulfidized,
ayer on the surface. Temperature and time are the key factors controlling the rate
erity of high temperature corrosive attack Chattopadhyay (2001).
xamples are presented below. An important concern in the oil and gas production
y is the behavior of materials in an aggressive environment with the presence of
ed sand particles, which contribute to corrosion, erosion and overall wear of the
Al-Fadhli et al (2006) have HVOF-sprayed Inconel-625 onto stainless steel
ents used in oil/gas industry. Coatings were applied on three different metallic
: (a) plain stainless steel (SS), (b) spot-welded stainless steel (SW-SS), and (c) a
te surface of stainless steel and carbon steel welded together (C-SS-CS). These
urfaces were tested in a jet impingement rig under two fluid conditions: (i) free from
olids, (ii) containing 1% silica sand. The coating was found to be highly sensitive to
ence of sand particles in the impinging fluid. As the period of coating exposure to
w o f sl urr y f lui d i ncr eas ed , we ight l oss increased significantly. This increment was
ent on the type of substrate material.
HVOF-sprayed coatings present poor resistance to corrosive wear: the tungsten
in HVOF coatings dissolves as well as the cobalt-chromium matrix, leading to cobalt
on. WC and Co go through an oxidation process before dissolution, the oxidation of
WO3 makes the pH drop, accelerating the dissolution of cobalt and corrosion of hard
ading to its removal. So, there are serious implications when coatings are used in
e-erosive environments Souza and Neuville (2006). These authors have tested WC-Co-
OF-sprayed coatings. They have shown that the corrosion of these coatings is very
and corrosion rate increases with temperature. However, chromium forms an
yer, which protects from dissolution and retards the corrosion. Toma et al (2001)
imilar results, concluding that due to its low erosion-corrosion rate the HVOF
Cr3C2-NiCr coating can be considered to be an excellent replacement for the
sprayed Cr2O3 coatings. Espallargas et al (2008) found that both WC–Ni and Cr3C2–
atings are promising alternatives to hard chromium from the point of view of
corrosion resistance.
sprayed aluminum oxide and chromium oxide coatings are widely used to improve
tance of metallic components against various types of wear and corrosion. However
rosion resistance depends strongly on their porosity, especially open pores. Leivo et
used aluminum phosphates to seal the structures of Al2O3 and Cr2O3 coatings. The
wear resistance of sealed coatings did not decrease after immersion tests of 30 days
ds of pH 0 to 10 , e xc ep t fo r t he Al 203 coating, which corroded in pH 0 and pH 14
s. No corrosion was found with aluminum phosphates in very acidic solutions.
um phosphate is a good candidate to seal oxide coatings that are exposed in
e environments, excluding high basic environments of approximately pH 14.
engines, sulfur contain in the fuel induces corrosive attack possibility. Uusitalo et al
ave tested the newly developed ferrous powder (Fe–C–Ni–Cr–Cu–V–B alloy) plasma
with the Rota-Plasma® of Sultzer-Metco on Al-13Si cylinder wall. It presented
t corrosion and wear resistances, compared with currently used bulk casting materials
Fe – C – Si – B alloy and Fe – C – Si – Mo – B alloy for cylinder liners.
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al (2006) have tested the corrosion and corrosion–wear behavior of thermal sprayed
uctured FeCu/WC–Co coating in Hank’s solution and compared the results with
stainless steel AISI 304 and nanostructured WC–Co coatings. The multiphase
e of the FeCu/WC–Co coating induces a complex corrosion behavior. Under
n–wear conditions, the nanostructured FeCu/WC–Co coating exhibited a
vation/repassivation behavior comparable to that of stainless steel AISI 304 and
uctured WC–Co coatings.
y speaking, thermal sprayed coatings behave better when their density is improved.
mple Liu et al (2007) have investigated the effects of laser surface treatment on the
n and wear performance of Inconel 625, and Inconel 625-based WC HVOF-sprayed
atrix composite coatings. Significant improvement of corrosion and wear resistance
hieved after laser treatment as a result of the elimination of discrete splat-structure,
evice and porosity, and also the reduction of micro-galvanic driving force between
and the metal matrix. In addition, the formation of faceted dendritic structure of the
se was considered to be beneficial for the wear performance.
clusions
sprayed thick (from 50 to 3000 µm) coatings, including cold spray coatings are
nd more used in industry for the following reasons: (i) They provide specific
es onto substrates which properties are very different from those of the sprayed
(ii) They can be applied with rather low or no heat input to substrates (allowing for
spraying ceramics onto polymer substrates); (iii) Virtually any material that melts
decomposing or vaporizing can be sprayed including cermets or very complex
r ceramic mixtures, allowing tailoring coatings to the wished service property; (iv)
coatings can be strip off and the worn or damaged coatings recoated without
g part properties and dimensions; (v) Some spray processes can be moved on site,
g spraying rapidly big parts, which displacement would otherwise be rather long
ensive.
n thermal-sprayed coatings drawbacks are the following: (i) They are a line-of-sight
ogy, e.g. making it impossible to coat small and deep cavities; (ii) Most coatings have
structures with contacts between layered splats that represent between 15 and 60 %
plat surfaces depending on spray conditions; (iii) They have pores, cracks… that can
ected, depending on the spray process and spray conditions, and that must be sealed
in applications.
lk materials used in corrosion conditions can be sprayed, however splat boundaries
cks (for ceramics coatings) often dominate the corrosion properties of coatings.
al coatings (cathodic behavior relatively to ions, for example Zn or Al on steel) are
ely used for the protection of large steel structures such as bridges, pipelines, oil
owers, radio and television masts, overhead walkways and large manufacturing
, as well as for structures exposed to moist atmospheres and seawater such as ships,
platforms and seaports. Their porosity does not affect the anodic material
on, except when the whole cathodic coating structure is completely corroded.
as sealing or densification by shot peening are often used to extend their lifetime.
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References (91)
pplications require materials that exhibit strong resistance to chemical attacks and wear with an ability to
ion even in hostile environments and operating conditions [81]. Marine applications, aeronautical
as refineries and drilling applications, agricultural applications, and defense applications are few of those
e extreme as well as adverse environments [82, 83]. The materials used in these applications also need to
h, hardness and toughness to withstand the various structural and thermal loads experienced by them [84][85]
ways to modify or enhance surface properties, such as modification of chemical composition by surface
ding, carburizing, vanadizing and modification in the surface characteristics by mechanical and thermal
pment of layers or overlays on the surfaces using coating and cladding processes. Conventional surface
are thermal spraying [82] , high-velocity oxyfuel spraying [89], tungsten inert gas (TIG) cladding, laser
ed metal arc welding (SMAW) based cladding, etc [84] . Laser cladding is the most effective process in terms
es resulting in reduced cracks, porosity and errors in bonding along with the controlled cooling rate. ...
-Al-based alloy could significantly enhance the corrosion resistance due to self-sealing nature of Zn-Al alloys
his was attributed to formation of intermetallic phases such as MgZn 2 and MgZn 11 and, in some cases, Zn
Ref 70), of which plugs the pores and protects the substrate against electrolyte. As a result, Zn-AlMg
ven higher corrosion resistance than that of pure Zn and Zn-Al coatings (Ref 70, 73). ...
ocesses were used as deposition technique and a premier Ni20Cr-10Al-Y bond coat were used prior to
substrate. The scale on the NiCrAlY coating contained NiO, Cr 2 ...
ble
RAY TECHN
Amirhossein Mahdavi · Fardad Azarmi · André McDonald
gradation took place, the underneath sprayed layer was exposed to the corrosive atmosphere. Sprayed
nt a morphology containing pores and other defects, which is a consequence of the solidification of the
een successive splats and the thermal stresses that might generate during the spraying process [30][31] [32] .
aracterization of the carbide sprayed layer composing the C1 coating (which was evaluated in the previous
n the case of the C2 coating, oxides coming from metallic impurities were observed, which was similar to the
he previous tests. ...
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gradation
See alltook
› place, See
the underneath
all › sprayed layer
See all › was exposed to the corrosive atmosphere. Sprayed
Download citation Share Download full-text PDF
nt a40
morphology
Citations containing pores and other
91 References defects, which is a consequence of the solidification of the
10 Figures
een successive splats and the thermal stresses that might generate during the spraying process [30][31] [32] .
aracterization of the carbide sprayed layer composing the C1 coating (which was evaluated in the previous
structure with pores and cracks. ...
-Al-based alloy could significantly enhance the corrosion resistance due to self-sealing nature of Zn-Al alloys
his was attributed to formation of intermetallic phases such as MgZn 2 and MgZn 11 and, in some cases, Zn
Ref 70), of which plugs the pores and protects the substrate against electrolyte. As a result, Zn-AlMg
ven higher corrosion resistance than that of pure Zn and Zn-Al coatings (Ref 70, 73). ...
ocesses were used as deposition technique and a premier Ni20Cr-10Al-Y bond coat were used prior to
substrate. The scale on the NiCrAlY coating contained NiO, Cr 2 ...
ble
RAY TECHN
article with the substrate causes the particles to flatten to form a coating. The high-velocity impact and rapid
ted particles form cohesively bonded splats ranging in size from 10-100 m [2] . The physical properties of the
n the cohesive strengths between the splats, the size, and morphology of the porosity, the presence of cracks
h coating layer [5]. ...
e of Hardfaced/Thermally Sprayed Coatings for Increased Wear Resistance of Cutting Blades Used in
ble
low friction material, exhibits good sliding wear and oxidation resistance around the processing temperature
coatings, properties such as fatigue resistance, wear resistance and corrosion resistance of steel can be
baloy alloys are high wear and corrosion-resistant alloys which contain Ni or Co based materials. ...
plasma and electrochemical assisted coating techniques, thermal spraying techniques are also commonly
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ron materials
See all › [3][4][5][6][7][8].
See all › In particular,See
theall
surfaces
› of the rollers that are made of cast iron used in the
stries
40are coated with91
Citations materials such as Tungsten-Carbide-Cobalt
References 10 Figures (WC-Co)Download
which are citation
resistant to Share
wear by Download full-text PDF
iques [9, 10]. Within the scope of the research and development activities directed to the automotive
ngs are produced by thermal spraying techniques on aluminum-based parts manufactured by casting method
us tests [11]. ...
ospheric plasma spraying, the molten powder particles in HVOF are faster, have higher momentum and lower
ot evaporate when they hit the substrate, so the HVOF spraying process is suitable for achieving superhard
10)(11)(12) This deposition process has little environmental impact and is regarded as the most promising
ome plating; indeed, the US Federal Aviation Administration has approved this process for spraying many
s. (13) The temperature generated by HVOF spraying can reach 2000-3000 ℃. ...
f Cobalt-based Alloy Coating Applied Using High-velocity Oxygen Gas and Liquid Fuel Spraying
TER
Lung Pai · Chao-Ming Hsu
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MAN Diesel design and develop diesel engines for power plants and ship propulsion. The engines are produced on license at engine
builders particularly in Asia and there is a constant demand from engine builders, ship/plant owners and authorities that the engines
shall be more compact, yield more, consume less fuel, pollute less and at the same time they shall be reliable in operation. To meet
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