THERMO

ME304ES: THERMODYNAMICS UNIT – III
Pure Substances, p-V-T- surfaces, T-S and h-s diagrams, Mollier Charts, Phase
B.Tech. II Year I Sem. L T/P/D CTransformations
4 1/0/0 4 – Triple point at critical state properties during change of
phase, Dryness Fraction – Clausius – Clapeyron Equation Property tables.
Pre-requisite: Engineering Chemistry and Physics Mollier charts – Various Thermodynamic processes and energy Transfer –
Steam Calorimetry.
Course Objective: To understand the treatment of classical Thermodynamics Perfect Gas Laws – Equation of State, specific and Universal Gas constants –
and to apply the First and Second laws of Thermodynamics to engineering various Non-flow processes, properties, end states, Heat and Work Transfer,
applications changes in Internal Energy – Throttling and Free Expansion Processes – Flow
Course Outcomes: At the end of the course, the student should be able to processes
Understand and differentiate between different thermodynamic systems and UNIT - IV
processes. Understand and apply the laws of Thermodynamics to different Deviations from perfect Gas Model – Vader Waals Equation of State –
types of systems undergoing various processes and to perform thermodynamic Compressibility charts – variable specific Heats – Gas Tables
Mixtures of perfect Gases – Mole Fraction, Mass friction Gravimetric and
analysis. Understand and analyze the Thermodynamic cycles and evaluate
volumetric Analysis – Dalton’s Law of partial pressure, Avogadro’s Laws of
performance parameters.
additive volumes – Mole fraction , Volume fraction and partial pressure,
Equivalent Gas const. And Molecular Internal Energy, Enthalpy, sp. Heats and
Tables/Codes: Steam Tables and Mollier Chart, Refrigeration Tables
UNIT – I Entropy of Mixture of perfect Gases and Vapour, Atmospheric air -
Introduction: Basic Concepts: System, Control Volume, Surrounding, Psychrometric Properties – Dry bulb Temperature, Wet Bulb Temperature,
Boundaries, Universe, Types of Systems, Macroscopic and Microscopic Dew point Temperature, Thermodynamic Wet Bulb Temperature, Specific
viewpoints, Concept of Continuum, Thermodynamic Equilibrium, State, Humidity, Relative Humidity, saturated Air, Vapour pressure, Degree of
Property, Process, Exact & Inexact Differentials, Cycle – Reversibility – Quasi saturation – Adiabatic Saturation , Carrier’s Equation – Psychrometric chart.
– static Process, Irreversible Process, Causes of Irreversibility – Energy in State UNIT - V
Power Cycles : Otto, Diesel, Dual Combustion cycles, Sterling Cycle, Atkinson Cycle,
and in Transition, Types, Displacement & Other forms of Work, Heat, Point
Ericsson Cycle, Lenoir Cycle – Description and representation on P–V and T-S diagram,
and Path functions, Zeroth Law of Thermodynamics – Concept of Temperature
Thermal Efficiency, Mean Effective Pressures on Air standard basis – comparison of
– Principles of Thermometry – Reference Points – Const. Volume gas
Cycles.
Thermometer – Scales of Temperature, Ideal Gas Scale
Refrigeration Cycles:
UNIT - II
Brayton and Rankine cycles – Performance Evaluation – combined cycles,
PMM I - Joule’s Experiments – First law of Thermodynamics – Corollaries –
Bell-Coleman cycle, Vapour compression cycle-performance Evaluation.
First law applied to a Process – applied to a flow system – Steady Flow Energy
Equation.
TEXT BOOKS:
Limitations of the First Law – Thermal Reservoir, Heat Engine, Heat pump ,
1. Engineering Thermodynamics / PK Nag / Mc Graw Hill
Parameters of performance, Second Law of Thermodynamics, Kelvin-Planck
2. Thermodynamics for Engineers / Kenneth A. Kroos ; Merle C. Potter/
and Clausius Statements and their Equivalence / Corollaries, PMM of Second
Cengage
kind, Carnot’s principle, Carnot cycle and its specialties, Thermodynamic scale
of Temperature, Clausius Inequality, Entropy, Principle of Entropy Increase –
REFERENCE BOOKS:
Energy Equation, Availability and Irreversibility – Thermodynamic Potentials,
1. Engineering Thermodynamics / Chattopadhyay/ Oxford
Gibbs and Helmholtz Functions, Maxwell Relations – Elementary Treatment of
2. Engineering Thermodynamics / Rogers / Pearson
the Third Law of Thermodynamics

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