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S 482

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S-482 (R-13)

Institute for Excellence in Higher Education (IEHE), Bhopal


B.Sc. (HONOURS): PART-II Semester: IV
SUBJECT: CHEMISTRY PAPER: HONOURS - II

TITLE: Inorganic Chemistry-II


Maximum Marks: 100
SYLLABUS

1. Chemistry of First Transition Series:


Characteristic Properties of d-Block Elements, Properties of Elements of First
Transition Series, their Binary Compounds and Complexes illustrating Relative
Stability of their Oxidation States, Coordination Number and Geometry.

2. Chemistry of Second and Third Transition Series:


General Characteristics, Comparative Treatment with their 3d analogues in respect
of – Ionic Radii, Oxidation States, Magnetic behavior and Spectral Properties and
Sterio-chemistry.

3. Coordination Compounds:
Werner’s Coordination Theory and its Experimental Verification, Effective
Atomic Number Concept, Chelates, Nomenclature of Coordination Compounds,
Isomerism in Coordination Compounds, VBT of Transition Metal Complexes.
Biological Role of Coordination Compounds-Haemoglobin and Myoglobin.

4. Metal Ligand Bonding in Transition Metal Complexes:


Limitation of VBT and Elementary idea of CFT, Crystal Field Splitting in
Octahedral, Tetrahedral and Square Planar Complexes, Factors Affecting Crystal
Field Parameters.

5. Magnetic Properties of Transition Metal Complexes:


Types of Magnetic Behaviour, Methods of Determining magnetic Susceptibility,
Spin only Formula, L-S Coupling, Correlation of µs and µexp values, Orbital
Contribution to Magnetic Moments, Application of Magnetic Moment Data for 3d
Metal Complexes.

6. Electronic Spectra of Transition Metal Complexes:


Types of Electronic Transitions, Selection Rules for d-d transition, Spectroscopic
Ground States, Spectro-chemical Series. Orgel Energy Level Diagram for d1 to d 9
states, Discussion of Electronic Spectrum of [Ti(H2O)6]3+ Complex Ion.

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S-482 (R-13)

7. Thermodynamics and Kinetic Aspects of Metal Complexes:


A Brief Outline of Thermodynamic Stability of Metal Complexes and Factors
affecting stability, Substitution Reaction of Square Planar Complexes.

8. Chemistry of Lanthanide Elements:


Electronic Structure, Oxidation State and Ionic Radii and Lanthanide contraction.
Complex Formation, Occurrence and Isolation of Lanthanides.

9. Chemistry of Actinides:
General Features and Chemistry of Actinides, Chemistry of Separation of Np, Pu,
Am from U, Similarities between later Actinides and later Lanthanides.

10. Organometallic Chemistry:

A Brief Account of Metal-ethylene Complexes and Homogeneous Hydrogenation,


Mononuclear Carbonyls and Nature of Bonding in Metal Carbonyls.

Reference Books:
1. Gurdeep Raj, Inorganic Chemistry, Krishna Publication
2. Malik Waheed, Inorganic Chemistry, S. Chand Publication
3. Madan R.D., Modern Inorganic Chemistry, S. Chand Publication
4. Satya Prakash, Advanced Inorganic Chemistry, S. Chand Publication
5. Lee J.D., Concise Inorganic Chemistry, Blackwell Publication
6. Huheey James, Inorganic Chemistry, Addison Wesely Publication
7. Cotton & Wilkenson, Advanced Inorganic Chemistry, Wiley John Publication
8. Malik Waheed, Selected Topic in Inorganic Chemistry, S. Chand Publication.

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