MSC Syllabus All
MSC Syllabus All
MSC Syllabus All
Unit - 1 : Studies and Application of Lanthanides and Actinides: - Spectral and Magnetic properties. - Modern methods of separation of Lanthanides and Actinides. - Organometallic Compounds of lanthanides. - Application of lanthanides and actinides compounds in Industries. - Use of lanthanides compounds as Shift reagents. Unit - 2 : Nuclear Chemistry : - Radioactive decay and equilibrium. - Nuclear Reactions - Types, Q value, Cross Section of reactions. - Chemical effects of nuclear transformation. - Nuclear Fission - Fission Products, Fission Yield and Nuclear Reactors. - Nuclear Fusion and stellar energy. - Radioactive techniques: (i) Tracer techniques (neutron activation analysis), (ii) Countering Techniques such as G.M Ionization and Proportional counters. Unit - 3 : Inorganic Rings, Cages and Clusters : - Polyhedral Boranes : Higher Boranes, Carboranes, Metallo-boranes and Metallocarboranes Classification, Nomenclature, preparation, Structure and Bonding, Wades rule. - Metal carbonyl hydrides and Metal carbonyl clusters, LNCC & HNCC, Capping rule. Unit - 4 : Inorganic Polymers : - Charecterestic properties and Classification. - Types of Inorganic Polymerization (step-growth, chain-growth, ring-opening, Reductive Coupling, Condensation synthesis ) - Synthesis, properties and applications of important inorganic polymers : Polyphosphazenes , phosphonitrilic halides. Polysiloxanes (Silicones), polysilanes. Coordinate Polymers. - Condensed Phosphates, Silicates, and sulphur-nitrogen compounds. - Isopoly and Hetropoly acid and Salts : Synthesis and structural principles with refer ence to those of Mo and W. Unit - 5 : Nanoscience and Nanotechnology : - Introduction to nanotechnology, scope of applications. - Techniques for synthesis of nanoparticles. - Important nano materials (nanooptics, nanomagnetics, nanoelectronics) - Carbonnanotubes - types, properties & applications.
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Books Recommended
1. Chris J. Jones, d- and f- Block Chemistry , (2002), Wiely Interscience & RSC, 2. V.S. Sastri, J.C.G. Bunzli, V.R. Rao, G.V.S. Rayudu, J.R. Perumareddi, Modern Aspects of rare earths and their complexes, (2003) Elsevier publication. 3. H.J. Arnikar, Essentials of Nuclear Chemistry, 4th Edition (1995), Wiely-Eastern Ltd., New Delhi. 4. B. G. Harvey, Introduction to Nuclear Physics and Chemistry, (1969) Prentice Hall, Inc. 5. Attila Vertes (editor), Handbook of Nuclear Chemistry, 2nd Edition, (2011), Springer. 6. G. Fridlander, J.W. Kennedy, E. S. Macias, and J. M. Miller, Nuclear & Radiochemistry, 3rd Edition (1981), John Wiley, New York. 7. Tristram Chivers, Ian Manners, Inorganic Rings and Polymers of the p-Block Elements : From Fundamentals to Applications, (2009) Royal Society of Chemistry. 8. P. Braunstein, L. A. Oro, P. R. Raithby (editors), Metal Clusters in Chemistry, (1999), Wiley-VCH. 9. J.D. Woollins, Non-Metal Rings, Cages and Clusters, (1988), John Wiley & Sons. 10. James E. Mark, Harry R. Allcock, Robert West, Inorganic Polymers - 2nd Edition, (2005), Oxford University Press. 11. Mao-Chun Hong, Ling Chen (editors), Design and Construction of Coordination Polymers (2009), John Wiley & Sons 12. Chris Binns, Introduction to Nanoscience and Nanotechnology (2010), John Wiley & Sons, Inc. 13. C. N. R. Rao, A. Muller, A. K. Cheetham (Eds.), The Chemistry of Nanomaterials, (2004), Wiley-VCH Verlag.
M.Sc Chemistry
Inorganic Chemistry Practical Syllabus
Semester : 1
A. Qualitative Analysis of Inorganic Mixture - (21 Marks)
Identification of seven radicals including insoluble residue and rare earth metal ions by semi micro analysis. (i) Rare elements: Tl, W, Se, Mo, Ti, Zr, Ce, Th, V, U, Li (ii) Insolubles: PbSO4, SrSO4, Al2O3, Cr2O3, Fe2O3, SnO2, AgX, TiO2, ThO2, WO2.xH2O
B.
1. 2. 3. 4. 5. 6. 7.
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Books Recommended
1. Geoffrey A. Lawrance, Introduction to Coordination Chemistry, (2010), Wiley & Sons. 2. Rob Janes and Elaine Moore, Metal-Ligand Bonding (2004), RSC. 3. Yves Jean, Molecular Orbitals of Transition Metal Complexes, (2005), Oxford University Press. 4. C H Langford & H B Gray, Ligand Substitutin Processes,(1965), W.A.Benjamin Inc. 5. Robert B. Jordan, Reaction Mechanisms of Inorganic and Organometallic System, 3rd ed (2007), Oxford University Press. 6. Fred Basolo, Ralph G Pearson, Mechanisms of Inorganic Reactions, 2nd Ed (1984), Wiely Eastern Ltd.
Semester : 2
A. Quantitative Analysis : (20 Marks)
Quantitative Separation and determination of two metal ions : Cu-Ni, Ni-Zn, Cu-Zn etc using volumetric and gravimetric methods.
B. Chromatography :
(15 Marks)
1. Paper chromatographic separation of Pb, Ag and Hg ions . 2. Determination of the Rf value of Pb, Hg, Cu and Cd ions by using paper chromatographic technique. 3. Determination of the Rf value of Fe, Al, Cr ions by using paper chromatographic technique. 4. Determination of the Rf value of Ba, Sr, Ca ions by using paper chromatographic technique. 5.TLC separation and determination of the Rf values of Ni, Mn, Co and Zn ions. 6. Radial paper chromatographic seperation of Cu, Cd ions. 7. Radial paper chromatographic seperation of Ni, Cu ions.
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Books Recommended
1. Didier Astruc, Organometallic Chemistry and Catalysis, (2007), Springer. 2. Robert H Crabtree, The Organometallic Chemistry of the Transition Metals, 4th Ed (2005), Wiley Interscience. 3. Helmut Werner, Landmarks in Organo-Transition Metal Chemistry, (2009), Springer. 4. R.C. Mehrotra and A. Singh, Organometallic chemistry: A unified approach, (1991), Wiley, New York. 5. Ayodhya Singh, R. Singh, Organometallic Chemistry, (2006) Campus Books International. Page: 5
6. R.H. Crabtree, The Organometallic Chemistry of the Transition Metals, 1st Edn.(1988), John-Wiley & Sons, New York. 7. J. P. Collman, L. S. Hegedus, J. R. Norton and Richard G. Finke, Principles and Applications of Organotransition Metal Chemistry, 1st Edn.(1987), University Science Books, Mill Valley, California. 8. Ionel Haiduc, Frank Thomas Edelmann, Supramolecular organometallic chemistry, (2000), Wiley-VCH 9. Peter J. Cragg, A Practical Guide to Supramolecular Chemistry, (2005), John Wiley & Sons Ltd. 10. Katsuhiko Ariga,Toyoki Kunitake, Supramolecular Chemistry-Fundamentals & Applications (2006), Springer-Verlag. 11. Jean-Marie Lehn, Supramolecular Chemistry, (1995) VCH, Weinheim.
Semester: 3
A. Colorimetry / Spectrophotometry (25 Marks)
(a) Determination of the wavelength of maximum absoption. 1. To carry out absorbance measurements for Chromium (VI) and Manganese (VII) solutions on a spectrophotometer and draw its UV-VIS spectrum and determine the wavelength of maximum absoption (l max) of Chromium (VI) and Manganese (VII) and compute the corresponding molar absorption coefficient. (b) Verification of Beer-Lambert law and Determination of Metal Ions (in ppm) in supplied solution. 1. Verification of the Beer-Lambert law and determination the concentration of supplied KMnO4 solution. 2. To test the validity of the Beer-Lambert law and determine the concentration of supplied K2Cr2O4 solution. 3. To analyse the validity of Beers law using colorimeter and determine the concentration of supplied CuSO4.5H2O 4. Determination of the concentration of supplied NiSO4.7H2O solution as Ni-dmg complex spectrophotometrically. (c) Determination of Metal Ions (in ppm) in unknown sample. 1. Spectrophotometric Determination of Iron in Vitamin Tablets. 2. Spectrophotometric Determination of Manganese in Steel. (d) Spectrophotometric Titration. 1.Determination of the concentration of the supplied FeCl3 solution by spectrophotometric titration with EDTA. 2. Determination of Copper by EDTA Page: 6
(e) Determination of composition of binary mixture. 1. To calculate the concentrations of Chromium (VI) and Manganese (VII) in a mixture from the absorption measurements of the mixture at two different wavelengths. 2. To calculate the concentrations of Cobalt (II) and Chromium (III) in a mixture from the absorption measurements of the mixture at two different wavelengths. (f) Spectrophotometric determination of anions. 1.To determine the concentration of given unknown phosphate solution by Molybdophosphoric acid Method with the help of spectrophotometer. 2.To determine the concentration of given unknown phosphate solution by Phosphovanadomo- ybdate method with the help of spectrophotometer. (g) Determination of Dissociation Constants of an Indicator. 1. To determine the dissociation constant , pKa, of an acidbase indicator (methyl red) by spectrophotometric method. 2. To determine the dissociation constant , pKa, of an acidbase indicator (Bromothymol Blue or Phenol Red) by spectrophotometric method. (h) Determination of Composition (formula) and Stability Constant of Complexs. 1. Fe(III) thiocynate complex by Job's method. 2. Fe(III) sulpho salicylic acid (SSA) complex by Job's method. 3. Copper-ethylene diamine complex by mole fraction or Slope ratio method.
B.
1. Determination of Na concentration in the given solution flame photometrically by calibration curve method 2. Using a flame photometer, determine K in the given solution 3. Determination of calcium concentration flame photometrically 4. Determination of total Na, K & Ca concentration in a plant material 5. Determination of total sodium, potassium, calcium concentration in milk 6. Determination of total Na, K, Ca concentration in banana 7. Determination of Lithium concentration flame photometrically
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Unit -1 : Electronic Spectra of Transition Metal Complexes : - Types of electronic transition, selection rule of d-d transition. - Spectroscopic ground states, correlation. - Orgel energy level and Tanabe-Sugano diagrams for transition metal complexes. - Calculation of ligand-field parameters (Racah parameters). - Charge transfer spectra. Inter-valance charge transfer spectra. Unit - 2 : Magenetic properties of transitional metals: - Different types of magnetic behavior. - Factors affecting observed magnetic moments. - Origin of magnetic moment, spin contribution, spin only formulas, orbital contribution, spin-spin coupling. - Derivation of Van-Vleck equation. - Methods of magnetic susceptibility measurement. - Ferromagnetism, Antiferromagnetism, Mechanism of Antiferromagnetism interaction. - Spin cross over and anomalous magnetic moments. - Application of magnetic measurements for structural elucidation. Unit - 3 : Environmental Chemistry - Soil & Water (a) Lithosphere (Soils) : - Nature and Composition of Soil. - Micro and macro nutrients in soil. - Pollutants in Soil - Fertilizers, pesticides, plastics and metals. Waste Treatment. (b) Hydrosphere (Water) : - Hydrosphere (Sources of water - oceans, lakes, revers, glaciers and groundwater etc.) and Hydrological cycles. - Chemical composition of water and water quality standards. - Aquatic pollutants Inorganic - metals, contents of chloride, sulphate, phosphate and nitrate. Organic - Pesticide, agricultural, industrial & sewage detergents, oil spills & oil pollutants. Solid Waste, Micro organism. - Water quality parameters - dissolved oxygen, biochemical Oxygen demand . - Purification and treatment of water. Unit - 4 : Environmental Chemistry - Atmosphere (Air ) - Chemical composition of atmosphere- particles, ions and radicals and their formation. - Heat (energy & radiation) budget of the Earth atmosphere systems. - Vertical stability of atmosphere. - Chemical and photochemical reactions in atmosphere, smog formation. - Oxides of N,C,S,O and their effect, Green house effect, Acid rain. - Air pollution controls and their chemistry.
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Unit - 5 : Green Chemistry : - Introduction to green chemistry. - Principles of green chemistry. - Designing and chemical synthesis, examples of green synthesis/ reactions. - Future trends in green chemistry.
Books Recommended
1. Derek Sutton, Electronic spectra of transition metal complexes: An introductory text (1968), McGraw-Hill. 2. R.L.Carlin, A. J. van Duyneveldt, Magenetic properties of transitional metals Compounds (1979), Springer-Verlag. 3. Rob Janes and Elaine Moore, Magnetism and the magnetic properties of transition-metal complexes (2004), RSC. 4. G.W. Vanloon, S.J. Duffer, Environmental Chemistry - A Global Perspective, (2000) Oxford University Press. 5. F.W. Fifield and W.P.J. Hairens, Environmental Analytical Chemistry, 2nd Edition (2000), Black Well Science Ltd. 6. Colin Baird, Environmental Chemistry, (1995) W.H. Freeman and Company, New York. 7. A.K. De, Environmental Chemistry, 4th Edition (2000), New Age International Private Ltd., New Delhi. 8. Peter O. Warner, Analysis of Air Pollutants,1st Edition (1996), John Wiley, New York. 9. S.M. Khopkar, Environmental Pollution Analysis, 1st Edition (1993), Wiley Estern Ltd., New Delhi. 10. S.K. Banerji, Environmental Chemistry, 1st Edition (1993), Prentice-Hall of India, New Delhi. 11.James H. Clark, Duncan J. Macquarrie, Handbook of Green Chemistry and Technology, (2002)Wiley. 12.V. K. Ahluwalia, M. Kidwai, New Trends in Green Chemistry (2004), Springer. 13. R. L.Carlin, Magnetochemistry, Springer. 14. D.N. Sathyanarayana, Electronic Absorption Spectroscopy and Related Techniques (2001), Universities Press (India) Ltd., Hyderabad. 15. Oliver Kahn, Molecular Magnetism, (1993) VCH, Weinheim.
Semester: 4
A. Water Analysis (10 Marks)
1. 2. 3. 4. 5. 6. 7. Determination of alkalinity of the given water sample To determine temporary hardness of water by the HCl method Determination of total hardness of water by complexometric titration method Determination of temporary hardness of water by EDTA method Determination of calcium and magnesium in water by EDTA method To determine chloride content of the given water sample by Mohrs method Determination of COD of the water sample Page: 9
Determination of DO in water by iodometric method Determination of percentage of available chlorine in the supplied sample of bleaching powder To determine the residual chlorine Determination of pH & electrical conductivity Determination of dissolved carbon dioxide Determination of Inorganic P, total P & Sulphate spectrophotometrically.
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Unit-1: (a) Role of Metal ions in Biological Systems : - Functions of metal ions in biological systems. - Transport of ions through cell membrane - Na+/K+ Pump. (b) Oxygen carrier Systems: - Structure and function of Hemoglobin, Myoglobin, Hemerythrin & Hemocyanin. - Mechanism of dioxygen binding with heme proteins. - Nature of Iron-dioxygen linkage in Hemoglobin - Model system - Model Synthetic complexes of Iron and Cobalt as Oxygen carrier. Unit-2 : (a) Photosynthetic Pigments : - Complexes of Porphyrin. - Redox mechanism in Photosystems (PS-I and PS-II), Cleavage of Water in PS-II. (b) Biological Nitrogen Fixation : - Enzymetic reduction of Nitrogen to Ammonia - Nitrogenase Structure and mechanism. - Molybdenum Nitrogenase - Spectroscopic and other studies. - Model Systems for Nitrogenase. Unit-3: (a) Electron Transfer in Biology : - Structure and Function of Metallic Proteins in Electron Transport Process, Cytochrome, Iron-sulphur Proteins. (b) Metal Storage, Transport and Biomineralisation : - Metal Storage and Transport - Structure and Function of Feritin, Transfrsin and Siderophores. - Biomineralisation. Unit-4: (a) Calcium in Biology: - Role of Calcium in living systems. -Transport and regulation of Calcium - pathways and mechanism, Calcium Channels and pumps. - Calcium binding proteins - Intracellular, Mediated membrane and Extracellular . (b) Metalloenzymes: - Zinc enzymes - Carboxypeptidase and Carbonic anhydrase. - Iron enzyme - Catalase, Peroxidase and Cytochrome P-450. - Copper enzymes - Superoxides dismutase. - Molybdenum enzymes - Oxatransferase enzymes, Xanthine oxidase. - Vitamin B12 Coenzyme (Adenosyl Coenzyme).
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Unit-5: (a) Metal - Nuclic Acid Interactions : - Metal ions and Nucleic Acids Interactions (binding) - Types & suitable examples. - Metal complexes (e.g., Cisplatin) interaction with DNA. (b) Metals in Medicine: - Metal Deficiency and disease. - Toxic effects of Metals. - Metals used for diagnosis. - Metals used in Chemotherapy with particular reference to Anticancer drugs.
Books Recommended
1. S. J. Lippard and J. M. Berg, Principles of Bioinorganic Chemistry, (1994), University Science Books. 2. I. Bertini, H. B. Grey, S. J. Lippard and J. S. Valentine, Bioinorganic Chemistry, (1998) Viva Books Pvt. Ltd., New Delhi. 3. Harry B. Gray, Edward I. Stiefel, Joan Selverstone Valentine and Ivano Bertini, Biological Inorganic Chemistry: Structure and Reactivity, (2006),University Science Books. 4. Robert Crichton, Biological Inorganic Chemistry: An Introduction (2008), Elsevier Science. 5. M. N. Hughes, Inorganic Chemistry of Biological Processes, 2nd Ed.(1981), John-Wiley & Sons, New York. 6. W. Kaim and B. Schwederski, Bioinorganic Chemistry: Inorganic Elements in the Chemistry of Life, An Introduction and Guide, (1995) Wiley, New York. 7. Nicholas V. Hud, Nucleic Acid - Metal Ion Interactions, (2009), Royal Society of Chemistry. 8. Ivano Bertini, A.Sigel, H.Sigel (Editors), Handbook on Metalloproteins (2001), Marcell Dekker,Inc, 9. James C. Dabrowiak, Metals in Medicine (2009), John Wiley & Sons, Ltd. 10. Rosette M. Roat-Malone, Bioinorganic Chemistry - A Short Course, 2nd Edition, (2007), Wiley. 11. H.B. Kraatz, N. Metzler-Nolte (Eds.), Concepts and Models in Bioinorganic Chemistry (2006), Wiley-VCH. 12. D. L. Nelson and M.M. Cox, Lehninger Principles of Biochemistry, 3rd edition (2002) McMillan North Publication.
7. Catherine Housecroft, Alan G. Sharpe, Inorganic Chemistry, 3rd Edition, (2007), Prentice Hall. 8. William W. Porterfield, Inorganic Chemistry: A Unified Approach, (1983), Longman. 9. Gary Wulfsberg, Inorganic Chemistry (2000), University Science Books. 10. Gary L. Miessler, Donald A. Tarr, Inorganic Chemistry, 4th Ed. (2011), Prentice Hall, Pearson.
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