(b) x3 + 6x2 + 36x + 27 = 0

(c) x3 - 6x2 - 36x + 27 = 0

(d) x3 + 6x2 - 36x + 27 = 0

8) If A = f(t) = t2 - 3t + 7, then

is equal to

(a)

(b)

(c)

(d)

9) is equal to

(a) 0

(b) a+b+c

(c) (a + b + c)2

(d) (a + b + c)3

10) If co is a complex cube root of unity, then sin

is equal to

(a)
✁✂✄☎✆✝☎✞✂✁✞✟✆
 (b)

(c)

(d)

18) The position vectors of P and Q are respectively and , If R is a

point on such that = 5 , then the position vector of
R is

(a) 5 4

(b) 5 +4

(c) 4 -5

(d) 4 +5

19) If the position vectors of A, B and C are respectively 2 - + ,

3 - 5 and 3 4 - 4 , then cos2 A is equal to

(a) 0

(b)

(c)

(d) 1

20) Let be a unit vector, = 2 + - and = + 3 . Then,

maximum value of [ ] is

(a) -1

(b)
✁✁✁✂✄☎✆✝✞✆✟✄✂✟✠✝
 (c) 4x + 3y = 7a

(d) 4x - 3y = 0

38) The length of the sub tangent at (2, 2) to the curve x5 = 2y4 is

(a)

(b)

(c)

(d)

39) If constant, then f(x) is equal to

(a)

(b)

(c)

(d)

40) If

= f(x) + constant, then f(x) is equal to

(a) cos (xex)

(b) sin (xex)

(c) 2 tan-1 (x)

(d) tan (x ex)

✁✂✄☎✆✝☎✞✂✁✞✟✆
 (b) y cos x = ex + c

(c) y = ex sin x + c

(d) y sin x = ex + c

45) The solution of the differential equation

xy2 dy - (x3 + y3) dx = 0 is

(a) y3 = 3x3 + c

(b) y3 = 3x3 log (cx)

(c) y3 = 3x3 + log (cx)

(d) y3 + 3x3 = log (cx)

Physics
✁✂✄☎✆✝☎✞✂✁✞✟✆
46) The energy (E), angular momentum (L) and universal
gravitational constant (G) are chosen as fundamental quantities.
The dimensions of universal gravitational constant in the
dimensional formula of Planck's constant (h) is

(a) Zero

(b) -1

(c)

(d) 1

47) The component of vector = ax + ay + az along the

direction of is

(a) ax - ay + az

(b) ax - ay

(c) (ax - ay)/

(d) (ax + ay + az)

48) A body thrown vertically up to reach its maximum height in t

second. The total time from the time of projection to reach a
point at half of its maximum height while returning (in second) is

(a)

(b)

(c)

(d)

49) If a body is projected with an angle e to the horizontal, then ✁✂✄☎✆✝☎✞✂✁✞✟✆

 (a) its velocity is always perpendicular to its acceleration

(b) its velocity becomes zero at its maximum height

(c) its velocity makes zero angle with the horizontal at its
maximum height

(d) the body just before hitting the ground, the direction of
velocity coincides with the acceleration

50) A river of salty water is flowing with a velocity 2 m/s, If the

density of the water is 1.2 g/cc, then the kinetic energy of each
cubic metre of water is

(a) 2.4 J

(b) 24 J

(c) 2.4 kJ

(d) 4.8 kJ

51) A ball is dropped from a height h on a floor of coefficient of

restitution e. The total distance covered by the ball just before
second hit is

(a) h(1 - 2e2)

(b) h(1 + 2e2)

(c) h(1 + e2)

(d) he2

52) Two particles A and B initially at rest, move towards each other,
under mutual force of attraction. At an instance when the speed
of A is v and speed of B is 2v, the speed of centre of mass (CM)
is
✁✂✄☎✆✝☎✞✂✁✞✟✆
 (a) Zero

(b) v

(c) 2.5v

(d) 4v

53) Starting from rest, the time taken by a body sliding down on a
rough inclined plane at 45° with the horizontal is, twice the time
taken to travel on a smooth plane of same inclination and same
distance. Then the coefficient of kinetic friction is

(a) 0.25

(b) 0.33

(c) 0.50

(d) 0.75

54) A steel wire can withstand a load up to 2940 N. A load of 150 kg

is suspended from a rigid support. The maximum angle through
which the wire can be displaced from the mean position, so that
the wire does not break when the load passes through the
position of equilibrium, is

(a) 30°

(b) 60°

(c) 80°

(d) 85°

55) The moment of inertia of a thin circular disc about an axis

passing through its centre and perpendicular to its plane is 1.
Then, the moment of inertia of the disc about an axis parallel to
its diameter and touching the edge of the rim is
✁✂✄☎✆✝☎✞✂✁✞✟✆
 (a) I

(b) 2I

(c) I

(d) I

56) The orbit of geo-stationary satellite is circular, the time period of

satellite depends on

(i) mass of the satellite

(ii) mass of the earth

(iii) radius of the orbit

(iv) height of the satellite from the surface of earth

Which of the following is correct?

(a) (i) only

(b) (i) and (ii)

(c) (i), (ii) and (iii)

(d) (ii), (iii) and (iv)

57) A particle is executing simple harmonic motion with an amplitude

A and time period T. The displacement of the particles after 2 T
period from its initial position is

(a) A

(b) 4A

(c) 8A

(d) Zero
✁✁✁✂✄☎✆✝✞✆✟✄✂✟✠✝
58) A load of 1 kg weight is a attached to one end of a steel wire of
area of cross-section 3 mm2 and Young's modulus 1011 N/m2.
The other end is suspended vertically from a hook on a wall,
then the load is pulled horizontally and released. When the load
passes through its lowest position the fractional change in length
is (g = 10 m/s2)

(a) 0.3 × 10-4

(b) 0.3 × 10-3

(c) 0.3 × 103

(d) 0.3 × 104

59) The surface tension of soap solution is 0.03 N/m. The work done
in blowing to form a soap bubble of surface area 40 cm2, (in J),
is

(a) 1.2 × 10-4

(b) 2.4 × 10-4

(c) 12 × 10-4

(d) 24 × 10-4

60) Two rain drops reach the earth with different terminal velocities
having ratio 9: 4. Then the ratio of their volumes is

(a) 3:2

(b) 4:9

(c) 9:4

(d) 27 : 8

61) ✁✂✄☎✆✝☎✞✂✁✞✟✆
One litre of oxygen at a pressure of 1 atm and two litres of
 nitrogen at a pressure of 0.5 atm, are introduced into a vessel of
volume 1 L. If there is no change in temperature, the final
pressure of the mixture of gas (in atm) is

(a) 1.5

(b) 2.5

(c) 2

(d) 4

62) There is some change W length when a 33000 N tensile force is

applied on a steel rod of area of cross-section 10-3 m2. The
change of temperature required to produce the same elongation,
if the steel rod is heated, is (The modulus of elasticity is 3 ×
1011N/m2 and the coefficient of linear expansion of steel is 1.1 ×
10-5/oC).

(a) 20°C

(b) 15°C

(c) 10°C

(d) 0°C

63) In the adiabatic compression, the decrease in volume is

associated with

(a) increase in temperature and decrease in pressure

(b) decrease in temperature and increase in pressure

(c) decrease in temperature and decrease in pressure

(d) increase in temperature and increase in pressure

64) ✁✂✄☎✆✝☎✞✂✁✞✟✆
Which of the following is true in the case of an adiabatic process,
67) A car is moving with a speed of 72 km/h towards a hill. Car
blows horn at a distance of 1800 m from the hill. If echo is heard
after 10 s, the speed of sound (in m/s) is

(a) 300

(b) 320

(c) 340

(d) 360

68) The refractive index of a material of a planoconcave lens is 5/3,

the radius of curvature is 0.3 m. The focal length of the lens in
air is

(a) - 0.45 m

(b) - 0.6 m

(c) - 0.75 m

(d) -1.0 m

69) Statement (S): Using Huygen's eye-piece measurements can

be taken but are not correct.

Reason (R): The cross wires, scale .and final image are not
magnified proportionately because the image of the object is
magnified by two lenses, whereas the cross wire scale is
magnified by one lens only.

Identify the correct one of the following

(a) Both (S) and (R) are true, (R) explains (S).

(b) Both (S) and (R) are true, but (R) canner explain (S).

(c) Only (S) is correct, but (R) is wrong.

(d) Both-(S) and (R) are wrong. ✁✂✄☎✆✝☎✞✂✁✞✟✆

70) An achromatic combination of lenses produces

(a) images in black and white

(b) coloured images ,

(c) images unaffected by variation of refractive index with

wavelength

(d) highly enlarged images are formed

71) In Fraunhofer diffraction experiment, L is the distance between

screen and the obstacle, b is the size of obstacle and A. is
wavelength of incident light. The general condition for the
applicability of Fraunhofer diffraction is

(a)

(b)

(c)

(d)

72) With a standard rectangular bar magnet 'the time period of a

vibration magnetometer is 4 s. The bar magnet is cut parallel to
its length into four equal pieces. The time period of vibration
magnetometer when one piece is used (in second) (bar magnet
breadth is, small) is

(a) 16

(b) 8

(c) 4

(d) 2
✁✁✁✂✄☎✆✝✞✆✟✄✂✟✠✝
 (a) 19 G

(b)

(c) 20 G

(d)

79) In a galvanometer 5% of the total current in the circuit passes

through it. If the resistance of the galvanometer is G, the shunt
resistance 5 connected to the galvanometer is

(a) 19 G

(b)

(c) 20 G

(d)

80) Two concentric coils of 10 turns each are placed in the same
plane. Their radii are 20 cm and 40 cm and carry 0.2 A and 0.3
A. current respectively in opposite directions. The magnetic
induction (in tesla) at the centre is

(a)

(b)

(c)

(d)

81) The number of turns in primary- and secondary coils of a

transformer is 50 and 200 respectively. If the current in the
primary coil is 4 A, then the current in the secondary coil is
✁✂✄☎✆✝☎✞✂✁✞✟✆
88) If the mass defect of 5B11 is 0.081 u, its average binding energy
(in MeV) is

(a) 8.60

(b) 6.85

(c) 5.60

(d) 5.86

89) The atomic numbers of elements A, B, C and D are Z - 1, Z, Z +

1 and Z + 2, respectively. If B' is a noble gas, choose the
correct answers from the following statements

(1) A' has higher electron affinity

(2) 'C" exists in +2 oxidation state

(3) 'D' is an alkaline earth metal

(a) (1) and (2)

(b) (2) and (3)

(c) (1) and (3)

(d) (1), (2) and (3)

90) The bond length of HCI molecule is 1.275 Å and its dipole
moment is 1.03 D. The ionic character of the molecule (in
percent) (charge of the electron = 4.8 × 10-10 esu) is

(a) 100

(b) 67.3

(c) 33.66
✁✁✁✂✄☎✆✝✞✆✟✄✂✟✠✝
(d) 16.83
91) Which one of the following is a correct set?

(a) H2O, Sp3, angular

(b) BCl3, Sp3, angular

(c) NH+4, dsp2, square planar

(d) CH4, dsp2, tetrahedral

92) Match the following:

The correct match is

A B C D

(a) iv i ii iii
✁✂✄☎✆✝☎✞✂✁✞✟✆
(b) v i ii iii
 (c) iv i iii ii

(d) i iv ii iii

93) What is the temperature at which the kinetic energy of 0.3 moles
of helium is equal to the kinetic energy of 0.4 moles of argon -at
400 K?

(a) 400 K

(b) 873 K

(c) 533 K

(d) 300 K

94) When 25 g of a non-volatile solute is dissolved in 100.g of water,

the vapour pressure is lowered by 2.25 × 10-1 mm. If the vapour
pressure of water at 20°C is 17.5 mm, what is the molecular
weight of the solute?

(a) 206

(b) 302

(c) 350

(d) 276

95) 50 mL of H2O is added to 50 mL of 1 × 10-3 M barium hydroxide

solution. What is the pH of the resulting solution?

(a) 3.0

(b) 3.3

(c) 11.0

(d) 11.7 ✁✂✄☎✆✝☎✞✂✁✞✟✆

96) Assertion (A): The aqueous solution of CH3COONa is alkaline in
nature.

Reason (R): Acetate ion undergoes anionic hydrolysis

The correct answer is

(a) both (A) and (R) are true and (R) is the correct
explanation of (A).

(b) both (A) and (R) are true but (R) is not the correct
explanation of (A).

(c) (A) is true but (R) is not true.

(d) (A) is not true but (R) is true.

97) When same quantity of electricity is passed through aqueous

AgNO3 and H2SO4 solutions connected in series, 5.04 × 10-2 g of
H2 is liberated. What is the mass of silver (in grams) deposited?
(Eq. wts. of hydrogen = 1. 008, silver = 108)

(a) 54

(b) 0.54

(c) 5.4

(d) 10.8

98) When electric current is passed through acidified water for 1930
s, 1120 mL of H2 gas is collected (at STP) at the cathode. What
is the current passed in amperes?

(a) 0.05

(b) 0.50

(c) 5.0 ✁✂✄☎✆✝☎✞✂✁✞✟✆

 (b) +393

(c) +655

(d) -655

103) Which one of the following graphs represents "Freundlich

adsorption isotherm?

✁✂✄☎✆✝☎✞✂✁✞✟✆
 (b) (i) and (ii) only

(c) (ii), (iii) and (iv) only

(d) (iii) and (iv) only

106) Boron halides behave as Lewis acids because of their

nature.

(a) proton donor

(b) covalent

(c) electron deficient

(d) ionising

107) Identify B in the following reaction

(a) corundum

(b) quartz

(c) silica

(d) carborundum

108) The correct order of reducing abilities of hydrides of V group

elements is

(a) NH3 < PH3 < AsH3 < SbH3 < BiH3

(b) NH3 > PH3 > AsH3 > SbH3 > BiH3

(c) NH3 < PH3 > AsH3 > SbH3 > BiH3
✁✂✄☎✆✝☎✞✂✁✞✟✆
(d) SbH3 > BiH3 > AsH3 > NH3 > PH3
 (c) coordination

(d) hydrate

113) Among the following compounds, which one is not responsible

for depletion of ozone layer?

(a) CH4

(b) CFCl3

(c) NO

(d) Cl2

114) Which of the following correspond (s) has 'Z' configuration?

(a) (i) only

(b) (ii) only

(c) (iii) only

(d) (i) and (iii)

✁✂✄☎✆✝☎✞✂✁✞✟✆
118) The correct order of reactivity of hydrogen halides with ethyl
alcohol is

(a) HF > HCI > HBr > HI

(b) HCl > HBr > HF > HI

(c) HBr > HCl > HI > HF

(d) HI > HBr > HCl > HF

119) The IUPAC name of

(a) ethoxy propane'

(b) 1, 1-dimethyl ether

(c) 2-ethoxy isopropane

(d) 2-ethoxy propane

120) Acetone on addition to methyl magnesium bromide forms a

complex, which on decomposition with acid gives X and
Mg(OH)Br. Which one of the following is X?

(a) CH3OH

(b) (CH3)3COH

(c) (CH3)2 CHOH

(d) CH3CH2OH
✁✂✄☎✆✝☎✞✂✁✞✟✆
 (D) Chlorophyll (iv) Oil of winter green

(v) Fe2+ paramagnetic

The correct match is

A B C D

(a) (v) (i) (ii) (iii)

(b) (iv) (ii) (i) (iii)

(c) (iii) (i) (ii) (iv)

(d) (v) (ii) (iii) (i)

124) If is the weight average molecular weight and is the

number average molecular weight of a polymer, the poly
dispersity index (PDI) of the polymer is given by

(a)

(b)

(c)

(d)

125) Hydrolysis of sucrose with dilute aqueous sulphuric acid yields

(a) 1: 1 D - (+)- glucose; D-(-)-fructose

(b) 1: 2 D - ( + )-glucose; D-(-)-fructose

(c) 1: 1 D-H-glucose; p- (+) -fructose

(d) 1: 2 D-(-)-glucose; D- (+) -fructose

✁✂✄☎✆✝☎✞✂✁✞✟✆
 English & Reasoning

Directions: In each of the following questions, choose the most

appropriate alternative to fill in the blank.

126) The teacher ordered Kamal to leave the room him to

return.

(a) stopped

(b) refused

(c) forbade

(d) callenged

127) I hope you must have ✁.... by now that failures are the
stepping stones to success

(a) know

(b) felt

(c) decided

(d) realised

128) In a little published deal, Pepsi Cola has the entire soft drink
market in Afghanistan.

(a) conquered

(b) swallowed
✂✂✂✄☎✆✝✞✟✝✠☎✄✠✡✞
(c) captured
 (d) occupied

Directions: In each of the following questions, put the parts P,

Q, R and S in their proper order to produce the correct sentence.

129) The Bible,

(P) has in many respects

(Q) the sacred book of all Christians

(R) among all the books of the world

(S) a unique character and position

(a) QPSR

(b) QRPS

(c) RPQS

(d) RQPS

130) The ultimate hope

(P) will force the nations

(Q) that the destructive nature of weapons

(R) to give up war

(S) has not been fulfilled

(a) PQRS

(b) PRQS

(c) QPRS

(d) RSQP

✁✂✄☎✆✝☎✞✂✁✞✟✆
131) It was

(P) in keeping with my mood

(Q) a soft summer evening,

(R) as I walked sedately

(S) in the direction of the new house

(a) QPRS

(b) QRPS

(c) SQPR

(d) SRPQ

Directions: In each of the following questions, choose the

alternative which is most nearly the some in meaning to the
"word given in capitol letters.

132) EPHEMERAL

(a) Uneral

(b) Mythical

(c) Short-living

(d) Artificial

133) STUBBORN

(a) Easy

(b) Obstinate

(c) Willing
✁✂✄☎✆✝☎✞✂✁✞✟✆
(d) Pliable
134) PROGNOSIS

(a) Indentification

(b) Preface

(c) Forecast

(d) Scheme

Directions: In each of the following questions, choose the

alternative which is opposite in meaning to the word given in
capitol letters.

135) INFALLIBLE

(a) Erring

(b) Untrustworthy

(c) Dubious

(d) Unreliable

136) GATHER

(a) Separate

(b) Suspend

(c) Scatter

(d) Spend

137) EXALT
✁✂✄☎✆✝☎✞✂✁✞✟✆
(a) Depreciate
 (b) Ennoble

(c) Glorify

(d) Simplify

Directions: In each of the following questions, choose the

alternative which can be substituted for the' given
words/sentence.

138) Elderly woman in charge of a girl on social occasions

(a) Spinster

(b) Matron

(c) Chaperon

(d) Chandler

139) Land so surrounded by water as to be almost an island

(a) Archipelago

(b) Isthmus

(c) Peninusula

(d) Lagoon

140) A Place adjoining kitchen, for washing dishes etc.

(a) Cellar

(b) Wardrobe

(c) Scullery
✁✂✄☎✆✝☎✞✂✁✞✟✆
(d) Pantry
 Direction: In each of these questions, two figure/words are
given to the left of the sign:: and one figures word to the right of
the sign:: with four alternatives under it out of which one of the
alternatives has the same relationship with the figures/words to
the right of the sign:: as between the two figures/words to the
left of the sign (::). Find the correct alternative.

141)

142) Direction: In the question, three words are given. They are
followed by four words one of which stands for the class to which
these three words belong. Identify that word.

Newspaper, Hoarding. Television

(a) Press

(b) Media

(c) Broadcast

(d) Rumour
✁✂✄☎✆✝☎✞✂✁✞✟✆
143) Direction: Find out the number which will come next in the
series.

2, 5, 14, 122, 365

(a) 1029

(b) 1094

(c) 1059

(d) 1000

144) Direction: In the given question, some statements are followed

by one or more inferences. The inference or inferences may be
wrongly or correctly drawn. Select one of the alternatives which
contains the correctly drawn inference or inferences.

Which of the conclusions drawn from the given statements are

correct?

Given statements

Foreigners in Jordon without a valid work permit will be

deported. A few Indian emplyees in the building industry in
jordon do not possess valid work permits.

Inferences

(1) All Indians engaged in building industry in Jordon will be

deported to India.

(2) A few Indians in building industry in Jordon will be

deported.

(3) A bulk of Indians in Jordon will be deported to India.

(4) Indian employees in building industry without work permit

will be deported from Jordon.

The inferences correctly drawn are

(a) 1 and 3
✁✂✄☎✆✝☎✞✂✁✞✟✆
 (b) -3 and 4

(c) -2 and 4

(d) 1 and 2

145) Select the series which obeys the given rule:

Any figure can be traced by a single unbroken line without

retracing

✁✂✄☎✆✝☎✞✂✁✞✟✆
146) Select from amongst the four alternative figures, the one which
complete the pattern in the problem figure.
147) Direction: In the following question a piece of paper is folded,
cut and unfolded. One of the four figures given below is exactly
like this unfolded paper. Find this out.

✁✂✄☎✆✝☎✞✂✁✞✟✆
148) Direction: In the question a figure is given, its components are
 given in one of the four alternative figures. Find this one

149) Direction: In the given question, Jour numbers/number-pairs

are given. Select the one which is different from the other three.

(a) 1234

(b) 2345

(c) 4567

(d) 7896

Direction: Find the group of letters from the four alternative

which is obtained by applying the same rule to this given word to
the right of the sign ::

150) FILM: ADGH:: MILK: ?

(a) ADGF

(b) HDGE

(c) HDGF
✁✂✄☎✆✝☎✞✂✁✞✟✆
(d) HEGF
 ANSWERS

MATHEMATICS

1. (c) 2. (c) 3. (c) 4. (b) 5. (c). 6. (d)

7. (d) 8. (b) 9. (d) 10. (a) 11. (c) 12. (b)

13. (b) 14. (b) 15. (b) 16. (d) 17. (a) 18. (a)

19. (c) 20. (d) 21. (b). 22. (b) 23. (a) 24. (b) ✁✂✄☎✆✝☎✞✂✁✞✟✆
25. (b) 26. (a) 27. (c) 28. (c) 29. (c) 30. (d)

31. (c) 32. (b) 33. (c) 34. (b) 35. (c) 36. (b)

37. (c) 38. (b) 39. (c) 40. (d) 41. (c) 42. (b)

43. (d) 44. (b) 45. (b)

PHYSICS

46. (a) 47. (c) 48. (b) 49. (c) 50. (c) 51. (b)

52. (a) 53. (d) 54. (b) 55. (d) 56. (d) 57. (d)

58. (a) 59. (b) 60. (d) 61. (c) 62. (c) 63. (d)

64. (a) 65. (a) 66. (c) 67. (c) 68. (a) 69. (a)

70. (c) 71. (c) 72. (c) 73. (a) 74. (b) 75. (b)

76. (c) 77. (b) 78. (a) 79. (b) 80. (b) 81. (a)

82. (b) 83. (a) 84. (c) 85. (d)

CHEMISTRY

86. (b) 87. (a) 88. (b) 89. (c) 90. (d) 91. (a)

92. (a) 93. (c) 94. (c) 95. (c) 96. (a) 97. (c)

98. (c) 99. (a) 100. (b) 101. (c) 102. (a) 103. (c)

104. (d) 105. (b) 106. (c) 107. (d) 108. (a) 109. (b)

110. (b) 111. (b) 112. (a) 113. (a) 114. (d) 115. (d)

116. (a) 117. (d) 118. (d) 119. (d) 120. (b) 121. (c)

122. (c) 123. (a) 124. (b) 125. (a) ✁✂✄☎✆✝☎✞✂✁✞✟✆

ENGLISH & REASONING

126. (c) 127. (d) 128. (c) 129. (a) 130. (c) 131. (a)

132. (c) 133. (b) 134. (c) 135. (a) 136. (c) 137. (a)

138. (c) 139. (c) 140. (c) 141. (a) 142. (b) 143. (b)

144. (c) 145. (b) 146. (b) 147. (a) 148. (c) 149. (d)

150. (c)

✁✂✄☎✆✝☎✞✂✁✞✟✆
 Hints and Solutions

Mathematics

1) Given that, f (x) = |x| and g(x) = [x 3]

For

Now, for 0 < f(x) < 1,

g(f(x)) = [f(x) 3]

= 3

Again, for 1 < f(x) < 1.6

g(f(x)) = 2

hence, required set is { 3, 2}.

2) Now,

= n(n + 1)

3) Required number of arrangements

= 6P5 × 4!
✁✁✁✂✄☎✆✝✞✆✟✄✂✟✠✝
 Physics

46. h GxLyEz

[M1L2T 1][M 1L3T 2]x[M1L2T 1]y[M1L2T 2]z

[M1L2T 1][M 1L3T 2]x[M1L2T 1]y[M1L2T 2]z

Comparing the power, we get

1=✁x+y+z ✂ ✄☎✆

2 = 3x + 2y + 2z ✂ ✄☎☎✆

✁1 = ✁2x ✁ y ✁ 2z ✂ (iii)

On solving Eq. (i), (ii) and (iii), we get

x=0

47. Let

48. The ball is thrown vertically upwards then according to equation

of motion

(0)2 ✁ u2 = ✁2gh ✂ ✄☎✆

✝✝✝✞✟✠✡☛☞✡✌✟✞✌✍☛
 = 4.48 L CO2

56 g carbon monoxide on combustion gives = 2 × 22.4 L CO2

0.56 g carbon monoxide on combustion will give

= L CO2

= 0.448 L CO2

Hence, A (iv), B (i), C (ii), D (iii)

93. Number of moles of helium = 0.3

Number of moles of argon = 0.4

We know that KE = nRT

KE of helium = 0.3 × R × T ✁ ✂✄☎

KE of argon = 0.4 × R × 400 ✁ ✂✄✄☎
According to question

KE of helium = KE of argon

0.3 × R × T = 0.4 × R × 400

T = 533 K

94. Given,

Weight of non-volatile solute,

w = 25 g

Weight of solvent, W = 100 g ✆✆✆✝✞✟✠✡☛✠☞✞✝☞✌✡

 po ps = 0.225 mm

Vapour pressure of pure solvent,

po = 17.5 mm

Molecular weight of solvent (H2O), M = 18 g

Molecular weight of solute, m = ?

✁✂✂✄☎✆✝✞✟ ✠✄ ✡☛✄☞✌✠✍✎ ✌☛✏

m=

= 350 g

95. In water, barium hydroxide is hydrolysed as follows,

Ba(OH)2 Ba2+ + 2OH✑

conc. of Ba2+ = 1 × 10✑3 M

conc. Of [OH✑] = 2 × 1 × 10✑3 M

= 2 × 10✑3 M

pOH = log [OH✑]

= log (2 × 10✑ 3)

= 2.69

pH + pOH = 14

pH = 14 pOH ✒✒✒✓✔✕✖✗✘✖✙✔✓✙✚✗
104) The reaction in which H2O2 is reduced while the other reactant is
oxidised, represents the oxidising property of H2O2.

105) (i) The alkali metal superoxides contain O-2 ion, which has an
unpaired electron, hence they are paramagnetic in nature.

(ii) The basic character of alkali metal hydroxides increases on

moving down the group.

(iii) The conductivity of alkali metal chlorides in their aqueous

solution increases on moving down the group because in
aqueous solution alkali metal chlorides ionise to give alkali
metal ions. On moving down the group the size of alkali
metal ion increases, thus degree of hydration decreases,
due to this reason their conductivity in aqueous solution
increases on moving down the group.
✁✂✄☎✆✝☎✞✂✁✞✟✆
 Thus, basic nature of carbonates in aqueous solution is due
to anionic hydrolysis.

106) According to Lewis, the compound which can accept a lone pair
of electron, are called acids.

Boron halides, being electron deficient compounds, can accept a

lone pair of electrons, so termed as Lewis acid.

107) Orthosilicic acid (H4SiO4), on heating at high temperature, loses

two water molecules and gives silica (SiO2) which on reduction
with carbon gives carborundum (SiC) and CO.

108) The reducing character of the hydrides of group V elements

depends upon the stability of hydrides. With progressive
decrease in stability, the reducing character of hydrides
increases as we move down the group. Thus, ammonia, being
stable, has least reducing ability. The order of reducing abilities
of V group hydrides is

NH3 < PH3 < AsH3 < SbH3 < BiH3

109) The structure of peroxodisulphuric acid (H2S2O8R) is

✁✂✄☎✆✝☎✞✂✁✞✟✆
116)

Hence, reagent X and Yare respectively

Na, NH3 and Pd/BaSO4 + H2.

117) In a reaction, the reagent, which is reduced or remove hydrogen

from the other reactant

✁✂✄☎✆✝☎✞✂✁✞✟✆
 Hence, in all of the above reactions, chlorine acts as an oxidising
agent.

118) Among hydrogen halides, as the size of halide ion increases, its
reactivity towards ethyl alcohol also increases. Thus, the order of
reactivity of hydrogen halides is

HI> HBr > HCI> HF

119)

✁✂✄☎✆✝☎✞✂✁✞✟✆
 alkoxy alkane. Oxy is attached with the lower group. Hence, the
IUPAC name of above compound is 2-ethoxy propane.

120)

121) Acetic acid on reduction with lithium aluminiumhydride (LiAlH4✁✂✄☎✆✝☎✞✂✁✞✟✆

)
gives ethyl alcohol while on reduction with HI and red P gives
 Hence, reagent A and B are respectively LiAlH4 and Hi/red P.

122) Nitrobenzene on reduction with lithium aluminium hydride

(LiAlH4) gives azobenzene.

123) Aspirin is used as analgesics as well as antipyretics, ie, it serve a

dual purpose.

Chlorophyll is used in photosynthesis. Oxyhaemoglobin contains

Fe2+ ion, so it is paramagnetic and haemoglobin works as
oxygen carrier.
✁✂✄☎✆✝☎✞✂✁✞✟✆
Hence, A-(v), B-(i), C-(ii), D-(iii).
124) The ratio of weight average molecular weight and the number
average molecular weight is called poly dispersity index (PDI).

where,

= weight average molecular weight

= number average molecular weight

PDI is unity for natural monodispersed polymer but for synthetic

polymers it is always greater than unity.

125) On hydrolysis with dilute aqueous sulphuric acid, sucrose gives a

equimolar mixture of D-(+) glucose and D-(-)-fructose.

Sucrose is dextrorotatory but after hydrolysis gives

dextrorotatory glucose and laevorotatory fructose, laevorotatory
fructose is more, so the mixture is laevorotatory.

✁✂✄☎✆✝☎✞✂✁✞✟✆