Intermolecular Forces Worksheet With Key
Intermolecular Forces Worksheet With Key
Intermolecular Forces Worksheet With Key
Baxley
a. H2S
b. CCl4
c. SO2
d. BrF
d. PCl5
2. List all types of IMFs that would occur in each of the following (you should have a good
enough understanding of electronegativities to answer all of these, except maybe SO2,
without look up the electronegativity numbers).
a. CH3CF3
b. CCl4
c. SO2
d. BrF
e. (CH3)3N
f. PCl5
3. H2S, O2 and CH3OH all have comparable molecular masses. List the dominant type of IMF
for the pure substances, then rank the strength of each compound based on IMFs within the
samples.
(1 = strongest, 2 = in between, 3 = weakest).
4. Circle all of the species below that can form a hydrogen bond in its pure form. Explain why
the other species couldn't hydrogen bond.
C2H6 CH3NH2 KCl CH3CH2CH2OH CH3OCH3
5. Rank the following compounds from weakest intermolecular forces to strongest. Justify your
answers.
H2S I2 N2 H2O
6. Rank the following from weakest intermolecular forces to strongest. Justify your answers.
H2Se H2S H2Po H2Te
Chem128 Dr. Baxley
a. H2S bent
b. CCl4 tetrahedral
d. BrF no shape
2. List all types of IMFs that would occur in each of the following (you should have a good
enough understanding of electronegativities to answer all of these, except maybe SO2,
without look up the electronegativity numbers).
b. CCl4 dispersion
f. PCl5 dispersion
3. H2S, O2 and CH3OH all have comparable molecular masses. List the dominant type of IMF
for the pure substances, then rank the strength of each compound based on IMFs within the
samples.
(1 = strongest, 2 = in between, 3 = weakest).
4. Circle all of the species below that can form a hydrogen bond in its pure form. Explain why
the other species couldn't hydrogen bond.
C2H6 CH3NH2 KCl CH3CH2CH2OH CH3OCH3
C2H6 does not have O, N or F
KCl is ionic and does not have any hydrogens
In CH3OCH3 the H’s are not directly bonded to the O
5. Rank the following compounds from weakest intermolecular forces to strongest. Justify your
answers.
H2S I2 N2 H2O
N2 < I2 < H2S < H2O
N2 and I2 are nonpolar, so they only have dispersion forces; I2 has stronger forces because it
is larger
H2S has dipole-dipole, so it is stronger than I2
H2O has hydrogen bonding, so it is stronger than H2S
6. Rank the following from weakest intermolecular forces to strongest. Justify your answers.
H2Se H2S H2Po H2Te
This prediction agrees with experimental data. See figure 12.14 comparing boiling points of
these compounds.