Page 1/7

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 21.05.2015 Version number 1 Revision: 21.05.2015

* SECTION 1: Identification of the substance/mixture and of the company/undertaking

- 1.1 Product identifier
- Trade name: KEMPEROL CP
- 1.2 Relevant identified uses of the
substance or mixture and uses advised
against No further relevant information available.
- Application of the substance / the mixture Catalyst
- 1.3 Details of the supplier of the safety data sheet
- Manufacturer/Supplier: KEMPER SYSTEM GmbH & Co. KG
Holländische Strasse 32-36
34246 Vellmar
Deutschland / Germany
Telefon: +49 (0)561 / 8295-0
Telefax: +49 (0)561 / 8295-5110
E-Mail: MSDS@KEMPER-SYSTEM.COM
- Further information obtainable from: Forschung und Entwicklung
Research and Development
- 1.4 Emergency telephone number: Giftinformationszentrum der Länder Rheinland-Pfalz und Hessen
Langenbeckstraße 1; Gebäude 601; 55131 Mainz
Tel. Nr.: +49 (0)6131 / 19 24 0
Universitätsmedizin der Johannes Gutenberg-Universität Mainz

SECTION 2: Hazards identification

- 2.1 Classification of the substance or mixture
- Classification according to Regulation (EC) No 1272/2008

GHS02 flame

Org. Perox. CD H242 Heating may cause a fire.

GHS08 health hazard

Repr. 2 H361 Suspected of damaging fertility or the unborn child.

GHS09 environment

Aquatic Acute 1 H400 Very toxic to aquatic life.

GHS07

Eye Irrit. 2 H319 Causes serious eye irritation.

Skin Sens. 1 H317 May cause an allergic skin reaction.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
- Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xn; Harmful

R62: Possible risk of impaired fertility.

Xi; Irritant

R36: Irritating to eyes.

Xi; Sensitising

R43: May cause sensitisation by skin contact.

O; Oxidising

R7: May cause fire.

N; Dangerous for the environment

R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
- Information concerning particular hazards
for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline
for preparations of the EU" in the latest valid version.
(Contd. on page 2)
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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 21.05.2015 Version number 1 Revision: 21.05.2015

Trade name: KEMPEROL CP

(Contd. of page 1)
- Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and
literature data.
- 2.2 Label elements
- Labelling according to Regulation (EC) No
1272/2008 The product is classified and labelled according to the CLP regulation.
- Hazard pictograms

GHS02 GHS07 GHS08 GHS09

- Signal word Danger
- Hazard-determining components of
labelling: dicyclohexyl phthalate
dibenzoyl peroxide
- Hazard statements H242 Heating may cause a fire.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H361 Suspected of damaging fertility or the unborn child.
H400 Very toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.
- Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking.
P220 Keep away from oxidising and acidic substances, as well as heavy metal compounds.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
P410 Protect from sunlight.
P411+P235 Store at temperatures not exceeding 30°C. Keep cool.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
- 2.3 Other hazards
- Results of PBT and vPvB assessment
- PBT: Not applicable.
- vPvB: Not applicable.

SECTION 3: Composition/information on ingredients

- 3.2 Chemical characterisation: Mixtures
- Description: Mixture of substances listed below with nonhazardous additions.
- Dangerous components:
CAS: 94-36-0 dibenzoyl peroxide 25-50%
EINECS: 202-327-6 Xi R36; Xi R43; E R3; O R7; N R50
Org. Perox. B, H241; Aquatic Acute 1, H400; Eye Irrit. 2, H319; Skin Sens. 1, H317
CAS: 84-61-7 dicyclohexyl phthalate 25-50%
EINECS: 201-545-9 Xn R62; Xi R43
R53
Repr. 2, H361; Skin Sens. 1, H317; Aquatic Chronic 3, H412
- Additional information: For the wording of the listed risk phrases refer to section 16.

SECTION 4: First aid measures

- 4.1 Description of first aid measures
- After inhalation: Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
- After skin contact: Immediately wash with water and soap and rinse thoroughly.
- After eye contact: Rinse opened eye for several minutes under running water.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
- After swallowing: If symptoms persist consult doctor.
- 4.2 Most important symptoms and effects,
both acute and delayed No further relevant information available.
- 4.3 Indication of any immediate medical
attention and special treatment needed No further relevant information available.

SECTION 5: Firefighting measures

- 5.1 Extinguishing media
- Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
Use fire extinguishing methods suitable to surrounding conditions.
(Contd. on page 3)
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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 21.05.2015 Version number 1 Revision: 21.05.2015

Trade name: KEMPEROL CP

(Contd. of page 2)
Alcohol resistant foam
ABC powder
- 5.2 Special hazards arising from the
substance or mixture No further relevant information available.
- 5.3 Advice for firefighters
- Protective equipment: Do not inhale explosion gases or combustion gases.

* SECTION 6: Accidental release measures

- 6.1 Personal precautions, protective
equipment and emergency procedures Keep away from ignition sources.
- 6.2 Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
- 6.3 Methods and material for containment
and cleaning up: Dispose contaminated material as waste according to item 13.
Do not flush with water or aqueous cleansing agents
- 6.4 Reference to other sections See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage

- 7.1 Precautions for safe handling Store in cool, dry place in tightly closed receptacles.
Use only in well ventilated areas.
- Information about fire - and explosion
protection: No special measures required.
- 7.2 Conditions for safe storage, including any incompatibilities
- Storage:
- Requirements to be met by storerooms and
receptacles: No special requirements.
- Information about storage in one common
storage facility: Do not store together with oxidising and acidic materials as well as heavy-metal compounds.
Store away from foodstuffs.
- Further information about storage
conditions: Protect from frost.
Keep container tightly sealed.
- Storage class: 5.2
- 7.3 Specific end use(s) No further relevant information available.

* SECTION 8: Exposure controls/personal protection

- Additional information about design of
technical facilities: No further data; see item 7.
- 8.1 Control parameters
- Ingredients with limit values that require monitoring at the workplace:
94-36-0 dibenzoyl peroxide
WEL Long-term value: 5 mg/m³
84-61-7 dicyclohexyl phthalate
WEL Long-term value: 5 mg/m³
- DNELs
94-36-0 dibenzoyl peroxide
Oral Long term - systemic effects 1.65 mg/kg (worker)
Dermal Long term - systemic effects 6.6 mg/kg (worker)
Inhalative Long term - systemic effects 11.75 mg/m³ (worker)
84-61-7 dicyclohexyl phthalate
Dermal Long term - systemic effects 0.5 mg/kg (worker)
Inhalative Long term - systemic effects 35.2 mg/m³ (worker)
- Additional information: The lists valid during the making were used as basis.
- 8.2 Exposure controls
- Personal protective equipment:
- General protective and hygienic measures: Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
(Contd. on page 4)
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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 21.05.2015 Version number 1 Revision: 21.05.2015

Trade name: KEMPEROL CP

(Contd. of page 3)
- Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use self-contained respiratory protective device.
Use suitable respiratory protective device in case of insufficient ventilation.
- Protection of hands:
Protective gloves

Only use chemical-protective gloves with CE-labelling of category III.

The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Due to missing tests no recommendation to the glove material can be given for the product/
the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion
and the degradation
- Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer.
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to
be checked prior to the application.
Recommended thickness of the material: ≥ 0.7 mm
Synthetic rubber gloves
- Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
The determined penetration times according to EN 374 part III are not performed under practical
conditions. Therefore a maximum wearing time, which corresponds to 50% of the penetration time, is
recommended.
Value for the permeation: Level ≤ 3
- Eye protection:
Tightly sealed goggles

- Body protection: Protective work clothing

Impervious protective clothing

* SECTION 9: Physical and chemical properties

- 9.1 Information on basic physical and chemical properties
- General Information
- Appearance:
Form: Powder
Colour: White
- Odour: Characteristic
- Odour threshold: Not determined.
- pH-value: Not applicable.
- Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: Undetermined.
- Flash point: 180 °C
- Flammability (solid, gaseous): May cause fire.
- Ignition temperature:
Decomposition temperature: Not determined.
- Self-igniting: Product is not selfigniting.
- Danger of explosion: Not determined.
- Explosion limits:
Lower: Not determined.
Upper: Not determined.
- Density at 20 °C: 1.23 g/cm³
- Relative density Not determined.
- Vapour density Not applicable.
- Evaporation rate Not applicable.
- Solubility in / Miscibility with
water: Insoluble.
(Contd. on page 5)
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according to 1907/2006/EC, Article 31
Printing date 21.05.2015 Version number 1 Revision: 21.05.2015

Trade name: KEMPEROL CP

(Contd. of page 4)
- Partition coefficient (n-octanol/water): Not determined.
- Viscosity:
Dynamic: Not applicable.
Kinematic: Not applicable.
- Solvent content:
VOC (EC) 0.00 %
- 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

- 10.1 Reactivity
- 10.2 Chemical stability
- Thermal decomposition / conditions to be
avoided: No decomposition if used according to specifications.
- 10.3 Possibility of hazardous reactions No dangerous reactions known.
- 10.4 Conditions to avoid No further relevant information available.
- 10.5 Incompatible materials: No further relevant information available.
- 10.6 Hazardous decomposition products: No dangerous decomposition products known.

* SECTION 11: Toxicological information

- 11.1 Information on toxicological effects
- Acute toxicity
- LD/LC50 values relevant for classification:
94-36-0 dibenzoyl peroxide
Oral LD50 >5000 mg/kg (rat)
Inhalative LC50/4 h >24.3 mg/l (rat)
84-61-7 dicyclohexyl phthalate
Oral LD50 >2000 mg/kg (rat)
- Primary irritant effect:
- Skin corrosion/irritation No irritant effect.
- Serious eye damage/irritation Irritating effect.
- Respiratory or skin sensitisation Sensitisation possible through skin contact.
- Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Irritant
- CMR effects (carcinogenity, mutagenicity
and toxicity for reproduction) Repr. 2

SECTION 12: Ecological information

- 12.1 Toxicity
- Aquatic toxicity:
94-36-0 dibenzoyl peroxide
EC50/48 h 0.11 mg/l (daphnia)
- 12.2 Persistence and degradability No further relevant information available.
- 12.3 Bioaccumulative potential No further relevant information available.
- 12.4 Mobility in soil No further relevant information available.
- Ecotoxical effects:
- Remark: Very toxic for fish
- Additional ecological information:
- General notes: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms
- 12.5 Results of PBT and vPvB assessment
- PBT: Not applicable.
- vPvB: Not applicable.
- 12.6 Other adverse effects No further relevant information available.
GB
(Contd. on page 6)

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according to 1907/2006/EC, Article 31
Printing date 21.05.2015 Version number 1 Revision: 21.05.2015

Trade name: KEMPEROL CP

(Contd. of page 5)

SECTION 13: Disposal considerations

- 13.1 Waste treatment methods
- Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system.
- Uncleaned packaging:
- Recommendation: Disposal must be made according to official regulations.

SECTION 14: Transport information

- 14.1 UN-Number
- ADR, IMDG, IATA UN3106
- 14.2 UN proper shipping name
- ADR 3106 ORGANIC PEROXIDE TYPE D, SOLID (dibenzoyl peroxide),
ENVIRONMENTALLY HAZARDOUS
- IMDG ORGANIC PEROXIDE TYPE D, SOLID (dibenzoyl peroxide), MARINE
POLLUTANT
- IATA ORGANIC PEROXIDE TYPE D, SOLID (dibenzoyl peroxide)
- 14.3 Transport hazard class(es)
- ADR

- Class 5.2 (P1) Organic peroxides.

- Label 5.2
- IMDG

- Class 5.2 Organic peroxides.

- Label 5.2
- IATA

- Class 5.2 Organic peroxides.

- Label 5.2
- 14.4 Packing group
- ADR, IMDG, IATA Void
- 14.5 Environmental hazards: Product contains environmentally hazardous substances: dibenzoyl peroxide
- Marine pollutant: Yes
Symbol (fish and tree)
- Special marking (ADR): Symbol (fish and tree)
- 14.6 Special precautions for user Warning: Organic peroxides.
- Danger code (Kemler): 539
- EMS Number: F-J,S-R
- 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the
IBC Code Not applicable.
- Transport/Additional information:
- ADR
- Limited quantities (LQ) 500 g
- Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
- Transport category 2
- Tunnel restriction code D
- IMDG
- Limited quantities (LQ) 500 g
(Contd. on page 7)
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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 21.05.2015 Version number 1 Revision: 21.05.2015

Trade name: KEMPEROL CP

(Contd. of page 6)
- Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
- UN "Model Regulation": UN3106, ORGANIC PEROXIDE TYPE D, SOLID (dibenzoyl peroxide),
ENVIRONMENTALLY HAZARDOUS, 5.2

SECTION 15: Regulatory information

- 15.1 Safety, health and environmental
regulations/legislation specific for the
substance or mixture No further relevant information available.
- 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

* SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not
establish a legally valid contractual relationship.
- Relevant phrases H241 Heating may cause a fire or explosion.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H361 Suspected of damaging fertility or the unborn child.
H400 Very toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.
R3 Extreme risk of explosion by shock, friction, fire or other sources of ignition.
R36 Irritating to eyes.
R43 May cause sensitisation by skin contact.
R50 Very toxic to aquatic organisms.
R53 May cause long-term adverse effects in the aquatic environment.
R62 Possible risk of impaired fertility.
R7 May cause fire.
- Department issuing MSDS: research & development
- Contact: research & development
- Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
DNEL: Derived No-Effect Level (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Org. Perox. B: Organic Peroxides, Type B
Org. Perox. CD: Organic Peroxides, Types C, D
Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2
Skin Sens. 1: Sensitisation - Skin, Hazard Category 1
Repr. 2: Reproductive toxicity, Hazard Category 2
Aquatic Acute 1: Hazardous to the aquatic environment - AcuteHazard, Category 1
Aquatic Chronic 3: Hazardous to the aquatic environment - Chronic Hazard, Category 3
- * Data compared to the previous version
altered.
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