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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 27.02.2017 Revision: 27.02.2017

* SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Trade name: MR 68 C Penetrant
red and fluorescent
1.2 Relevant identified uses of the substance or mixture and uses advised against
Life cycle stages
F Formulation or re-packing
IS Use at industrial Sites
Sector of Use
SU3 Industrial uses: Uses of substances as such or in preparations at industrial sites
Product category PC14 Metal surface treatment products
Process category
PROC7 Industrial spraying
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated facilities
PROC13 Treatment of articles by dipping and pouring
Environmental release category
ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article)
Article category AC7 Metal articles
Application of the substance / the mixture
Testing material for nondestructive surface crack detection
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
MR Chemie GmbH
Nordstr. 61-63
59427 Unna (Germany)
Tel. +49 (0)2303 95151 0
Fax: +49 (0)2303 95151 10
post@mr-chemie.de
www.mr-chemie.de
Further information obtainable from:
MR Chemie GmbH, Dep. safety data sheets, Tel.: +49/(0)2303/95151-38, QS@mr-chemie.de
1.4 Emergency telephone number:
24h- Emergency Contact Phone Number
For Chemical Emergency, Spill, Leak, Fire, Exposure or Accident

Call Day or Night within USA and Canada: 1 800 424 9300
Outside USA and Canada: 001 703 527 3887
In-Country Emergency Number for:

Germany: 0800-181-7059
China: 4001 204937 (Mandarin)
Hong Kong: 800 968 793 (Cantonese)
India: 000 800 100 7141 (Hindi)
South Africa: 0 800 983 611 (English)

(WISAG FMO Cargo Service GmbH & CO.KG)

* SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008

GHS02 flame

Aerosol 1 H222-H229 Extremely flammable aerosol. Pressurised container: May burst if heated.
(Contd. on page 2)
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GHS07

Eye Irrit. 2 H319 Causes serious eye irritation.

2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
Hazard pictograms

GHS02 GHS07

Signal word Danger

Hazard statements
H222-H229 Extremely flammable aerosol. Pressurised container: May burst if heated.
H319 Causes serious eye irritation.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P251 Do not pierce or burn, even after use.
P211 Do not spray on an open flame or other ignition source.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 C/122 F.
P501 Dispose of contents/container in accordance with local/regional/national/
international regulations.
Additional information:
Buildup of explosive mixtures possible without sufficient ventilation.
2.3 Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.

* SECTION 3: Composition/information on ingredients

3.2 Chemical characterisation: Mixtures
Description: Mixture of substances listed below with nonhazardous additions.
Dangerous components:
CAS: 106-97-8 butane 10-25%
EINECS: 203-448-7 Flam. Gas 1, H220
Reg.nr.: 01-2119486944-21-XXXX Press. Gas (Comp.), H280
CAS: 64742-47-8 Distillates (petroleum), hydrotreated light 10-25%
EINECS: 265-149-8 Asp. Tox. 1, H304
Reg.nr.: 01-2119484819-18-XXXX
CAS: 112-34-5 2-(2-butoxyethoxy)ethanol 10-25%
EINECS: 203-961-6 Eye Irrit. 2, H319
Reg.nr.: 01-2119475104-44-XXXX
(Contd. on page 3)
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(Contd. of page 2)
CAS: 74-98-6 propane 10-25%
EINECS: 200-827-9 Flam. Gas 1, H220
Reg.nr.: 01-2119486944-21-XXXX Press. Gas (Comp.), H280
CAS: 102-71-6 2,2',2''-nitrilotriethanol 5-10%
EINECS: 203-049-8 substance with a Community workplace exposure
Reg.nr.: 01-2119486482-31-XXXX limit
CAS: 509-34-2 3',6'-Bis(diethylamino)spiro(isobenzofuran-1(3H),9'- 1-5%
EINECS: 208-096-8 (9H)xanthen)-3-on
Aquatic Acute 1, H400
Acute Tox. 4, H302; Eye Irrit. 2, H319
Aquatic Chronic 3, H412
Propellant: Propane-Butane
Additional information: For the wording of the listed hazard phrases refer to section 16.

* SECTION 4: First aid measures

4.1 Description of first aid measures
General information: Immediately remove any clothing soiled by the product.
After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing: Not relevant - aerosol can.
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
Information for doctor:
Grease with skin-cream to restore fat film in order to prevent skin inflammation.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

* SECTION 5: Firefighting measures

5.1 Extinguishing media
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant
foam.
Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
5.2 Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Carbon monoxide (CO)
5.3 Advice for firefighters
Protective equipment: Wear self-contained respiratory protective device.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
6.3 Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
(Contd. on page 4)
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6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling No special precautions are necessary if used correctly.
Information about fire - and explosion protection:
Do not spray onto a naked flame or any incandescent material.
Keep ignition sources away - Do not smoke.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C,
e.g. electric lights. Do not pierce or burn, even after use.
7.2 Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Observe official regulations on storing packagings with pressurised containers.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Protect from heat and direct sunlight.
7.3 Specific end use(s) No further relevant information available.

* SECTION 8: Exposure controls/personal protection

Additional information about design of technical facilities: No further data; see item 7.
8.1 Control parameters
Ingredients with limit values that require monitoring at the workplace:
106-97-8 butane
WEL (Great Britain) Short-term value: 1810 mg/m, 750 ppm
Long-term value: 1450 mg/m, 600 ppm
Carc (if more than 0.1% of buta-1.3-diene)
AGW (Germany) Long-term value: 2400 mg/m, 1000 ppm
4(II);DFG
64742-47-8 Distillates (petroleum), hydrotreated light
MAK (Germany) Long-term value: 350* 5A** mg/m, 50* ppm
vgl.Abschn.Xc; *Dampf;**Aerosol
112-34-5 2-(2-butoxyethoxy)ethanol
IOELV (EU) Short-term value: 101.2 mg/m, 15 ppm
Long-term value: 67.5 mg/m, 10 ppm
WEL (Great Britain) Short-term value: 101.2 mg/m, 15 ppm
Long-term value: 67.5 mg/m, 10 ppm
AGW (Germany) Long-term value: 67 mg/m, 10 ppm
1.5(I);EU, DFG, Y, 11
74-98-6 propane
AGW (Germany) Long-term value: 1800 mg/m, 1000 ppm
4(II);DFG
102-71-6 2,2',2''-nitrilotriethanol
MAK (Germany) Long-term value: 5E mg/m
(Contd. on page 5)
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DNELs
112-34-5 2-(2-butoxyethoxy)ethanol
Dermal Long-term - systemic effects, worker 20 mg/kg bw/day (worker)
Inhalative Acute - local effects, worker 101.2 mg/m (worker)
Long-term - systemic effects, worker 67.5 mg/m (worker)
Long-term - local effects, worker 67.5 mg/m (worker)
102-71-6 2,2',2''-nitrilotriethanol
Dermal Long-term - systemic effects, worker 6.3 mg/kg bw/day (worker)
Inhalative Long-term - systemic effects, worker 5 mg/m (worker)
Long-term - local effects, worker 5 mg/m (worker)
PNECs
112-34-5 2-(2-butoxyethoxy)ethanol
Aquatic compartment, freshwater 1 mg/L (freshwater)
Aquatic compartment - marine water 0.1 mg/L (marine water)
Aquatic compartment - water intermittent releases 3.9 mg/L (intermittent release water)
Aquatic compartment- sediment in freshwater 4 mg/kg sed dw (sediment fresh water)
Aquatic compartment sediment in marine water 0.4 mg/kg sed dw (sediment marine water)
Terrestrial compartment - soil 0.4 mg/kg dw (soil)
Oral secondary poisoning 56 mg/kg food (food secundary poisoning)
102-71-6 2,2',2''-nitrilotriethanol
Aquatic compartment, freshwater 0.32 mg/L (freshwater)
Aquatic compartment - marine water 0.032 mg/L (marine water)
Aquatic compartment - water intermittent releases 5.12 mg/L (intermittent release water)
Aquatic compartment- sediment in freshwater 1.7 mg/kg sed dw (sediment fresh water)
Aquatic compartment sediment in marine water 0.17 mg/kg sed dw (sediment marine water)
Terrestrial compartment - soil 0.151 mg/kg dw (soil)
Sewage treatment plant 10 mg/L (sewage treatment plant)
Additional information: The lists valid during the making were used as basis.
8.2 Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Respiratory protection:
Filter AX
For good ventilation provide, this can be achieved by local or space exhaust. If the concentration
lies over the job limit values, then, a certified respirator suitable for this purpose must be used.
Protection of hands:
For the protection against chemicals in areas with heightened risk of injury (mechanical hazard) no
recommendation for a suitable glove material can be given.
Check the permeability prior to each anewed use of the glove.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Material of gloves
Butyl rubber, BR
Recommended thickness of the material: 0.5 mm
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
(Contd. on page 6)
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to be checked prior to the application.
Penetration time of glove material
Value for the permeation: Level 4
Supplier for suitable protection gloves:
ASD ArbeitsSicherheit Dortmund
Torstr. 101 - 37355 Niederorschel OT Rdigershagen
Tel.: 02301 / 919543 - Fax: 02301 / 9453893
E-Mail: m.schnellhardt@t-online.de - http://www.arbeitssicherheitdortmund.de
The exact break trough time has to be found out by the manufacturer of the protective gloves and
has to be observed.
Eye protection: Safety glasses
Body protection: Protective work clothing

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
General Information
Appearance:
Form: Aerosol
Colour: Red
Odour: Characteristic
Odour threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/freezing point: Undetermined.
Initial boiling point and boiling range: Not applicable, as aerosol.
Flash point: -97 C
Basis: propellant
Flammability (solid, gas): Not applicable.
Ignition temperature: Not determined - aerosol.
Decomposition temperature: Not determined.
Auto-ignition temperature: Product is not selfigniting.
Explosive properties: Product is not explosive. However, formation of
explosive air/vapour mixtures are possible.
Explosion limits:
Lower: 0.5 Vol %
Upper: 10.9 Vol %
Vapour pressure at 20 C: 8300 hPa
Basis: propellant
Spray can internal pressure (20 C): 4.5 bar
Spray can internal pressure (50 C): 8.5 bar
Density at 20 C: 0.91 g/cm
Basis: active substance
Relative density Not determined.
Vapour density Not determined.
Evaporation rate Not applicable.
Solubility in / Miscibility with
water: Not miscible or difficult to mix.
(Contd. on page 7)
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Partition coefficient: n-octanol/water: Not determined.

Viscosity:
Dynamic: Not determined.
Kinematic at 20 C: 15.3 mm/s
Organic solvents: 65.0 %
VOC (EU) 41.32 %
9.2 Other information No further relevant information available.

* SECTION 10: Stability and reactivity

10.1 Reactivity No further relevant information available.
10.2 Chemical stability
Thermal decomposition / conditions to be avoided:
Danger of bursting of the aerosol can during overheating
10.3 Possibility of hazardous reactions No dangerous reactions known.
10.4 Conditions to avoid No further relevant information available.
10.5 Incompatible materials: No further relevant information available.
10.6 Hazardous decomposition products: No dangerous decomposition products known.

* SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity Based on available data, the classification criteria are not met.
LD/LC50 values relevant for classification:
106-97-8 butane
Inhalative LC50/4 h 658 mg/l (rat)
112-34-5 2-(2-butoxyethoxy)ethanol
Dermal LD50 4000 mg/kg (rbt)
102-71-6 2,2',2''-nitrilotriethanol
Oral LD50 8000 mg/kg (rat)
Primary irritant effect:
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Serious eye damage/irritation
Causes serious eye irritation.
Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
STOT-single exposure Based on available data, the classification criteria are not met.
STOT-repeated exposure Based on available data, the classification criteria are not met.
Aspiration hazard Based on available data, the classification criteria are not met.

* SECTION 12: Ecological information

12.1 Toxicity
Aquatic toxicity: No further relevant information available.
12.2 Persistence and degradability No further relevant information available.
12.3 Bioaccumulative potential No further relevant information available.
(Contd. on page 8)
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12.4 Mobility in soil No further relevant information available.
Additional ecological information:
General notes:
Do not allow product to reach ground water, water course or sewage system.
Water hazard class 1: weakly water-endangering
12.5 Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
12.6 Other adverse effects No further relevant information available.

* SECTION 13: Disposal considerations

13.1 Waste treatment methods
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage
system.
Eliminate in accordance with local regulations.
Waste disposal key:
For this product no waste key number can be specified, because only the intended purpose permits
an allocation. The waste key number is to be specified in arrangement with the regional waste
disposal.
The indications for Waste key reflect the pure unmodified product and are only a recommendation.
European waste catalogue
10 00 00 WASTES FROM THERMAL PROCESSES
10 10 00 wastes from casting of non-ferrous pieces
10 10 15* waste crack-indicating agent containing hazardous substances
15 00 00 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND
PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED
15 01 00 packaging (including separately collected municipal packaging waste)
15 01 10* packaging containing residues of or contaminated by hazardous substances
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.

* SECTION 14: Transport information

14.1 UN-Number
ADR, IMDG, IATA UN1950
14.2 UN proper shipping name
ADR 1950 AEROSOLS
IMDG AEROSOLS
IATA AEROSOLS, flammable
14.3 Transport hazard class(es)
ADR

Class 2 5F Gases.
(Contd. on page 9)
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Label 2.1
IMDG, IATA

Class 2.1
Label 2.1
14.4 Packing group
ADR, IMDG, IATA Void
14.5 Environmental hazards: Not applicable.
14.6 Special precautions for user Warning: Gases.
Danger code (Kemler): -
EMS Number: F-D,S-U
Stowage Code SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity
of 1 litre: Category A. For AEROSOLS with a
capacity above 1 litre: Category B. For WASTE
AEROSOLS: Category C, Clear of living quarters.
Segregation Code SG69 For AEROSOLS with a maximum capacity of
1 litre: Segregation as for class 9. Stow "separated
f rom " c lass 1 ex cept f or divis ion 1.4. For
AEROSO LS with a c apacity above 1 litre:
Segregation as for the appropriate subdivision of
class 2. For WASTE AEROSOLS: Segregation as
for the appropriate subdivision of class 2.
14.7 Transport in bulk according to Annex II
of Marpol and the IBC Code Not applicable.
Transport/Additional information:
ADR
Limited quantities (LQ) 1L
Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
Transport category 2
Tunnel restriction code D
IMDG
Limited quantities (LQ) 1L
Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
UN "Model Regulation": UN 1950 AEROSOLS, 2.1

* SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
Directive 2012/18/EU
Named dangerous substances - ANNEX I None of the ingredients is listed.
Seveso category P3a FLAMMABLE AEROSOLS
Qualifying quantity (tonnes) for the application of lower-tier requirements 150 t
(Contd. on page 10)
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Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t
REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3, 55
National regulations:
Waterhazard class:
W ater hazard class 1: slightly hazardous for water.(In accordance with classification
VwVwS,appendix 4)
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

The data in this safety data sheet are based on our knowledge at the time of the revision.The
information should give you reference points for a safe handling of the product specified in this
safety data sheet. The data are not transferable to other products. If the product specified in this
safety data sheet is mixed or processed with other materials, the data cannot be transferred without
examination.
Relevant phrases
The wording of the listed risk phrases are those of the individual raw materials.
H220 Extremely flammable gas.
H280 Contains gas under pressure; may explode if heated.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H319 Causes serious eye irritation.
H400 Very toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.
Recommended restriction of use
Existing national and local laws concerning chemicals are to be considered.
Department issuing SDS:
MR Chemie GmbH, Dep. safety data sheets, Tel.: +49/(0)2303/95151-38
Contact:
MR Chemie GmbH, Dep. safety data sheets, Tel.: +49/(0)2303/95151-38, QS@mr-chemie.de
Abbreviations and acronyms:
ADR: Accord europen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Gas 1: Flammable gases Category 1
Aerosol 1: Aerosols Category 1
Press. Gas (Comp.): Gases under pressure Compressed gas
Acute Tox. 4: Acute toxicity Category 4
Eye Irrit. 2: Serious eye damage/eye irritation Category 2
Asp. Tox. 1: Aspiration hazard Category 1
Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard Category 1
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard Category 3
* Data compared to the previous version altered.
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