Page 1/8

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 17.07.2020 Version number 1 Revision: 17.07.2020

* SECTION 1: Identification of the substance/mixture and of the company/

undertaking
· 1.1 Product identifier
· Trade name: MANNOL Coolant G13
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture Heat transfer fluid
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
UAB "SCT Lubricants"
Silutes Pl. 119
LIT-95112 KLAIPEDA
LITHUANIA
renata@sct.lt
· Further information obtainable from: Product safety department.
· 1.4 Emergency telephone number: Giftinformationszentrum-Nord +49-551-19240

* SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008



 GHS08 health hazard

STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.



 GHS07

Eye Irrit. 2 H319 Causes serious eye irritation.

· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms



 

GHS07 GHS08

· Signal word Warning

· Hazard statements
H319 Causes serious eye irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
· Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash thoroughly after handling.
(Contd. on page 2)
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51.1.5
 Page 2/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.07.2020 Version number 1 Revision: 17.07.2020

Trade name: MANNOL Coolant G13

(Contd. of page 1)
P280 Wear protective gloves / eye protection / face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P314 Get medical advice/attention if you feel unwell.
P337+P313 If eye irritation persists: Get medical advice.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

* SECTION 3: Composition/information on ingredients

· 3.2 Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 107-21-1 ethanediol <30.0%
EINECS: 203-473-3 STOT RE 2, H373; Acute Tox. 4, H302
CAS: 111-46-6 2,2'-oxybisethanol 0–4%
EINECS: 203-872-2 Acute Tox. 4, H302
CAS: 3164-85-0 Potassium 2-ethylhexanoate <1.0%
EINECS: 221-625-7 Repr. 2, H361; Eye Dam. 1, H318; Skin Irrit. 2, H315; Aquatic Chronic 4,
H413
· Additional information: For the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures

· 4.1 Description of first aid measures
· General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least
48 hours after the accident.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: Call for a doctor immediately.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents:
Use fire extinguishing methods suitable to surrounding conditions.
Foam
Fire-extinguishing powder
(Contd. on page 3)
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51.1.5
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.07.2020 Version number 1 Revision: 17.07.2020

Trade name: MANNOL Coolant G13

(Contd. of page 2)
Sand
· 5.2 Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
· 5.3 Advice for firefighters
· Protective equipment: Mouth respiratory protective device.
· Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Ensure adequate ventilation
Particular danger of slipping on leaked/spilled product.
Wear protective clothing.
· 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection: Keep respiratory protective device available.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: None.
· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
107-21-1 ethanediol (30.0%)
WEL Short-term value: 104** mg/m³, 40** ppm
Long-term value: 10* 52** mg/m³, 20** ppm
Sk *particulate **vapour
(Contd. on page 4)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.07.2020 Version number 1 Revision: 17.07.2020

Trade name: MANNOL Coolant G13

(Contd. of page 3)
111-46-6 2,2'-oxybisethanol (4.0%)
WEL Long-term value: 101 mg/m³, 23 ppm
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use self-contained respiratory protective device.
· Protection of hands:


 Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the
preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to
be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has
to be observed.
· Eye protection:


 Tightly sealed goggles

SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Liquid
Colour: Green
· Odour: Product specific
· Odour threshold: Not determined.
· pH-value: Not determined.
(Contd. on page 5)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.07.2020 Version number 1 Revision: 17.07.2020

Trade name: MANNOL Coolant G13

(Contd. of page 4)

· Change in condition
Melting point/freezing point: Undetermined.
Initial boiling point and boiling range: >106 °C
· Flash point: Not applicable.
· Flammability (solid, gas): Not applicable.
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Product does not present an explosion hazard.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapour pressure: Not determined.
· Density at 20 °C: 1.03–1.04 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
· Solvent content:
Organic solvents: 0–4 %
VOC (EC) 0–4 %
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products:
Carbon monoxide
Aldehyde
Poisonous gases/vapours
Carbon dioxide
GB
(Contd. on page 6)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.07.2020 Version number 1 Revision: 17.07.2020

Trade name: MANNOL Coolant G13

(Contd. of page 5)

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
107-21-1 ethanediol
Oral LD50 5,840 mg/kg (rat)
Dermal LD50 9,530 mg/kg (rabbit)
111-46-6 2,2'-oxybisethanol
Oral LD50 12,565 mg/kg (rat)
Dermal LD50 11,890 mg/kg (rabbit)
· Primary irritant effect:
· Skin corrosion/irritation Based on available data, the classification criteria are not met.
· Serious eye damage/irritation
Causes serious eye irritation.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure
May cause damage to organs through prolonged or repeated exposure.
· Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
(Contd. on page 7)
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51.1.5
 Page 7/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.07.2020 Version number 1 Revision: 17.07.2020

Trade name: MANNOL Coolant G13

(Contd. of page 6)
· European waste catalogue
HP 5 Specific Target Organ Toxicity (STOT)/Aspiration Toxicity
HP 6 Acute Toxicity
HP 10 Toxic for reproduction
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

SECTION 14: Transport information

· 14.1 UN-Number
· ADR, ADN, IMDG, IATA not regulated
· 14.2 UN proper shipping name
· ADR, ADN, IMDG, IATA not regulated
· 14.3 Transport hazard class(es)
· ADR, ADN, IMDG, IATA
· Class not regulated
· 14.4 Packing group
· ADR, IMDG, IATA not regulated
· 14.5 Environmental hazards: Not applicable.
· 14.6 Special precautions for user Not applicable.
· 14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
· UN "Model Regulation": not regulated

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I None of the ingredients is listed.
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3
· DIRECTIVE 2011/65/EU on the restriction of the use of certain hazardous substances in
electrical and electronic equipment – Annex II
None of the ingredients is listed.
· National regulations:
· Other regulations, limitations and prohibitive regulations
· Substances of very high concern (SVHC) according to REACH, Article 57
12179-04-3 disodium tetraborate pentahydrate
(Contd. on page 8)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.07.2020 Version number 1 Revision: 17.07.2020

Trade name: MANNOL Coolant G13

(Contd. of page 7)
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H302 Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H361 Suspected of damaging fertility or the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
H413 May cause long lasting harmful effects to aquatic life.
· Department issuing SDS: Product safety department.
· Contact: Mrs. Zubaite
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
Acute Tox. 4: Acute toxicity - oral – Category 4
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Dam. 1: Serious eye damage/eye irritation – Category 1
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
Repr. 2: Reproductive toxicity – Category 2
STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2
Aquatic Chronic 4: Hazardous to the aquatic environment - long-term aquatic hazard – Category 4
· * Data compared to the previous version altered.
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51.1.5