Page 1/9

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 154 Revision: 21.12.2016

* SECTION 1: Identification of the substance/mixture and of the company/undertaking

· 1.1 Product identifier
· Trade name: SILICONE SPRAY BLANCO 400 ML
· Article number: 000662
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
· Sector of Use
SU21 Consumer uses: Private households / general public / consumers
SU22 Professional uses: Public domain (administration, education, entertainment, services, craftsmen)
· Product category PC24 Lubricants, greases, release products
· Process category
PROC7 Industrial spraying
PROC11 Non industrial spraying
· Environmental release category
ERC8a Widespread use of non-reactive processing aid (no inclusion into or onto article, indoor)
ERC8d Widespread use of non-reactive processing aid (no inclusion into or onto article, outdoor)
· Application of the substance / the mixture Lubricant
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Special Fills
Postbus 9
1715 ZG SPANBROEK
De Veken 129
1716 KG OPMEER
Tel.: 0226 - 35 25 75
Fax 0226 - 35 99 15

info@specialfills.nl
· Further information obtainable from: Department Product Safety
· 1.4 Emergency telephone number: Tel.: 0226 - 35 25 75 (8.00-17.00hrs)

* SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008

GHS02 flame

Aerosol 1 H222-H229 Extremely flammable aerosol. Pressurised container: May burst if heated.

GHS09 environment

Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.

GHS07

Skin Irrit. 2 H315 Causes skin irritation.

STOT SE 3 H336 May cause drowsiness or dizziness.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
(Contd. on page 2)
GB

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 Page 2/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 154 Revision: 21.12.2016

Trade name: SILICONE SPRAY BLANCO 400 ML

(Contd. of page 1)
· Hazard pictograms

GHS02 GHS07 GHS09

· Signal word Danger

· Hazard-determining components of labelling:
Naphtha (petroleum), hydrotreated light
· Hazard statements
H222-H229 Extremely flammable aerosol. Pressurised container: May burst if heated.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
· Precautionary statements
P102 Keep out of reach of children.
P260 Do not breathe spray.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P251 Do not pierce or burn, even after use.
P211 Do not spray on an open flame or other ignition source.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P501 Dispose of contents/container in accordance with local regulations.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

* SECTION 3: Composition/information on ingredients

· 3.2 Chemical characterisation: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
EC number: 927-510-4 Naphtha (petroleum), hydrotreated light 25-50%
Index number: 649-328-00-1 Flam. Liq. 2, H225
Reg.nr.: 01-2119475515-33 Asp. Tox. 1, H304
Aquatic Chronic 2, H411
Skin Irrit. 2, H315; STOT SE 3, H336
CAS: 74-98-6 propane 20-25%
EINECS: 200-827-9 Flam. Gas 1, H220
Index number: 601-003-00-5 Press. Gas C, H280
Reg.nr.: 01-2119486944-21-xxxx
CAS: 106-97-8 butane 12.5-20%
EINECS: 203-448-7 Flam. Gas 1, H220
Index number: 601-004-00-0 Press. Gas C, H280
Reg.nr.: 01-2119474691-32-xxxx
CAS: 75-28-5 isobutane 12.5-20%
EINECS: 200-857-2 Flam. Gas 1, H220
Index number: 601-004-00-0 Press. Gas C, H280
Reg.nr.: 01-2119485395-27-xxxx
· Additional information: For the wording of the listed hazard phrases refer to section 16.
GB
(Contd. on page 3)

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 Page 3/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 154 Revision: 21.12.2016

Trade name: SILICONE SPRAY BLANCO 400 ML

(Contd. of page 2)

* SECTION 4: First aid measures

· 4.1 Description of first aid measures
· After inhalation: In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing: Drink plenty of water and provide fresh air. Call for a doctor immediately.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

* SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· 5.2 Special hazards arising from the substance or mixture No further relevant information available.
· 5.3 Advice for firefighters
· Protective equipment: No special measures required.

* SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation
Keep away from ignition sources.
· 6.2 Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up: Ensure adequate ventilation.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

* SECTION 7: Handling and storage

· 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace.
· Information about fire - and explosion protection:
Do not spray onto a naked flame or any incandescent material.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50 °C, i.e. electric
lights. Do not pierce or burn, even after use.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store in a cool location.
Observe official regulations on storing packagings with pressurised containers.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Protect from heat and direct sunlight.
(Contd. on page 4)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 154 Revision: 21.12.2016

Trade name: SILICONE SPRAY BLANCO 400 ML

(Contd. of page 3)
· 7.3 Specific end use(s) No further relevant information available.

* SECTION 8: Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
106-97-8 butane
WEL Short-term value: 1810 mg/m³, 750 ppm
Long-term value: 1450 mg/m³, 600 ppm
Carc (if more than 0.1% of buta-1.3-diene)
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
· Respiratory protection: Not required.
· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection: Not required.

* SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Aerosol
Colour: Colourless
· Odour: Solvent-like
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/Melting range: Undetermined.
(Contd. on page 5)
GB

43.1.7
 Page 5/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 154 Revision: 21.12.2016

Trade name: SILICONE SPRAY BLANCO 400 ML

(Contd. of page 4)

Boiling point/Boiling range: Not applicable, as aerosol.

· Flash point: <0 °C (<32 °F)
Not applicable, as aerosol.
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: > 230 °C (> 446 °F)
· Decomposition temperature: Not determined.
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Product is not explosive. However, formation of explosive air/
vapour mixtures are possible.
· Explosion limits:
Lower: 0.9 Vol %
Upper: 10.9 Vol %
· Vapour pressure at 20 °C (68 °F): 3500 hPa (2625 mm Hg)
· Density at 20 °C (68 °F): 0.6353 g/cm³ (5.302 lbs/gal)
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not applicable.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
· Solvent content:
Organic solvents: 92.0 %
· EU-VOC: 584.5 g/l
· EU-VOC in %: 92.00 %
· 9.2 Other information No further relevant information available.

* SECTION 10: Stability and reactivity

· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products: No dangerous decomposition products known.

* SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
Naphtha (petroleum), hydrotreated light
Oral LD50 >5840 mg/kg (rat)
Dermal LD50 >2920 mg/kg (rat)
(Contd. on page 6)
GB

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 154 Revision: 21.12.2016

Trade name: SILICONE SPRAY BLANCO 400 ML

(Contd. of page 5)
Inhalative LC50 / 4 h >25200 mg/m3 (rat)
LC50 / 96 h 2.5 mg/l (Leuciscus idus)
106-97-8 butane
Inhalative LC50 / 4 h 658000 mg/m3 (rat)
· Primary irritant effect:
· Skin corrosion/irritation
Causes skin irritation.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure
May cause drowsiness or dizziness.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.

* SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity:
Naphtha (petroleum), hydrotreated light
EC50 / 24 h >10 mg/l (Daphnia magna)
>100 mg/l (fish)
LC50 / 48 h 4924 mg/l (fish)
LC50 / 96 h 2.5 mg/l (Pimephales promelas)
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: Toxic for fish
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

* SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· European waste catalogue
14 06 03* other solvents and solvent mixtures
15 01 04 metallic packaging
(Contd. on page 7)
GB

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 154 Revision: 21.12.2016

Trade name: SILICONE SPRAY BLANCO 400 ML

(Contd. of page 6)

· Uncleaned packaging:
· Recommendation: Non contaminated packagings may be recycled.

* SECTION 14: Transport information

· 14.1 UN-Number
· ADR, IMDG, IATA UN1950
· 14.2 UN proper shipping name
· ADR 1950 AEROSOLS, ENVIRONMENTALLY HAZARDOUS
· IMDG AEROSOLS (Naphtha (petroleum), hydrotreated light),
MARINE POLLUTANT
· IATA AEROSOLS, flammable
· 14.3 Transport hazard class(es)
· ADR

· Class 2 5F Gases.
· Label 2.1
· IMDG

· Class 2.1
· Label 2.1
· IATA

· Class 2.1
· Label 2.1
· 14.4 Packing group
· ADR, IMDG, IATA Void
· 14.5 Environmental hazards:
· Marine pollutant: Yes
Symbol (fish and tree)
· Special marking (ADR): Symbol (fish and tree)
· 14.6 Special precautions for user Warning: Gases.
· Danger code (Kemler): -
· EMS Number: F-D,S-U
· Stowage Code SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity of 1 litre:
Category A. For AEROSOLS with a capacity above 1 litre:
Category B. For WASTE AEROSOLS: Category C, Clear
of living quarters.
· Segregation Code SG69 For AEROSOLS with a maximum capacity of 1 litre:
Segregation as for class 9. Stow "separated from" class 1
except for division 1.4. For AEROSOLS with a capacity
above 1 litre: Segregation as for the appropriate
(Contd. on page 8)
GB

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 154 Revision: 21.12.2016

Trade name: SILICONE SPRAY BLANCO 400 ML

(Contd. of page 7)

· subdivision of class 2. For WASTE AEROSOLS:

Segregation as for the appropriate subdivision of class 2.
· 14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· Transport category 2
· Tunnel restriction code D
· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· UN "Model Regulation": UN 1950 AEROSOLS, 2.1, ENVIRONMENTALLY
HAZARDOUS

* SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Seveso category
P3a FLAMMABLE AEROSOLS
E2 Hazardous to the Aquatic Environment
· Qualifying quantity (tonnes) for the application of lower-tier requirements 150 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

* SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H220 Extremely flammable gas.
H225 Highly flammable liquid and vapour.
H280 Contains gas under pressure; may explode if heated.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
· Department issuing SDS: R&D legislation and regulatory advisor
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organisation
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
(Contd. on page 9)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.01.2017 Version number 154 Revision: 21.12.2016

Trade name: SILICONE SPRAY BLANCO 400 ML

(Contd. of page 8)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Gas 1: Flammable gases – Category 1
Aerosol 1: Aerosols – Category 1
Press. Gas C: Gases under pressure – Compressed gas
Flam. Liq. 2: Flammable liquids – Category 2
Skin Irrit. 2: Skin corrosion/irritation – Category 2
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
Asp. Tox. 1: Aspiration hazard – Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
· * Data compared to the previous version altered.
GB

43.1.7