Page 1/7

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 02.05.2023 Version number: 1 Revision: 02.05.2023

* SECTION 1: Identification of the substance/mixture and of the company/undertaking

· 1.1 Product identifier
· Trade name: COPPER COMPOUND
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
· Sector of Use
SU3 Industrial uses: Uses of substances as such or in preparations at industrial sites
SU21 Consumer uses: Private households / general public / consumers
· Product category PC24 Lubricants, greases, release products
· Application of the substance / the mixture Lubricant
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Spanjaard (Pty) Ltd.
748-750 Fifth Street, Wynberg
Sandton, SOUTH AFRICA, 2090
Tel: +27 11 386 7100
· Further information obtainable from:
Clinton Palmer - Operations Executive
clinton@spanjaard.biz
· 1.4 Emergency telephone number: NCEC: +44 1865 407333

* SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms Void
· Signal word Void
· Hazard statements
H412 Harmful to aquatic life with long lasting effects.
· Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read carefully and follow all instructions.
P273 Avoid release to the environment.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

* SECTION 3: Composition/information on ingredients

· 3.2 Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 13463-67-7 titanium dioxide 10-15%
EINECS: 236-675-5 Carc. 2, H351
Index number: 022-006-00-2
(Contd. on page 2)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.05.2023 Version number: 1 Revision: 02.05.2023

Trade name: COPPER COMPOUND

(Contd. of page 1)
CAS: 7440-50-8 Copper 2.5-<5%
EINECS: 231-159-6 Aquatic Chronic 2, H411
Index number: 029-024-00-X
· Additional information: For the wording of the listed hazard phrases refer to section 16.
· Non-hazardous components
CAS: 74869-21-9 Lubricating greases (Petroleum Based) 50-75%
EINECS: 278-011-7
Index number: 649-243-00-X
CAS: 7782-42-5 Graphite 1-5%
EINECS: 231-955-3

* SECTION 4: First aid measures

· 4.1 Description of first aid measures
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions.
· 5.2 Special hazards arising from the substance or mixture No further relevant information available.
· 5.3 Advice for firefighters
· Protective equipment: No special measures required.

* SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures Not required.
· 6.2 Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to item 13.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

* SECTION 7: Handling and storage

· 7.1 Precautions for safe handling No special precautions are necessary if used correctly.
· Information about fire - and explosion protection: No special measures required.
(Contd. on page 3)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.05.2023 Version number: 1 Revision: 02.05.2023

Trade name: COPPER COMPOUND

(Contd. of page 2)

· 7.2 Conditions for safe storage, including any incompatibilities

· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: None.
· 7.3 Specific end use(s) No further relevant information available.

* SECTION 8: Exposure controls/personal protection

· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
13463-67-7 titanium dioxide
WEL (Great Britain) Long-term value: 10* 4** mg/m³
*total inhalable **respirable
AGW (Germany) Long-term value: 1.25* 10** mg/m³
2(II);*alveolengängig**einatembar; AGS, DFG, Y
7782-42-5 Graphite
AGW (Germany) Long-term value: 1.25* 10** mg/m³
2(II);*alveolengängig**einatembar; AGS, DFG, Y
7440-50-8 Copper
WEL (Great Britain) Short-term value: 2** mg/m³
Long-term value: 0.2* 1** mg/m³
*fume **dusts and mists (as Cu)
MAK (Germany) Long-term value: 0.01 A mg/m³
als Cu
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Appropriate engineering controls No further data; see item 7.
· Individual protection measures, such as personal protective equipment
· General protective and hygienic measures: Wash hands before breaks and at the end of work.
· Respiratory protection:
Not necessary if room is well-ventilated.
Suitable respiratory protective device recommended.
· Hand protection
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye/face protection Not required.
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(Contd. on page 4)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.05.2023 Version number: 1 Revision: 02.05.2023

Trade name: COPPER COMPOUND

(Contd. of page 3)

* SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Physical state Solid
· Colour: Gold coloured
· Odour: Odourless
· Odour threshold: Not determined.
· Melting point/freezing point: Undetermined.
· Boiling point or initial boiling point and boiling range >2,500 °C
· Flammability Not determined.
· Lower and upper explosion limit
· Lower: Not determined.
· Upper: Not determined.
· Flash point: Not applicable.
· Decomposition temperature: Not determined.
· pH Not applicable.
· Viscosity:
· Kinematic viscosity Not applicable.
· Dynamic: Not applicable.
· Solubility
· water: Insoluble.
· Partition coefficient n-octanol/water (log value) Not determined.
· Vapour pressure: Not applicable.
· Density and/or relative density
· Density: Not determined.
· Relative density Not determined.
· Vapour density Not applicable.
· Particle characteristics See item 3.
· 9.2 Other information
· Appearance:
· Form: Pasty
· Important information on protection of health and
environment, and on safety.
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Product does not present an explosion hazard.
· Solvent content:
· VOC (EC) 0.00 %
· Change in condition
· Evaporation rate Not applicable.
· Information with regard to physical hazard classes
· Explosives Void
· Flammable gases Void
· Aerosols Void
· Oxidising gases Void
· Gases under pressure Void
· Flammable liquids Void
· Flammable solids Void
· Self-reactive substances and mixtures Void
· Pyrophoric liquids Void
· Pyrophoric solids Void
· Self-heating substances and mixtures Void
(Contd. on page 5)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.05.2023 Version number: 1 Revision: 02.05.2023

Trade name: COPPER COMPOUND

(Contd. of page 4)

· Substances and mixtures, which emit flammable gases

in contact with water Void
· Oxidising liquids Void
· Oxidising solids Void
· Organic peroxides Void
· Corrosive to metals Void
· Desensitised explosives Void

SECTION 10: Stability and reactivity

· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products: No dangerous decomposition products known.

* SECTION 11: Toxicological information

· 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
13463-67-7 titanium dioxide
Oral LD50 >20,000 mg/kg (rat)
Dermal LD50 >10,000 mg/kg (rabbit)
Inhalative LC50/4 h >6.82 mg/l (rat)
· Skin corrosion/irritation Based on available data, the classification criteria are not met.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
· 11.2 Information on other hazards
· Endocrine disrupting properties
None of the ingredients is listed.

* SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
(Contd. on page 6)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.05.2023 Version number: 1 Revision: 02.05.2023

Trade name: COPPER COMPOUND

(Contd. of page 5)
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Endocrine disrupting properties For information on endocrine disrupting properties see section 11.
· 12.7 Other adverse effects
· Remark: Harmful to fish
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Harmful to aquatic organisms

* SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

* SECTION 14: Transport information

· 14.1 UN number or ID number
· ADR, ADN, IMDG, IATA Void
· 14.2 UN proper shipping name
· ADR, ADN, IMDG, IATA Void
· 14.3 Transport hazard class(es)
· ADR, ADN, IATA
· Class Void
· IMDG -
· Class Void
· 14.4 Packing group -
· ADR, IMDG, IATA Void
· 14.5 Environmental hazards: Not applicable.
· 14.6 Special precautions for user Not applicable.
· 14.7 Maritime transport in bulk according to IMO
instruments Not applicable.
· UN "Model Regulation": Void

* SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms Void
(Contd. on page 7)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 02.05.2023 Version number: 1 Revision: 02.05.2023

Trade name: COPPER COMPOUND

(Contd. of page 6)
· Signal word Void
· Hazard statements
H412 Harmful to aquatic life with long lasting effects.
· Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read carefully and follow all instructions.
P273 Avoid release to the environment.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I None of the ingredients is listed.
· DIRECTIVE 2011/65/EU on the restriction of the use of certain hazardous substances in electrical and
electronic equipment – Annex II
None of the ingredients is listed.
· REGULATION (EU) 2019/1148
· Annex I - RESTRICTED EXPLOSIVES PRECURSORS (Upper limit value for the purpose of licensing under
Article 5(3))
None of the ingredients is listed.
· Annex II - REPORTABLE EXPLOSIVES PRECURSORS
None of the ingredients is listed.
· Regulation (EC) No 273/2004 on drug precursors
None of the ingredients is listed.
· Regulation (EC) No 111/2005 laying down rules for the monitoring of trade between the Community and third
countries in drug precursors
None of the ingredients is listed.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H351 Suspected of causing cancer.
H411 Toxic to aquatic life with long lasting effects.
· Date of previous version: 26.04.2023
· Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Carc. 2: Carcinogenicity – Category 2
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered.
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