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    Perhitungan CP Protein

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    Hardi
    The document discusses the calculation of estimated Cp values for various functional groups and amino acid components of proteins using the Joback method. It provides tables of ΔCp values for different functional groups from Perry (1999) and estimates the Cp of individual amino acids like isoleucine, leucine, lysine, etc. constituting a typical 21 gram portion of protein by summing the contribution of their functional groups. These individual amino acid Cp values are then weighted according to their composition in protein to obtain an estimated Cp of 611.904 J/mol.K for proteins.

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    Perhitungan CP Protein

    Uploaded by

    Hardi
    73 views3 pages
    The document discusses the calculation of estimated Cp values for various functional groups and amino acid components of proteins using the Joback method. It provides tables of ΔCp values for different functional groups from Perry (1999) and estimates the Cp of individual amino acids like isoleucine, leucine, lysine, etc. constituting a typical 21 gram portion of protein by summing the contribution of their functional groups. These individual amino acid Cp values are then weighted according to their composition in protein to obtain an estimated Cp of 611.904 J/mol.K for proteins.

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    The document discusses the calculation of estimated Cp values for various functional groups and amino acid components of proteins using the Joback method. It provides tables of ΔCp values for different functional groups from Perry (1999) and estimates the Cp of individual amino acids like isoleucine, leucine, lysine, etc. constituting a typical 21 gram portion of protein by summing the contribution of their functional groups. These individual amino acid Cp values are then weighted according to their composition in protein to obtain an estimated Cp of 611.904 J/mol.K for proteins.

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    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd
    Download as doc, pdf, or txt
    73 views3 pages

    Perhitungan CP Protein

    Uploaded by

    Hardi
    The document discusses the calculation of estimated Cp values for various functional groups and amino acid components of proteins using the Joback method. It provides tables of ΔCp values for different functional groups from Perry (1999) and estimates the Cp of individual amino acids like isoleucine, leucine, lysine, etc. constituting a typical 21 gram portion of protein by summing the contribution of their functional groups. These individual amino acid Cp values are then weighted according to their composition in protein to obtain an estimated Cp of 611.904 J/mol.K for proteins.

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    © All Rights Reserved
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    of 3

     Perhitungan estimasi Cpi dengan Metode Joback :

    Data harga ∆Cpi beberapa gugus dapat dilihat pada Tabel 2-394 Perry (1999).

    Tabel LB.2 Nilai ∆Cpi Beberapa Gugus untuk Estimasi Kapasitas Panas Cairan
    (Perry, 1999)
    Gugus ∆Cpi (J/mol.K)
    -CH- 20,92
    -CC- 7,36
    -CC= 15,90
    -NH- 87,86
    -CN- 58,16
    -CO= 52,97
    -CO- 111,29
    -OH- 44,77
    Sumber: Perry (1999)

     Perhitungan Estimasi Cp Protein


    Tabel LB.3 senyawa kandungan didalam protein per 21 gram (Putri, dkk., 2013)
    Komposisi Bobot berat
    Isoleosin 2,5
    Leucine 4,9
    Lysine 2,7
    Phenylanine 2,9
    Tyrosine 1,7
    Methiosine 1,5
    Thereonine 2,3
    Triptofan 0,6
    Valine 3,8

    a. Isoleosin (C6H13NO2)
    Cpl = 6 (-CH-) + 6 (-CC-) + 2 (-NH-) + 1 (-CN-) + 1 (-CO=) + 1 (-
    CO-) + 1 (-OH-)
    = 6 (20,92) + 6 (7,36) + 2 (43,93) + 1 (58,16) + 1 (52,97) + 1
    (111,29) + 1 (44,77)
    = 524,73 J/mol.K

    b. Leucine (C57H110O6)

    LB-1
    Cpl = 1 (-CO=) + 1 (-CO-) + 1 (-OH-) + 5 (-CC-) + 5 (-NH-) + 8 (-
    CH) + 1 (-CN-)
    = 1 (52,97) + 1 (111,29) + 1 (44,77) + 5 (7,36) + 5 (43,93) + 8
    (20,92) + 1 (58,16)
    = 691 J/mol.K

    c. Lysine (C6H14O2N2)
    Cpl = 2 (-CN-) + 5 (-CC-) + 5 (-NH-) + 9 (-CH-) + 2 (-CO-)
    = 2 (58,16) + 5 (7,36) + 5 (43,93) + 9 (20,92) + 2 (111,29)
    = 783,63 J/mol.K

    d. Phenylalanine (C9H11O6)
    Cpl = 3 (-CC=) + 6 (-CC-) + 3 (-NH-) + 2 (-CO-)
    = 3 (15,90) + 6 (7,36) + 3 (43,93) + 2 (111,58)
    = 446,23 J/mol.K

    e. Tyrosine (C9H11NO3)
    Cpl = 3 (-CH=) + 1 (-CH-) + 32 (-CH2-) + 3 (-CH3-) + 3 (-COO-)
    = 18 (21,76) + 1 (20,92) + 32 (30,38) + 3 (36,82) + 3 (60,67)
    = 1.677,23 J/mol.K

    f. Methionine (C5H11NO2S)
    Cpl = 7 (-CH-) + 2 (-CS-) + 3 (-CC-) + 1 (-CO=) + 1 (-COOH-) + 2 (-
    NH-)
    = 7 (20,92) + 2 (26,11) + 3 (7,36) + 1 (52,97) + 1(79,91) + 2
    (43,93)
    = 441,48 J/mol.K

    g. Thereonin (C4H9NO3)
    Cpl = 3 (-CH-) + 3 (-CC-) + 1 (-COOH-) + 2 (-OH-) + 2 (-NH-) + 2 (-
    CO-)
    = 3 (20,92) + 3 (7,36) + 1 (79,91) + 2 (44,77) + 2 (43,93) + 2
    (111,29)
    = 564,73 J/mol.K

    LB-2
    h. Triptofan (C11H12N2O2)
    Cpl = 4 (-CC=) + 7 (-CC-) + 3 (-NH-) + 3 (-CN-) + 1 (-COOH-) + 8 (-
    CH-)
    = 4 (15,90) + 7 (7,36) + 3 (43,93) + 3 (58,16) + 1 (79,91) + 8 (-
    20,92)
    = 668,66 J/mol.K

    i. Valine (C5H11NO2)
    Cpl = 1 (-COOH-) + 6 (-CH-) + 2 (-NH-) + 4 (-CC-) + 1 (-CN-)
    = 1 (79,91) + 6 (20,92) + 2 (43,93) + 4 (7,36) + 1 (58,16)
    = 380,89 J/mol.K

    Komposisi trigliserida ditunjukkan pada Tabel LA.2.


    Cp Protein =  x . Cp l

    = 0,119 (524,73) + 0,233 (691) + 0,129 (783,63) + 0,138


    (446,23) + 0,089 (500,65) + 0,071 (441,48) + 0,109
    (564,73) + 0,029 (668,66) + 0,181 (380,89)
    = 611,904 J/mol.K

    LB-3

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