Chem-Aqua 15000MT
Chem-Aqua 15000MT
Chem-Aqua 15000MT
2. HAZARDS IDENTIFICATION
Emergency Overview
DANGER
Corrosive
Causes skin and eye burns
May cause delayed lung injury and burns
Harmful or fatal if swallowed
Component CAS-No
2-Phosphonobutane-1,2,4-tricarboxylic acid, sodium salt 40372-66-5
Sodium hydroxide 1310-73-2
Sodium polyacrylate 9003-04-7
Polymaleic acid, sodium salt 70247-90-4
Tolyltriazole Sodium Salt 64665-57-2
Sodium molybdate 7631-95-0
General advice Do not get in eyes, on skin or on clothing. Do not breathe mist.
Eye Contact Immediately flush eyes for at least 15 minutes. Get medical attention. Get medical attention
immediately.
Skin Contact Remove immediately all contaminated clothing. Wash off immediately with plenty of water for at least
15 minutes. Get medical attention immediately.
Inhalation Move to fresh air. In case of shortness of breath, give oxygen. If breathing has stopped, apply artificial
respiration. Get medical attention immediately.
Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately. Never give
anything by mouth to an unconscious person.
Notes to physician The product causes burns of eyes, skin and mucous membranes. Control of circulatory system, shock
therapy if needed.
5. FIRE-FIGHTING MEASURES
Page 1 / 4
775C - CHEM-AQUA 15000MT Issuing Date 07/17/2014
surrounding environment.
Specific hazards arising from the chemical
Contact with metals may evolve flammable hydrogen gas. Material can create slippery conditions.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
NFPA Health 3 Flammability 1 Instability 0
HMIS Health 3 Flammability 1 Instability 0
Personal Precautions Use personal protective equipment. Ensure adequate ventilation. Material can create slippery
conditions.
Environmental Precautions Do not flush into surface water or sanitary sewer system.
Methods for Containment Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous
earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see
section 13)
Methods for Cleaning Up Pick up and transfer to properly labeled containers.
Neutralizing Agent Acetic acid, diluted.
Exposure Guidelines
Component ACGIH TLV OSHA PEL NIOSH
Sodium hydroxide Ceiling: 2 mg/m3 TWA: 2 mg/m3 10 mg/m3
Ceiling: 2 mg/m3
Sodium polyacrylate 3 mg/m3 PNOS 5 mg/m3 PNOR No data available
Sodium molybdate TWA: 0.5 mg/m3 TWA: 5 mg/m3 No data available
Engineering Measures Ensure adequate ventilation, especially in confined areas. Where reasonably practicable this should
be achieved by the use of local exhaust ventilation and good general extraction.
Personal Protective Equipment
Eye/Face Protection Tightly fitting safety goggles. Face-shield.
Skin Protection Wear suitable protective clothing, Impervious gloves.
Respiratory Protection In case of inadequate ventilation wear respiratory protection. When workers are facing concentrations
above the exposure limit they must use appropriate certified respirators.
General Hygiene Considerations Wear protective gloves/clothing. Ensure that eyewash stations and safety showers are close to the
workstation location. Remove and wash contaminated clothing before re-use.
Page 2 / 4
775C - CHEM-AQUA 15000MT Issuing Date 07/17/2014
Component Information
Acute Toxicity
Component LD50 Oral LD50 Dermal LC50 Inhalation Draize Test Other
Sodium hydroxide no data available = 1350 mg/kg ( Rabbit ) no data available no data available no data available
Sodium polyacrylate 5000 mg/kg 2000 mg/kg no data available no data available no data available
Sodium molybdate = 4000 mg/kg ( Rat ) no data available > 2080 mg/m3 ( Rat ) 4 h no data available no data available
Chronic Toxicity
Component Mutagenicity Sensitization Developmental Toxicity Reproductive Toxicity Target Organ Effects
Sodium hydroxide no data available no data available no data available no data available eyes, respiratory system,
skin
Sodium molybdate no data available no data available no data available no data available respiratory system, eyes,
kidneys, blood, bone,
pancreas
Carcinogenicity
Component ACGIH IARC NTP OSHA Other
Sodium molybdate A3 not applicable not applicable not applicable not applicable
Product Information
Toxicity to fish
Pimephales promelas (fathead minnow) LC50 1,588 mg/L 96h
Component Information
Component Toxicity to Algae Toxicity to Fish Microtox Water Flea log Pow
Sodium hydroxide no data available LC50 = 45.4 mg/L Oncorhynchus no data available no data available N/A
mykiss 96 h
DOT
Proper Shipping Name Corrosive liquid, basic, inorganic, n.o.s.
Hazard Class 8
UN-No UN3266
Packing Group II
Description UN3266, Corrosive liquid, basic, inorganic, n.o.s.,(Sodium tolytriazole, Sodium hydroxide), 8, PG II
TDG
Proper shipping name Corrosive liquid, basic, inorganic, n.o.s.
Hazard Class 8
UN-No UN3266
Packing Group II
Description UN3266, Corrosive liquid, basic, inorganic, n.o.s.,(Sodium tolytriazole, Sodium hydroxide), 8, PG II
ICAO
UN-No UN3266
Proper Shipping Name Corrosive liquid, basic, inorganic, n.o.s.
Hazard Class 8
Packing Group II
Shipping Description UN3266, Corrosive liquid, basic, inorganic, n.o.s.,(Sodium tolytriazole, Sodium hydroxide), 8, PG II
Page 3 / 4
775C - CHEM-AQUA 15000MT Issuing Date 07/17/2014
IATA
UN-No UN3266
Proper Shipping Name Corrosive liquid, basic, inorganic, n.o.s.
Hazard Class 8
Packing Group II
Shipping Description UN3266, Corrosive liquid, basic, inorganic, n.o.s.,(Sodium tolytriazole, Sodium hydroxide), 8, PG II
IMDG/IMO
Proper Shipping Name Corrosive liquid, basic, inorganic, n.o.s.
Hazard Class 8
UN-No UN3266
Packing Group II
Shipping Description UN3266, Corrosive liquid, basic, inorganic, n.o.s.,(Sodium tolytriazole, Sodium hydroxide), 8, PG II
Inventories
TSCA Complies
DSL Complies
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which
are subject to the reporting requirements of the Act and and Title 40 of the Code of Federal Regulations, Part 372.
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains
all the information required by the CPR.
WHMIS Hazard Class
E Corrosive material D2B Toxic materials
Page 4 / 4