Location via proxy:   [ UP ]  
[Report a bug]   [Manage cookies]                
Scribd Logo
Upload

Welcome to Scribd!

  • 72 views

    Sulfida

    Uploaded by

    Fendi Setyo Budi
    This document describes the iodometric method for determining sulfide concentration in a sample. The method involves titrating an excess of iodine solution added to the sample with a standard sodium thiosulfate solution until the blue starch indicator color disappears. The sulfide concentration is then calculated based on the volumes and normalities of the iodine and thiosulfate solutions used. The precision of the method depends on the clarity of the sample endpoint, and can determine sulfide concentration within 0.1 mg/L for a 200 mL clean water sample. Quality control procedures summarized in Table 4020:I should also be followed.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd

    Sulfida

    Uploaded by

    Fendi Setyo Budi
    72 views3 pages
    This document describes the iodometric method for determining sulfide concentration in a sample. The method involves titrating an excess of iodine solution added to the sample with a standard sodium thiosulfate solution until the blue starch indicator color disappears. The sulfide concentration is then calculated based on the volumes and normalities of the iodine and thiosulfate solutions used. The precision of the method depends on the clarity of the sample endpoint, and can determine sulfide concentration within 0.1 mg/L for a 200 mL clean water sample. Quality control procedures summarized in Table 4020:I should also be followed.

    Original Title

    sulfida

    Copyright

    © © All Rights Reserved

    Available Formats

    DOCX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    This document describes the iodometric method for determining sulfide concentration in a sample. The method involves titrating an excess of iodine solution added to the sample with a standard sodium thiosulfate solution until the blue starch indicator color disappears. The sulfide concentration is then calculated based on the volumes and normalities of the iodine and thiosulfate solutions used. The precision of the method depends on the clarity of the sample endpoint, and can determine sulfide concentration within 0.1 mg/L for a 200 mL clean water sample. Quality control procedures summarized in Table 4020:I should also be followed.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    72 views3 pages

    Sulfida

    Uploaded by

    Fendi Setyo Budi
    This document describes the iodometric method for determining sulfide concentration in a sample. The method involves titrating an excess of iodine solution added to the sample with a standard sodium thiosulfate solution until the blue starch indicator color disappears. The sulfide concentration is then calculated based on the volumes and normalities of the iodine and thiosulfate solutions used. The precision of the method depends on the clarity of the sample endpoint, and can determine sulfide concentration within 0.1 mg/L for a 200 mL clean water sample. Quality control procedures summarized in Table 4020:I should also be followed.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    You are on page 1of 3

    4500-S2— F.

    Iodometric Method
    1. Reagents

    a. Hydrochloric acid (HCl), 6N.


    b. Standard iodine solution, 0.0250N: Dissolve 20 to 25 g KI in a little water and add 3.2 g
    iodine. After iodine has dissolved, dilute to 1000 mL and standardize against 0.0250 N Na2S2O3,
    using starch solution as indicator.
    c. Standard sodium thiosulfate solution, 0.0250N: See Section 4500-O.C.2e.
    d. Starch solution: See Section 4500-O.C.2d.

    2. Procedure

    a. Measure from a buret into a 500-mL flask an amount of iodine solution estimated to be an
    excess over the amount of sulfide present. Add distilled water, if necessary, to bring volume to
    about 20 mL. Add 2 mL 6N HCl. Pipet 200 mL sample into flask, discharging sample under
    solution surface. If iodine color disappears, add more iodine until color remains. Back-titrate with
    Na2S2O3 solution, adding a few drops of starch solution as endpoint is approached, and continuing
    until blue color disap- pears.
    b. If sulfide was precipitated with zinc and ZnS filtered out, return filter with precipitate to
    original bottle and add about 100 mL water. Add iodine solution and HCl and titrate as in ¶ a
    above.
    3. Calculation

    One milliliter 0.0250N iodine solution reacts with 0.4 mg S2—:

    [(A × B) — (C × D)] × 16 000


    mg S2—/L =
    mL sample

    where:

    A = mL iodine solution,

    B = normality of iodine solution,

    C = mL Na2S2O3 solution, and

    D = normality of Na2S2O3 solution.

    4. Precision

    The precision of the endpoint varies with the sample. In clean waters it should be
    determinable within 1 drop, which is equiv- alent to 0.1 mg/L in a 200-mL sample.

    5. Quality Control

    The quality control practices considered to be an integral part of each method are
    summarized in Table 4020:I.

    You might also like