AUTOTREAT

Wilhelmsen Ships Service AS

Catalogue number: 698720 Issue Date: 29/11/2018
Version No: 4.4 Print Date: 10/04/2020
Safety Data Sheet L.GHS.NOR.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier
Product name AUTOTREAT

Synonyms Product Part Number: 698720 (25 liter). Pr No: 52699

Proper shipping name POTASSIUM HYDROXIDE SOLUTION
Other means of
698720, 698720
identification

Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Water treatment

Details of the supplier of the safety data sheet

Outback (M)SDS portal:
Wilhelmsen Ships Service AS*
Registered company name Wilhelmsen Ships Service AS http://jr.chemwatch.net/outb/account
Central Warehouse
/autologin?login=wilhelmsen
--------Use our Outback portal to obtain our
(M)SDSs in other languages and/or
Strandveien 20 Lysaker 1366 format.--------- For questions relating to our Willem Barentszstraat 50 Rotterdam
Address
Norway SDSs please use Email: Netherlands
WSS.GLOBAL.SDSINFO@wilhelmsen.com
--------- Norway

Telephone +47 67 58 40 00 Not Available +31 10 4877 777

Fax Not Available Not Available +31 10 4877888
Website http://www.wilhelmsen.com/ http://www.wilhelmsen.com http://www.wilhelmsen.com
Email wss.norway.cs@wilhelmsen.com wss.global.sdsinfo@wilhelmsen.com wss.rotterdam@wilhelmsen.com

Emergency telephone number

American Chemistry Council 24hrs
Association / Organisation Giftinformasjonssentralen - 24 timer Dutch nat. poison centre
- Chemtrec
Emergency telephone
+47 22591300 +1 703 527 3887 + 31 30 274 88 88
numbers

Other emergency
Not Available +1 800 424 9300 Not Available
telephone numbers

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

Classification according to H290 - Metal Corrosion Category 1, H302 - Acute Toxicity (Oral) Category 4, H314 - Skin Corrosion/Irritation Category 1A

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AUTOTREAT

regulation (EC) No
1272/2008 [CLP] [1]
Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI

Label elements

Hazard pictogram(s)

SIGNAL WORD DANGER

Hazard statement(s)
H290 May be corrosive to metals.

H302 Harmful if swallowed.

H314 Causes severe skin burns and eye damage.

Precautionary statement(s) General

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.

P103 Read label before use.

Precautionary statement(s) Prevention

P260 Do not breathe mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P234 Keep only in original packaging.

P270 Do not eat, drink or smoke when using this product.

Precautionary statement(s) Response

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor/physician/first aider.
P321 Specific treatment (see advice on this label).
P363 Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Precautionary statement(s) Storage

P405 Store locked up.

Precautionary statement(s) Disposal

P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances
See section below for composition of Mixtures

Mixtures
CAS No %[weight] Name Classification according to regulation (EC) No 1272/2008 [CLP]
potassium
1310-58-3 5-10 Skin Corrosion/Irritation Category 1A, Acute Toxicity (Oral) Category 4; H314, H302 [2]
hydroxide

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AUTOTREAT

Acute Toxicity (Oral) Category 4, Skin Corrosion/Irritation Category 1B, Flammable Liquid
100-37-8 1-5 diethylaminoethanol Category 3, Acute Toxicity (Dermal) Category 4, Acute Toxicity (Inhalation) Category 4;
H302, H314, H226, H312, H332 [2]
Acute Toxicity (Inhalation) Category 4, Skin Corrosion/Irritation Category 1B, Acute
141-43-5 1-5 ethanolamine * Toxicity (Oral) Category 4, Acute Toxicity (Dermal) Category 4; H332, H314, H302, H312
[2]

Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from
C&L; * EU IOELVs available

SECTION 4 FIRST AID MEASURES

Description of first aid measures

If this product comes in contact with the eyes:

Immediately hold eyelids apart and flush the eye continuously with running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally
Eye Contact
lifting the upper and lower lids.
Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
Transport to hospital or doctor without delay.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

If skin or hair contact occurs:

Immediately flush body and clothes with large amounts of water, using safety shower if available.
Skin Contact Quickly remove all contaminated clothing, including footwear.
Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre.
Transport to hospital, or doctor.
If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid
procedures.
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket
mask as trained. Perform CPR if necessary.
Transport to hospital, or doctor, without delay.
Inhalation Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema.
Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs).
As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in
semi-recumbent posture) and must be kept under medical observation even if no symptoms are (yet) manifested.
Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone
derivative may be considered.
This must definitely be left to a doctor or person authorised by him/her.
(ICSC13719)

For advice, contact a Poisons Information Centre or a doctor at once.

Urgent hospital treatment is likely to be needed.
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and
Ingestion prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Transport to hospital or doctor without delay.

Indication of any immediate medical attention and special treatment needed

For acute or short-term repeated exposures to highly alkaline materials:
Respiratory stress is uncommon but present occasionally because of soft tissue edema.
Unless endotracheal intubation can be accomplished under direct vision, cricothyroidotomy or tracheotomy may be necessary.
Oxygen is given as indicated.
The presence of shock suggests perforation and mandates an intravenous line and fluid administration.
Damage due to alkaline corrosives occurs by liquefaction necrosis whereby the saponification of fats and solubilisation of proteins allow deep penetration into
the tissue.
Alkalis continue to cause damage after exposure.
INGESTION:
Milk and water are the preferred diluents
No more than 2 glasses of water should be given to an adult.
Neutralising agents should never be given since exothermic heat reaction may compound injury.
* Catharsis and emesis are absolutely contra-indicated.
* Activated charcoal does not absorb alkali.
* Gastric lavage should not be used.
Supportive care involves the following:
Withhold oral feedings initially.
If endoscopy confirms transmucosal injury start steroids only within the first 48 hours.
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Carefully evaluate the amount of tissue necrosis before assessing the need for surgical intervention.
Patients should be instructed to seek medical attention whenever they develop difficulty in swallowing (dysphagia).
SKIN AND EYE:
Injury should be irrigated for 20-30 minutes.
Eye injuries require saline. [Ellenhorn & Barceloux: Medical Toxicology]

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media
Water spray or fog.
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.

Special hazards arising from the substrate or mixture

Fire Incompatibility None known.

Advice for firefighters

Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or water course.
Fire Fighting Use fire fighting procedures suitable for surrounding area.
Do not approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.
Fire/Explosion Hazard May emit corrosive fumes.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

See section 8

Environmental precautions
See section 12

Methods and material for containment and cleaning up

Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or
disposal of material.
Check regularly for spills and leaks.
Clean up all spills immediately.
Minor Spills Avoid breathing vapours and contact with skin and eyes.
Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Wipe up.
Place in a suitable, labelled container for waste disposal.

Chemical Class: bases

For release onto land: recommended sorbents listed in order of priority.

SORBENT
RANK APPLICATION COLLECTION LIMITATIONS
TYPE

LAND SPILL - SMALL

cross-linked polymer - particulate 1 shovel shovel R,W,SS

cross-linked polymer - pillow 1 throw pitchfork R, DGC, RT

sorbent clay - particulate 2 shovel shovel R, I, P

Major Spills
foamed glass - pillow 2 throw pitchfork R, P, DGC, RT
expanded minerals - particulate 3 shovel shovel R, I, W, P, DGC

foamed glass - particulate 4 shovel shovel R, W, P, DGC,

LAND SPILL - MEDIUM

cross-linked polymer -particulate 1 blower skiploader R,W, SS

sorbent clay - particulate 2 blower skiploader R, I, P

expanded mineral - particulate 3 blower skiploader R, I,W, P, DGC

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cross-linked polymer - pillow 3 throw skiploader R, DGC, RT

foamed glass - particulate 4 blower skiploader R, W, P, DGC

foamed glass - pillow 4 throw skiploader R, P, DGC., RT

Legend
DGC: Not effective where ground cover is dense
R; Not reusable
I: Not incinerable
P: Effectiveness reduced when rainy
RT:Not effective where terrain is rugged
SS: Not for use within environmentally sensitive sites
W: Effectiveness reduced when windy
Reference: Sorbents for Liquid Hazardous Substance Cleanup and Control;
R.W Melvold et al: Pollution Technology Review No. 150: Noyes Data Corporation 1988
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or water course.
Stop leak if safe to do so.
Contain spill with sand, earth or vermiculite.
Collect recoverable product into labelled containers for recycling.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Safe handling WARNING: To avoid violent reaction, ALWAYS add material to water and NEVER water to material.
Avoid smoking, naked lights or ignition sources.
Avoid contact with incompatible materials.
When handling, DO NOT eat, drink or smoke.
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Other information
Protect containers against physical damage and check regularly for leaks.
Observe manufacturer's storage and handling recommendations contained within this SDS.
DO NOT store near acids, or oxidising agents
No smoking, naked lights, heat or ignition sources.

Conditions for safe storage, including any incompatibilities

Lined metal can, lined metal pail/ can.
Plastic pail.
Polyliner drum.
Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
For low viscosity materials
Drums and jerricans must be of the non-removable head type.
Where a can is to be used as an inner package, the can must have a screwed enclosure.
Suitable container For materials with a viscosity of at least 2680 cSt. (23 deg. C) and solids (between 15 C deg. and 40 deg C.):
Removable head packaging;
Cans with friction closures and
low pressure tubes and cartridges
may be used.
-
Where combination packages are used, and the inner packages are of glass, porcelain or stoneware, there must be sufficient
inert cushioning material in contact with inner and outer packages unless the outer packaging is a close fitting moulded plastic
box and the substances are not incompatible with the plastic.
Sodium hydroxide/ potassium hydroxide:
reacts with water evolving heat and corrosive fumes
reacts violently with acids, trans-acetylene dichloride, aminotetrazole, p-bis(1,3-dibromoethyl), benzene, bromoform,
halogenated compounds, nitrogen-containing compounds, organic halogens, chlorine dioxide ((explodes), chloroform,
Storage incompatibility
cresols, cyclopentadiene, 4-chloro-2-methylphenol, cis-dichloroethylene, 2,2-dichloro-3,3-dimethylbutane, ethylene
chlorohydrin, germanium, iodine pentafluoride, maleic anhydride, p-nitrotoluene,nitrogen trichloride, o-nitrophenol,
phosphonium iodide, potassium peroxodisulfate, propylene oxide, 1,2,4,5-tetrachlorobenzene (highly toxic substance is
forme), 2,2,3,3-tetrafluoro-1-propanol, tetrahydrofuran, thorium dicarbide, trichloroethanol, 2,4,6-trinitrotoluene, vinyl acetate

Continued...
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AUTOTREAT

reacts with fluorine, nitroalkanes, (forming explosive compounds)

incompatible with acetic acid, acetaldehyde, acetic anhydride, acrolein, acrylonitrile, allyl chloride, organic anhydride,
acrylates, alcohols, aldehydes, alkylene oxides, substituted allyls, ammonium chloroplatinate, benzanthrone, bromine,
benzene-1,4-diol, carbon dioxide, cellulose nitrate, chlorine trifluoride, 4-chlorobutyronitrile, chlorohydrin, chloronitrotoluenes,
chlorosulfonic acid, cinnamaldehyde, caprolactam solution, chlorocresols, 1,2-dichloroethylene, epichlorohydrin, ethylene
cyanohydrin, formaldehyde (forms formic acid and flammable hydrogen gas), glycols, glyoxal, hexachloroplatinate, hydrogen
sulfide, hydroquinone, iron-silicon, isocyanates, ketones, methyl azide, 4-methyl-2-nitrophenol, mineral acids (forming
corresponding salt),nitrobenzene, N-nitrosohydroxylamine, nitrates pentol, phenols, phosphorus, phosphorus pentaoxide,
beta-propiolactone, sodium, sulfur dioxide, tetrahydroborate, 1,1,1,2-tetrachloroethane, 2,2,2-trichloroethanol,
trichloronitromethane, zirconium
ignites on contact with cinnamaldehyde or zinc and reacts explosively with a mixture of chloroform and methane
forms heat-, friction-, and/ or shock-sensitive- explosive salts with nitro-compounds, cyanogen azide, 3-ethyl-4-hydroxy-1,2,5-
oxadiazole, 3-methyl-2-penten-4-yn-1-ol, N,N'-bis(2,2,2-trinitroethyl)urea, trichloroethylene (forms dichloroacetylene)
increase the explosive sensitivity of nitromethane
attacks some plastics, rubber, coatings and metals: aluminium, tin, zinc,etc, and their alloys, producing flammable hydrogen
gas

Reacts vigorously with acids

Avoid strong acids, acid chlorides, acid anhydrides and chloroformates.
Avoid contact with copper, aluminium and their alloys.

+ X + X + + +

X — Must not be stored together

0 — May be stored together with specific preventions
+ — May be stored together

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes

Norway regulations on action

rvalues o​ a nd limitf values ​
physical and chemical
factors in the work potassium hydroxide Kaliumhydroksid Not Available Not Available 2 mg/m3 T
environment and infection
risk groups for biological
factors (Norwegian)

Norway regulations on action

rvalues o​ a nd limitf values ​
physical and chemical
factors in the work diethylaminoethanol 2-(dietylamino)etanol 10 ppm / 50 mg/m3 Not Available Not Available H
environment and infection
risk groups for biological
factors (Norwegian)

EU Consolidated List of
Indicative Occupational
ethanolamine 2-Aminoethanol 1 ppm / 2.5 mg/m3 7.6 mg/m3 / 3 ppm Not Available Skin
Exposure Limit Values
(IOELVs)

Norway regulations on action

rvalues o​ a nd limitf values ​
physical and chemical
factors in the work ethanolamine 2-aminoetanol 1 ppm / 2,5 mg/m3 Not Available Not Available HE
environment and infection
risk groups for biological
factors (Norwegian)

EMERGENCY LIMITS

Ingredient Material name TEEL-1 TEEL-2 TEEL-3

potassium hydroxide Potassium hydroxide 0.18 mg/m3 2 mg/m3 54 mg/m3

diethylaminoethanol Diethylethanolamine, N,N-; (Diethylaminoethanol) 6 ppm 83 ppm 500 ppm

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ethanolamine Ethanolamine 6 ppm 170 ppm 1,000 ppm

Ingredient Original IDLH Revised IDLH

potassium hydroxide Not Available Not Available

diethylaminoethanol 100 ppm Not Available

ethanolamine 30 ppm Not Available

MATERIAL DATA
for potassium hydroxide:
The TLV-TWA is protective against respiratory tract irritation produced at higher concentrations
For diethylaminoethanol:
Odour Threshold Value: 0.011 ppm (detection), 0.040 ppm (recognition)
The TLV-TWA is thought to be protective against irritation and sensitisation.
Odour Safety Factor(OSF)
OSF=1.8E2 (2-DIETHYLAMINOETHANOL)
for monoethanolamine:
Odour threshold: 3-4 ppm.
Continuous exposure at 5 ppm produced only slight systemic effects. Intermittent exposure produces a lesser degree of toxicity in laboratory animals. This
decreased toxicity is related to the rate of elimination;
the longer retained, the greater the toxicity,. The TLV-TWA is thought to be protective against the risk of irritation and neuropathic effects.
Odour Safety Factor (OSF)
OSF=0.77 (ETHANOL AMINE)

Exposure controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed
engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to
provide this high level of protection.
The basic types of engineering controls are:
Appropriate engineering
Process controls which involve changing the way a job activity or process is done to reduce the risk.
controls
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation
that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if
designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use.
Employers may need to use multiple types of controls to prevent employee overexposure.

Personal protection

Safety glasses with unperforated side shields may be used where continuous eye protection is desirable, as in laboratories;
spectacles are not sufficient where complete eye protection is needed such as when handling bulk-quantities, where there is
a danger of splashing, or if the material may be under pressure.
Chemical goggles.whenever there is a danger of the material coming in contact with the eyes; goggles must be properly
fitted.
Eye and face protection Full face shield (20 cm, 8 in minimum) may be required for supplementary but never for primary protection of eyes; these
afford face protection.
Alternatively a gas mask may replace splash goggles and face shields.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy
document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should
include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience.
Skin protection See Hand protection below

Elbow length PVC gloves

Hands/feet protection
When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.
Body protection See Other protection below

Overalls.
PVC Apron.
Other protection PVC protective suit may be required if exposure severe.
Eyewash unit.
Ensure there is ready access to a safety shower.

Recommended material(s)
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the computer-generated selection:
AUTOTREAT

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Material CPI
BUTYL C

NATURAL RUBBER C
NATURAL+NEOPRENE C

NEOPRENE C
NITRILE C

NITRILE+PVC C

PVA C

PVC C

VITON C

* CPI - Chemwatch Performance Index

A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the glove, a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent basis, factors such as "feel" or convenience (e.g. disposability), may dictate a choice of
gloves which might otherwise be unsuitable following long-term or frequent use. A qualified practitioner should be consulted.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance Pale yellow liquid with no odour; soluble in water.

Relative density (Water =

Physical state Liquid 1.105 - 1.125
1)
Partition coefficient
Odour Not Available Not Available
n-octanol / water
Auto-ignition temperature
Odour threshold Not Available Not Available
(°C)
Decomposition
pH (as supplied) 13-14 Not Available
temperature

Melting point / freezing

Not Available Viscosity (cSt) Not Available
point (°C)

Initial boiling point and

>100-760 Molecular weight (g/mol) Not Available
boiling range (°C)

Flash point (°C) >62 Taste Not Available

Evaporation rate Not Available Explosive properties Not Available

Flammability Combustible. Oxidising properties Not Available

Surface Tension (dyn/cm

Upper Explosive Limit (%) Not Available Not Available
or mN/m)

Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available

Solubility in water Miscible pH as a solution (1%) Not Available

Vapour density (Air = 1) Not Available VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7

Unstable in the presence of incompatible materials.

Chemical stability Product is considered stable.
Hazardous polymerisation will not occur.

Possibility of hazardous
See section 7
reactions

Conditions to avoid See section 7

Incompatible materials See section 7

Hazardous decomposition
See section 5
products

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SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Evidence shows, or practical experience predicts, that the material produces irritation of the respiratory system, in a substantial
number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to a chemical insult by first
removing or neutralising the irritant and then repairing the damage. The repair process, which initially evolved to protect
mammalian lungs from foreign matter and antigens, may however, produce further lung damage resulting in the impairment of
gas exchange, the primary function of the lungs. Respiratory tract irritation often results in an inflammatory response involving the
recruitment and activation of many cell types, mainly derived from the vascular system.
Inhalation of alkaline corrosives may produce irritation of the respiratory tract with coughing, choking, pain and mucous
membrane damage. Pulmonary oedema may develop in more severe cases; this may be immediate or in most cases following a
Inhaled latent period of 5-72 hours. Symptoms may include a tightness in the chest, dyspnoea, frothy sputum, cyanosis and dizziness.
Findings may include hypotension, a weak and rapid pulse and moist rales.
Inhalation of of potassium hydroxide dust may be fatal due to spasm, inflammation and oedema of the larynx and bronchi,
chemical pneumonitis and severe pulmonary oedema. Symptoms of overexposure include burning sensation, coughing,
wheezing, laryngitis, shortness of breath, headache, nausea and vomiting
The material has NOT been classified by EC Directives or other classification systems as "harmful by inhalation". This is because
of the lack of corroborating animal or human evidence. In the absence of such evidence, care should be taken nevertheless to
ensure exposure is kept to a minimum and that suitable control measures be used, in an occupational setting to control vapours,
fumes and aerosols.
Ingestion of alkaline corrosives may produce immediate pain, and circumoral burns. Mucous membrane corrosive damage is
characterised by a white appearance and soapy feel; this may then become brown, oedematous and ulcerated. Profuse
salivation with an inability to swallow or speak may also result. Even where there is limited or no evidence of chemical burns,
both the oesophagus and stomach may experience a burning pain; vomiting and diarrhoea may follow. The vomitus may be thick
and may be slimy (mucous) and may eventually contain blood and shreds of mucosa. Epiglottal oedema may result in respiratory
distress and asphyxia. Marked hypotension is symptomatic of shock; a weak and rapid pulse, shallow respiration and clammy
Ingestion skin may also be evident.
The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because
of the lack of corroborating animal or human evidence. The material may still be damaging to the health of the individual,
following ingestion, especially where pre-existing organ (e.g liver, kidney) damage is evident. Present definitions of harmful or
toxic substances are generally based on doses producing mortality rather than those producing morbidity (disease, ill-health).
Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupational setting however, ingestion of insignificant
quantities is not thought to be cause for concern.
The material can produce severe chemical burns following direct contact with the skin.
Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce
health damage following entry through wounds, lesions or abrasions.
Potassium hydroxide burns are not immediately painful; onset of pain may be delayed minutes or hours; thus care should be
taken to avoid contamination of gloves and boots.
Skin Contact
Skin contact with alkaline corrosives may produce severe pain and burns; brownish stains may develop. The corroded area may
be soft, gelatinous and necrotic; tissue destruction may be deep.
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with
harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
Direct contact with alkaline corrosives may produce pain and burns. Oedema, destruction of the epithelium, corneal opacification
and iritis may occur. In less severe cases these symptoms tend to resolve. In severe injuries the full extent of the damage may
Eye
not be immediately apparent with late complications comprising a persistent oedema, vascularisation and corneal scarring,
permanent opacity, staphyloma, cataract, symblepharon and loss of sight.

Repeated or prolonged exposure to corrosives may result in the erosion of teeth, inflammatory and ulcerative changes in the
mouth and necrosis (rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumonia may ensue.
Gastrointestinal disturbances may also occur. Chronic exposures may result in dermatitis and/or conjunctivitis.
Chronic Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and related systemic
problems.
Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving
organs or biochemical systems.

TOXICITY IRRITATION
AUTOTREAT
Not Available Not Available

TOXICITY IRRITATION

Oral (rat) LD50: =214-324 mg/kg[2] Eye (rabbit):1mg/24h rinse-moderate

potassium hydroxide
Skin (human): 50 mg/24h SEVERE

Skin (rabbit): 50 mg/24h SEVERE

TOXICITY IRRITATION

diethylaminoethanol Dermal (rabbit) LD50: 1108.8 mg/kg[2] Eye (rabbit) : 5 mg - SEVERE

Inhalation (mouse) LC50: 5 mg/l/4h[2] Eye: adverse effect observed (irritating)[1]

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AUTOTREAT

Oral (rat) LD50: 1300 mg/kg[2] Skin (rabbit): 10 mg/24h - open

Skin (rabbit): 500 mg-open - mild

Skin: adverse effect observed (corrosive)[1]

TOXICITY IRRITATION

ethanolamine Dermal (rabbit) LD50: 1000 mg/kg[2] Eye (rabbit): 0.76 mg - SEVERE

Oral (rat) LD50: >500 mg/kg[2] Skin (rabbit):505 mg open-moderate

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS.
Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may
produce conjunctivitis.
The material may produce severe skin irritation after prolonged or repeated exposure, and may produce a contact dermatitis
POTASSIUM HYDROXIDE
(nonallergic). This form of dermatitis is often characterised by skin redness (erythema) thickening of the epidermis.
Histologically there may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the epidermis.
Prolonged contact is unlikely, given the severity of response, but repeated exposures may produce severe ulceration.
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic).
This form of dermatitis is often characterised by skin redness (erythema) and swelling epidermis. Histologically there may be
intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the epidermis.
For diethylaminoethanol (DEAE)
DIETHYLAMINOETHANOL Acute toxicity: DEAE was rapidly absorbed via the oral route. It is presumably absorbed by dermal and inhalation routes of
administration. In the rat it was widely distributed to many tissues. It was primarily excreted unchanged via the urine in rats.
Excretion via the feces was also observed in rats, but to a lesser extent. Urinary excretion was also reported in humans. The
major metabolites in rats were reported to be diethylaminoacetic acid and diethyl-(2- hydroxyethyl)-amino-oxide.
The LD50 for the rat after oral administration was 1320 mg/kg bw.
* Bayer
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic).
ETHANOLAMINE
This form of dermatitis is often characterised by skin redness (erythema) and swelling the epidermis. Histologically there may be
intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the epidermis.

Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a
non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high
levels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence of preceding respiratory disease,
AUTOTREAT &
in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes to hours of a documented
POTASSIUM HYDROXIDE
exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to severe bronchial
&
hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have
DIETHYLAMINOETHANOL
also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalation is an infrequent
& ETHANOLAMINE
disorder with rates related to the concentration of and duration of exposure to the irritating substance. Industrial bronchitis, on the
other hand, is a disorder that occurs as result of exposure due to high concentrations of irritating substance (often particulate in
nature) and is completely reversible after exposure ceases. The disorder is characterised by dyspnea, cough and mucus
production.

While it is difficult to generalise about the full range of potential health effects posed by exposure to the many different amine
compounds, characterised by those used in the manufacture of polyurethane and polyisocyanurate foams, it is agreed that
overexposure to the majority of these materials may cause adverse health effects.
Many amine-based compounds can induce histamine liberation, which, in turn, can trigger allergic and other physiological
effects, including bronchoconstriction or bronchial asthma and rhinitis.
Systemic symptoms include headache, nausea, faintness, anxiety, a decrease in blood pressure, tachycardia (rapid
heartbeat), itching, erythema (reddening of the skin), urticaria (hives), and facial edema (swelling). Systemic effects (those
affecting the body) that are related to the pharmacological action of amines are usually transient.
Typically, there are four routes of possible or potential exposure: inhalation, skin contact, eye contact, and ingestion.
Inhalation:
Inhalation of vapors may, depending upon the physical and chemical properties of the specific product and the degree and length
of exposure, result in moderate to severe irritation of the tissues of the nose and throat and can irritate the lungs.
DIETHYLAMINOETHANOL Products with higher vapour pressures have a greater potential for higher airborne concentrations. This increases the probability
& ETHANOLAMINE of worker exposure.
Higher concentrations of certain amines can produce severe respiratory irritation, characterised by nasal discharge, coughing,
difficulty in breathing, and chest pains.
Chronic exposure via inhalation may cause headache, nausea, vomiting, drowsiness, sore throat, bronchopneumonia, and
possible lung damage. Also, repeated and/or prolonged exposure to some amines may result in liver disorders, jaundice, and
liver enlargement. Some amines have been shown to cause kidney, blood, and central nervous system disorders in laboratory
animal studies.
While most polyurethane amine catalysts are not sensitisers, some certain individuals may also become sensitized to amines
and may experience respiratory distress, including asthma-like attacks, whenever they are subsequently exposed to even very
small amounts of vapor. Once sensitised, these individuals must avoid any further exposure to amines. Although chronic or
repeated inhalation of vapor concentrations below hazardous or recommended exposure limits should not ordinarily affect
healthy individuals, chronic overexposure may lead to permanent pulmonary injury, including a reduction in lung function,

Continued...
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AUTOTREAT

breathlessness, chronic bronchitis, and immunologic lung disease.

Inhalation hazards are increased when exposure to amine catalysts occurs in situations that produce aerosols, mists, or heated
vapors.

The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to
irritants may produce conjunctivitis.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

Serious Eye
STOT - Single Exposure
Damage/Irritation

Respiratory or Skin
STOT - Repeated Exposure
sensitisation

Mutagenicity Aspiration Hazard

Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification

SECTION 12 ECOLOGICAL INFORMATION

Toxicity

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

AUTOTREAT Not Not Not
Not Available Not Available
Available Available Available

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

LC50 96 Fish 80mg/L 4

potassium hydroxide
EC0 48 Crustacea <1mg/L 2

NOEC 24 Fish 28mg/L 2

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

LC50 96 Fish 1-780mg/L 2

EC50 48 Crustacea 83.6mg/L 2
diethylaminoethanol
EC50 72 Algae or other aquatic plants 28mg/L 2
EC10 72 Algae or other aquatic plants 7.6mg/L 2
NOEC 72 Algae or other aquatic plants 5mg/L 2

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

LC50 96 Fish 2-70mg/L 2

ethanolamine EC50 48 Crustacea 32.6mg/L 2

EC50 72 Algae or other aquatic plants 2.1mg/L 2

NOEC 504 Crustacea 0.85mg/L 2

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity
3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5.
ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8.
Vendor Data

Prevent, by any means available, spillage from entering drains or water courses.
DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air
diethylaminoethanol LOW LOW

ethanolamine LOW LOW

Bioaccumulative potential
Ingredient Bioaccumulation

diethylaminoethanol LOW (BCF = 6.1)

Continued...
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AUTOTREAT

ethanolamine LOW (LogKOW = -1.31)

Mobility in soil
Ingredient Mobility

diethylaminoethanol LOW (KOC = 5.979)

ethanolamine HIGH (KOC = 1)

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

DO NOT allow wash water from cleaning or process equipment to enter drains.
It may be necessary to collect all wash water for treatment before disposal.
In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
Where in doubt contact the responsible authority.
Recycle wherever possible.
Product / Packaging Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable
disposal treatment or disposal facility can be identified.
Treat and neutralise at an approved treatment plant.
Treatment should involve: Neutralisation with suitable dilute acid followed by: burial in a land-fill specifically licensed to accept
chemical and / or pharmaceutical wastes or Incineration in a licensed apparatus (after admixture with suitable combustible
material).
Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant NO

Land transport (ADR)

UN number 1814
UN proper shipping name POTASSIUM HYDROXIDE SOLUTION

Class 8
Transport hazard class(es)
Subrisk Not Applicable

Packing group II

Environmental hazard Not Applicable

Hazard identification (Kemler) 80

Classification code C5

Special precautions for Hazard Label 8

user Special provisions Not Applicable
Limited quantity 1L

Tunnel Restriction Code 2 (E)

Air transport (ICAO-IATA / DGR)

UN number 1814

UN proper shipping name Potassium hydroxide solution

ICAO/IATA Class 8

Transport hazard class(es) ICAO / IATA Subrisk Not Applicable

ERG Code 8L

Continued...
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Packing group II
Environmental hazard Not Applicable

Special provisions A3 A803

Cargo Only Packing Instructions 855

Cargo Only Maximum Qty / Pack 30 L

Special precautions for
Passenger and Cargo Packing Instructions 851
user
Passenger and Cargo Maximum Qty / Pack 1L

Passenger and Cargo Limited Quantity Packing Instructions Y840

Passenger and Cargo Limited Maximum Qty / Pack 0.5 L

Sea transport (IMDG-Code / GGVSee)

UN number 1814
UN proper shipping name POTASSIUM HYDROXIDE SOLUTION

IMDG Class 8
Transport hazard class(es)
IMDG Subrisk Not Applicable

Packing group II
Environmental hazard Not Applicable

EMS Number F-A , S-B

Special precautions for
Special provisions Not Applicable
user
Limited Quantities 1L

Inland waterways transport (ADN)

UN number 1814
UN proper shipping name POTASSIUM HYDROXIDE SOLUTION

Transport hazard class(es) 8 Not Applicable

Packing group II
Environmental hazard Not Applicable

Classification code C5

Special provisions Not Applicable

Special precautions for
Limited quantity 1L
user
Equipment required PP, EP
Fire cones number 0

Transport in bulk according to Annex II of MARPOL and the IBC code

Not Applicable

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

POTASSIUM HYDROXIDE IS FOUND ON THE FOLLOWING REGULATORY LISTS

Europe EC Inventory European Union (EU) Regulation (EC) No 1272/2008 on Classification,
Europe European Customs Inventory of Chemical Substances Labelling and Packaging of Substances and Mixtures - Annex VI
European Union - European Inventory of Existing Commercial Chemical dNorway regulations on n action values ​ and limit
a values ​ for physical
Substances (EINECS) chemical factors in the work environment and infection risk groups for
biological factors (Norwegian)

DIETHYLAMINOETHANOL IS FOUND ON THE FOLLOWING REGULATORY LISTS

Continued...
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AUTOTREAT

EU REACH Regulation (EC) No 1907/2006 - Annex XVII - Restrictions on the European Union - European Inventory of Existing Commercial Chemical
manufacture, placing on the market and use of certain dangerous substances, Substances (EINECS)
mixtures and articles European Union (EU) Regulation (EC) No 1272/2008 on Classification,
Europe EC Inventory Labelling and Packaging of Substances and Mixtures - Annex VI
Europe European Customs Inventory of Chemical Substances dNorway regulations on n action values ​ and limit
a values ​ for physical
chemical factors in the work environment and infection risk groups for
biological factors (Norwegian)

ETHANOLAMINE IS FOUND ON THE FOLLOWING REGULATORY LISTS

EU Consolidated List of Indicative Occupational Exposure Limit Values European Union - European Inventory of Existing Commercial Chemical
(IOELVs) Substances (EINECS)
EU European Chemicals Agency (ECHA) Community Rolling Action Plan European Union (EU) Regulation (EC) No 1272/2008 on Classification,
(CoRAP) List of Substances Labelling and Packaging of Substances and Mixtures - Annex VI
Europe EC Inventory dNorway regulations on n action values ​ and limit
a values ​ for physical
Europe European Customs Inventory of Chemical Substances chemical factors in the work environment and infection risk groups for
biological factors (Norwegian)

National Inventory Status

National Inventory Status
Australia - AICS Yes
Canada - DSL Yes

Canada - NDSL No (potassium hydroxide; diethylaminoethanol; ethanolamine)

China - IECSC Yes
Europe - EINEC / ELINCS /
Yes
NLP
Japan - ENCS Yes

Korea - KECI Yes

New Zealand - NZIoC Yes
Philippines - PICCS Yes

USA - TSCA Yes

Taiwan - TCSI Yes
Mexico - INSQ Yes

Vietnam - NCI Yes

Russia - ARIPS Yes
Yes = All CAS declared ingredients are on the inventory
Legend: No = One or more of the CAS listed ingredients are not on the inventory and are not exempt from listing(see specific ingredients
in brackets)

SECTION 16 OTHER INFORMATION

Revision Date 29/11/2018

Initial Date 19/03/2018

CONTACT POINT
- For quotations contact your local Customer Services - http://wssdirectory.wilhelmsen.com/#/customerservices - - Responsible for safety data sheet Wilhelmsen
Ships Service AS - Prepared by: Product HSE Manager, - Email: Email: WSS.GLOBAL.SDSINFO@wilhelmsen.com - Telephone: Tel.: +31 10 4877775

Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch
Classification committee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks
in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available
engineering controls must be considered.

For detailed advice on Personal Protective Equipment, refer to the following EU CEN Standards:
EN 166 Personal eye-protection
EN 340 Protective clothing
EN 374 Protective gloves against chemicals and micro-organisms
EN 13832 Footwear protecting against chemicals
EN 133 Respiratory protective devices

Continued...
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Definitions and abbreviations

PC－TWA: Permissible Concentration-Time Weighted Average
PC－STEL: Permissible Concentration-Short Term Exposure Limit
IARC: International Agency for Research on Cancer
ACGIH: American Conference of Governmental Industrial Hygienists
STEL: Short Term Exposure Limit
TEEL: Temporary Emergency Exposure Limit。
IDLH: Immediately Dangerous to Life or Health Concentrations
OSF: Odour Safety Factor
NOAEL :No Observed Adverse Effect Level
LOAEL: Lowest Observed Adverse Effect Level
TLV: Threshold Limit Value
LOD: Limit Of Detection
OTV: Odour Threshold Value
BCF: BioConcentration Factors
BEI: Biological Exposure Index

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end of SDS