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Safety-Super Gas - LPG MSDS PDF

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MATERIAL SAFETY DATA SHEET (MSDS)

1. CHEMICAL IDENTITY
Chemical Name Liquefied Petroleum Gas Trade name LPG
LPG, Propane, Butane,
Synonyms Chemical classification Aromatic mixture
Propylene, Purofax, Bottled gas
C3H6-C3H6-C4H10
Formula CAS Number 68476-85-7
(Mixture)
UN number 1075 UN Hazard class 2
Hazchem code ( EAC) 2WE
REGULATED IDENTIFICATION Hazardous ingredients CAS No.
Shipping Name Petroleum gases, liquified Propane
106-97-8
Shipping code/ Label Flammable , class2 Butane 10
Hazardous waste Id No. 5 Propylene 115-07-1

2. PHYSICAL AND CHEMICAL DATA


Gas at 15 c and 1
Boiling point/ Range >-40 Physical state Appearance Colourless
atm
Vapour Pressure Mercaptane added
Melting/ Freezing Point C NP DNA Odour
( at 20 C ) mm Hg for Odour
Solubility in water
Vapour Density ( Air =1) 1.5 Floats Other Information’s
( at 30 C)
Specific gravity ( at 50 C ) Soluble in Organic solvents,
0.51-0.58 pH Not pertinent
(water =1) Alcohol

3. FIRE AND EXPLOSION DATA


Flash point C (CC) Flammability LFL % v 1.9
NA TDG Flammability 2
(OC) UFL % v 9.5
Explosion sensitivity to May Explosion sensitivity to May Auto ignition
466.1
impact explode static electricity explode Temperature C
Hazardous will not
Combustible Material NO Explosive Material NO
Polymerization occur
Flammable Material YES Oxidizer NO Corrosive Material NO
Pyrophoric Material NO Organic Peroxide NO Other information
Hazardous Combustion Products Emits CO, CO2

4. REACTIVITY DATA
Chemical stability Stable
Incompatibility with other Materials Strong oxidiser
Reactivity No reaction with common materials but may react with oxidising materials.
Hazardous Reaction Products Not available.

5. HEALTH HAZARD DATA


Route of entry Inhalation, Skin
Effect of exposure/
Concentration in air greater than 10 % causes dizziness in few minutes. 1 % conc. gives the same
Symptoms
symptoms in 10 mts. High concentration causes asphyxiation. Liquid on skin causes frostbite.
If inhaled remove the victim to fresh air area. Provide artificial respiration.
Emergency treatment Skin: Remove the wetted cloths and wash the affected area with plenty of water.
Eyes: Flush with plenty of water for 15 min. seeks medical aid.
Permissible Exposure Limit TLV-TWA ( ACGIH) 1000 ppm STEL(ACGIH) Not listed
LD 50 orl-rat: Not listed Odour
IDLH 5000 to 20000 ppm
LCLo ihl-hmn: threshold
Health Flammability Reactivity Special
NFPA Hazard signals
1 4 0 -
MATERIAL SAFETY DATA SHEET (MSDS)

6. PREVENTIVE MEASURES

PERSONAL PROTECTIVE Avoid contact with liquid or gas. Provide hand gloves, safety goggles, gas mask,
MATERIAL protective clothing and shoes.
HANDLING AND STORAGE Keep in tightly closed cylinders in a cool, well ventilated area, away from heat,
PRECAUTIONS flame, sparks.

7. EMERGENCY AND FIRST AID MEASURES

FIRE ( Class of fire : C )


Fire extinguish media Water spray, DCP, CO2
Special Procedures Keep the containers cool by spraying water if exposed to fire.
Unusual Hazards Otherwise containers will explode in fire.
EXPOSURE
Eyes : Flush with plenty of water for at least 10 minutes
Skin: Remove contaminated clothing and wash affected skin with water.
First Aid Measures___
Inhalation: Remove victims to fresh air. If not breathing, give artificial respiration.
Ingestion: if conscious, have victim drink water or milk. Do not induced vomiting.
Obtain medical attention immediately.
Antidotes/ Dosages No specific antidote. Treat symptomatically.
SPILLS
Steps to be taken Shut off leaks if without risk. Warn everybody that air mixture is explosive.
Waste Disposal Method Allow gas to burn under control.

8. ADDITIONAL INFORMATION/ REFERENCES

ECOLOGICAL INFORMATION
Ecotoxicity DNA
Persistence DNA
A common air contaminant. Flammable when exposed to heat or flame. Keep
OTHER INFORMATION containers tightly closed. Slightly explosion hazard. No food chain concentration
potential
REFERENCES ( FOR OBTAINING MORE INFORMATION)
1. Hazardous chemicals Data Book: G 1. Hand book of environmental data: Karen Verschueren: van
Weiss: Noyes Data corp USA Nostrand Reinhold Co., USA

9. MANUFACTURER/SUPPLIER'S DATA

Contact person in Emergency Emergency leader


SHV Energy Private Limited
IVth Floor, SDE Serene Chambers, 8.2.334,
Road No.7, Banjara Hills, Hyderabad-34

PH : +191-4023540079 Local Bodies Involved The District Magistrate


Fax: +91-40-23540083 Standard Packing By Tank trucks
Term card details/ Ref Not pertinent
Others -

10. DISCLAIMER

Information contained in this material safety data sheet is believed to be reliable but no representation; guarantee or
warranties of any kind are made as to its accuracy, suitability for a particular application or results to be obtained from
them. It is up to the user/distributor to ensure that the information contained in the material safety data sheet is relevant to
the product manufactured/ handled or sold by him as the case may be. SHV makes no warranties, expressed or implied, in
respect of the adequacy of this document for any particular purpose.

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