JEE (Main) Online Exam (07-01-2020) Shift-II PDF

CAREER POINT JEE Main Online Paper
JEE Main Online Exam 2020

Questions & Solutions
07th January 2020 | Shift - II
PHYSICS
 
Q.1 A particle of mass m and charge q has an initial velocity v  v 0 ĵ . If an electric field E  E0 î and magnetic

field B  B0 î act on the particle, its speed will double after a time :
3 mv 0 2mv 0 3mv 0 2mv 0
(1) (2) (3) (4)
qE0 qE 0 qE0 qE0
Ans. [3]
 Vx2  Vy2  V 2
 V02  V 2  4 V02 
 V  3 V0 

Velocity in the direction of E will change
ux = 0
vx = 3 V0
qE 0
ax 
m
3mV0
t
qE 0
Q.2 In the figure, potential difference between A and B is :

10 k A
30V 10k 10k
B
(1) 10V (2) zero (3) 5 V (4) 15 V
Ans. [1]
10 k A
i1 i
30V 10k 10k
CAREER POINT Ltd., CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744-6630500 www.careerpoint.ac.in 1
30
i1 
15  10 3
i1 = 2 × 10–3
i1
i1   10 3
2
V = iR = 10–3 × 10 × 103 = 10V
Q.3 An emf of 20 V is applied at time t = 0 to a circuit containing in series 10 mH inductor and 5 resistor. The
ratio of the currents at time t =  and at t = 40 s is close to: (Take e2 = 7.389)
(1) 1.15 (2) 1.06 (3) 1.46 (4) 0.84
Ans. [2]
i  i 0 (1  e  Rt / L )
540
3
i  i 0 (1  e 1010 )
i0
1
i
Then most appropriate option is 1.06
Q.4 In a Young's double slit experiment, the separation between the slits is 0.15 mm. In the experiment, a source
of light of wavelength 589 nm is used and the interference pattern is observed on a screen kept 1.5 m away.
The separation between the successive bright fringes on the screen is -
(1) 6.9 mm (2) 4.9 mm (3) 3.9 mm (4) 5.9 mm
Ans. [4]
D

d
1.5  589  10 9
=
0.15  10 3
= 5.9 mm
Q.5 A box weighs 196 N on a spring balance at the north pole. Its weight recorded on the same balance if it is
shifted to the equator is close to (Take g = 10 ms–2 at the north pole and the radius of the earth = 6400 km)
(1) 194.32 N (2) 195.66 N (3) 195.32 N (4) 194.66 N
Ans. [3]
W = Mg – M2R
2
 2  3
= 196  (19.6)    6400  10
 24  3600 
W  195 .32
Q.6 Mass per unit area of a circular disc of radius a depends on the distance r from its centre as (r) = A + Br.
The moment of inertia of the disc about the axis, perpendicular to the plane and passing through its centre is-
 A aB   A aB   aA B   A B
(1) 2a 4    (2) a 4    (3) 2a 4    (4) 2a 4   
4 5  4 5   4 5  4 5
Ans. [1]
dr
dI = dmr 2
= 2r(dr)r2
a
 dI  2r 3 ( A  Br ) dr

0
 A aB 
I = 2a 4   
4 5 
Q.7 In a building there are 15 bulbs of 45W, 15 bulbs of 100 W, 15 small fans of 10 W and 2 heaters of 1 kW.
The voltage of electric main is 220 V. The minimum fuse capacity (rated value) of the building will be -
(1) 15 A (2) 10 A (3) 25 A (4) 20 A
Ans. [4]
Total Power = 15 × 45 + 15 × 100 + 15 ×10 + 2 × 103 = VI
4325 4325
I 
V 220
= 19.66
I  20 A
Q.8 A stationary observer receives sound from two identical tuning forks, one of which approaches and the other
one recedes with the same speed (much less than the speed of sound). The observer hears 2 beats/sec. The
oscillation frequency of each tuning fork is 0 = 1400 Hz and the velocity of sound in air is 350 m/s. The
speed of each tuning fork is close to -
1 1 1
(1) m/s (2) m/s (3) m/s (4) 1 m/s
4 2 8
Ans. [1]
v v
f0 f0
observer
 c 
f1   f 0
cv
 c 
f2   f 0
cv
beat frequency = f1 – f2
 1 1 
= cf0   
 c  v c  v
 2v 
= cf0  2 2 
c v 
c >> v
2f 0 v
= 2
c
1
v m/s
4
Q.9 Two ideal Carnot engines operate in cascade (all heat given up by one engine is used by the other engine to
produce work) between temperature, T1 and T2. The temperature of the hot reservoir of the first engine is T1
and the temperature of the cold reservoir of the second engine is T2. T is temperature of the sink of first
engine which is also the source for the second engine. How is T related to T1 and T2, if both the engines
perform equal amount of work ?
T1  T2 2T1T2
(1) T  T1T2 (2) T  (3) T  (4) T = 0
2 T1  T2
Ans. [2]
T1
Q1
H W
Q2
T
Q2
H W
Q3
T2
Q2 T
 .......... (i)
Q1 T1
Q3 T2
 .......... (ii)
Q1 T
Q3 T2
 .......... (iii)
Q1 T1
work is same
Q1 – Q2 = Q2 – Q3
 Q1 + Q3 = 2Q2
T T
 1  2  2
T T
T  T2
T 1 
2
Q.10 The activity of a radioactive sample falls from 700 s–1 to 500s–1 in 30 minutes . Its half life is close to -
(1) 66 min (2) 52 min (3) 62 min (4) 72 min
Ans. [3]
A = A0 e – t
500 = 700 e – ×30
7
ln    30
5
ln 2 30
T   ln 2
 7
ln
5
THalf  62 min
Q.11
B
(T)
2.0
1.0
–150 –50
H
50 150 A/m
–1.0
–2.0
The figure gives experimentally measured B vs. H variation in a ferromagnetic material. The retentivity,
co-ercivity and saturation, respectively, of the material are -
(1) 1.0 T, 50A / m and 1.5 T (2) 1.5 T, 50 A/m and 1.0 T
(3) 1.5 T, 50 A/m and 1.0 T (4) 150 A/m, 1.0 T and 1.5 T
Ans. [1]
Saturation
Retentivity
magnetization
Co-ericivity
Retentivity = 1.0 T
Co-ercivity = 50 A/m
Saturation = 1.5 T
Q.12 The electric field of a plane electromagnetic wave is given by –

 î  ĵ
E  E0 cos ( kz  t )
2
 
At t = 0, a positively charged particle is at the point (x,y, z) =  0, 0,  . If its instantaneous velocity at
 k
(t = 0) is v 0 k̂ , the force acting on it due to the wave is -
î  ĵ î  ĵ
(1) parallel to k̂ (2) antiparallel to (3) zero (4) parallel to
2 2
Ans. [2]
  î  ĵ 
E   E0   cos  (at t = 0)
 2 
 
  
Force due to magnetic field is in direction q( v  B) & v || k̂
hence
   
F  q( E  V B)

F is in direction of E
 î  ĵ 
i.e.   
 2 
 
Q.13 An elevator in a building can carry a maximum of 10 person, with the average mass of each person being 68
kg. The mass of the elevator itself is 920 kg and it moves with a constant speed of 3 m/s. The frictional force
opposing the motion is 6000 N. If the elevator is moving up with its full capacity, the power delivered by the
motor to the elevator (g = 10 m/s2) must be at least :
(1) 56300 W (2) 48000 W (3) 66000 W (4) 62360 W
Ans. [3]
T
6000
6800 9200
T = 6800 + 9200 + 6000
= 22000 N
Power = TV = 22000 × 3
= 66000 W
Q.14 A planar loop of wire rotates in a uniform magnetic field. Initially, at t = 0, the plane of the loop is
perpendicular to the magnetic field. If it rotates with a period of 10s about an axis in its plane then the
magnitude of induced emf will be maximum and minimum, respectively at -
(1) 2.5 s and 7.5 s (2) 2.5 s and 5.0 s (3) 5.0 s and 7.5 s (4) 5.0 s and 10.0 s
Ans. [2]
 
  B A  BA cos t
|| BA sin t

max when t  t = 2.5 sec
2
min when t =  t = 5 sec
Q.15 An electron (of mass m) and a photon have the same energy E in the range of a few eV. The ratio of the de-
Broglie wavelength associated with the electron and the wavelength of the photon is (c = speed of light in
vaccum)
1 1 1
1
1  2E  2 1  E 2  E 2
(1)   (2)   (3)   (4) c( 2mE) 2
c m  c  2m   2m 
Ans. [2]
h h
 De  broglie  
p 2mE
hc
 Photon 
E
1 E
Ratio =
c 2m
Q.16 An ideal fluid flows (laminar flow) through a pipe of non-uniform diameter. The maximum and minimum
diameters of the pipes are 6.4 cm and 4.8 cm, respectively. The ratio of the minimum and the maximum
velocity of fluid in this pipe is :
9 3 3 81
(1) (2) (3) (4)
16 2 4 256
Ans. [1]
A1v1 = A2v2
v min A
 min
v max A max
2
v min  4.8 
 
v max  6.4 
9
=
16
B2
Q.17 The dimension of , where B is magnetic field and 0 is the magnetic permeability of vaccum, is :
2 0
(1) ML2T–2 (2) MLT–2 (3) ML–1T–2 (4) ML2T–1
Ans. [3]
B2
= Energy per unit volume
2 0
ML2 T 2
Dimension 
L3
ML–1 T–2
Q.18 A thin lens made of glass (refractive index = 1.5) of focal length f = 16 cm is immersed in a liquid of
refractive index 1.42. If its focal length in liquid is fl , then the ratio fl / f is closed to the integer
(1) 1 (2) 17 (3) 9 (4) 5
Ans. [3]
1  2  1   1 1 
     
f  1   R1 R 2 
1  1.5  1   1 1 
     .... (i)
f  1   R1 R 2 
1  1.5  1.42   1 1 
     .... (ii)
f1  1.42   R1 R 2 
f1 0.5
  9
f 0.056
Q.19 A mass of 10 kg is suspended by a rope of length 4m, from the ceiling, A force F is applied horizontally at
the mid-point of the rope such that the top half of the rope makes an angle of 45° with the vertical. Then F
equals : (Take g = 10 ms–2 and the rope to be massless) -
(1) 90 N (2) 100 N (3) 70 N (4) 75 N
Ans. [2]
45°
T
F
m = 10 kg
T cos 45° = 100

T sin 45° = 100 = F
F  100 N
Q.20 Under an adiabatic process, the volume of an ideal gas gets doubled. Consequently the mean collision time
C 
between the gas molecule changes from 1 to 2 . If P   for this gas then a good estimate for 2 is given
CV 1
by -
 1

1 2 1 1 
(1)   (2) (3)   (4) 2
2 2 2
Ans. [BONUS] (NTA answer is [1])
V
 ..... (i)
T
TV–1 = constant ..... (ii)
V
   1
V 2
1 
 V 2
 1
2 2
 ( 2)
1
Q.21 The balancing length for a cell is 560 cm in a potentiometer experiment. When an external resistance of 10
is connected in parallel to the cell, the balancing length changes by 60 cm. If the internal resistance of the cell
N
is  , where N is an integer then value of N is ................ .
10
Ans. [12]
E0 R0
560
E0 G
N
r
10
E = 560 x ...... (i)

x  potential gradient
E – ir = 500x
10E
 500x ...... (ii)
10  r
(i)  (ii)
500
E0 G
10
r = 1.2 
N
  1.2
10
N  12
Q.22 A 60 pF capacitor is fully charged by a 20 V supply. It is then disconnected from the supply and is connected
to another uncharged 60pF capacitor in parallel. The electrostatic energy that is lost in this process by the
time the charge is redistributed between them is (in nJ) .................... .
Ans. [6]
V0 0
C
V0/2 C 0
1  1  V 2 
E  CV02  2  C  0  
2 2  2  
 
CV02
=
4
= 6 × 10 –9 = 6 n J
    
Q.23 The sum of two forces P and Q is R such that |R ||P|. The angle  (in degrees) that the resultant of
  
2 P and Q will make with Q is, .............. .
(1) (2) (3) (4)
Ans. [90]
   
R Q R'  Q

 
P 2P
  
P Q  R
P2 + Q2 + 2PQcos = R2 = P2
2Pcos + Q = 0 …(1)
2P sin 
tan = …(2)
2P cos   Q
From (1) & (2)
 = 90º
Q.24 M grams of steam at 100° C is mixed with 200 g of ice at its melting point in a thermally insulated container.
If it produces liquid water at 40°C [heat of vaporization of water is 540 cal/g and heat of fusion of ice is 80
cal/g], the value of M is ................ .
Ans. [40]
M gm steam + M gm ice
100ºC 0ºC
200×80
M×540 =16000
M gm water 200 gm water

100ºC 0ºC
MST 200×1×40
=M × 1 × 60 =8000
= 60 M
M gm water 200 gm water
40ºC 40ºC
Total heat = 600 M Total heat = 24000 M
600 M = 240000
M = 40 gm
Q.25
F
Consider a uniform cubical box of side a on a rough floor that is to be moved by applying minimum possible
force F at a point b above its centre of mass (see figure). If the coefficient of friction is  = 0.4, the maximum
b
possible value of 100  for box not to topple before moving is .................. .
a
Ans. [50]
N
a
b F
a
Mg
Torque about C.O.M.
a a
Fb + f =N …(1)
2 2
F  f = µN …(2)
N = Mg …(3)
 a a
µN  b   = Mg
 2  2
b
= 0.75
a
which is not possible
b
Hence, answer should be = 0.5 (maximum possible)
a
 b 
Ans. 50  100  50  
 a 

Questions & Solutions
CHEMISTRY
Q.1 Among the statements(a)-(d), the incorrect ones are :
(a) Octahedral Co(III) complexes with strong field ligands have very high magnetic moments
(b) When 0 < P, the d-electron configuration of Co(III) in an octahedral complex is t 4eg e 2eg
(c) Wavelength of light absorbed by [Co(en)3] 3+ is lower than that of [CoF6]3–
(d) If the 0 for an octahedral complex of Co(III) is 18,000 cm–1, the t for its tetrahedral complex with the
same ligand will be 16,000 cm–1
(1) (c) and (d) only (2) (a) and (d) only (3) (a) and (b) only (4) (b) and (c) only
Ans. [2]
Sol. Strong field ligands have high pairing energy.
For strong field ligand : - 0 = t × 1.125
18000
= t
1.125
16000 = t
Q.2 If the following reaction sequence,

NH2
Ac2O Br2
A AcOH
B the major product B is :
CH3
NHCOCH3 NHCOCH3 NHCOCH3 NHCOCH3
COCH3 Br Br
(1) (2) (3) (4)
Br
CH3 CH3 CH2Br CH3
Ans. [4]
O O
NH2 NH–C–CH3 NH–C–CH3
Br
Ac2O Br2
Sol. A AcOH
CH3 CH3 CH3
Q.3 Two open beakers one containing a solvent and the other containing a mixture of that solvent with a non
volatile solute are together sealed in a container. Over time :
(1) the volume of the solution decreases and the volume of the solvent increases
(2) the volume of the solution and the solvent does not change
(3) the volume of the solution increases and the volume of the solvent decreases
(4) the volume of the solution does not change and the volume of the solvent decreases
Ans. [3]
Sol. Lowering of V.P in second Beaker will take place.
Q.4 Among statement (a) – (d), the correct ones are :

(a) Decomposition of hydrogen peroxide gives dioxygen.
(b) Like hydrogen perioxide, compound, such as KClO3, Pb(NO3)2 and NaNO3 when heated liberate
dioxygen.
(c) 2-Ethylanthraquinone is useful for the industrial preparation of hydrogen peroxide.
(d) Hydrogen peroxide is used for the manufacture of sodium perborate.
(1) (a), (c) and (d) only (2) (a), (b), (c) and (d)
(3) (a) and (c) only (4) (a), (b) and (c) only
Ans. [2]
Sol. Theory Based
Q.5 The correct order of stability for the following alkoxides is :

O– O– O–
O2 N
NO2 NO2
(A) (B) (C)
(1) (C) > (A) > (B) (2) (B) > (C) > (A) (3) (B) > (A) > (C) (4) (C) > (B) > (A)
Ans. [4]
Sol.
Θ O (stable by –M of NO2)
O–CH=CH–N
O
Θ
O–C=CH2 (stable by Resonance)
NO2
Q.6 A chromatography column, packed with silica gel as stationary phase, was used to separate a mixture of
compounds consisting of (A) benzanilide (B) aniline and (C) acetophenone. When the column is eluted with
a mixture of solvent, hexane : ethyl acetate (20 : 80), the sequence of obtained compounds is :
(1) (B), (C) and (A) (2) (C), (A) and (B) (3) (A), (B) and (C) (4) (B), (A) and (C)
Ans. [2]
O O
C–CH3 C–NH2 NH2
Sol. > >
Acetophenone Acetannilide Anniline

(C) (A) (B)
Anniline has higher viscosity due to efficient H-Bonding.
Q.7 In the following reactions, products (A) and (B), respectively, are :
NaOH + Cl2  (A) + side products
(hot and conc.)
Ca(OH)2 + Cl2  (B) + side products
(dry)
(1) NaClO3 and Ca(ClO3)2 (2) NaClO3 and Ca(OCl)2
(3) NaOCl and Ca(OCl)2 (4) NaOCl and Ca(ClO3)2
Ans. [2]
Sol. 6NaOH + 3Cl2  5NaCl + NaClO3 + 3H2O
2Ca(OH)2 + Cl2  Ca(OCl)2 + CaCl2 + H2O
Q.8 The ammonia (NH3) released on quantitative reaction of 0.6 g urea (NH2CONH2) with sodium hydroxide
(NaOH) can be neutralized by :
(1) 200 ml of 0.4 N HCl (2) 200 ml of 0.2 N HCl
(3) 100 ml of 0.1 N HCl (4) 100 ml of 0.2 N HCl
Ans. [4]
Sol. 2 × moles of urea = moles of NH3
moles of NH3 = moles of HCl
100 0.2
= moles of HCl = 0.02 mole of HCl
1000
Q.9 For the following reactions

CH3CH2CH2Z + BrΘ
ks
CH3CH2CH2Br + ZΘ
ke
CH3CH=CH2 + HZ + BrΘ
where,
CH3
|
ZΘ=CH3CH2OΘ (A) or H3C–C–OΘ (B),
|
CH3
ks
ks and ke, are, respectively, the rate constants for substitution and elimination, and µ = , the correct option
ke
is _______.
(1) µB > µA and ke(A) > ke(B) (2) µB > µA and ke(B) > ke(A)
(3) µA > µB and ke(B) > ke(A) (4) µA > µB and ke(A) > ke(B)
Ans. [3]
Sol. Bulkier the base, elimination will be favoured
ksA
µA = (For A : ks > ke)
k eA
ksB
µB = (For B : ks < ke)
k eB
Q.10 Identify the correct labels of A, B and C in the following graph from the option given below :
A
B
C
no. of
molecules
speed
Root mean square speed (Vrms); most probable speed (Vmp); Average speed (Vav)
(1) A – Vrms; B – Vmp; C-Vav (2) A-Vmp; B-Vav; C-Vrms
(3) A-Vmp; B-Vrms; C-Vav (4) A-Vav; B-Vrms; C-Vmp
Ans. [2]
Sol. Vrms > Vavg > Vmps
Q.11 The equation that is incorrect is :

(1) (0m ) NaBr – (0m ) NaCl = (0m ) KBr – (0m ) KCl
(2) (0m ) H 2O = (0m ) HCl + (0m ) NaOH – (0m ) NaCl
(3) (0m ) NaBr – (0m ) NaI = (0m ) KBr – (0m ) NaBr
(4) (0m ) KCl – (0m ) NaCl = (0m ) KBr – (0m ) NaBr

Ans. [3]
Sol. 0m NaI – 0m NaBr = 0m I – 0m Br
0m NaBr – 0m KBr = 0m Na – 0m K
Q.12 The redox reaction among the following is :

(1) combination of dinitrogen with dioxygen at 200 K
(2) reaction of H2SO4 with NaOH
(3) formation of ozone from atmospheric oxygen in the presence of sunlight
(4) reaction of [Co(H2O)6]Cl3 with AgNO3
Ans. [1]
Sol. N2 + O2  2NO (Ox. state charge)
3O2  2O3
2NaOH + H2SO4  Na2SO4 + 2H2O
AgNO3 + NaCl  NaNO3 + AgCl
Q.13 For the reaction

2H2(g) + 2NO(g)  N2(g) + 2H2O(g)
the observed rate expression is, rate = kf[NO]2 [H2]. The rate expression for the reverse reaction is :
(1) kb[N2][H2O]2/[H2] (2) kb[N2][H2O] (3) kb[N2][H2O]2/[NO] (4) kb[N2][H2O]2
Ans. [1]
Sol. 2H2(g) + 2NO(g)  N2(g) + 2H2O(g)
According to Rate expression forward
2NO + H2 are Reactants
Hence one mole of H2 is reacted in second step
kb[N2][H2O]2/[H2]
Q.14 The bond order and the magnetic characteristics of CN– are :
1 1
(1) 2 , diamagnetic (2) 3, paramagnetic (3) 2 , paramagnetic (4) 3, diamagnetic
2 2
Ans. [4]
Sol. CNΘ has 14 electron
1s2, *1s2 2s2 *2s2 22py = 22pz *22py = *22pz
Nb – Na
Bond order = = 3 (CΘ N)
2
diamagnetic  all electrons are paired
Q.15 In the following reaction sequence, structures of A and B, respectively will be :

O
HBr Na
 A Ether (Intramolecular Product) B
CH2Br
Br Br Br CH2Br
(1) OH & (2) OH &

CH2Br O CH2Br O
OH OH OH OH
(3) Br & (4) Br &

CH2Br CH2Br
Ans. [4]
H  OH
O O CH2 CH
Sol. HBr (i) BrΘ 2
A
SN2 (ii) Na + ether
CH2 CH2
CH2Br CH2Br
Q.16 Which of the following statements is correct ?

(1) Gluconic acid is obtained by oxidation of glucose with HNO3
(2) Gluconic acid is a partial oxidation product of glucose
(3) Gluconic acid can form cyclic (acetal/hemiacetal) structure
(4) Gluconic acid is a dicarboxylic acid
Ans. [2]
Sol.
O
||
CHO C–OH
H OH OH
HO H AgNO3 HO H
or
H OH CuSO4 H OH
H or H
OH Br2 + H2O
OH
CH2OH CH2OH
glucose gluconic acid
Q.17 Within each pair of element F & Cl, S & Se, and Li & Na, respectively, the elements that release more
energy upon and electron gain are :
(1) Cl, S and Li (2) F, Se and Na (3) Cl, Se and Na (4) F, S and Li
Ans. [1]
Sol.
Cl > F (exception)
{3rd period > 2nd period}
S > Se (exception)
For non metals
Li > Na (small size)
Q.18 The refining method used when the metal and the impurities have low and high melting temperatures,
respectively, is :
(1) distillation (2) liquation
(3) zone refining (4) vapour phase refining
Ans. [2]
Sol. Theory Based
Q.19 The number of possible optical isomers for the complexes MA2B2 with sp3 and dsp2 hybridized metal atom,
respectively, is :
Note : A and B are unidentate neutral and unidentate monoanionic ligands, respectively.
(1) 0 and 1 (2) 0 and 0 (3) 0 and 2 (4) 2 and 2
Ans. [2]
Sol. MA2B2 shows geometrical isomerism not optical isomerism.
Q.20 Consider the following reaction :

anhyd. AlCl3
(a) + Cl
Cl Cl
an hyd. AlCl3
(b) Cl2 (excess) dark
Cl Cl
Cl Cl
an hyd.
(c) + Cl2=CH–Cl CH=CH2
AlCl3
an hyd.
(d) + CH2=CH–CH2Cl CH2–CH=CH2
AlCl3
Which of these reactions are possible ?

(1) (a) and (b) (2) (b) and (d) (3) (a) and (d) (4) (b), (c) and (d)
Ans. [2]
Sol. Vinyl halides and Aryl halides do not give Friedel Craft Reaction due to partial double bond character.
Q.21 The flocculation value of HCl for arsenic sulphide sol. is 30 m mol L–1. If H2SO4 is used for the flocculation
of arsenic sulphide, the amount, in grams, of H2SO4 in 250 ml required for the above purpose is _________.
(molecular mass of H2SO4 = 98 g/mol)
Ans. [0.3675]
Sol.  1 litre solution of 30 m mol of HCl is required
For 1 litre solution 15 m mol H2SO4 is required.
15
250 ml of solution required : - × 10–3 (m mol) of H2SO4
4
= 0.3675 gm
Q.22 3 g of acetic acid is added to 250 mL of 0.1 M HCl and the solution made up to 500 mL. To 20 mL of this
1
solution mL of 5 M NaOH is added. The pH of the solution is _________.
2
[Given : pKa of acetic acid = 4.75, molar mass of acetic acid = 60 g/mol, log3 = 0.4771]
Neglect any changes in volume.
Ans. [5.22]
Sol. m mole of acetic acid in 20 ml = 2
m mole of HCl in 20 ml = 1
m mole of NaOH 20 ml = 2.5
NaOH + CH3COOH  CH3COONa + H2O
(left)
1.5 2 0 0
0 0.5 1.5
3/ 2
pH = pKa + log
2
= 4.74 + log 3 = 5.22
Q.23 Consider the following reactions :

NaCl + K2Cr2O7 + H2SO4  (A) + side products
(Conc.)
(A) + NaOH  (B) + side products
(B) + H2SO4 + H2O2  (C) + Side products
(dilute)
The sum of the total number of atoms in one molecule each of (A), (B) and (C) is ___________.
Ans. [18]
K2Cr2O7 NaOH H2O2/H
Sol. NaCl H
CrO2Cl2 NaCrO4 CrO5
(A) (B)
CrO2Cl2  5
NaCrO4  7
CrO5  6
18 atoms
Q.24 The standard heat of formation (  f H 0298 ) of ethane (in kJ/mol), if the heat of combustion of ethane,
hydrogen and graphite are –1560, –393.5 and –286 kJ/mol, respectively is ________.
Ans. [192.5]
Sol. 2C(graphite) + 3H2(g)  1C2H6 Hf(C2H6)
7
(1) C2H6 + O2  2CO2 + 3H2O HC= –1560
2
1
(2) H2 + O2  H2O HC = –393.5
2
(3) C(graphite) + O2  CO2 HC = –286 kJ/mol
Hf (C2H6) = 3(–393.5) + 2(–286) + 1560
= –1180.5 + (–572) + 1560
= 192.5
Q.25 The number of sp2 hybridised carbons present in "Aspartame" is ____.

Ans. [9]
Sol.
O O O
HO–C–CH2–CH–C–NH–CH–C–O–CH3
NH2 CH2

Questions & Answer
MATHS
Q.1 The number of ordered pairs (r, k) for which 6.35Cr = (k2 – 3).36Cr+1, where k is an integer, is:
(1) 6 (2) 3 (3) 2 (4) 4
Ans. [4]
Sol. 6.35Cr = (k2 – 3) 36Cr+1
36 35
6.35Cr = (k2 – 3). C r.
r +1
r +1
⇒ k2 – 3 =
6
k∈I ⇒ r can be
(1) r = 5 ⇒ k = ±2
(2) r = 35 ⇒ k = ±3
4 ordered pairs (5, 2), (5, –2), (35, 3), (35, 3)
2
Q.2 The value of α for which 4α e −α|x| dx = 5, is:
∫
−1
⎛ 3⎞ ⎛4⎞
(1) loge 2 (2) loge ⎜ ⎟ (3) loge ⎜ ⎟ (4) loge2
⎝2⎠ ⎝ 3⎠
Ans. [4]
2
Sol. 4α e −α|x| dx = 5
∫
−1
0 2
4α e αx dx + e −αx dx = 5
∫ ∫
−1 0
0 2
αx
⎛e ⎞ ⎛ e −αx ⎞
⇒ 4α ⎜⎜ ⎟ + 4α⎜
⎟
⎟
⎜ −α ⎟ = 5
⎝ α ⎠ −1 ⎝ ⎠0
⎛ 1 − e − α e −2 α − 1 ⎞
⇒ 4α ⎜⎜ − ⎟ =5
⎝ α − α ⎟⎠
Let e–α = t
∴ 4t2 + 4t –3 = 0
1
⇒t=
2
–α 1
e =
2
α= n2
⎛ f (x) ⎞
Q.3 Let f(x) be a polynomial of degree 5 such that x = ±1 are its critical points. If lim ⎜ 2 + 3 ⎟ = 4, then which
x → 0⎝ x ⎠
one of the following is not ture?
(1) f is an odd function
(2) f(1) – 4f(–1) = 4
(3) x = 1 is a point of minima and x = –1 Is a point of maxima of f
(4) x = 1 is a point of maxima and x = –1 Is a point of minimum of f
Ans. [4]
Sol. f '(x) = 0 at x = 1, –1, also 0 is a repeated root.
∴ f '(x) = a (x + 1)(x – 1) x2
= a(x2 – 1)x2
f'(x) = ax4 – x2
ax 5 ax 3
f(x) = − +C
5 3
∵ f(0) = 0 ⇒ c = 0
f (x)
lim =2
x →0 x3
a
⇒0– =2
3
⇒ a = –6
6
∴ f(x) = – x5 + 2x3
5
∴ f '(x) = –6(x2 – 1)(x2)
– + + –
–1 0 1
Minima at x = –1
Maxima at x = 1
Q.4 Let a, b and c be three unit vectors such that a + b + c = 0 . If λ = a.b + b.c + c.a and d = a × b + b × c + c × a ,
then the ordered pair, (λ, d ) is equal to:
⎛ 3 ⎞ ⎛ 3 ⎞ ⎛3 ⎞ ⎛3 ⎞
(1) ⎜ − , 3c × b ⎟ (2) ⎜ − , 3a × b ⎟ (3) ⎜ , 3b × c ⎟ (4) ⎜ , 3a × c ⎟
⎝ 2 ⎠ ⎝ 2 ⎠ ⎝ 2 ⎠ ⎝ 2 ⎠
Ans. [2]
2
Sol. a+b+c = 0
3 + 2 (a.b + b.c + c.a ) = 0

3
a.b + b.c + c.a = −
2
3
λ=–
2
d = a ×b + b×c + c×a
= a × b + b × ( −a − b) + ( −a − b) × a
d = 3(a × b)
⎛1⎞ 1
Q.5 Let y = y(x) be a function of x satisfying y 1 − x 2 = k – x 1 − y 2 where k is a constant and y ⎜ ⎟ = – .
⎝2⎠ 4
dy 1
Then at x = , is equal to:
dx 2
2 5 5 5
(1) (2) (3) − (4) –
5 2 4 2
Ans. [4]
Sol. y. 1 − x 2 = k – x. 1 − y 2
On differentiating
− 2x x.2 yy'
y. + 1 − x 2 .y' = + − 1 − y2
2 2
2 1− x 2 1− y
1 1 1
Put x = ,y=– & x.y = –
2 4 8
On solving we get
− 5
y' =
2
Q.6 The coefficient of x7 in the expression (1 + x)10 + x(1 + x)9 + x2(1 + x)8+……..+ x10 is:
(1) 210 (2) 120 (3) 330 (4) 420
Ans. [3]
Sol. (1 + x)10 + x(1 + x)9 + x2(1 + x)8 +………+ x10
⎡ ⎛ x ⎞11 ⎤
⎢1 − ⎜ ⎟ ⎥
⎢ ⎝ 1 + x ⎠ ⎦⎥
10 ⎣
(1 + x)
⎛ x ⎞
⎜1 − ⎟
⎝ 1+ x ⎠
⇒ (1 + x)11 – x11
Coefficient of x7 is 11C7 = 330
Q.7 Let α and β be the roots of the equation x2 – x – 1 = 0. If pk = (α)k + (β)k, k ≥ 1, then which one of the
following statements is not true?
(1) p5 = p2 . p3 (2) p3 = p5 – p4
(3) (p1 + p2 + p3 + p4 + p5) = 26 (4) p5 = 11
Ans. [1]
Sol. p5 = α5 + β5
∵ α2 = α + 1
= (α + 1)2.α + (β + 1)2.β
= (α2 + 2α + 1) α + (β2 + 2β + 1)β
= (3α + 2) α + (3β + 2)β
= 3α2 + 2α + 3β2 + 2β
= 5α + 5β + 6 [∵ α + β = 1]
= 5(1) + 6 = 11
p2 = α2 + β2 = α + β + 2 = 3
p3 = α3 + β3 = (α + 1).α + (β + 1).β
= α2 + β2 + α + β
=α+β+3
=1+3=4
Hence p5 ≠ p2.p3
Q.8 If the sum of the first 40 terms of the series, 3 + 4 + 8 + 9 + 13 + 14 + 18 + 19 +…… is (102)m, then m is
equal to:
(1) 20 (2) 25 (3) 10 (4) 5
Ans. [1]
Sol. 3 + 4 + 8 + 9 + 13 + 14 +…….upto 40 terms
⇒ 7 + 17 + 27 +…….20 terms
20
S= [2 × 7 + 19 × 10]
2
= 102 × 20 = 102 m
∴ m = 20
Q.9 The area (in sq. units) of the region {(x, y) ∈ R2 |4x2 ≤ y ≤ 8x + 12} is:
128 127 124 125
(1) (2) (3) (4)
3 3 3 3
Ans. [1]
Sol. For point of intersection
4x2 = 8x + 12
x = –1, 3
y = 4x2 y = 8x + 12
–1 3
3
2
Area = ∫ [(8x + 12) − 4x
−1
] dx
3
2
⎡ 8x 4x 3 ⎤
= ⎢ + 12x − ⎥
⎣ 2 3 ⎦ −1
4
= (36 + 36 – 36) – (4 – 12 + )
3
128
=
3
9
Q.10 Let a1, a2, a3, ……. be a G.P. such that a1 < 0, a1 + a2 = 4 and a3 + a4 = 16. If ∑a
i =1
i = 4λ, then λ is equal to:
511
(1) (2) –171 (3) –513 (4) 171
3
Ans. [2]
Sol. a1 + a2 = 4 ⇒ a1 + a1r = 4 ………(i)
a3 + a4 = 16 ⇒ a1r2 + a1r3 = 16 ………(ii)
equation (i) ÷ (ii)
1 1
⇒ 2 =
r 4
⇒ r = ±2
4
r = 2 ⇒ a1 =
3
r = –2 ⇒ a1 = –4
9
a ( r 9 − 1) (( −2) 9 − 1)
∑i =1
ai =
( r − 1)
= ( −4)
( −2 − 1)
4
= (–513) = 4λ
3
⇒ λ = –171
Q.11 If θ1 and θ2 be respectively the smallest and the largest values of θ in (0, 2π) – {π} which satisfy the
θ2
25 2
equation, 2cot θ –
sin θ
+ 4 = 0, then ∫ cos
θ1
3θ dθ is equal to:
π π π 1 2π
(1) (2) (3) + (4)
3 9 3 6 3
Ans. [1]
5
Sol. 2cot2θ – +4=0
sin θ
cos2 θ 5
2 2
− +4=0
sin θ sin θ
2sin2θ – 5sinθ + 2 = 0
(2sinθ – 1)(sinθ – 2) = 0
1
sinθ = only
2
π 5π
∴θ= ,
6 6
↓ ↓
θ1 θ2
5π 5π
6 6
2 ⎛ 1 + cos 6θ ⎞
∫ cos
π
3θ dθ = ∫ ⎜⎝
π
2
⎟dθ
⎠
6 6
5π
1⎛ sin 6θ ⎞ 6
= ⎜θ + ⎟
2⎝ 6 ⎠π
6
π
=
3
x 2 y2
Q.12 If 3x + 4y = 12 2 is a tangent to the ellipse + = 1 for some a ∈ R, then the distance between the foci
a2 9
of the ellipse is:
(1) 4 (2) 2 2 (3) 2 5 (4) 2 7
Ans. [4]
Sol. 3x + 4y = 12 2
3x
y=– +3 2
4
line is tangent to ellipse
∴ c2 = a2m2 + b2
2
⎛ 3⎞
( 3 2 )2 = a2 ⎜ − ⎟ + 9
⎝ 4⎠
9a 2
18 = +9
16
a2
2= +1
16
a2 = 16
b2
∴ e2 = 1 –
a2
9
e2 = 1 –
16
7
e=
4
Distance between focii = 2ae
7
=2×4×
4
= 2 7
Q.13 Let A = [aij] and B = [bij] be two 3 × 3 real matrices such that bij = (3)(i+j–2)aji, where i, j = 1, 2, 3. If the
determinant of B is 81, then the determinant of A is:
1 1 1
(1) 3 (2) (3) (4)
9 81 3
Ans. [2]
b11 b12 b13 30 a11 31 a 21 32 a 31
Sol. |B| = b 21 b 22 b 23 = 31 a12 32 a 22 33 a 32
b 31 b 32 b 33 32 a13 33 a 23 34 a 33
81 = 33 . 33 . 32 |A|
1
⇒ |A| =
9
Q.14 The locus of the mid-points of the perpendiculars drawn from points on the line, x = 2y to the line x = y is:
(1) 2x – 3y = 0 (2) 5x – 7y = 0 (3) 7x – 5y = 0 (4) 3x – 2y = 0
Ans. [2]
Sol.
y=x
B(β, β) x
=y
M(h, k) 2
A(2α, α)
k−α
Slope AB = =–1
h − 2α
k+k
⇒α= …… (1)
3
β + 2α β+α
also = h, =k
2 2
α = 2h – 2k …… (2)
from (1) & (2)
h+k
= 2h – 2k
3
⇒ 5h = 7k
⇒ 5x = 7y
Q.15 Let the tangents drawn from the origin to the circle, x2 + y2 – 8x – 4y + 16 = 0 touch it at the points A and B.
The (AB)2 is equal to:
56 64 32 52
(1) (2) (3) (4)
5 5 5 5
Ans. [2]
A
B
OA = S1
= 16 = 4
Radius = R = 16 + 4 − 16 = 2
2RL 2×4×2 16
Length of AB = = =
2 2 16 + 4 20
L +R
16 × 16 64
AB2 = =
20 5
Q.16 The value of c in the Lagrange's mean value theorem for the function f(x) = x3 – 4x2 + 8x + 11,
when x ∈ [0, 1] is:
4− 5 2 7 −2 4− 7
(1) (2) (3) (4)
3 3 3 3
Ans. [4]
f(x) = x3 – 4x2 + 8x + 11, x ∈ [0, 1]
Using LMVT
f (1) − f (0)
f ′(c) =
1− 0
16 − 11
3c2 – 8c + 8 =
1− 0
2
3c – 8c + 3 = 0
4− 7
c= ∈ (0, 1)
3
Q.17 Let A, B, C and D be four non-empty sets. The contrapositive statement of "If A ⊆ B and B ⊆ D, then
A ⊆ C" is:
(1) If A ⊆ C, then A ⊆ B and B ⊆ D (2) If A ⊆ C, then A ⊆ B and B ⊆ D
(3) If A ⊆ C, then A ⊆ B or B ⊆ D (4) If A ⊆ C, then B ⊂ A or D ⊂ B
Ans. [3]
Sol. If A ⊆ B and B ⊆ D then A ⊆ C
Contrapositive is
If A ⊆ C, then A ⊆ B or B ⊆ D
3 + i sin θ
Q.18 If , θ ∈ [0, 2π], is a real number, then an argument of sinθ + icosθ is:
4 − i cos θ
⎛ 3⎞ ⎛4⎞ ⎛4⎞ ⎛ 3⎞
(1) π – tan–1 ⎜ ⎟ (2) π – tan–1 ⎜ ⎟ (3) tan–1 ⎜ ⎟ (4) –tan–1 ⎜ ⎟
⎝4⎠ ⎝ 3⎠ ⎝ 3⎠ ⎝4⎠
Ans. [2]
3 + i sin θ (4 + i cos θ)
Let z = ×
4 − i cos θ (4 + i cos θ)
12 – sin θ cos θ + i(4sin θ + 3cos θ)
=
16 + cos 2 θ
z is real
∴ 4sinθ + 3cosθ = 0
−3
⇒ tanθ = [∵ θ lies is 2nd quadrant]
4
⎛ cos θ ⎞
arg(sinθ + icosθ) = π + tan–1 ⎜ ⎟
⎝ sin θ ⎠
⎛4⎞
= π – tan–1 ⎜ ⎟
⎝3⎠
Q.19 In a workshop, there are five machines and the probability of any one of them to be out of service on a day is
3
1 ⎛ 3⎞
. If the probability that at most two machines will be out of service on the same day is ⎜ ⎟ k, then k is
4 ⎝4⎠
equal to:
17 17 17
(1) 4 (2) (3) (4)
4 8 2
Ans. [3]
3
⎛3⎞
Prob. (at most two machines will be out of service) = ⎜ ⎟ .k
⎝4⎠
5 4 2 3 3
⎛3⎞ ⎛ 1 ⎞⎛ 3 ⎞ ⎛1⎞ ⎛3⎞ ⎛3⎞
⇒ 5 C0 ⎜ ⎟ + 5 C1 ⎜ ⎟⎜ ⎟ +5 C2 ⎜ ⎟ ⎜ ⎟ = ⎜ ⎟ .k
⎝4⎠ ⎝ 4 ⎠⎝ 4 ⎠ ⎝4⎠ ⎝4⎠ ⎝4⎠
3 3
17 ⎛ 3 ⎞ ⎛3⎞
⇒ . ⎜ ⎟ = ⎜ ⎟ .k
8 ⎝4⎠ ⎝4⎠
17
⇒k=
8
dy
Q.20 Let y = y(x) be the solution curve of the differential equation, (y2 – x) = 1, satisfying y(0) = 1. This
dx
curve intersects the x-axis at a point whose abscissa is:
(1) 2 (2) 2 + e (3) 2 – e (4) –e
Ans. [3]
dx
= y2 – x
dy
dy
+ x = y2
dx
I.F. = e ∫ = ey
1dy
⇒ x.ey = 2
∫ y .e dy
y
x.ey 2 y
= y .e – ∫ 2y.e dy y
xey = y2ey – 2yey + 2ey + C

∵ y(0) = 1
⇒C=–e
∴ xey = y2ey – 2yey + 2ey – e
put y = 0
∴x=0–0+2–e
⇒x=2–e
Q.21 Let X = {n ∈ N : 1 ≤ n ≤ 50}. If A = {n ∈ X : n is a multiple of 2} and B = {n ∈ X : n is a multiple of 7},

then the number of elements in the smallest subset of X containing both A and B is__________.
Ans. [29]
Sol. A = {2, 4, 6, 8..........50} ⇒ 25 elements
A = {7, 14, 21, ..........49} ⇒ 7 elements
A ∩ B = {14, 28, 42} = 3 elements
Required number of elements = 25 + 7 – 3 = 29
Q.22 If the mean and variance of eight numbers 3, 7, 9, 12, 13, 20, x and y be 10 and 25 respectively, then x.y is
equal to_________.
Ans. [54]
3 + 7 + 9 + 12 + 13 + 20 + x + y
Sol. Means = 10 =
8
16 = x + y ___(1)
2
Variance σ2 = 25 = ∑ i – (mean)2
x
8
3 + 7 + 9 + 12 + 132 + 202 + x 2 + y 2
2 2 2 2
25 = – 100
8
125 × 8 = 9 + 49 + 81 + 144 + 169 + 400 + x2 + y2
x2 + y2 = 148 ___(2)
(x + y)2 = x2 + y2 + 2xy
256 = 148 + 2xy
x.y = 54
⎧1 ⎛ 1 + 3x ⎞
⎛ 1 1⎞ ⎪ loge ⎜ ⎟, when x ≠ 0 is continuous, then k is equal
Q.23 If the function f defined on ⎜ − , ⎟ by f(x) = ⎨ x ⎝ 1 − 2x ⎠
⎝ 3 3 ⎠ ⎪⎩ k, when x = 0
to________.
Ans. [5]
⎛1 1 ⎞
Sol. lim f (x) = lim ⎜ n(1 + 3x) − n(1 − 2x) ⎟
x →0 x →0 x x
⎝ ⎠
⎛ 3 n(1 + 3x) 2 n(1 − 2x) ⎞
= lim ⎜ − ⎟
x →0
⎝ 3x −2x ⎠
=3+2=5
f is continuous ∴ lim f (x) = f(0)
x →0
∴ f(0) = 5 = k
Q.24 If the system of linear equations,

x+y+z=6
x + 2y + 3z = 10
3x + 2y + λz = μ
has more than two solutions, then μ – λ2 is equal to_________.
Ans. []
1 1 1
Sol. Δ= 1 2 3 =0
3 2 λ
⇒ 1(2λ – 6) – 1(λ – 9) + 1(– 4) = 0
⇒ 2λ – 6 – λ + 9 – 4 = 0
⇒λ=1
6 1 1
Δx = 10 2 3 = 0
μ 2 λ
⇒ 6(2λ – 6) – 1(10λ – 3μ) + 1(20 – 2μ) = 0
⇒ 12λ – 36 – 10λ + 3μ + 20 – 2μ = 0
⇒ 2λ + μ = 16
⇒ 2 + μ = 16
⇒ μ = 14
μ – λ2 = 14 – 1 = 13
Q.25 If the foot of the perpendicular drawn from the point (1, 0, 3) on a line passing through (α, 7, 1) is
⎛ 5 7 17 ⎞
⎜ , , ⎟ , then α is equal to________.
⎝3 3 3 ⎠
Ans. [4]
⎛ 5 7 17 ⎞
Sol. Δ≡ ⎜ , , ⎟
⎝3 3 3 ⎠
⎛ 5 7 17 ⎞
D ⎜ , , ⎟
A(α, 7, 1) ⎝3 3 3 ⎠
P(1, 0, 3)
AD.PD = 0
⎛⎛ 5 ⎞ˆ ⎛ 7 ⎞ ˆ ⎛ 17 ⎞ ˆ ⎞ ⎛ 2 ˆ 7 ˆ 8 ˆ ⎞
⎜ ⎜ 3 − α ⎟ i + ⎜ 3 − 7 ⎟ j + ⎜ 3 − 1⎟ k ⎟ . ⎜ 3 i + 3 j + 3 k ⎟ = 0
⎝⎝ ⎠ ⎝ ⎠ ⎝ ⎠ ⎠ ⎝ ⎠
⎛5 ⎞ 2 7 ⎛ −14 ⎞ 14 8
⎜ − α⎟ + × ⎜ ⎟+ × = 0
⎝3 ⎠3 3 ⎝ 3 ⎠ 3 3
2(5 – 3α) – 14 × 7 + 14 × 8 = 0
5 – 3α – 49 + 56 = 0
3α = 12
α=4

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CAREER POINT JEE Main Online Paper

JEE Main Online Exam 2020

Q.2 In the figure, potential difference between A and B is :

30V 10k 10k

Q.12 The electric field of a plane electromagnetic wave is given by –

T cos 45° = 100

E = 560 x ...... (i)

M gm water 200 gm water

Total heat = 600 M Total heat = 24000 M

JEE Main Online Exam 2020

Q.2 If the following reaction sequence,

CH3 CH3 CH3

Q.4 Among statement (a) – (d), the correct ones are :

Q.5 The correct order of stability for the following alkoxides is :

Acetophenone Acetannilide Anniline

Q.9 For the following reactions

Q.11 The equation that is incorrect is :

(2) (0m ) H 2O = (0m ) HCl + (0m ) NaOH – (0m ) NaCl

(3) (0m ) NaBr – (0m ) NaI = (0m ) KBr – (0m ) NaBr

(4) (0m ) KCl – (0m ) NaCl = (0m ) KBr – (0m ) NaBr

0m NaBr – 0m KBr = 0m Na – 0m K

Q.12 The redox reaction among the following is :

Q.13 For the reaction

Q.15 In the following reaction sequence, structures of A and B, respectively will be :

(1) OH & (2) OH &

(3) Br & (4) Br &

Q.16 Which of the following statements is correct ?

Q.20 Consider the following reaction :

Which of these reactions are possible ?

Q.23 Consider the following reactions :

Q.25 The number of sp2 hybridised carbons present in "Aspartame" is ____.

JEE Main Online Exam 2019

3 + 2 (a.b + b.c + c.a ) = 0

xey = y2ey – 2yey + 2ey + C

Q.21 Let X = {n ∈ N : 1 ≤ n ≤ 50}. If A = {n ∈ X : n is a multiple of 2} and B = {n ∈ X : n is a multiple of 7},

Q.24 If the system of linear equations,

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