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    Kineticsprelims 2010

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    Clarissa Alfaro
    This document contains a 15 multiple choice question exam on kinetics for a technological institute course. The exam covers topics like reaction rates, rate laws, batch reactors, gas phase reactions, reaction orders, half lives, and reaction problems. Students are asked to calculate quantities like concentration, time, pressure, and rate constants based on given rate laws and initial conditions.

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    Kineticsprelims 2010

    Uploaded by

    Clarissa Alfaro
    112 views2 pages
    This document contains a 15 multiple choice question exam on kinetics for a technological institute course. The exam covers topics like reaction rates, rate laws, batch reactors, gas phase reactions, reaction orders, half lives, and reaction problems. Students are asked to calculate quantities like concentration, time, pressure, and rate constants based on given rate laws and initial conditions.

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    Kinetics reviewer

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    kineticsprelims 2010

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    This document contains a 15 multiple choice question exam on kinetics for a technological institute course. The exam covers topics like reaction rates, rate laws, batch reactors, gas phase reactions, reaction orders, half lives, and reaction problems. Students are asked to calculate quantities like concentration, time, pressure, and rate constants based on given rate laws and initial conditions.

    Copyright:

    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd
    Download as doc, pdf, or txt
    112 views2 pages

    Kineticsprelims 2010

    Uploaded by

    Clarissa Alfaro
    This document contains a 15 multiple choice question exam on kinetics for a technological institute course. The exam covers topics like reaction rates, rate laws, batch reactors, gas phase reactions, reaction orders, half lives, and reaction problems. Students are asked to calculate quantities like concentration, time, pressure, and rate constants based on given rate laws and initial conditions.

    Copyright:

    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd
    Download as doc, pdf, or txt
    of 2

    TECHNOLOGICAL INSTITUTE OF THE PHILIPPINES

    KINETICS (CHE 573)


    PRELIM EXAMINATION
    STUDENT NO._____________________________ SECTION : _______________
    INSTRUCTOR : ENGR. LORRAINE A. CARRILLO DATE: July 21, 2010
    MULTIPLE CHOICE. ENCIRCLE THE CORRECT ANSWER. NO POINTS FOR CORRECT CHOICE BUT WITH NO
    DETAILED SOLUTION.
    1. For the reaction A B, The time to reduce the number of moles by a factor of 10 (Na = Na0/10) in a batch
    reactor for the above reaction with -rA = kCA, when k = 0.046 min-1
    a. 25 minutes b. 50.0 minutes c. 75 minutes d. none of the given

    A 200 - Liter constant-volume batch reactor is pressurized to 20 atm with a mixture of 75% A and 25% inert. The
    gas-phase reaction is carried out isothermally at 227 C.
    2. Assuming that the ideal gas law is valid, What is the initial concentration of A?
    a. 0.488m/L b. 0.366 moles/L c. 0.477moles/L d. 0.45 moles/L
    3. If the reaction is first order:  ra  kCa with k = 0.1 per min.
    Calculate the time necessary to consume 99% of A.
    a. 46.1 min b. 4.61 min c. 15.9 min d. 1.59 min
    2
    4. If the reaction is second order:  ra  kCa with k = 0.7 L/mol-min, the time necessary to consume 80% A
    a. 46.1 min b. 4.61 min c. 15.9 min d. 1.59 min

    5. The final pressure at T = 127°C.


    a. 34 atm b. 25.6 atm c. 23. 4 atm d. none of the given

    6. The following reaction is investigated in a constant density batch reactor:


    The reaction rate is: A + 2B 2R + S and the rate law is –ra = kCaCb2
    The reactor is initially charged with C ao and Cbo and Cao / Cbo = 3.0. Find the value of k if Cao = 0.01 mol/L and after
    10 min of reaction the conversion of A is 50 percent.
    a. 2.59 b. 94.37 c. 72.11 / hour d. NOTG

    7. The concentration of A after 25 minutes


    a. 0.0015 b. 0.0023 c. 0.0035 d. NOTG

    The homogeneous first – order gas phase reaction 2A 3B where in pure A at 1 atm was introduced into a
    constant – volume batch reactor. After 1 minute, the pressure increased to 1.5 atm.
    8. The relationship of the total pressure of the system to the partial pressure of A is
    a. 2PT= 2Pao – Pa b. Pa = 3Pao – PT c. 2PT = 3Pao – Pa d. Pa = 3PT – 2Pa

    9. The total pressure after 4 minutes if the reaction is zero order at T= 25°C.
    a. 2 atm b. 3.5 atm c. 2.4 atm d. none of the given

    10. The value of the rate constant k if the reaction is first order at the same temperature, same feed conditions.
    a. 1 b. 2 c. 3 d. none of the given

    11. The total pressure after 2 minutes if the reaction is first order at the same temperature, same feed conditions.
    a. 1.43 atm b. 1.76 atm c. 2.20 atm d. none of the given

    12. The Reaction: is carried out in a reactor. If at a particular point, the rate of
    disappearance of A is 10 mol/dm3/s, what are the rates of B and C?
    a. - rB = 15, rC = 30 b. - rB = 25, rC = 10 c. - rB = 15, rC = 25 d. - rB = 15, rC = -20

    13. The natural abundance of 235- U in uranium is 0.79 atom %. If a sample of uranium is enriched to 3 at. % and then is
    stored in salt mines under the ground, how long will it take the sample to reach the natural abundance level of 235U
    (assuming no other processes form 235U; this is not the case if 238U is present since it can decay to form 235U) ? The half-
    life of 235U is 7.13 X 10 8 years.
    a. 8.13 X 10 9 b. 1.4 X 10 9 c. 7.25 X 10 9 d. none of the given
    14. N2O5 decomposes into NO2 and N03 with a rate constant of 1.96 X 1014 exp [ -10,660/T]s-l. At t = 0, pure N2O5 is
    admitted into a constant temperature and volume reactor with an initial pressure of 2 atm. After 1 min, what is the total
    pressure of the reactor? T = 273 K .
    a. 3.5 atm b. 2.24 atm c. 2.64 atm d. none of the given

    15. Create a first-order reaction problem solving for the half –life of a reaction.

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