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    CHEM 18.1 Schematic Diagram Reviewer

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    Alphonse Rossaint Sambrano
    This document provides information on qualitative analysis reactions involving various cations and anions. It lists precipitating agents, final reagents, and the chemical reactions and observations for identifying cations like Pb2+, Hg22+, Ag+, Bi3+, Mn2+, Fe3+, Ba2+, Cu2+, Ni2+, Mg2+, Zn2+, Cd2+, Na+, K+, and NH4+. It also provides information on identifying anions like Cl-, Br-, I-, CO32-, C2O42-, S2O32-, S2-, SCN-, PO43-, SO42-, SO32-, NO3-, and NO2- using reagents like AgNO3, BaCl2, FeCl3, Fe

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    CHEM 18.1 Schematic Diagram Reviewer

    Uploaded by

    Alphonse Rossaint Sambrano
    254 views2 pages
    This document provides information on qualitative analysis reactions involving various cations and anions. It lists precipitating agents, final reagents, and the chemical reactions and observations for identifying cations like Pb2+, Hg22+, Ag+, Bi3+, Mn2+, Fe3+, Ba2+, Cu2+, Ni2+, Mg2+, Zn2+, Cd2+, Na+, K+, and NH4+. It also provides information on identifying anions like Cl-, Br-, I-, CO32-, C2O42-, S2O32-, S2-, SCN-, PO43-, SO42-, SO32-, NO3-, and NO2- using reagents like AgNO3, BaCl2, FeCl3, Fe

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    CHEM-18.1-Schematic-Diagram-Reviewer

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    This document provides information on qualitative analysis reactions involving various cations and anions. It lists precipitating agents, final reagents, and the chemical reactions and observations for identifying cations like Pb2+, Hg22+, Ag+, Bi3+, Mn2+, Fe3+, Ba2+, Cu2+, Ni2+, Mg2+, Zn2+, Cd2+, Na+, K+, and NH4+. It also provides information on identifying anions like Cl-, Br-, I-, CO32-, C2O42-, S2O32-, S2-, SCN-, PO43-, SO42-, SO32-, NO3-, and NO2- using reagents like AgNO3, BaCl2, FeCl3, Fe

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    254 views2 pages

    CHEM 18.1 Schematic Diagram Reviewer

    Uploaded by

    Alphonse Rossaint Sambrano
    This document provides information on qualitative analysis reactions involving various cations and anions. It lists precipitating agents, final reagents, and the chemical reactions and observations for identifying cations like Pb2+, Hg22+, Ag+, Bi3+, Mn2+, Fe3+, Ba2+, Cu2+, Ni2+, Mg2+, Zn2+, Cd2+, Na+, K+, and NH4+. It also provides information on identifying anions like Cl-, Br-, I-, CO32-, C2O42-, S2O32-, S2-, SCN-, PO43-, SO42-, SO32-, NO3-, and NO2- using reagents like AgNO3, BaCl2, FeCl3, Fe

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    EXE

    IONS PRECIPITATING AGENT FINAL REAGENT REACTIONS INVOLVED OBSERVATIONS


    R
    Pb2+ 1 M KI Pb2+(aq) +2I-(aq) ⇌ PbI2(s) Yellow ppt
    Hg22+ 6 M NH3 HgCl2(aq) + NH3(aq) ⇌ HgNH2Cl(s) +HCl(aq) Black/white ppt
    12 6 M HCl
    + Ag(NH3)2+(aq) +Cl-(aq) + 2H3O+ ⇌ AgCl(s) +
    Ag 6 M HNO3 White ppt
    2NH4+(aq) +2H2O(l)
    6 M NaOH 2Bi(OH)3(s) + 2Sn(OH)3-(aq) + 2OH-(aq) ⇌
    Bi3+ Black ppt
    SnCl2 2Bi(s) + 2Sn(OH)62-(aq) + H2O2(Aq)
    13 6 M NH3 3% H2O2 Mn2+(aq) + 4H3O+(aq) + BiO3-(aq) ⇌ Bi3+(aq) +
    Mn2+ Purple sol’n
    NaBiO3 MnO4-(aq) + 3H2O(l) + 3H2(g)
    Fe3+ 0.1 M KSCN Fe3+(aq) + SCN-(aq) ⇌ FeSCN2+(aq) Blood red sol’n
    Ba2+ 0.5 M (NH4)2C2O4 0.1 M K2CrO4 Ba2+(aq) + CrO42-(aq) ⇌ BaCrO4(s) Yellow ppt
    14
    Ca2+ Ammonium Oxalate 0.5 M (NH4)2C2O4 Ca2+(aq) + C2O42-(aq) ⇌ CaC2O4(s) White ppt
    2Cu(NH3)42+(aq) + 4H3O+(aq) + Fe(CN)64-(aq)
    Cu2+ 0.1 M K4Fe(CN)6 Maroon ppt
    Conc’d HNO3 ⇌ Cu2Fe(CN)6(s) + 4NH4+(aq) + 4H2O(l)
    6 M HCl Ni(NH3)62+(aq) + 2DMG ⇌ Ni(DMG)2(s) +
    Ni2+ 1% dimethylglyoxime (DMG) Cherry red ppt
    6NH3(aq)
    15 Mg (aq) + NH4 (aq) + HPO42-(aq) + OH-(aq) ⇌
    2+ +
    Mg2+ 0.1 M Na2HPO4
    MgNH4PO4(s) + H2O(l) White ppt
    2+ 6 M NaOH
    Zn 0.1 M K4Fe(CN)6 2Zn (aq) + Fe(CN)64-(aq) ⇌ Zn2Fe(CN)6(s)
    2+
    1 M NaOH
    0.1 M K4Fe(CN)6 Cd2+(aq) + Fe(CN)64-(aq) ⇌ Cd2Fe(CN)6(s) White ppt
    Cd2+
    0.2 M Na2S Cd2+(aq) + S2-(aq) ⇌ CdS(s) Yellow ppt
    Na+ Intense yellow flame
    Conc’d HCl (Flame test) No pertinent chemical reactions
    K+ Reddish violet flame
    16
    Litmus changes from
    NH4+ 6 M NaOH (Litmus paper test) NH4+(aq) + OH-(aq) ⇌ NH3(aq) + H2O(l)
    red to blue
    Cl- Br- I- CO32- C2O42- S2O32- S2- SCN- PO43- SO42- SO32- NO3- NO2-
    Cream/ Cream/
    White/ Dark Pale Dark Intense
    AgNO3 light light White White White White White White
    Gray Gray yellow brown yellow
    gray gray
    AgNO3 White/ Dark Pinkish
    Gray Yellow White White Brown White White White White White
    HNO3 Gray brown white
    Pale Yellow Pale Light Light Light Light Light Light Light Intense
    FeCl3 Yellow yellow
    Black
    yellow orange yellow yellow yellow yellow yellow yellow yellow yellow

    BaCl2 Clear Clear Clear Clear Clear White Clear Clear White White Clear Clear Clear

    BaCl2 Light
    Clear Clear Clear Clear White Clear Clear White White Clear Clear Clear
    HNO3 yellow
    Intense Intense Yellow Intense Intense Intense Blood Intense Yellow
    FeSO4 Yellow Yellow Yellow Yellow
    yellow yellow orange yellow yellow yellow red yellow brown
    FeSO4 Yellow Yellow Yellow Yellow Yellow Yellow Yellow Yellow Yellow Yellow Yellow
    Red Yellow
    H2SO4 (insol.) (insol.) (insol.) (insol.) (insol.) (insol.) (insol.) (insol.) (insol.) (insol.) (insol.)

    NOTES:
     Start with flame test and NH4+ test (Group E) then take note of the observations
     Then, start from the top and work way downward (Group A)
     DO NOT DISCARD SUPERNATANT, it will be used for succeeding tests
     If no precipitate forms after testing all groups, go back to results of flame test and NH 4+ test (Group E)
     Group B (Exer 13) – do not perform CB2 for Cr3+
     Group C (Exer 14) – remove last step of PC1; disregard PC2 (no Co 2+); remove last three steps of CC3; disregard PC5 (no Sr 2+)

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