UDK 621.791:621.791.053:669.14.018.

8 ISSN 1580-2949
Review article/Pregledni ~lanek MTAEC9, 47(4)403(2013)

A. CALIK, M. S. KARAKAª: EFFECT OF HEAT TREATMENT ON THE MICROSTRUCTURE ...

EFFECT OF HEAT TREATMENT ON THE

MICROSTRUCTURE AND MECHANICAL PROPERTIES
OF MARTENSITIC STAINLESS-STEEL JOINTS WELDED
WITH AUSTENITIC STAINLESS-STEEL FILLERS
VPLIV TOPLOTNE OBDELAVE NA MIKROSTRUKTURO IN
MEHANSKE LASTNOSTI MARTENZITNIH NERJAVNIH SPOJEV,
VARJENIH Z AVSTENITNIMI NERJAVNIMI ELEKTRODAMI

Adnan Calik, Mustafa Serdar Karakaº

Department of Manufacturing Engineering, Faculty of Technology, Suleyman Demirel University, 32260 Cunur, Isparta, Turkey
adnancalik@sdu.edu.tr

Prejem rokopisa – received: 2012-11-08; sprejem za objavo – accepted for publication: 2013-01-04

AISI 422 martensitic stainless steels were welded according to the ISO 15792-1 standard with austenitic stainless-steel filler.
The effects of tempering and preheating heat treatments were also evaluated. The microstructures of the welds were
characterized with optical microscopy. Mechanical properties were determined via microhardness, tensile and fatigue tests, and
compared to those of the unwelded AISI 422 steel. X-ray diffraction was used to characterize the phases present in the weld.
Chromium carbides were observed at the grain boundaries of the welds. The precipitation was caused mainly by the diffusion of
carbon into the austenitic stainless steel during the welding. The microhardness decreased from the base metal to the weld. The
tensile-strength and percent-elongation values were improved with preheating and tempering heat treatments. The highest
fatigue limit was obtained with preheating.
Keywords: welding, heat treatment, stainless steel, fatigue, hardness

Martenzitno nerjavno jeklo AISI 422 je bilo varjeno skladno s standardom ISO 15792-1 z elektrodami iz avstenitnega
nerjavnega jekla. Ocenjen je bil vpliv kaljenja in predogrevanja. Mikrostruktura zvarov je bila opredeljena s svetlobno
mikroskopijo. Mehanske lastnosti so bile dolo~ene z mikrotrdoto, nateznimi in utrujenostnimi preizkusi in primerjane z
nevarjenim jeklom AISI 422. Rentgenska difrakcija je bila uporabljena za karakterizacijo faz v zvaru. Po mejah zrn v zvaru je
bilo opaziti kromove karbide. Ve~ino izlo~anja je povzro~ila difuzija ogljika v avstenitno jeklo med varjenjem. Mikrotrdota se je
zmanj{evala od osnovnega materiala do zvara. Vrednosti natezne trdnosti in dele` raztezka so se pove~ali s predgrevanjem in s
toplotno obdelavo. Najvi{ja odpornost proti utrujanju je bila dose`ena s predgrevanjem.
Klju~ne besede: varjenje, toplotna obdelava, nerjavno jeklo, utrujenost, trdota

1 INTRODUCTION strength. For the fillet-welded and butt-welded joints the

fatigue strength is strongly dependent on the welding
For metals, fatigue failures occur more often in
procedure.8,9
welded joints than in unwelded structures. Weld defects
In spite of a poor weldability, martensitic stainless
and imperfections affect the fatigue and other mechani-
steels may be welded in the annealed, stress-relieved and
cal properties of structures.1,2 In general, fatigue strength
tempered conditions. As an alloying element, Cr has
decreases significantly with the introduction of any stress
very significant effects on the metallurgical aspect of the
raisers in metals. Machine parts contain stress raisers in
martensitic stainless steels. Cr and C are specifically
industrial applications. Fatigue cracks in structural parts added to steel to ensure the formation of martensite after
almost always initiate at geometrical irregularities.3 the hardening. Ni can be added, and it enhances both the
Weld defects and imperfections can be accepted as yield strength and ductility of these steels. The hardness
critical stress raisers in welded structures. Fatigue pro- in this type of material is dependent on the carbon
perties of welded joints are more complicated because of content.10 The carbon content can also affect the hard-
the nature of the weld. Slag inclusions, pores, undercuts, ness of the heat-affected zone (HAZ). Thus, the influ-
incomplete fusion and residual stresses all affect the ence of hardness of HAZ may be controlled with
crack initiation and crack-propagation stages of the welding characteristics. In general, the welding of the
fatigue life of a welded joint.4–6 In addition, surface martensitic stainless steels with a carbon content higher
roughness and section changes may also affect the than 0.25 % is not recommended. In the 0.05–0.15 % C
existing or newly developing fatigue cracks. The fatigue range, the hardness increases with the increasing carbon
behavior of a welded joint is influenced by the thickness concentration. Austenitic or ferritic-austenitic electrodes
of a plate as well as by the other geometrical para- are used for martensitic stainless steels. The hardness
meters.7 However, there is conflicting evidence with and ductility of a weld and HAZ vary in a welded struc-
regard to the effect of a welding procedure on the fatigue ture. To avoid this harmful effect on the welded AISI 420

Materiali in tehnologije / Materials and technology 47 (2013) 4, 403–407 403

A. CALIK, M. S. KARAKAª: EFFECT OF HEAT TREATMENT ON THE MICROSTRUCTURE ...

Table 1: Chemical composition of the AISI 422 steel in mass fractions, w/%
Tabela 1: Kemijska sestava jekla AISI 422 v masnih dele`ih, w/%

Element C Si S P Mn Ni Cr Mo V Fe
Composition 0.220 0.220 0.023 0.02 0.403 1.268 11.15 0.086 0.017 Bal.

steel, preheating and a slow cooling rate after the weld-

ing must be considered.11,12 Table 2: Dimensions (mm) of the type 1.3 weld test specimen
depicted in Figure 1
In this study, an attempt has been made to clarify the
Tabela 2: Dimenzije (mm) preizku{anca za varjenje vrste 1.3, prika-
effects of pre- and post-weld treatments on the welding zanega na sliki 1
of the martensitic stainless steel with an austenitic stain-
less-steel filler. The present study highlights the effects t a b u l
of preheating and tempering on the microstructural, 20 ≥ 150 16 6 10 ≥ 150
hardness and tensile properties, and on the fatigue
behavior of the welded joints. The specimens were thoroughly cleaned with acetone
before the welding. The austenitic stainless-steel
2 EXPERIMENTAL PROCEDURE electrodes (E310L) of a 3.25 mm diameter were used for
the welding tests. The chemical composition of the
2.1 Materials welding electrodes is shown in Table 3. In order to
AISI 422 steel in its annealed state was used as the prevent hydrogen-induced cracking, the electrodes were
base metal for the welding experiments. The chemical dried in a muffle furnace at 573 K for 2 h before the
composition of the steel is given in Table 1. This steel is welding. The welding procedure was then carried out
widely used in the transmission systems of diesel loco- manually in a single V-butt-joint configuration using a
motives. Cylindrical as-cast billets of 80 mm diameters UMS 250 DC type electric-arc welding machine with a
and 1 m lengths were hot-forged at 800 °C into the plates total of 13 passes. The current was held constant at 170
of 25 mm thickness. A. The total of 13 runs were needed to fill the groove
The forged plates were then machined to the weld between the butt joints.
specimen dimensions specified in the ISO 15792-1 Table 3: Chemical composition of the E310L filler electrode in mass
standard. The geometry of the weld specimens is shown fractions, w/%
in Figure 1a. Type 1.3 specimens were used and their Tabela 3: Kemijska sestava varilne elektrode E310L v masnih dele`ih,
dimensions are given in Table 2. An OFHC (Oxygen w/%
Free High Conductivity) copper backing strip was used
C Mn Si Ni Cr Fe
during the welding. The sequence of the welding passes 0.10 2.0 0.4 20 25 Bal.
is shown in Figure 1b.
The effects of preheating and tempering heat treat-
ments were investigated. The welding parameters and
notations used for the as-welded, preheated and tem-
pered specimens are summarized in Table 4. From here
onwards, the codes AW, PH and TP shall be used to
express the as-welded, preheated and tempered speci-
mens, respectively.

Table 4: Welding parameters used for the test specimens

Tabela 4: Parametri varjenja, uporabljeni pri preizkusnih vzorcih

Specimen Filler metal Preheating PWHT

AW E310L N/A N/A
PH E310L 623 K, 2 h N/A
TP E310L N/A 1023 K, 3 h

2.2 Metallography
The microstructures of the welded joints were eva-
luated using optical microscopy. The specimens exa-
mined were prepared using standard metallographic
Figure 1: a) Shape and dimensions of a weld specimen as indicated in
the ISO 15792-1 standard; b) sequence of the welding passes techniques. The original microstructure of the original
Slika 1: a) Oblika in dimenzije varjenih vzorcev, kot je prikazano v AISI 422 steel (before the welding) is shown in Figure
ISO 15792-1 standardu, b) potek zaporedja prehodov v zvaru 2. This reveals a fine, fully martensitic microstructure.

404 Materiali in tehnologije / Materials and technology 47 (2013) 4, 403–407

 A. CALIK, M. S. KARAKAª: EFFECT OF HEAT TREATMENT ON THE MICROSTRUCTURE ...

with the ISO 1143-1 standard. Microhardness measure-

ments were made utilizing a Vickers indenter with a load
of 100 g and dwell time of 15 s. For each of the me-
chanical tests, a minimum of three measurements/tests
were made for each experimental condition.

3 RESULTS AND DISCUSSION

After the welding, the specimens generally consisted
of three distinctive regions: (i) the weld metal; (ii) the
heat-affected zone (HAZ) and (iii) the base metal that
was not affected by the welding process. The micro-
structures of the AW specimen are shown in Figure 3.
The weld metal shows a microstructure consisting main-
Figure 2: Microstructure of the AISI 422 base metal
Slika 2: Mikrostruktura osnovnega materiala AISI 422 ly of austenite (Figure 3a), with delta ferrite present at
the grain boundaries.
The HAZ of the AW specimen revealed both mar-
2.3 Mechanical testing tensite and austenite phases. The coexistence of the two
phases in the AW specimen is shown in Figure 3b. The
Tensile, fatigue, and microhardness test specimens
microstructure also shows the presence of precipitates
were extracted from the welded samples. Tensile tests
(possibly inclusions) located at the centers of the
were carried out at room temperature in accord with the
ISO 6892-1 standard. Yield strength (YS), ultimate austenite phases. The XRD pattern of the weld in Figure
tensile strength (UTS) and fraction of elongation (% EL) 4 indicates the presence of chromium carbides (Cr23C6,
values were determined. Fatigue tests were done using a Cr7C3). High temperatures, combined with the diffusion
rotating bar bending fatigue testing machine in accord of C from the martensitic stainless steel to the austenitic
stainless steel may have caused the formation of these
carbides during the welding.
The microstructures of the PH specimen are shown in
Figure 5. The microstructure of the weld metal reveals
an austenitic structure with possible delta ferrite
segregated at the grain boundaries (Figure 5a). The heat
affected zone (HAZ) between the weld and the base
metal reveals the presence of martensite and austenite
phases (Figure 5b).
The microstructures of the TP specimen are shown in
Figure 6. The microstructure of the weld metal is auste-
nitic, similar to the weld metal observed in the AW and
PH specimens. However, the dendritic morphology of
the austenitic structure is much more visible (Figure 6a).

Figure 4: XRD pattern of the AW specimen indicating the presence of

Figure 3: Microstructure of the AW specimen: a) weld metal; b) HAZ chromium carbides
Slika 3: Mikrostruktura AW-vzorcev: a) zvar, b) toplotno vplivana Slika 4: Rentgenski (XRD) posnetek, ki ka`e prisotnost kroma v
cona (HAZ) vzorcu AW

Materiali in tehnologije / Materials and technology 47 (2013) 4, 403–407 405

A. CALIK, M. S. KARAKAª: EFFECT OF HEAT TREATMENT ON THE MICROSTRUCTURE ...

Figure 6: Microstructure of the TP specimen: a) weld metal; b) HAZ

Figure 5: Microstructure of the PH specimen: a) weld metal; b) HAZ
Slika 6: Mikrostruktura TP-vzorca: a) zvar, b) toplotno vplivana cona
Slika 5: Mikrostruktura PH-vzorca: a) zvar, b) toplotno vplivana cona (HAZ)
(HAZ)

The heat affected zone (HAZ) between the weld and the
base metal again reveals a microstructure consisting of
martensite and austenite phases (Figure 6b). Compared
to the AW and PH specimens, the martensite phase in the
TP specimen has a coarser appearance due to the effects
of tempering.
The hardness test results are summarized in Figure 7.
Microhardness measurements were made both across
and along the weld centerline. Figure 7a indicates a
decrease in the microhardness towards the weld metal for
all the welded joints. This is expected, since the base
metal consists of martensite and the weld metal consists
of either austenite or a mixture of austenite and some
delta ferrite. Figure 7b shows the microhardness distri-
bution for the weld from top to bottom. While the
microhardness distribution for the AW specimen is more
or less constant, a steady decrease is observed for the PH
and TP specimens. As welding was carried out in 13
passes, each pass resulted in a tempering treatment on
the previous pass, which led to the softening of the
underlying layers.
The tensile-test results for the welded specimens are
Figure 7: Microhardness distribution for the welded joints: a) across
listed in Table 5. Failures occurred within the weld the weld centerline and b) on the weld centerline from top to bottom
metal. The YS showed no change with preheating and Slika 7: Razporeditev mikrotrdote v varjenih spojih: a) preko sredine
remained constant at 490 MPa. The tempering treatment zvara in b) na sredini zvara od vrha do dna

406 Materiali in tehnologije / Materials and technology 47 (2013) 4, 403–407

 A. CALIK, M. S. KARAKAª: EFFECT OF HEAT TREATMENT ON THE MICROSTRUCTURE ...

4 CONCLUSIONS

The effect of preheating and post-weld tempering on

the microstructure and mechanical properties of welded
martensitic stainless steels was studied. The conclusions
drawn from this study are as follows:
1) The grain boundary precipitation of chromium
carbides was observed in the welded joints. The
precipitation was mainly caused by the diffusion of
carbon into the austenitic stainless steel during the
welding.
2) A decrease in the microhardness was observed
moving from the base metal to the weld. The decrease in
and absence of the martensite phase in the HAZ and the
weld, respectively, were the main causes for a decreased
Figure 8: Wöhler (S – N) diagram showing fatigue test results
hardness.
Slika 8: Wöhlerjeva krivulja (S – N) prikazuje rezultate preizkusov 3) An increase in the tensile strength and percent
utrujenosti elongation was observed after the preheating and
tempering heat treatments.
resulted in a decrease in the YS to 467 MPa. The UTS 4) Preheating provided the best fatigue results for the
increased from 630 MPa to 660 MPa with preheating. welded specimens. The fatigue limits observed for the
The tempering further increased the UTS to 683 MPa. tempered specimens were slightly lower than those
The elongation values increased with preheating and found in the preheated specimens.
tempering treatments. With preheating, the fraction of
EL values increased from 12.5 % to 18.8 %. With
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