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    Time: 1 Hrs Max. Marks: 75 Single Correct: OH H OH H CH Oh CH Oh O

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    lakshmi.vedanarayanan7785
    This document contains a 75-mark, single correct chemistry exam with multiple choice questions. The exam tests knowledge of organic chemistry concepts like monomers, amino acids, carbohydrates, reactions, and mechanisms. It contains 7 single answer multiple choice questions, 3 short answer comprehension questions, 9 assertion-reason questions, 12 questions asking to identify suitable reagents, and 14 matching questions. The exam covers a wide range of organic chemistry topics and tests understanding at various levels of complexity.

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    Time: 1 Hrs Max. Marks: 75 Single Correct: OH H OH H CH Oh CH Oh O

    Uploaded by

    lakshmi.vedanarayanan7785
    93 views5 pages
    This document contains a 75-mark, single correct chemistry exam with multiple choice questions. The exam tests knowledge of organic chemistry concepts like monomers, amino acids, carbohydrates, reactions, and mechanisms. It contains 7 single answer multiple choice questions, 3 short answer comprehension questions, 9 assertion-reason questions, 12 questions asking to identify suitable reagents, and 14 matching questions. The exam covers a wide range of organic chemistry topics and tests understanding at various levels of complexity.

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    Quiz

    Original Title

    Test-1

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    This document contains a 75-mark, single correct chemistry exam with multiple choice questions. The exam tests knowledge of organic chemistry concepts like monomers, amino acids, carbohydrates, reactions, and mechanisms. It contains 7 single answer multiple choice questions, 3 short answer comprehension questions, 9 assertion-reason questions, 12 questions asking to identify suitable reagents, and 14 matching questions. The exam covers a wide range of organic chemistry topics and tests understanding at various levels of complexity.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    93 views5 pages

    Time: 1 Hrs Max. Marks: 75 Single Correct: OH H OH H CH Oh CH Oh O

    Uploaded by

    lakshmi.vedanarayanan7785
    This document contains a 75-mark, single correct chemistry exam with multiple choice questions. The exam tests knowledge of organic chemistry concepts like monomers, amino acids, carbohydrates, reactions, and mechanisms. It contains 7 single answer multiple choice questions, 3 short answer comprehension questions, 9 assertion-reason questions, 12 questions asking to identify suitable reagents, and 14 matching questions. The exam covers a wide range of organic chemistry topics and tests understanding at various levels of complexity.

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    You are on page 1of 5

    Time : 1 hrs Max.

    Marks: 75
    Single correct
    Q.1 Monomer used to prepare Orlon is: [7 × 3=21]
    (A) CH2=CHCN (B) CH2=CH–Cl (C) CH2=CHF (D) CH2=CCl2

    Q.2 Which one of the following is non-reducing sugar?


    (A) Glucose (B) Arabinose (C) Fructose (D) Sucrose

    Q.3 A tripeptide has ...... peptide bonds :


    (A) three (B) two (C) four (D) one

    Q.4 Structure of D mannose is


    CHO
    |
    HO  C  H
    |
    HO  C  H
    |
    H  C  OH
    |
    H  C  OH
    |
    CH 2OH
    Structure of L mannose will be

    (A) (B) (C) (D)

    Q.5 How many products are produced respectively when optically pure glucose and fructose are reduced
    one by one by NaBH4.
    (A) 1 & 1 (B) 2 & 2 (C) 1 & 2 (D) 2 & 1

    Q.6 Correct statement about I and II


    CH2OH
    H O OH
    CH2OH CH2OH H
    H O H H O H CH2OH OH H
    HO O O H
    H H
    OH H OH H OH
    (I) O (II) H H
    OH OH OH H
    OH OH H H
    H H
    H OH
    (A) I is reducing sugar (B) II is reducing sugar
    (C) I & II both are reducing sugar (D) None of the two is reducing sugar

    Page No.1

    Q.7 N H 3 – CH(R)– CO2H has its Ka1 = 10–7. The isoelectric point of the -amino acid occur at pH = 8.2
    hence pKa2 of the conjugate acid of -amino acid is equal to
    (A) 9.4 (B) 1.2 (C) 7.6 (D) 2.4

    Comprehension [3 × 3 = 9]
    Question No. 8 to 10 (3 questions)
    A research scholar synthesised the compound A in the laboratory

    A:

    He wanted to study this compound in acidic medium and kept for some time in it. After an hour, when
    isolated the compound, to his surprise, he got the mixture of two compounds B, C. He studied their
    properties and compared them with A.
    A B C
    reaction with HaHCO 3 brisk effervescence no no
    blue litmus red no no
    NaOI no no yellow ppt.
    [Ag(NH 3) 2] no no silver - mirror

     B  C carbon  54.55%,
    H3O
    clue original A 
    hydrogen  9.1%
    Q.8 B formed is

    (A) (B) (C) (D) none

    Q.9 Compound C is
    O
    ||
    (A) CH 3CCH 3 (B) CH3CH2CHO (C) HCHO (D) CH3CHO
    Q.10 B is formed due to
    (A) cleavage of C–O bond followed by esterification between –COOH and –OH present.
    (B) decarboxylation of –COOH group
    (C) oxidation of –CH2COOH into –COOH
    (D) none

    Assertion & Reason [3 × 3 =9]


    O O
    || 18 | | 18
    Q.11 Statement-1: Me 3C  C  OH + MeOH conc . H 2SO4
     Me 3C  C  OMe (major)
    Statement-2: During esterification, removed water molecule contains H of alcohol and OH of carboxylic
    acid.
    (A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
    (B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
    (C) Statement-1 is true, statement-2 is false.
    (D) Statement-1 is false, statement-2 is true.

    Page No.2
    Me Me Me
    | | conc.H 2SO 4 |
    Q.12 Statement-1: Me  C  CH 2  C  Me   
     Me 3C  CH  CMe 2 + Me3C  CH 2  C  CH 2
    | | P1 P2
    Me OH Major

    Statement-2: P1 is having 6 H while P2 is having 5  H so P1 is Saytzef's alkene.


    (A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
    (B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
    (C) Statement-1 is true, statement-2 is false.
    (D) Statement-1 is false, statement-2 is true.

    Q.13 Statement-1 : Rate of nitration is C6H6 ~  C6D6  ~ CT


    6 6
    Statement-2 : Formation of wheland intermediate is rate determining step in nitration of benzene, not
    the breaking of C–H or C–D bond.
    (A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
    (B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
    (C) Statement-1 is true, statement-2 is false.
    (D) Statement-1 is false, statement-2 is true.

    More than one may be correct

    Q.14 Suitable reagent(s) to carry out following conversion is / are [3 × 4 = 12]


    O
    N C–CH3  N Et
    CH3 CH3
    CH 2  SH
    (A) | / H2 / Ni followed by OHr (B) N2H4 / H2O2
    CH 2  SH
    (C) N2H4 / EtONa (D) Zn / Hg / HCl

    Q.15 Which is not cleaved by HIO4?


    (A) glycerol (B) glycol (C) 1,3-propandiol (D) 1-methoxy-2-propanol


    Q.16 + PhN 2 Cl–  ? H
    3O
    

    Final product is a mixture containing:

    (A) (B) (C) (D)

    Page No.3
    Match the column [14]
    Q.17 Column I Column II
    H 2O Cu Cl
    (A) Mg2C
    3  A2
    2  ? (P) Purple colour
    NH 4OH

    neutral
    O3 Cr2O3 Oleum ( i ) NaOH ,
    (B) HexaneAl
    2    B C    D FeCl
    3  ? (Q) Yellow colour
     
    ( ii ) H
    Et SO air FeSO
    (C) Ethanol 2 
    4  E  F  4  ? (R) Red colour
    hv KCNS
    O

    NK
    Na Br O
    (D) 
    Ethylpropandioate G 2 H
     I (S) No colour
    3 H O
      J Ninhydrin
      ?

    Subjective [2 × 5 = 10]
    Q.18 Reaction :–1 CH3–CH2–CH2–CH2–CH3 Cl
    2 Optically active monochloro product(s) are (R)
    
    h

    Cl
    Reaction :–2 2 Optically active di-chloro product(s) are (S)
    
    h

    Cl
    Reaction :–3 2 Optically active di-chloro product(s) are (P)
    
    h

    Reaction :–4 2-methoxy propane Cl


    2 Optically active mono chloro product(s) are (Q)
    
    h
    Sum of P + Q + R + S is

    Q.19 (reaction-1)
    ( i ) x CH MgBr
    3
       
    
    ( ii ) H 3O 

    ( i ) y CH MgBr
    3 (reaction-2)
       
    

    ( ii ) H3O

    O OH
    || | (reaction-3)
    Et  O  C  O  Et ( i ) z PhMgBr
      Ph  C  Ph
    ( ii ) H  |
    Ph
    What is the value of x + y + z = ?

    Page No.4
    Answers
    1. A 2. D 3. B 4. C

    5. C 6. C 7. A 8. A

    9. D 10. A 11. D 12. D

    13. A 14. A, C 15. C, D 16. A, B, C, D

    17. (A) R, (B) P, (C) R (D) P

    18. 9 19. 12

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