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    Time: 1 Hrs Max. Marks: 79 Single Correct: O Ph-C-O

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    lakshmi.vedanarayanan7785
    The document contains a 19 question chemistry exam covering topics like organic reactions, stereochemistry, and spectroscopy. It tests the ability to name organic compounds, identify reaction intermediates and products, determine stereochemical outcomes, and calculate values like number of isomers. The exam has multiple choice, matching, and short answer questions requiring reasoning about reaction mechanisms and structural properties.

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    Time: 1 Hrs Max. Marks: 79 Single Correct: O Ph-C-O

    Uploaded by

    lakshmi.vedanarayanan7785
    47 views6 pages
    The document contains a 19 question chemistry exam covering topics like organic reactions, stereochemistry, and spectroscopy. It tests the ability to name organic compounds, identify reaction intermediates and products, determine stereochemical outcomes, and calculate values like number of isomers. The exam has multiple choice, matching, and short answer questions requiring reasoning about reaction mechanisms and structural properties.

    Original Description:

    Quiz

    Original Title

    Test-4

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    The document contains a 19 question chemistry exam covering topics like organic reactions, stereochemistry, and spectroscopy. It tests the ability to name organic compounds, identify reaction intermediates and products, determine stereochemical outcomes, and calculate values like number of isomers. The exam has multiple choice, matching, and short answer questions requiring reasoning about reaction mechanisms and structural properties.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    47 views6 pages

    Time: 1 Hrs Max. Marks: 79 Single Correct: O Ph-C-O

    Uploaded by

    lakshmi.vedanarayanan7785
    The document contains a 19 question chemistry exam covering topics like organic reactions, stereochemistry, and spectroscopy. It tests the ability to name organic compounds, identify reaction intermediates and products, determine stereochemical outcomes, and calculate values like number of isomers. The exam has multiple choice, matching, and short answer questions requiring reasoning about reaction mechanisms and structural properties.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 6

    Time : 1 hrs Max.

    Marks: 79
    Single correct [6 × 5=30]
    O CH 2  Ph O Me
    || | || |
    Q.1 HOOC  CH 2  NH  C  CH — NH  C  CH  NH 2
    What will be the correct representation of the above tripeptide.
    (A) Gly-Phe-Ala (B) Ala-Gly-Phe (C) Gly-Ala-Phe (D) Ala-Phe-Gly

    (i ) LAH
    SOCl2 (ii ) H3O
    Q.2 4-Pentenoic acid  (X) (Y)   (Z)
    (iii ) dil OH
    Identify final (major) product:
    O
    ||
    (A) CH 2  CH  CH 2  CH 2  C  N (B) CH2=CH–CH2–CH2–CH2–N

    OH
    |
    (C) CH 2  CH 2  CH 2  CH 2  CH  N (D) CH3–CH2–CH2–CH2–CH2– OH

    Q.3  X. X will be
    

    (A) (B) (C) (D) None

    Q.4 Suitable reagent(s) to convert acetyl chloride into acetaldehyde is / are :


    (a) Na–C2H5OH (b) NaBH4 (c) H2/Pd–BaSO4 (d) LiAlH (CMe3)3
    (A) a, b, c (B) c, d (C) b, c, d (D) a, b, c, d

    O 18
    Q.5 || + H–O HCl
     (X)
    Ph  C  O  H 
    Major product (X) is.
    18
    O O O
    18
    (A) Ph–C–O (B) Ph–C–O (C) Ph–C–O (D) Ph–O

    Page No.1
     
    Q.6 EtO
     A H3O B Zn
    (Hg)
     C
     HCl

    C is:

    (A) (B) (C) (D)

    Comprehension [3 × 3 = 9]

    Comprehension (Q.7 & Q.9)


    Dr. Sandy Robertson worked out following reaction sequence.

    Br alc.KOH
    NBS

    alc.KOH
     (A)  (B) 2  (C)   (D) HgSO
     4  (E)
    CCl NaNH
    4 dil. H SO
    2 2 4

    KOH
    (G) excess
     (F)
    Q.7 Select true statement(s):
    (A) when D is treated with D2 Pd BaSO4 it gives cis alkene.
    (B) when D is treated with Na liq. ND3 it gives trans alkene.
    (C) both
    (D) none

    Q.8 True about E is:


    (A) It gives positive Fehling test.
    (B) It does not give positive test with Braddy's reagent.
    (C) It gives positive Iodoform test.
    (D) It gives effervescence with NaHCO3.

    Q.9 G is:

    (A) Ph  C  CH (B) Ph  C  CHO


    || ||
    O O
    (C) Ph  CH  CHO (D) Ph  CH  COOK
    | |
    OH OH
    More than one may be correct [3 × 3 = 9]

    Q.10 HgSO4 / H2SO4 and B2H6 / NaOH H2O2 will give same major product, when react with which of the
    following.
    (A) O2N– C  CH (B)
    H
    (C) (D)

    Q.11 In which of the following case configuration about chiral C* is retained:

    Na CH Br SOCl CH ONa
    (A)  3 (B) 2  3

    PCl CH ONa H  / MeOH


    (C) 3  3 (D)   
    

    Q.12 Final product of which of following reaction give positive iodoform test.

    (A) + CH3MgBr (1 mole)  (a)

    O
    ||
    (B) CH 3  C  O  Et + PhMgBr (1 mole)  (b)

    O
    ||
    (C) Cl  C  Cl + CH3MgBr (excess)  
    
    (c)
    ( 2) H

    O O
    || ||
    (D) CH 3  C  O  C  CH 3 + PhMgBr (excess)  
    
    (d)
    ( 2) H
    2 Match the column [2 × 8 = 16]

    Q.13 Column I Column II

    O NO2

    CH2 – C – O
    (A) (P) Positional isomers
    OH

    O NO2

    O– C – CH2 (Q) Metamers


    OH

    (B) (R) Geometrical isomers

    C C
    T C–O–C–C=C H C–O–C–C=C
    (C) C=C C=C (S) First is Z and second is E.
    H D T D

    Q.14 Column I Column II


    (Product differentiate by)
    O3
    (A) CH3–CH=CH2 
    Zn
    (U) + (V) (P) By Haloform test

    CH 3
    |
    O3
    (B) CH 3  C  CH  CH 3  (W) + (X) (Q) By Fehling test
    Zn
    O
    || 
    (C) Ph  C  O  Ph H (Y) + (Z)
    3O (R) By aq. NaHCO3

    (S) By Tollen Test


    Subjective [5 × 3 = 16]

    Q.15 Cyclohexane-1,4-dione is a polar compound, having dipole moment value of 1.2 D. If mol
    fraction of its chair form is 0.80, what will be the dipole moment of twisted boat form?

    Q.16 Number of meso isomer of the given compound is


    Br Br
    C
    C

    Br Br

    Me
    H D
    Q.17 Number of optically active isomer of H D
    H D
    Me

    Q.18 Total number of geometrical isomer possible for

    PhNHNH
    Q.19 2  ?
      
    ( Excess)

    Total how many osazones are obtained in this reaction sequence (z).
    Answers
    1. D 2. B 3. C 4. B

    5. A 6. C 7. A 8. C

    9. D 10. A, B, C 11. A, C 12. A, B

    13. (A) Q, S (B) P,S (C) R,S 14. (A) P, (B) Q,S (C) R

    15. 6 16. 1 17. 2

    18. 0 19. 1

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