SINGLE CORRECT

1. Which one of the following is correct?

(A) If one component of a binary liquid-liquid solution deviate negatively from Raoult’s law, then
the solution will form minimum boiling point azeotrope.
(B) for a solution of two liquids (A and B), Vsol > VA + VB; then A and B can be separated by
fractional distillation.
(C) Deep sea divers use a mixture of He and O2 instead of air due to less solubility of He in blood
in comparison to N2, which cause the bends, i.e. pain due to bubbling of untreated gas
dissolved in blood.
(D) All of the above.

2. A compound is composed of two elements A and B, element A constitute f.c.c. lattice, while B
occupy all the tetrahedral voids, in this way another simple cubic is constituted by element B,
inside the fcc unit cell of element A. If all the points/particles along any one edge of inner cube of
every unit cell, are missing then what is the new empirical formula of the compound
(A) A4B6 (B) A2B8
(C) A2B3 (D) AB4

3. Which of the following gives yellow precipitate with aq. AgNO3?

(A) KIO3 (B) KI
(C) CHI3 (D) CH2I2

4. How many planes of symmetry and axis of symmetry are there in one molecule of PCl 3F2,
respectively?
(A) 4, 7 (B) 7, 13
(C) 7, 10 (D) 4, 10

5. Two cylinders A and B of equal volumes are filled and equal masses of N2 and O2, respectively.
Cylinder A is kept at 300 K while B is kept at 600 K, then (assume ideal behaviour of both gases)
(A) Average kinetic energy of N2 (per mole) in A is equal to that of O2 in B.
(B) Molecules in cylinder B move twice as fast as those in A.
(C) Pressure in flask A is less than that of B.
(D) Average velocity of N2 is equal to rms velocity of O2, in the given conditions.

st rd +
6. The ratio of time periods taken by electron in 1 and 3 orbits of He ion, for each revolution is.....
(A) 1 : 9 (B) 1 : 27
(C) 8 : 27 (D) 8 : 9

7. The equilibrium constant of mutarotation of -D-glucose to -D-glucose is 1.8. If specific rotation

of -D-glucose is 112o and that of mixture is 59o; what is specific rotation of -D-glucose?
(A) - 112o (B) - 59o
o
(C) +29.6 (D) - 29.6o
8. Which of the following is correct?
(A) cis-cycloalkane is always more stable than trans cycloalkane.
Cl Cl
(B) C C C C C does not show geometrical isomerism
H H

N C N show geometrical isomerism.

(C)
NH

(D) does not show any type of isomerism

NH

9. Which of the following will undergo E1cB.?

(A) (B)
Br
Br

(C) O OH (D) Br

10. From which of the following halogen can be replaced by H2O by SN1?
(A) CH3 — Br (B)
Br
(C) (D)
Br Br

11. OH

H SO
2


4
X

O
Product X is :
(A) OH (B) OH

(C) O (D) OH

OH
12. Which of the following can not be used for protection of carbonyl group?
(A) CH2(OH)CH2CHO (B) CH2(OH)—CH2CH2(OH)/H+
+
(C) CH2(OH) CH2(OH)/H (D) HS(CH2)3SH

13. The configuration of the C-2 epimer of D-glucose is

(A) 2R, 3S, 4R, 5S (B) 2R, 3S, 4R, 5R
(C) 2S, 3S, 4R, 5R (D) 2S, 3R, 4R, 5S

14.
OCH2CH CH2
H3C CH3

 ?

The product is
(A) OCH3 (B) OH
H3C CH3 H3C CH3

CH2CH CH2

CH CH2
(C) OH (D) OH
H3C CH3 H3C CH3

CH2CH CH2

CH2 CH CH2
HCO H H O Phthalic Anhydride/H
15. Acetophenone 
3
 A 3
  Indicator D  is
B  C 
Major 

(A) PhOH (B) O

C CH3

C CH3
O
(C) OH (D) O
OH
C OH

C OPh
O
O

O
16. The complex [Fe(H2O)5(NO)]2+ is formed in the ring test for nitrate when freshly prepared FeSO4
solution is added to aqueous solution of NO3 followed by addition of conc. H2SO4. The complex is
formed by charge transfer in which:
2+ 3+ +
(A) Fe charges to Fe , NO to NO
(B) Fe charge to Fe and NO changes to NO+
3+ 2+

(C) Fe2+ changes to Fe+ and NO changes to NO+

(D) Fe2+ changes to Fe3+ and NO+ changes to NO

17. Which of the following match is correct?

Ore/ Minerals Element
(A) Bauxite B
(B) Magnetite Mn
(C) Bornite B
(D) Cerussite Pb

18. Which of the following is correct about Boron nitride {(BN)x}?

(A) All the atoms of the ring are uncharged
(B) It is insulator, unlike graphite
(C) Inter-layer distance in its graphite like structures, is less than that of graphite
(D) Resonance energy of each hexagon of (BN)x is greater than that of Benzene.

19. Which of the following is true?

(A) Oxides of Ge, Sn and Pb are amphoteric in nature
(B) Producer gas is produdced in incomplete combustion of C by air (O2 + N2)
(C) SnO is much better reducing agent than PbO.
(D) All are correct

20. Which of the following can not be used as nitrating agent in Electrophilic Aromatic Substitution of
benzene?
(A) N2O5/MeCN (B) C2H5ONO2
(C) C2H5NO2 (D) NO2.SO3

21. NH2

1 CH3COCl Conc. H2SO4 HNO3 (I) aq. H2SO4 / 

  X   Y   Z  P;
2 OH (II) OH

What is the product ‘P’ of the above reaction

(A) NH2 (B) NHAC

NO2 NO2

SO3H

(C) NH2 (D) NH2

HO 3S NO 2 NO 2

SO 3H
SO 3H
22. Which of the following is tetrahedral and paramagnetic complex?
2 2
(A) NiCl4  (B) Ni  CN4 
2
(C) Cu  NH3  4  (D) Ni  CO  4 

23. Which of the following statement is correct?

(A) Free energy (G) is a path function
(B) In the expression G = H – TS, TS is the part of the system’s energy that is disordered,
already.
(C) G for a system is equal to TSTotal in magnitude
(D) Statement A is incorrect but statement B and C are correct

24. All the elements A, B, C and D form homonuclear diatomic molecules and conform anion of type
X– also. In a series of experiments the following observations are made:
(i) 2B   C2  2C  B 2

(ii) 2A   C2  no reaction

(iii) 2D  C2  2C  D2

(iv) 2B   D2  B2  2D

Which of the following statement is correct?
(A) A2 is the strongest oxidizing agent among all A2, B2, C2 and D2.
(B) Correct order of reduction potentials is A2 > C2 > D2 > B2.
(C) (A) and (B) are correct statements as well as it can also be concluded that B corrode at
fastest rate among all the four elements.
(D) All the above statements are correct.
o
25. What is the solubility product of CaF2 at room temperature, if m Ca2   = 1.04  10
–2
Sm2/mol
o
m F   = 4.8  10 –3
Sm2/mol
 CaF  Saturated Solution)  4.25  10 3 S / m at room temperature.
2

H2O  2  104 S / m
(A) 4.05  10–4 M3 (B) 2.025  10–4 M3
(C) 3.32  10–11 M3 (D) 4.05  1010 M3

26. Some times yellow turbidity appears while passing H2S gas even in the absence of IInd group of
basic radicals. This is because:
(A) Sulphur is present in the mixture as impurity.
(B) IV group radicals are precipitated as sulphides.
(C) The oxidation of H2S gas by some acid radicals.
rd
(D) III group radicals are precipitated as hydroxides.

27. In low temperature range fraction of heat supplied to an ideal diatomic gas system, at constant
pressure, which bring change in its internal energy is approx.......?
(A) 0.71 (B) 0.75
(C) 0.60 (D) 0.50
28. By which of the following methods, Cl2 can be produced?
(A) By treating KClO3 with iodine (I2)
(B) By heating a mixture of NaBr and NaBrO3 with HCl
(C) By treating CaOCl2 and NaI mixture with HCl solution.
(D) By treating NaCl with H2SO4

29. Which of the following is optically active?

 (A) (B) O
H
Me NH C

H C N
Me
O Me
(C) O O (D) HO H

CH3
O
CH3

HO H

30. Which of the following will cause symmetric cleavage of B2H6?

(A) NH3 (B) N(CH3)3
(C) NH2 – C2H5 (D) HN(CH3)2