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Hoppes Elite Foaming Gun Cleaner PDF

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Revision date: 2/8/2019 Revision: 4 Supersedes date: 12/4/2018

SAFETY DATA SHEET


Foaming Bore Cleaner
According to Appendix D, OSHA Hazard Communication Standard 29 CFR §1910.1200

1. Identification

Product identifier
Product name Foaming Bore Cleaner

Chemical name Mixture

Product number EFGC4

Recommended use of the chemical and restrictions on use


Application Firearm bore cleaner

Uses advised against No specific uses advised against are identified.

Details of the supplier of the safety data sheet


Manufacturer Bushnell Holdings Inc
9200 Cody
Overland Park, KS 66214
1-800-423-3537
dangerous.goods@vistaoutdoor.com

Emergency telephone number


Emergency telephone Emergency Telephone Number (Hazardous Material/Dangerous Goods Transportation
Emergency Only) 1-800-424-9300 (Inside US Only) +01-703-527-3887 (Outside US) -
(CHEMTREC, Day and Night)

2. Hazard(s) identification

Classification of the substance or mixture


Physical hazards Not Classified

Health hazards Acute Tox. 4 - H302 Acute Tox. 4 - H332 Skin Corr. 1B - H314 Eye Dam. 1 - H318 Repr. 1B -
H360D STOT SE 3 - H335

Environmental hazards Aquatic Acute 2 - H401

Label elements

Pictogram

Signal word Danger

Hazard statements H302+H332 Harmful if swallowed or if inhaled.


H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
H360D May damage the unborn child.
H401 Toxic to aquatic life.

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Foaming Bore Cleaner

Precautionary statements P201 Obtain special instructions before use.


P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe vapor/ spray.
P261 Avoid breathing vapor/ spray.
P264 Wash contaminated skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301+P312 If swallowed: Call a poison center/ doctor if you feel unwell.
P301+P330+P331 If swallowed: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/ shower.
P304+P340 If inhaled: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P308+P313 If exposed or concerned: Get medical advice/ attention.
P310 Immediately call a poison center/ doctor.
P321 Specific treatment (see medical advice on this label).
P363 Wash contaminated clothing before reuse.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container in accordance with national regulations.

Contains Monoethanolamine, Alkylpolyglycoside C10-16, N-methyl-2-pyrrolidone

Other hazards
This product does not contain any substances classified as PBT or vPvB.

3. Composition/information on ingredients

Mixtures

Monoethanolamine 30-60%
CAS number: 141-43-5

Classification
Flam. Liq. 4 - H227
Acute Tox. 4 - H302
Acute Tox. 4 - H312
Acute Tox. 4 - H332
Skin Corr. 1B - H314
Eye Dam. 1 - H318
STOT SE 3 - H335
Aquatic Acute 2 - H401

Alkylpolyglycoside C10-16 5-10%


CAS number: 110615-47-9

Classification
Skin Irrit. 2 - H315
Eye Dam. 1 - H318

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N-methyl-2-pyrrolidone 1-5%
CAS number: 872-50-4

Classification
Skin Irrit. 2 - H315
Eye Irrit. 2A - H319
Repr. 1B - H360D
STOT SE 3 - H335

The full text for all hazard statements is displayed in Section 16.

4. First-aid measures

Description of first aid measures


General information Get medical attention immediately. Show this Safety Data Sheet to the medical personnel.
Chemical burns must be treated by a physician.

Inhalation Remove affected person from source of contamination. Move affected person to fresh air and
keep warm and at rest in a position comfortable for breathing. Maintain an open airway.
Loosen tight clothing such as collar, tie or belt. When breathing is difficult, properly trained
personnel may assist affected person by administering oxygen. Place unconscious person on
their side in the recovery position and ensure breathing can take place.

Ingestion Rinse mouth thoroughly with water. Remove any dentures. Give a few small glasses of water
or milk to drink. Stop if the affected person feels sick as vomiting may be dangerous. Do not
induce vomiting unless under the direction of medical personnel. If vomiting occurs, the head
should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. Move affected person to fresh air and keep warm and at rest in a
position comfortable for breathing. Place unconscious person on their side in the recovery
position and ensure breathing can take place. Maintain an open airway. Loosen tight clothing
such as collar, tie or belt.

Skin Contact It is important to remove the substance from the skin immediately. Take off immediately all
contaminated clothing. Rinse immediately with plenty of water. Continue to rinse for at least
15 minutes and get medical attention. Chemical burns must be treated by a physician.

Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
apart. Continue to rinse for at least 10 minutes.

Protection of first aiders First aid personnel should wear appropriate protective equipment during any rescue. If it is
suspected that volatile contaminants are still present around the affected person, first aid
personnel should wear an appropriate respirator or self-contained breathing apparatus. Wash
contaminated clothing thoroughly with water before removing it from the affected person, or
wear gloves. It may be dangerous for first aid personnel to carry out mouth-to-mouth
resuscitation.

Most important symptoms and effects, both acute and delayed


General information See Section 11 for additional information on health hazards. The severity of the symptoms
described will vary dependent on the concentration and the length of exposure.

Inhalation A single exposure may cause the following adverse effects: Severe irritation of nose and
throat. Symptoms following overexposure may include the following: Corrosive to the
respiratory tract.

Ingestion May cause chemical burns in mouth, esophagus and stomach. Symptoms following
overexposure may include the following: Severe stomach pain. Nausea, vomiting.

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Skin contact Causes severe burns. Symptoms following overexposure may include the following: Pain or
irritation. Redness. Blistering may occur.

Eye contact Causes serious eye damage. Symptoms following overexposure may include the following:
Pain. Profuse watering of the eyes. Redness.

Indication of immediate medical attention and special treatment needed


Notes for the doctor Treat symptomatically.

5. Fire-fighting measures

Extinguishing media
Suitable extinguishing media The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry
powder or water fog. Use fire-extinguishing media suitable for the surrounding fire.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

Special hazards arising from the substance or mixture


Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up.
This product is toxic. Severe corrosive hazard. Water used for fire extinguishing, which has
been in contact with the product, may be corrosive.

Hazardous combustion Thermal decomposition or combustion products may include the following substances: Very
products toxic or corrosive gases or vapors.

Advice for firefighters


Protective actions during Avoid breathing fire gases or vapors. Evacuate area. Keep upwind to avoid inhalation of
firefighting gases, vapors, fumes and smoke. Ventilate closed spaces before entering them. Cool
containers exposed to heat with water spray and remove them from the fire area if it can be
done without risk. Cool containers exposed to flames with water until well after the fire is out.
If a leak or spill has not ignited, use water spray to disperse vapors and protect men stopping
the leak. Avoid discharge to the aquatic environment. Control run-off water by containing and
keeping it out of sewers and watercourses. If risk of water pollution occurs, notify appropriate
authorities.

Special protective equipment Regular protection may not be safe. Wear chemical protective suit. Wear positive-pressure
for firefighters self-contained breathing apparatus (SCBA) and appropriate protective clothing. Standard
Firefighter's clothing including helmets, protective boots and gloves will provide a basic level
of protection for chemical incidents.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures


Personal precautions No action shall be taken without appropriate training or involving any personal risk. Keep
unnecessary and unprotected personnel away from the spillage. Wear protective clothing as
described in Section 8 of this safety data sheet. Follow precautions for safe handling
described in this safety data sheet. Wash thoroughly after dealing with a spillage. Ensure
procedures and training for emergency decontamination and disposal are in place. Do not
touch or walk into spilled material. Avoid inhalation of vapors and spray/mists. Use suitable
respiratory protection if ventilation is inadequate. Avoid contact with skin and eyes. Avoid
contact with contaminated tools and objects.

Environmental precautions
Environmental precautions Avoid discharge into drains or watercourses or onto the ground. Avoid discharge to the
aquatic environment.

Methods and material for containment and cleaning up

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Foaming Bore Cleaner

Methods for cleaning up Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spills
immediately and dispose of waste safely. This product is corrosive. Provide adequate
ventilation. Small Spillages: Collect spillage. Large Spillages: Absorb spillage with non-
combustible, absorbent material. The contaminated absorbent may pose the same hazard as
the spilled material. Collect and place in suitable waste disposal containers and seal securely.
Label the containers containing waste and contaminated materials and remove from the area
as soon as possible. Flush contaminated area with plenty of water. Wash thoroughly after
dealing with a spillage. For waste disposal, see Section 13.

Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on health
hazards. See Section 12 for additional information on ecological hazards. For waste disposal,
see Section 13.

7. Handling and storage

Precautions for safe handling


Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in
Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs.
Handle all packages and containers carefully to minimize spills. Keep container tightly sealed
when not in use. Avoid the formation of mists. This product is corrosive. Immediate first aid is
imperative. Avoid discharge to the aquatic environment. Do not handle until all safety
precautions have been read and understood. Do not handle broken packages without
protective equipment. Do not reuse empty containers.

Advice on general Wash promptly if skin becomes contaminated. Take off contaminated clothing and wash
occupational hygiene before reuse. Wash contaminated clothing before reuse. Do not eat, drink or smoke when
using this product. Wash at the end of each work shift and before eating, smoking and using
the toilet. Change work clothing daily before leaving workplace.

Conditions for safe storage, including any incompatibilities


Storage precautions Store away from incompatible materials (see Section 10). Store locked up. Keep only in the
original container. Keep container tightly closed, in a cool, well ventilated place. Keep
containers upright. Protect containers from damage. Utilize retaining walls to prevent soil and
water pollution in the event of spillage. The storage area floor should be leak-tight, jointless
and not absorbent.

Storage class Corrosive storage.

Specific end uses(s)


Specific end use(s) The identified uses for this product are detailed in Section 1.

8. Exposure Controls/personal protection

Control parameters
Occupational exposure limits
Monoethanolamine
Long-term exposure limit (8-hour TWA): OSHA 3 ppm 6 mg/m³
Long-term exposure limit (8-hour TWA): ACGIH 3 ppm 7.5 mg/m³
Short-term exposure limit (15-minute): ACGIH 6 ppm 15 mg/m³
OSHA = Occupational Safety and Health Administration.
ACGIH = American Conference of Governmental Industrial Hygienists.

Monoethanolamine (CAS: 141-43-5)

Immediate danger to life 30 ppm


and health

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Foaming Bore Cleaner

Exposure controls

Protective equipment

Appropriate engineering Provide adequate ventilation. Personal, workplace environment or biological monitoring may
controls be required to determine the effectiveness of the ventilation or other control measures and/or
the necessity to use respiratory protective equipment. Use process enclosures, local exhaust
ventilation or other engineering controls as the primary means to minimize worker exposure.
Personal protective equipment should only be used if worker exposure cannot be controlled
adequately by the engineering control measures. Ensure control measures are regularly
inspected and maintained. Ensure operatives are trained to minimize exposure.

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. Personal protective equipment for eye and face protection should
comply with OSHA 1910.133. Wear tight-fitting, chemical splash goggles or face shield. If
inhalation hazards exist, a full-face respirator may be required instead.

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if
a risk assessment indicates skin contact is possible. The most suitable glove should be
chosen in consultation with the glove supplier/manufacturer, who can provide information
about the breakthrough time of the glove material. To protect hands from chemicals, gloves
should comply with OSHA 1910.138 and be demonstrated to be impervious to the chemical
and resist degradation. Considering the data specified by the glove manufacturer, check
during use that the gloves are retaining their protective properties and change them as soon
as any deterioration is detected. Frequent changes are recommended.

Other skin and body Appropriate footwear and additional protective clothing complying with an approved standard
protection should be worn if a risk assessment indicates skin contamination is possible.

Hygiene measures Provide eyewash station and safety shower. Contaminated work clothing should not be
allowed out of the workplace. Wash contaminated clothing before reuse. Clean equipment
and the work area every day. Good personal hygiene procedures should be implemented.
Wash at the end of each work shift and before eating, smoking and using the toilet. When
using do not eat, drink or smoke. Preventive industrial medical examinations should be carried
out. Warn cleaning personnel of any hazardous properties of the product.

Respiratory protection Respiratory protection complying with an approved standard should be worn if a risk
assessment indicates inhalation of contaminants is possible. Ensure all respiratory protective
equipment is suitable for its intended use and is NIOSH approved. Check that the respirator
fits tightly and the filter is changed regularly. Gas and combination filter cartridges should
comply with OSHA 1910.134. Full face mask respirators with replaceable filter cartridges
should comply with OSHA 1910.134. Half mask and quarter mask respirators with replaceable
filter cartridges should comply with OSHA 1910.134.

Environmental exposure Keep container tightly sealed when not in use. Emissions from ventilation or work process
controls equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to
the process equipment will be necessary to reduce emissions to acceptable levels.

9. Physical and Chemical Properties

Information on basic physical and chemical properties


Appearance Clear, yellowish liquid.

Odor Characteristic.

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pH pH (concentrated solution): 13.1

Melting point Not determined.

Initial boiling point and range Not determined.

Flash point > 200°F Estimated value.

Evaporation rate Not determined.

Evaporation factor Not determined.

Flammability (solid, gas) Not determined.

Upper/lower flammability or Lower flammable/explosive limit: ~1.3 % Upper flammable/explosive limit: ~23.5 %
explosive limits

Vapor pressure Not determined.

Vapor density Not determined.

Relative density 1.034

Solubility(ies) Soluble in water.

Auto-ignition temperature Not determined.

Viscosity Not determined.

Explosive properties Not expected to present an explosion hazard due to static discharge

Explosive under the influence No


of a flame

Oxidizing properties Not determined.

10. Stability and reactivity

Reactivity See the other subsections of this section for further details.

Stability Stable at normal ambient temperatures and when used as recommended. Stable under the
prescribed storage conditions.

Possibility of hazardous No potentially hazardous reactions known.


reactions

Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.

Materials to avoid No specific material or group of materials is likely to react with the product to produce a
hazardous situation.

Hazardous decomposition Does not decompose when used and stored as recommended. Thermal decomposition or
products combustion products may include the following substances: Corrosive gases or vapors.

11. Toxicological information

Information on toxicological effects


Acute toxicity - oral
Notes (oral LD₅₀) Acute Tox. 4 - H302 Harmful if swallowed.

ATE oral (mg/kg) 1,666.67

Acute toxicity - dermal

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Notes (dermal LD₅₀) Based on available data the classification criteria are not met.

ATE dermal (mg/kg) 3,666.67

Acute toxicity - inhalation


Notes (inhalation LC₅₀) Acute Tox. 4 - H332 Harmful if inhaled.

ATE inhalation (dusts/mists 5.0


mg/l)

Skin corrosion/irritation
Animal data Skin Corr. 1B - H314 Causes severe burns.

Serious eye damage/irritation


Serious eye damage/irritation Eye Dam. 1 - H318 Corrosive to skin. Corrosivity to eyes is assumed.

Respiratory sensitization
Respiratory sensitization Based on available data the classification criteria are not met.

Skin sensitization
Skin sensitization Based on available data the classification criteria are not met.

Germ cell mutagenicity


Genotoxicity - in vitro Based on available data the classification criteria are not met.

Carcinogenicity
Carcinogenicity Based on available data the classification criteria are not met.

IARC carcinogenicity None of the ingredients are listed or exempt.

Reproductive toxicity
Reproductive toxicity - fertility Based on available data the classification criteria are not met.

Reproductive toxicity - Based on available data the classification criteria are not met.
development

Specific target organ toxicity - single exposure


STOT - single exposure STOT SE 3 - H335 May cause respiratory irritation.

Target organs Respiratory system, lungs

Specific target organ toxicity - repeated exposure


STOT - repeated exposure Not classified as a specific target organ toxicant after repeated exposure.

Aspiration hazard
Aspiration hazard Based on available data the classification criteria are not met.

General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Inhalation Corrosive to the respiratory tract. Symptoms following overexposure may include the
following: Severe irritation of nose and throat.

Ingestion May cause chemical burns in mouth, esophagus and stomach. Symptoms following
overexposure may include the following: Severe stomach pain. Nausea, vomiting.

Skin Contact Causes severe burns. Symptoms following overexposure may include the following: Pain or
irritation. Redness. Blistering may occur.

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Eye contact Causes serious eye damage. Symptoms following overexposure may include the following:
Pain. Profuse watering of the eyes. Redness.

Route of entry Ingestion Inhalation Skin and/or eye contact

Target Organs Respiratory system, lungs

12. Ecological Information

Ecotoxicity Not regarded as dangerous for the environment. However, large or frequent spills may have
hazardous effects on the environment.

Toxicity Based on available data the classification criteria are not met.

Persistence and degradability


Persistence and degradability The degradability of the product is not known.

Bioaccumulative potential
Bio-Accumulative Potential No data available on bioaccumulation.

Mobility in soil
Mobility No data available.

Other adverse effects


Other adverse effects None known.

13. Disposal considerations

Waste treatment methods


General information The generation of waste should be minimized or avoided wherever possible. Reuse or recycle
products wherever possible. This material and its container must be disposed of in a safe
way. Disposal of this product, process solutions, residues and by-products should at all times
comply with the requirements of environmental protection and waste disposal legislation and
any local authority requirements. When handling waste, the safety precautions applying to
handling of the product should be considered. Care should be taken when handling emptied
containers that have not been thoroughly cleaned or rinsed out. Empty containers or liners
may retain some product residues and hence be potentially hazardous.

Disposal methods Do not empty into drains. Dispose of surplus products and those that cannot be recycled via a
licensed waste disposal contractor. Waste, residues, empty containers, discarded work
clothes and contaminated cleaning materials should be collected in designated containers,
labeled with their contents. Incineration or landfill should only be considered when recycling is
not feasible.

14. Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, DOT).

DOT transport notes Limited Quantity by Ground This product is not regulated for road transportation in
accordance with 49 CFR Exceptions.

UN Number
Not applicable.

UN proper shipping name


Not applicable.

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Transport hazard class(es)


No transport warning sign required.

Packing group
Not applicable.

Environmental hazards

Environmentally Hazardous Substance


No.

Special precautions for user


Not applicable.

Transport in bulk according to Not applicable.


Annex II of MARPOL 73/78
and the IBC Code

15. Regulatory information

US Federal Regulations
SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities
None of the ingredients are listed or exempt.

CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA)


None of the ingredients are listed or exempt.

SARA Extremely Hazardous Substances EPCRA Reportable Quantities


None of the ingredients are listed or exempt.

SARA 313 Emission Reporting


The following ingredients are listed or exempt:
N-methyl-2-pyrrolidone
0.1 %
1.0 %

CAA Accidental Release Prevention


None of the ingredients are listed or exempt.

FDA - Essential Chemical


None of the ingredients are listed or exempt.

FDA - Precursor Chemical


None of the ingredients are listed or exempt.

SARA (311/312) Hazard Categories


None of the ingredients are listed or exempt.

OSHA Highly Hazardous Chemicals


None of the ingredients are listed or exempt.

US State Regulations
California Proposition 65 Carcinogens and Reproductive Toxins
The following ingredients are listed or exempt:
N-methyl-2-pyrrolidone
Known to the State of California to cause developmental and reproductive toxicity.

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California Air Toxics "Hot Spots" (A-I)


None of the ingredients are listed or exempt.

California Air Toxics "Hot Spots" (A-II)


None of the ingredients are listed or exempt.

California Directors List of Hazardous Substances


The following ingredients are listed or exempt:
Monoethanolamine

Massachusetts "Right To Know" List


The following ingredients are listed or exempt:
N-methyl-2-pyrrolidone
Monoethanolamine

Rhode Island "Right To Know" List


The following ingredients are listed or exempt:
Monoethanolamine

Minnesota "Right To Know" List


The following ingredients are listed or exempt:
N-methyl-2-pyrrolidone
Monoethanolamine

New Jersey "Right To Know" List


The following ingredients are listed or exempt:
N-methyl-2-pyrrolidone
Monoethanolamine

Pennsylvania "Right To Know" List


The following ingredients are listed or exempt:
N-methyl-2-pyrrolidone
Monoethanolamine

Inventories
US - TSCA
All the ingredients are listed or exempt.
N-methyl-2-pyrrolidone
Water

US - TSCA 12(b) Export Notification


None of the ingredients are listed or exempt.

16. Other information

Classification abbreviations Acute Tox. = Acute toxicity


and acronyms Eye Dam. = Serious eye damage
Skin Corr. = Skin corrosion
STOT SE = Specific target organ toxicity-single exposure

Training advice Read and follow manufacturer's recommendations. Only trained personnel should use this
material.

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Foaming Bore Cleaner

Revision comments Revised formulation.

Revision date 2/8/2019

Revision 4

Supersedes date 12/4/2018

SDS No. 4570

Hazard statements in full H227 Combustible liquid.


H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H360D May damage the unborn child.
H401 Toxic to aquatic life.

End of Safety Data Sheet

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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