MSDS Amilor
MSDS Amilor
MSDS Amilor
BASIC DANGEROUS MAC w.z., mg/m3 Hazard class CAS No. EC No.
COMPONENTS (if applicable)
MAC w.z. – Maximum allowable concentration of chemicals in the working zone area,
mg/m3 (maximum single/shift-average)
Signal word – a word used for laying emphasis on degree of hazard of chemical products
and chosen according to GOST 31340-2013
1. Identification of chemicals and data about a manufacturer or supplier
1.1. Identification of chemicals
1.1.1. Technical name: Amilor - sodium carboxymethyl starch, KMK 100
(hereinafter referred to as product)
1.1.2. Application short recommendations: The product is purposed for application in the oil-
(including application limitations) extracting industry [1]
2. Hazard identification
2.1. Hazard level of chemicals in the mass: Classification according to GOST 12.1.007: acute
(Data about hazard classification according to the legislation toxicity. [2,9]
of the Russian Federation GOST 12.1.007-76) and GHS - a low hazardous product according to the exposure on
(GOST 32419-2013, GOST 32423-2013, GOST 32424-
2013, GOST 324252013)
the body, hazard class 4; [2,9]
Classification according to GHS:
‒ Chemical products, causing serious eye damage/
irritation, class 3;
‒ Chemical products, causing corrosion
(necrosis)/irritation of skin, class 3;
5.1. General description of fire and explosion hazard: Combustible substance (powder) [23,24]
(in accordance with GOST 12.1.004)
5.2. Indices of fire and explosion hazard: T flash-ignition temperature 320°C, Tself-ignition
(Range of indices in accordance with GOST 12.1.044 and GOST temperature 420°C; lower flame propagation limit:
Р 51330.0) 40-60 g/cm3. [23,24]
5.3. Hazard caused by Products of combustion and/or When heated, thermal destruction with the formation
thermal destruction: of carbon oxide affecting central nervous and
cardiovascular systems, blood, liver, kidneys, with
signs of exposure - drowsiness, nausea, vomiting,
movement disorder, convulsions, fainting, loss of
consciousness. [23,24]
5.4. Recommended fire-fighting equipment: Sand, diffused water, generated mechanical foam, dry
chemicals. [23,24]
5.5. Forbidden fire-fighting equipment: It is not recommended to apply straight streams of
water. [23,24]
5.6. PPE for fire-fighting: Fire-retardant suit complete with a self-rescue device
(PPE of firemen) SPI-20 [23,24,19]
5.7. Specificity upon fire-fighting: Polymer and paper packaging burns, if exposed to
fire. Dust explosion is possible, if a high
concentration of powder or granules mixes with the
air. In case of contact with the surface aqueous
solutions or wet powders make it extremely slippery,
injures after falls are possible. [21,23,24]
6. Measures for prevention and elimination of
emergencies and consequences of them.
6.1. Prevention of hazardous imact
on people, environment, buildings, constructions
etc. in case of emergency.
6.1.1. Necessary general actions in case of Stop work, send off strangers, keep a windward side,
emergencies: avoid low places, move the vehicle to a safe place.
Isolate the hazardous zone within a radius of not less
than 50 m, correct the specified distance according to
results of chemical survey. Enter the emergency zone
with complete protective clothes on, observe fire
safety measures, do not smoke, and eliminate sources
of fire and sparks. Render first medical aid to injured
persons, send people from the emergency zone for a
medical checkup, call emergency services. [16,19]
6.1.2. PPE in case of emergencies: Protective multi-service suit L-1 or L-2 complete
(PPE of emergency crews) with an industrial gas mask with an aerosol filter and
cartridges A, B, В8, BKF. [16,19]
7.2.2. Containers and package: The product shall be packed into polypropylene bags
(including materials they are made of) according to GOST 30090 and paper multiply bags
according to GOST 2226. Subject to the agreement
with a consumer, other types of containers and
packages providing quality, safety, hermetic sealing
of the product can be used. [1]
7.3. Security measures and storage rules in a life: Do not apply in household use. [1]
8. Control devices for hazardous exposure and
PPE.
8.1. Parametres of a working zone, Health standards are given according to the product
subject to compulsory control (MAC w.z. or SRLI components:
w.z.): - carboxymethyl starch: MAC w.z. control acc.to
starch 2-hydroxyethyl ether (starch oxyethyl) and
starch: 10 mg/m3, aerosol. [3,23]
- starch: MAC w.z.: 10 mg/m3, aerosol. [3,24]
8.2. Provision measures for hazardous substances in Ventilation efficiency. Equipment, containers shall be
allowable concentration: hermetically sealed, avoid dust formation, high
temperatures. Use the product in well-ventilated premises.
Control of concentration of hazardous substances in air of
a working zone, sanitary and hygienic control of
ventilation systems. Laboratory work shall be
performed only in the exhaust fume hood with
ventilation switched on, periodical wet cleaning of
premises. [1,8,13,14,19]
8.3. PPE of the personnel:
8.3.1. General recommendations: Avoid direct contact to the product, dust forming. Do
not eat, drink and do not smoke in the working area.
Use PPE. Make periodical hygienic cleaning of
personal protection equipment. Availability of
replacement PPE. Observe HSE. Availability of fire-
fighting equipment. Persons aged 18 are allowed by
re-sults of medical checkups. Labour protection
briefing. [13]
8.3.2. Respiratory protective equipment (RPE types): Respirators RPG-67А, Lepestok according to GOST
12.4.004. [1,23,24,19,15]
8.3.3. Protection means (material, type): Acid and alkali resistant rubber gloves type I-II
(special clothes, special footwear, hand protection, eye according to GOST 20010.
protection): Specialized clothing (cotton suit), leather boots or
rubber high boots according to 12.4.137, goggles
with a side protection in accordance with GOST
12.4.013. [1,23,24,19,15]
8.3.4. PPE for household used: Do not apply in household use. [1]
9.2. Parametres specifying basic properties of Moisture content is not more than 12%. [1]
chemicals, hazardous properties first: Melting temperature: about 170°С
(temperature values, рН, solubility, n-octanol/water index etc.) The substance is not soluble in water or in fat. [1]
12.3.2. Ecotoxicity parametres: Ecological toxicity parameters for the product were not
(СL, EU for fishes, daphnias magna, seaweed etc.) determined (studied). [20,22,23,24]
12.3.3. Migration and transformation in Biodeterioration and biodissimilation properties are
environment owing to biodeterioration and other moderate. The product is not transformed in the
processes (oxidation, hydrolysis etc.): environment. [23,24]
14.6. Transport marking: “Keep away from sun light”, “Keep dry”, “Temperature
(manipulation signs according to GOST 14192) ranges”, “Tight packing”, “Top”, “Do not turn over”,
“Piling limit according to the weight”. [1,11]
14.7. Emergency cards: Not required, the product is not classified as a hazardous
(for railway, sea and other carriages) cargo. [19,20,22]