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Safety Data Sheet According To Regulation (EC) No 1907/2006, Annex II

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Safety data sheet according to Regulation (EC) No 1907/2006, Annex II


Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047

Safety data sheet


according to Regulation (EC) No 1907/2006, Annex II
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Marine Antikalk 5 L
Art.: 25047

1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture:
Cleaner
Uses advised against:
No information available at present.

1.3 Details of the supplier of the safety data sheet


LIQUI MOLY GmbH
Jerg-Wieland-Str. 4
89081 Ulm-Lehr
Tel.: (+49) 0731-1420-0
Fax: (+49) 0731-1420-88

Qualified person's e-mail address: info@chemical-check.de, k.schnurbusch@chemical-check.de Please DO NOT use for requesting Safety
Data Sheets.

1.4 Emergency telephone number


Emergency information services / official advisory body:
---
Telephone number of the company in case of emergencies:
+49 (0) 700 / 24 112 112 (LMR)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture


Classification according to Regulation (EC) 1272/2008 (CLP)
Hazard class Hazard category Hazard statement
Eye Irrit. 2 H319-Causes serious eye irritation.
Skin Irrit. 2 H315-Causes skin irritation.
Aquatic Chronic 3 H412-Harmful to aquatic life with long lasting effects.

2.2 Label elements


Labeling according to Regulation (EC) 1272/2008 (CLP)
Page 2 of 13
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047

Warning

H319-Causes serious eye irritation. H315-Causes skin irritation. H412-Harmful to aquatic life with long lasting effects.

P101-If medical advice is needed, have product container or label at hand. P102-Keep out of reach of children.
P273-Avoid release to the environment. P280-Wear protective gloves / eye protection / face protection.
P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. P314-Get medical advice / attention if you feel unwell.
P501-Dispose of contents / container to an approved waste disposal facility.

2.3 Other hazards


The mixture does not contain any vPvB substance (vPvB = very persistent, very bioaccumulative) or is not included under XIII of the regulation
(EC) 1907/2006 (< 0,1 %).
The mixture does not contain any PBT substance (PBT = persistent, bioaccumulative, toxic) or is not included under XIII of the regulation (EC)
1907/2006 (< 0,1 %).
Dangerous vapours

SECTION 3: Composition/information on ingredients

3.1 Substance
n.a.
3.2 Mixture
Sulphamidic acid
Registration number (REACH) 01-2119846728-23-XXXX
Index 016-026-00-0
EINECS, ELINCS, NLP 226-218-8
CAS 5329-14-6
content % 10-<25
Classification according to Regulation (EC) 1272/2008 (CLP) Eye Irrit. 2, H319
Skin Irrit. 2, H315
Aquatic Chronic 3, H412

2,2'-(octadec-9-enylimino)bisethanol
Registration number (REACH) 01-2119510876-35-XXXX
Index ---
EINECS, ELINCS, NLP 246-807-3
CAS 25307-17-9
content % 0,1-<0,25
Classification according to Regulation (EC) 1272/2008 (CLP) Acute Tox. 4, H302
Skin Corr. 1B, H314
Aquatic Acute 1, H400 (M=10)
Aquatic Chronic 1, H410 (M=1)
Eye Dam. 1, H318

For the text of the H-phrases and classification codes (GHS/CLP), see Section 16.
The substances named in this section are given with their actual, appropriate classification!
Page 3 of 13
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047

For substances that are listed in appendix VI, table 3.1 of the regulation (EC) no. 1272/2008 (CLP regulation) this means that all notes that may
be given here for the named classification have been taken into account.

SECTION 4: First aid measures

4.1 Description of first aid measures


First-aiders should ensure they are protected!
Never pour anything into the mouth of an unconscious person!
Inhalation
Supply person with fresh air and consult doctor according to symptoms.
Skin contact
Remove polluted, soaked clothing immediately, wash thoroughly with plenty of water and soap, in case of irritation of the skin (flare), consult a
doctor.
Eye contact
Remove contact lenses.
Wash thoroughly for several minutes using copious water. Seek medical help if necessary.
Ingestion
Rinse the mouth thoroughly with water.
Do not induce vomiting - give copious water to drink. Consult doctor immediately.
4.2 Most important symptoms and effects, both acute and delayed
If applicable delayed symptoms and effects can be found in section 11 and the absorption route in section 4.1.
In certain cases, the symptoms of poisoning may only appear after an extended period / after several hours.
eyes, reddened
watering eyes
reddening of the skin
Dermatitis (skin inflammation)
4.3 Indication of any immediate medical attention and special treatment needed
Symptomatic treatment.

SECTION 5: Firefighting measures

5.1 Extinguishing media


Suitable extinguishing media
Water jet spray/foam/CO2/dry extinguisher
Unsuitable extinguishing media
None known
5.2 Special hazards arising from the substance or mixture
In case of fire the following can develop:
Ammonia
Oxides of carbon
Oxides of sulphur
Oxides of nitrogen
Oxides of phosphorus
Irritating vapours
Irritating gases
Corrosive vapours
Hydrogen cyanide
Nitro gases
5.3 Advice for firefighters
In case of fire and/or explosion do not breathe fumes.
Protective respirator with independent air supply.
According to size of fire
Full protection, if necessary.
Dispose of contaminated extinction water according to official regulations.

SECTION 6: Accidental release measures


Page 4 of 13
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047

6.1 Personal precautions, protective equipment and emergency procedures


Ensure sufficient supply of air.
Avoid contact with eyes or skin.
If applicable, caution - risk of slipping.
6.2 Environmental precautions
If leakage occurs, dam up.
Resolve leaks if this possible without risk.
Prevent surface and ground-water infiltration, as well as ground penetration.
Prevent from entering drainage system.
If accidental entry into drainage system occurs, inform responsible authorities.
6.3 Methods and material for containment and cleaning up
Soak up with absorbent material (e.g. universal binding agent, sand, diatomaceous earth, sawdust) and dispose of according to Section 13.
Flush residue using copious water.
6.4 Reference to other sections
For personal protective equipment see Section 8 and for disposal instructions see Section 13.

SECTION 7: Handling and storage

In addition to information given in this section, relevant information can also be found in section 8 and 6.1.
7.1 Precautions for safe handling
7.1.1 General recommendations
Ensure good ventilation.
Avoid contact with eyes or skin.
Eating, drinking, smoking, as well as food-storage, is prohibited in work-room.
Observe directions on label and instructions for use.
Use working methods according to operating instructions.
7.1.2 Notes on general hygiene measures at the workplace
General hygiene measures for the handling of chemicals are applicable.
Wash hands before breaks and at end of work.
Keep away from food, drink and animal feedingstuffs.
Remove contaminated clothing and protective equipment before entering areas in which food is consumed.
7.2 Conditions for safe storage, including any incompatibilities
Keep out of access to unauthorised individuals.
Store product closed and only in original packing.
Not to be stored in gangways or stair wells.
Store at room temperature.
7.3 Specific end use(s)
No information available at present.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Sulphamidic acid
Area of application Exposure route / Effect on health Descriptor Value Unit Note
Environmental
compartment
Environment - freshwater PNEC 0,3 mg/l
Environment - marine PNEC 0,03 mg/l
Environment - water, PNEC 0,3 mg/l
sporadic (intermittent)
release
Environment - sewage PNEC 200 mg/l
treatment plant
Page 5 of 13
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047

Environment - sediment, PNEC 0,3 mg/kg dw


freshwater
Environment - sediment, PNEC 0,03 mg/kg dw
marine
Environment - soil PNEC 3 mg/kg dw
Consumer Human - oral Long term, systemic DNEL 1,06 mg/kg
effects bw/day
Consumer Human - inhalation Long term, systemic DNEL 1,85 mg/m3
effects
Workers / employees Human - inhalation Long term, systemic DNEL 7,5 mg/m3
effects

2,2'-(octadec-9-enylimino)bisethanol
Area of application Exposure route / Effect on health Descriptor Value Unit Note
Environmental
compartment
Environment - freshwater PNEC 0,00021 mg/l
4
Environment - sediment, PNEC 0,0171 mg/kg dw
marine
Environment - sediment, PNEC 0,171 mg/kg dw
freshwater
Environment - water, PNEC 0,00087 mg/l
sporadic (intermittent)
release
Environment - sewage PNEC 1,5 mg/l
treatment plant
Environment - soil PNEC 5 mg/kg dw
Environment - oral (animal PNEC 2 mg/kg
feed)
Environment - marine PNEC 0,00002 mg/l
1
Environment - sediment, PNEC 1,692 mg/kg dw
freshwater
Environment - sediment, PNEC 0,1692 mg/kg dw
marine
Consumer Human - oral Long term, systemic DNEL 0,179 mg/kg bw/d
effects
Consumer Human - dermal Long term, systemic DNEL 0,179 mg/kg bw/d
effects
Consumer Human - inhalation Long term, systemic DNEL 0,621 mg/m3
effects
Workers / employees Human - dermal Long term, systemic DNEL 0,25 mg/kg bw/d
effects
Workers / employees Human - inhalation Long term, systemic DNEL 1,76 mg/m3
effects

8.2 Exposure controls


8.2.1 Appropriate engineering controls
Ensure good ventilation. This can be achieved by local suction or general air extraction.
If this is insufficient to maintain the concentration under the WEL or AGW values, suitable breathing protection should be worn.
Applies only if maximum permissible exposure values are listed here.

8.2.2 Individual protection measures, such as personal protective equipment


General hygiene measures for the handling of chemicals are applicable.
Wash hands before breaks and at end of work.
Keep away from food, drink and animal feedingstuffs.
Remove contaminated clothing and protective equipment before entering areas in which food is consumed.

Eye/face protection:
Tight fitting protective goggles with side protection (EN 166).
Page 6 of 13
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047

Skin protection - Hand protection:


Chemical resistant protective gloves (EN 374).
If applicable
Protective gloves made of butyl (EN 374).
Protective Neoprene® / polychloroprene gloves (EN 374).
Protective nitrile gloves (EN 374).
Protective PVC gloves (EN 374).
Minimum layer thickness in mm:
0,5
Permeation time (penetration time) in minutes:
480
The breakthrough times determined in accordance with EN 16523-1 were not obtained under practical conditions.
The recommended maximum wearing time is 50% of breakthrough time.
Protective hand cream recommended.

Skin protection - Other:


Protective working garments (e.g. safety shoes EN ISO 20345, long-sleeved protective working garments).

Respiratory protection:
Normally not necessary.

Thermal hazards:
Not applicable

Additional information on hand protection - No tests have been performed.


In the case of mixtures, the selection has been made according to the knowledge available and the information about the contents.
Selection of materials derived from glove manufacturer's indications.
Final selection of glove material must be made taking the breakthrough times, permeation rates and degradation into account.
Selection of a suitable glove depends not only on the material but also on other quality characteristics and varies from manufacturer to
manufacturer.
In the case of mixtures, the resistance of glove materials cannot be predicted and must therefore be tested before use.
The exact breakthrough time of the glove material can be requested from the protective glove manufacturer and must be observed.

8.2.3 Environmental exposure controls


No information available at present.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties


Physical state: Liquid
Colour: Red
Odour: Characteristic
Odour threshold: Not determined
pH-value: >2
Melting point/freezing point: Not determined
Initial boiling point and boiling range: Not determined
Flash point: n.a.
Evaporation rate: Not determined
Flammability (solid, gas): Not determined
Lower explosive limit: Not determined
Upper explosive limit: Not determined
Vapour pressure: Not determined
Vapour density (air = 1): Not determined
Density: 1,08 g/cm3 (20°C)
Bulk density: Not determined
Solubility(ies): Not determined
Water solubility: Soluble
Partition coefficient (n-octanol/water): Not determined
Auto-ignition temperature: Not determined
Decomposition temperature: Not determined
Viscosity: 1,5 mm2/s (40°C)
Page 7 of 13
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047

Explosive properties: Not determined


Oxidising properties: Not determined
9.2 Other information
Miscibility: Not determined
Fat solubility / solvent: Not determined
Conductivity: Not determined
Surface tension: Not determined
Solvents content: Not determined

SECTION 10: Stability and reactivity

10.1 Reactivity
The product has not been tested.
10.2 Chemical stability
Stable with proper storage and handling.
10.3 Possibility of hazardous reactions
No dangerous reactions are known.
10.4 Conditions to avoid
None known
10.5 Incompatible materials
Avoid contact with strong alkalis.
Avoid contact with strong oxidizing agents.
10.6 Hazardous decomposition products
No decomposition when used as directed.

SECTION 11: Toxicological information

11.1 Information on toxicological effects


Possibly more information on health effects, see Section 2.1 (classification).
Marine Antikalk 5 L
Art.: 25047
Toxicity / effect Endpoint Value Unit Organism Test method Notes
Acute toxicity, by oral route: n.d.a.
Acute toxicity, by dermal route: n.d.a.
Acute toxicity, by inhalation: n.d.a.
Skin corrosion/irritation: n.d.a.
Serious eye damage/irritation: n.d.a.
Respiratory or skin n.d.a.
sensitisation:
Germ cell mutagenicity: n.d.a.
Carcinogenicity: n.d.a.
Reproductive toxicity: n.d.a.
Specific target organ toxicity - n.d.a.
single exposure (STOT-SE):
Specific target organ toxicity - n.d.a.
repeated exposure (STOT-RE):
Aspiration hazard: n.d.a.
Symptoms: n.d.a.

Sulphamidic acid
Toxicity / effect Endpoint Value Unit Organism Test method Notes
Acute toxicity, by oral route: LD50 >2000 mg/kg Rat OECD 401 (Acute Oral
Toxicity)
Acute toxicity, by dermal route: LD50 >2000 mg/kg Rat OECD 402 (Acute
Dermal Toxicity)
Skin corrosion/irritation: Rabbit OECD 404 (Acute Irritant
Dermal
Irritation/Corrosion)
Page 8 of 13
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047

Serious eye damage/irritation: Rabbit OECD 405 (Acute Eye Irritant(IUCLID)


Irritation/Corrosion)
Germ cell mutagenicity: Salmonella OECD 471 (Bacterial Negative(IUCLID
typhimurium Reverse Mutation Test) )
Specific target organ toxicity - NOAEL 1000 mg/kg Rat (oral, 90 h)
repeated exposure (STOT-RE):
Symptoms: respiratory
distress,
coughing,
mucous
membrane
irritation

2,2'-(octadec-9-enylimino)bisethanol
Toxicity / effect Endpoint Value Unit Organism Test method Notes
Acute toxicity, by oral route: LD50 1260 mg/kg Rat OECD 401 (Acute Oral
Toxicity)
Skin corrosion/irritation: Rabbit OECD 404 (Acute Skin Corr. 1B
Dermal
Irritation/Corrosion)
Serious eye damage/irritation: Eye Dam. 1
Respiratory or skin Guinea pig OECD 406 (Skin No (skin contact)
sensitisation: Sensitisation)
Germ cell mutagenicity: OECD 471 (Bacterial Negative
Reverse Mutation Test)
Germ cell mutagenicity: OECD 473 (In Vitro Negative
Mammalian
Chromosome
Aberration Test)
Germ cell mutagenicity: OECD 476 (In Vitro Negative
Mammalian Cell Gene
Mutation Test)
Reproductive toxicity (Effects NOAEL 125 mg/kg Rat OECD 422 (Combined
on fertility): bw/d Repeated Dose Tox.
Study with the
Reproduction/Developm.
Tox. Screening Test)
Specific target organ toxicity - NOAEL 30 mg/kg Rat OECD 407 (Repeated
single exposure (STOT-SE), Dose 28-Day Oral
oral: Toxicity Study in
Rodents)

SECTION 12: Ecological information

Possibly more information on environmental effects, see Section 2.1 (classification).


Marine Antikalk 5 L
Art.: 25047
Toxicity / effect Endpoint Time Value Unit Organism Test method Notes
12.1. Toxicity to fish: n.d.a.
12.1. Toxicity to daphnia: n.d.a.
12.1. Toxicity to algae: n.d.a.
12.2. Persistence and n.d.a.
degradability:
12.3. Bioaccumulative n.d.a.
potential:
12.4. Mobility in soil: n.d.a.
12.5. Results of PBT n.d.a.
and vPvB assessment
12.6. Other adverse n.d.a.
effects:
Page 9 of 13
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047

Other information: DOC-elimination


degree(complexi
ng organic
substance)>=
80%/28d: No
Other information: The surfactant(s)
contained in this
mixture
complies(comply)
with the
biodegradability
criteria as laid
down in
Regulation (EC)
No.648/2004 on
detergents. Data
to support this
assertion are
held at the
disposal of the
competent
authorities of the
Member States
and will be made
available to
them, at their
direct request or
at the request of
a detergent
manufacturer.

Sulphamidic acid
Toxicity / effect Endpoint Time Value Unit Organism Test method Notes
12.1. Toxicity to fish: LC50 96h 70,3 mg/l Pimephales OECD 203 (Fish,
promelas Acute Toxicity
Test)
12.1. Toxicity to daphnia: EC50 48h 71,6 mg/l Daphnia magna OECD 202
(Daphnia sp.
Acute
Immobilisation
Test)
12.1. Toxicity to algae: IC50 72h >29 mg/l Chlorella vulgaris
12.2. Persistence and Not
degradability: biodegradable,
Not relevant for
inorganic
substances.
12.3. Bioaccumulative Log Pow -4,34
potential:
Water solubility: 213 g/l 20°C

2,2'-(octadec-9-enylimino)bisethanol
Toxicity / effect Endpoint Time Value Unit Organism Test method Notes
12.2. Persistence and 28d >60 % OECD 301 B Readily
degradability: (Ready biodegradable
Biodegradability -
Co2 Evolution
Test)
12.3. Bioaccumulative BCF 234
potential:
12.1. Toxicity to fish: LC50 96h 0,1 mg/l Brachydanio rerio OECD 203 (Fish,
Acute Toxicity
Test)
Page 10 of 13
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047

12.1. Toxicity to daphnia: EC50 48h 0,043 mg/l Daphnia magna OECD 202
(Daphnia sp.
Acute
Immobilisation
Test)
12.1. Toxicity to algae: EC50 72h 0,0867 mg/l Pseudokirchneriell OECD 201 (Alga,
a subcapitata Growth Inhibition
Test)
Toxicity to bacteria: EC50 3h 128 mg/l activated sludge OECD 209
(Activated Sludge,
Respiration
Inhibition Test
(Carbon and
Ammonium
Oxidation))
Other organisms: NOEC/NOEL 56d 500 mg/kg dw Eisenia foetida OECD 222
(Earthworm
Reproduction Test
(Eisenia
fetida/Eisenia
andrei))
12.5. Results of PBT No PBT
and vPvB assessment substance, No
vPvB substance
12.4. Mobility in soil: Koc 90520 OECD 106
(Adsorption/Desor
ption Using a
Batch Equilibrium
Method)

SECTION 13: Disposal considerations

13.1 Waste treatment methods


For the substance / mixture / residual amounts
EC disposal code no.:
The waste codes are recommendations based on the scheduled use of this product.
Owing to the user's specific conditions for use and disposal, other waste codes may be
allocated under certain circumstances. (2014/955/EU)
20 01 29 detergents containing hazardous substances
Recommendation:
Sewage disposal shall be discouraged.
Pay attention to local and national official regulations.
E.g. suitable incineration plant.
E.g. dispose at suitable refuse site.
For contaminated packing material
Pay attention to local and national official regulations.
Empty container completely.
Uncontaminated packaging can be recycled.
Dispose of packaging that cannot be cleaned in the same manner as the substance.

SECTION 14: Transport information

General statements
14.1. UN number: 1760
Transport by road/by rail (ADR/RID)
14.2. UN proper shipping name:
UN 1760 CORROSIVE LIQUID, N.O.S. (SULPHAMIC ACID)
14.3. Transport hazard class(es): 8
14.4. Packing group: III
Page 11 of 13
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047

Classification code: C9
LQ: 5L
14.5. Environmental hazards: Not applicable
Tunnel restriction code: E
Transport by sea (IMDG-code)
14.2. UN proper shipping name:
CORROSIVE LIQUID, N.O.S. (SULPHAMIC ACID)
14.3. Transport hazard class(es): 8
14.4. Packing group: III
EmS: F-A, S-B
Marine Pollutant: n.a
14.5. Environmental hazards: Not applicable
Transport by air (IATA)
14.2. UN proper shipping name:
Corrosive liquid, n.o.s. (SULPHAMIC ACID)
14.3. Transport hazard class(es): 8
14.4. Packing group: III
14.5. Environmental hazards: Not applicable
14.6. Special precautions for user
Persons employed in transporting dangerous goods must be trained.
All persons involved in transporting must observe safety regulations.
Precautions must be taken to prevent damage.
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Freighted as packaged goods rather than in bulk, therefore not applicable.
Minimum amount regulations have not been taken into account.
Danger code and packing code on request.
Comply with special provisions.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Observe restrictions:
Comply with trade association/occupational health regulations.

Directive 2010/75/EU (VOC): 0,2025 %


REGULATION (EC) No 648/2004
less than 5 %
non-ionic surfactants

National rules/regulation for the compliance with maximum quantities with regard to phosphates and or phosphorous compounds must be
observed and complied with.

15.2 Chemical safety assessment


A chemical safety assessment is not provided for mixtures.

SECTION 16: Other information

Revised sections: n.a.


Employee training in handling dangerous goods is required.
These details refer to the product as it is delivered.
Employee instruction/training in handling hazardous materials is required.

Classification and processes used to derive the classification of the mixture in accordance with
the ordinance (EG) 1272/2008 (CLP):

Classification in accordance with regulation Evaluation method used


(EC) No. 1272/2008 (CLP)
Page 12 of 13
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047

Eye Irrit. 2, H319 Classification according to calculation procedure.


Skin Irrit. 2, H315 Classification according to calculation procedure.
Aquatic Chronic 3, H412 Classification according to calculation procedure.

The following phrases represent the posted Hazard Class and Risk Category Code (GHS/CLP) of the product and the constituents (specified in
Section 2 and 3).
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

Eye Irrit. — Eye irritation


Skin Irrit. — Skin irritation
Aquatic Chronic — Hazardous to the aquatic environment - chronic
Acute Tox. — Acute toxicity - oral
Skin Corr. — Skin corrosion
Aquatic Acute — Hazardous to the aquatic environment - acute
Eye Dam. — Serious eye damage

Any abbreviations and acronyms used in this document:

acc., acc. to according, according to


ADR Accord européen relatif au transport international des marchandises Dangereuses par Route (= European Agreement concerning the
International Carriage of Dangerous Goods by Road)
AOX Adsorbable organic halogen compounds
approx. approximately
Art., Art. no. Article number
ASTM ASTM International (American Society for Testing and Materials)
BAM Bundesanstalt für Materialforschung und -prüfung (Federal Institute for Materials Research and Testing, Germany)
BAuA Bundesanstalt für Arbeitsschutz und Arbeitsmedizin (= Federal Institute for Occupational Health and Safety, Germany)
BSEF The International Bromine Council
bw body weight
CAS Chemical Abstracts Service
CLP Classification, Labelling and Packaging (REGULATION (EC) No 1272/2008 on classification, labelling and packaging of substances
and mixtures)
CMR carcinogenic, mutagenic, reproductive toxic
DMEL Derived Minimum Effect Level
DNEL Derived No Effect Level
dw dry weight
e.g. for example (abbreviation of Latin 'exempli gratia'), for instance
EC European Community
ECHA European Chemicals Agency
EEC European Economic Community
EINECS European Inventory of Existing Commercial Chemical Substances
ELINCS European List of Notified Chemical Substances
EN European Norms
EPA United States Environmental Protection Agency (United States of America)
etc. et cetera
EU European Union
EVAL Ethylene-vinyl alcohol copolymer
Fax. Fax number
gen. general
GHS Globally Harmonized System of Classification and Labelling of Chemicals
GWP Global warming potential
IARC International Agency for Research on Cancer
Page 13 of 13
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047

IATA International Air Transport Association


IBC (Code) International Bulk Chemical (Code)
IMDG-code International Maritime Code for Dangerous Goods
incl. including, inclusive
IUCLID International Uniform Chemical Information Database
LQ Limited Quantities
MARPOL International Convention for the Prevention of Marine Pollution from Ships
n.a. not applicable
n.av. not available
n.c. not checked
n.d.a. no data available
OECD Organisation for Economic Co-operation and Development
org. organic
PBT persistent, bioaccumulative and toxic
PE Polyethylene
PNEC Predicted No Effect Concentration
ppm parts per million
PVC Polyvinylchloride
REACHRegistration, Evaluation, Authorisation and Restriction of Chemicals (REGULATION (EC) No 1907/2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals)
REACH-IT List-No. 9xx-xxx-x No. is automatically assigned, e.g. to pre-registrations without a CAS No. or other numerical identifier. List
Numbers do not have any legal significance, rather they are purely technical identifiers for processing a submission via REACH-IT.
RID Règlement concernant le transport International ferroviaire de marchandises Dangereuses (= Regulation concerning the International
Carriage of Dangerous Goods by Rail)
SVHC Substances of Very High Concern
Tel. Telephone
UN RTDG United Nations Recommendations on the Transport of Dangerous Goods
VOC Volatile organic compounds
vPvB very persistent and very bioaccumulative
wwt wet weight

The statements made here should describe the product with regard to the necessary safety precautions - they are
not meant to guarantee definite characteristics - but they are based on our present up-to-date knowledge.
No responsibility.
These statements were made by:
Chemical Check GmbH, Chemical Check Platz 1-7, D-32839 Steinheim, Tel.: +49 5233 94 17 0, Fax:
+49 5233 94 17 90
© by Chemical Check GmbH Gefahrstoffberatung. The copying or changing of this document
is forbidden except with consent of the Chemical Check GmbH Gefahrstoffberatung.

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