Safety Data Sheet According To Regulation (EC) No 1907/2006, Annex II
Safety Data Sheet According To Regulation (EC) No 1907/2006, Annex II
Safety Data Sheet According To Regulation (EC) No 1907/2006, Annex II
Marine Antikalk 5 L
Art.: 25047
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture:
Cleaner
Uses advised against:
No information available at present.
Qualified person's e-mail address: info@chemical-check.de, k.schnurbusch@chemical-check.de Please DO NOT use for requesting Safety
Data Sheets.
Warning
H319-Causes serious eye irritation. H315-Causes skin irritation. H412-Harmful to aquatic life with long lasting effects.
P101-If medical advice is needed, have product container or label at hand. P102-Keep out of reach of children.
P273-Avoid release to the environment. P280-Wear protective gloves / eye protection / face protection.
P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. P314-Get medical advice / attention if you feel unwell.
P501-Dispose of contents / container to an approved waste disposal facility.
3.1 Substance
n.a.
3.2 Mixture
Sulphamidic acid
Registration number (REACH) 01-2119846728-23-XXXX
Index 016-026-00-0
EINECS, ELINCS, NLP 226-218-8
CAS 5329-14-6
content % 10-<25
Classification according to Regulation (EC) 1272/2008 (CLP) Eye Irrit. 2, H319
Skin Irrit. 2, H315
Aquatic Chronic 3, H412
2,2'-(octadec-9-enylimino)bisethanol
Registration number (REACH) 01-2119510876-35-XXXX
Index ---
EINECS, ELINCS, NLP 246-807-3
CAS 25307-17-9
content % 0,1-<0,25
Classification according to Regulation (EC) 1272/2008 (CLP) Acute Tox. 4, H302
Skin Corr. 1B, H314
Aquatic Acute 1, H400 (M=10)
Aquatic Chronic 1, H410 (M=1)
Eye Dam. 1, H318
For the text of the H-phrases and classification codes (GHS/CLP), see Section 16.
The substances named in this section are given with their actual, appropriate classification!
Page 3 of 13
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047
For substances that are listed in appendix VI, table 3.1 of the regulation (EC) no. 1272/2008 (CLP regulation) this means that all notes that may
be given here for the named classification have been taken into account.
In addition to information given in this section, relevant information can also be found in section 8 and 6.1.
7.1 Precautions for safe handling
7.1.1 General recommendations
Ensure good ventilation.
Avoid contact with eyes or skin.
Eating, drinking, smoking, as well as food-storage, is prohibited in work-room.
Observe directions on label and instructions for use.
Use working methods according to operating instructions.
7.1.2 Notes on general hygiene measures at the workplace
General hygiene measures for the handling of chemicals are applicable.
Wash hands before breaks and at end of work.
Keep away from food, drink and animal feedingstuffs.
Remove contaminated clothing and protective equipment before entering areas in which food is consumed.
7.2 Conditions for safe storage, including any incompatibilities
Keep out of access to unauthorised individuals.
Store product closed and only in original packing.
Not to be stored in gangways or stair wells.
Store at room temperature.
7.3 Specific end use(s)
No information available at present.
Sulphamidic acid
Area of application Exposure route / Effect on health Descriptor Value Unit Note
Environmental
compartment
Environment - freshwater PNEC 0,3 mg/l
Environment - marine PNEC 0,03 mg/l
Environment - water, PNEC 0,3 mg/l
sporadic (intermittent)
release
Environment - sewage PNEC 200 mg/l
treatment plant
Page 5 of 13
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047
2,2'-(octadec-9-enylimino)bisethanol
Area of application Exposure route / Effect on health Descriptor Value Unit Note
Environmental
compartment
Environment - freshwater PNEC 0,00021 mg/l
4
Environment - sediment, PNEC 0,0171 mg/kg dw
marine
Environment - sediment, PNEC 0,171 mg/kg dw
freshwater
Environment - water, PNEC 0,00087 mg/l
sporadic (intermittent)
release
Environment - sewage PNEC 1,5 mg/l
treatment plant
Environment - soil PNEC 5 mg/kg dw
Environment - oral (animal PNEC 2 mg/kg
feed)
Environment - marine PNEC 0,00002 mg/l
1
Environment - sediment, PNEC 1,692 mg/kg dw
freshwater
Environment - sediment, PNEC 0,1692 mg/kg dw
marine
Consumer Human - oral Long term, systemic DNEL 0,179 mg/kg bw/d
effects
Consumer Human - dermal Long term, systemic DNEL 0,179 mg/kg bw/d
effects
Consumer Human - inhalation Long term, systemic DNEL 0,621 mg/m3
effects
Workers / employees Human - dermal Long term, systemic DNEL 0,25 mg/kg bw/d
effects
Workers / employees Human - inhalation Long term, systemic DNEL 1,76 mg/m3
effects
Eye/face protection:
Tight fitting protective goggles with side protection (EN 166).
Page 6 of 13
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047
Respiratory protection:
Normally not necessary.
Thermal hazards:
Not applicable
10.1 Reactivity
The product has not been tested.
10.2 Chemical stability
Stable with proper storage and handling.
10.3 Possibility of hazardous reactions
No dangerous reactions are known.
10.4 Conditions to avoid
None known
10.5 Incompatible materials
Avoid contact with strong alkalis.
Avoid contact with strong oxidizing agents.
10.6 Hazardous decomposition products
No decomposition when used as directed.
Sulphamidic acid
Toxicity / effect Endpoint Value Unit Organism Test method Notes
Acute toxicity, by oral route: LD50 >2000 mg/kg Rat OECD 401 (Acute Oral
Toxicity)
Acute toxicity, by dermal route: LD50 >2000 mg/kg Rat OECD 402 (Acute
Dermal Toxicity)
Skin corrosion/irritation: Rabbit OECD 404 (Acute Irritant
Dermal
Irritation/Corrosion)
Page 8 of 13
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047
2,2'-(octadec-9-enylimino)bisethanol
Toxicity / effect Endpoint Value Unit Organism Test method Notes
Acute toxicity, by oral route: LD50 1260 mg/kg Rat OECD 401 (Acute Oral
Toxicity)
Skin corrosion/irritation: Rabbit OECD 404 (Acute Skin Corr. 1B
Dermal
Irritation/Corrosion)
Serious eye damage/irritation: Eye Dam. 1
Respiratory or skin Guinea pig OECD 406 (Skin No (skin contact)
sensitisation: Sensitisation)
Germ cell mutagenicity: OECD 471 (Bacterial Negative
Reverse Mutation Test)
Germ cell mutagenicity: OECD 473 (In Vitro Negative
Mammalian
Chromosome
Aberration Test)
Germ cell mutagenicity: OECD 476 (In Vitro Negative
Mammalian Cell Gene
Mutation Test)
Reproductive toxicity (Effects NOAEL 125 mg/kg Rat OECD 422 (Combined
on fertility): bw/d Repeated Dose Tox.
Study with the
Reproduction/Developm.
Tox. Screening Test)
Specific target organ toxicity - NOAEL 30 mg/kg Rat OECD 407 (Repeated
single exposure (STOT-SE), Dose 28-Day Oral
oral: Toxicity Study in
Rodents)
Sulphamidic acid
Toxicity / effect Endpoint Time Value Unit Organism Test method Notes
12.1. Toxicity to fish: LC50 96h 70,3 mg/l Pimephales OECD 203 (Fish,
promelas Acute Toxicity
Test)
12.1. Toxicity to daphnia: EC50 48h 71,6 mg/l Daphnia magna OECD 202
(Daphnia sp.
Acute
Immobilisation
Test)
12.1. Toxicity to algae: IC50 72h >29 mg/l Chlorella vulgaris
12.2. Persistence and Not
degradability: biodegradable,
Not relevant for
inorganic
substances.
12.3. Bioaccumulative Log Pow -4,34
potential:
Water solubility: 213 g/l 20°C
2,2'-(octadec-9-enylimino)bisethanol
Toxicity / effect Endpoint Time Value Unit Organism Test method Notes
12.2. Persistence and 28d >60 % OECD 301 B Readily
degradability: (Ready biodegradable
Biodegradability -
Co2 Evolution
Test)
12.3. Bioaccumulative BCF 234
potential:
12.1. Toxicity to fish: LC50 96h 0,1 mg/l Brachydanio rerio OECD 203 (Fish,
Acute Toxicity
Test)
Page 10 of 13
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047
12.1. Toxicity to daphnia: EC50 48h 0,043 mg/l Daphnia magna OECD 202
(Daphnia sp.
Acute
Immobilisation
Test)
12.1. Toxicity to algae: EC50 72h 0,0867 mg/l Pseudokirchneriell OECD 201 (Alga,
a subcapitata Growth Inhibition
Test)
Toxicity to bacteria: EC50 3h 128 mg/l activated sludge OECD 209
(Activated Sludge,
Respiration
Inhibition Test
(Carbon and
Ammonium
Oxidation))
Other organisms: NOEC/NOEL 56d 500 mg/kg dw Eisenia foetida OECD 222
(Earthworm
Reproduction Test
(Eisenia
fetida/Eisenia
andrei))
12.5. Results of PBT No PBT
and vPvB assessment substance, No
vPvB substance
12.4. Mobility in soil: Koc 90520 OECD 106
(Adsorption/Desor
ption Using a
Batch Equilibrium
Method)
General statements
14.1. UN number: 1760
Transport by road/by rail (ADR/RID)
14.2. UN proper shipping name:
UN 1760 CORROSIVE LIQUID, N.O.S. (SULPHAMIC ACID)
14.3. Transport hazard class(es): 8
14.4. Packing group: III
Page 11 of 13
Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revision date / version: 21.07.2020 / 0001
Replacing version dated / version: 21.07.2020 / 0001
Valid from: 21.07.2020
PDF print date: 13.08.2020
Marine Antikalk 5 L
Art.: 25047
Classification code: C9
LQ: 5L
14.5. Environmental hazards: Not applicable
Tunnel restriction code: E
Transport by sea (IMDG-code)
14.2. UN proper shipping name:
CORROSIVE LIQUID, N.O.S. (SULPHAMIC ACID)
14.3. Transport hazard class(es): 8
14.4. Packing group: III
EmS: F-A, S-B
Marine Pollutant: n.a
14.5. Environmental hazards: Not applicable
Transport by air (IATA)
14.2. UN proper shipping name:
Corrosive liquid, n.o.s. (SULPHAMIC ACID)
14.3. Transport hazard class(es): 8
14.4. Packing group: III
14.5. Environmental hazards: Not applicable
14.6. Special precautions for user
Persons employed in transporting dangerous goods must be trained.
All persons involved in transporting must observe safety regulations.
Precautions must be taken to prevent damage.
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Freighted as packaged goods rather than in bulk, therefore not applicable.
Minimum amount regulations have not been taken into account.
Danger code and packing code on request.
Comply with special provisions.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Observe restrictions:
Comply with trade association/occupational health regulations.
National rules/regulation for the compliance with maximum quantities with regard to phosphates and or phosphorous compounds must be
observed and complied with.
Classification and processes used to derive the classification of the mixture in accordance with
the ordinance (EG) 1272/2008 (CLP):
The following phrases represent the posted Hazard Class and Risk Category Code (GHS/CLP) of the product and the constituents (specified in
Section 2 and 3).
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
The statements made here should describe the product with regard to the necessary safety precautions - they are
not meant to guarantee definite characteristics - but they are based on our present up-to-date knowledge.
No responsibility.
These statements were made by:
Chemical Check GmbH, Chemical Check Platz 1-7, D-32839 Steinheim, Tel.: +49 5233 94 17 0, Fax:
+49 5233 94 17 90
© by Chemical Check GmbH Gefahrstoffberatung. The copying or changing of this document
is forbidden except with consent of the Chemical Check GmbH Gefahrstoffberatung.