MSDS Sayerlack
MSDS Sayerlack
MSDS Sayerlack
1.2 Relevant identified uses of the substance or mixture and uses advised against
Material uses : Paint or paint related material.
: Industrial use only.
Date of issue/Date of revision : 10, Sep, 2016. Date of previous issue : 29, May, 2016. Version :5 1/13
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II
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Classification
Product/ingredient Identifiers % Regulation (EC) No. 1272/2008 [CLP] Type
name
2-Butoxyethanol REACH #: ≤3 Acute Tox. 4, H302 [1] [2]
01-2119475108-36 Acute Tox. 4, H312
EC: 203-905-0 Acute Tox. 4, H332
CAS: 111-76-2 Skin Irrit. 2, H315
Index: 603-014-00-0 Eye Irrit. 2, H319
2-(2-Butoxyethoxy)- REACH #: ≤2.9 Eye Irrit. 2, H319 [1] [2]
ethanol 01-2119475104-44
EC: 203-961-6
CAS: 112-34-5
Index: 603-096-00-8
See Section 16 for the full text of the H
statements declared above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have been
assigned a workplace exposure limit and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
Occupational exposure limits, if available, are listed in Section 8.
SECTION 4: First aid measures
4.1 Description of first aid measures
General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery
position and seek medical advice.
Eye contact : Remove contact lenses, irrigate copiously with clean, fresh water, holding the
eyelids apart for at least 10 minutes and seek immediate medical advice.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
Date of issue/Date of revision : 10, Sep, 2016. Date of previous issue : 29, May, 2016. Version :5 2/13
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4.2 Most important symptoms and effects, both acute and delayed
There are no data available on the mixture itself. Procedure used to derive the classification according to Regulation
(EC) No. 1272/2008 [CLP/GHS]. See Sections 2 and 3 for details.
Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result
in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular
weakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with
the mixture may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption
through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
This takes into account, where known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
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6.2 Environmental : Do not allow to enter drains or watercourses. If the product contaminates lakes,
precautions rivers, or sewers, inform the appropriate authorities in accordance with local
regulations.
6.3 Methods and material : Contain and collect spillage with non-combustible, absorbent material e.g. sand,
for containment and earth, vermiculite or diatomaceous earth and place in container for disposal
cleaning up according to local regulations (see Section 13). Preferably clean with a detergent.
Avoid using solvents.
6.4 Reference to other : See Section 1 for emergency contact information.
sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
SECTION 7: Handling and storage
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe : Due to the organic solvents content of the mixture:
handling
Prevent the creation of flammable or explosive concentrations of vapours in air and
avoid vapour concentrations higher than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and
other sources of ignition have been excluded. Electrical equipment should be
protected to the appropriate standard.
Keep away from heat, sparks and flame. No sparking tools should be used.
Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or
mist arising from the application of this mixture. Avoid inhalation of dust from
sanding.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed.
Put on appropriate personal protective equipment (see Section 8).
Never use pressure to empty. Container is not a pressure vessel.
Always keep in containers made from the same material as the original one.
Comply with the health and safety at work laws.
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors. Vapours may form
explosive mixtures with air.
When operators, whether spraying or not, have to work inside the spray booth,
ventilation is unlikely to be sufficient to control particulates and solvent vapour in all
cases. In such circumstances they should wear a compressed air-fed respirator
during the spraying process and until such time as the particulates and solvent
vapour concentration has fallen below the exposure limits.
Date of issue/Date of revision : 10, Sep, 2016. Date of previous issue : 29, May, 2016. Version :5 4/13
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Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to monitoring standards, such as
the following: European Standard EN 689 (Workplace atmospheres - Guidance for
the assessment of exposure by inhalation to chemical agents for comparison with
limit values and measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for the assessment
of exposure to chemical and biological agents) European Standard EN 482
(Workplace atmospheres - General requirements for the performance of procedures
for the measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous substances will also be
required.
: Regular monitoring of all work areas should be carried out at all times, including
areas that may not be equally ventilated.
DNELs/DMELs
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Date of issue/Date of revision : 10, Sep, 2016. Date of previous issue : 29, May, 2016. Version :5 6/13
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10.2 Chemical stability : Stable under recommended storage and handling conditions (see Section 7).
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition
products.
10.5 Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidising agents, strong alkalis, strong acids.
10.6 Hazardous : Under normal conditions of storage and use, hazardous decomposition products
decomposition products should not be produced.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL
PROTECTION for additional handling information and protection of employees.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
There are no data available on the mixture itself. Procedure used to derive the classification according to Regulation
(EC) No. 1272/2008 [CLP/GHS]. See Sections 2 and 3 for details.
Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result
in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular
weakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with
the mixture may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption
through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
This takes into account, where known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.
Acute toxicity
Date of issue/Date of revision : 10, Sep, 2016. Date of previous issue : 29, May, 2016. Version :5 8/13
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Reproductive toxicity
No data available
Teratogenicity
No data available
Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of Target organs
exposure
No data available
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of Target organs
exposure
No data available
Aspiration hazard
Product/ingredient name Result
No data available
Date of issue/Date of revision : 10, Sep, 2016. Date of previous issue : 29, May, 2016. Version :5 9/13
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Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Product/ingredient name Result Species Exposure
2-Butoxyethanol Acute EC50 >1000 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 800000 μg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 1250000 μg/l Marine water Fish - Menidia beryllina 96 hours
2-(2-Butoxyethoxy)-ethanol Acute LC50 1300000 μg/l Fresh water Fish - Lepomis macrochirus 96 hours
Date of issue/Date of revision : 10, Sep, 2016. Date of previous issue : 29, May, 2016. Version :5 10/13
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14.2 UN proper - - -
shipping name
14.3 Transport - - -
Hazard Class(es)/
Label(s)
14.4 Packing - - -
group
14.5 No. No. No.
Environmental
hazards
Additional Special provisions - -
information Not Applicable
This mixture is not classified as dangerous according to international transport regulations (ADR/RID, IMDG,
ICAO/IATA).
14.6 Special precautions for : Transport within user’s premises: always transport in closed containers that are
user upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
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15.2 Chemical safety : No Chemical Safety Assessment has been carried out.
assessment
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Date of issue/Date of revision : 10, Sep, 2016. Date of previous issue : 29, May, 2016. Version :5 12/13
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: If there is no previous validation date please contact your supplier for more
information.
Version : 5
Notice to reader
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and
consult resources, as necessary or appropriate, to become aware of and understand the data contained in this
SDS and any hazards associated with the product. This information is provided in good faith and believed to
be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information
presented here applies only to the product as shipped. The addition of any material can change the
composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ
between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his
activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product
are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the
conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for
any purpose other than the purpose shown in the applicable section of this SDS without first referring to the
supplier and obtaining written handling instructions. Due to the proliferation of sources for information such
as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other
source.
Date of issue/Date of revision : 10, Sep, 2016. Date of previous issue : 29, May, 2016. Version :5 13/13