DIPSOL CHEMICALS CO., LTD. Ref. No.

MS04911 Issued: 07/07/1995

PROD NAME: DIPSOL L-800 Revised: 01/31/2012

MATERIAL SAFETY DATA SHEET

1．PRODUCT AND COMPANY IDENTIFICATION
Product name Dipsol L-800
Reference number (Ref. No.) MS04911
Product description Surface finishing agent
Manufacturer DIPSOL CHEMICALS CO., LTD.
Address 2-7-12, YAESU, CHUO-KU, Tokyo, Japan
Department Overseas sales division
Telephone number +81(3)3548-9355
Fax number +81(3)3548-9370

2．HAZARDS IDENTIFICATION
GHS classification:
Health hazards
・ Respiratory sensitizer - Category 1
・ Skin sensitizer - Category 1
Others not described in the above are "Classification not possible" or "Not applicable".
Label element
Symbol

Signal word: Danger

Hazard statements:
H317 May cause an allergic skin reaction
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
Precautionary statements:
Prevention
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P233 Keep container tightly closed.
P260 Do not breathe dust / fume / gas / mist / vapours / spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves / protective clothing / eye protection / face protection.
Response
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water / shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

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 DIPSOL CHEMICALS CO., LTD. Ref. No. MS04911 Issued: 07/07/1995
PROD NAME: DIPSOL L-800 Revised: 01/31/2012

MATERIAL SAFETY DATA SHEET

2．HAZARDS IDENTIFICATION (CONT.)
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice / attention.
P313 Get medical advice / attention.
P330 Rinse mouth.
P333+P313 If skin irritation or rash occurs: Get medical advice / attention.
P362 Take off contaminated clothing.
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
Disposal
P501 Dispose of contents / container in accordance with local / regional / national /
international regulations.

3．COMPOSITION / INFORMATION ON INGREDIENTS

Substance or Mixture : Mixture (Liquid)
Component wt% CAS No. UN Classification
Sodium Metabisulfite
5% 7681-57-4 Not applicable
Na2S2O5

Others 95% Proprietary Not applicable

4．FIRST-AID MEASURES
Inhalation:
If vapors, mists, or spray of this solution are inhaled remove victim to fresh air.
Keep person warm and at rest. If not breathing, or breathing is irregular or if respiratory arrest occurs
get medical attention immediately.
Skin contact:
Remove contaminated clothing and immediately wash skin off with soap and water to avoid inflammation
of skin. Promptly seek medical attention.
Eye contact:
Immediately flush with water for over 15 minutes and seek medical attention to avoid risk of irritating
cornea and mucous membrane and developing conjunctivitis. When rinsing lift upper and lower eyelids
up with fingers and move eyes in every direction possible. Remove contact lenses, if present and easy
to do.
Ingestion:
Keep at rest and seek medical care at the first available opportunity.
If possible, rinse out mouth and do not induce vomiting.
Caution:
Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and
get medical attention immediately. Maintain an open airway. Loosen tight clothing such as collar, tie,
belt or waistband. No action shall be taken involving personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained
breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. Wear protective gloves or wash contaminated clothing thoroughly with water before
removing.

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 DIPSOL CHEMICALS CO., LTD. Ref. No. MS04911 Issued: 07/07/1995
PROD NAME: DIPSOL L-800 Revised: 01/31/2012

MATERIAL SAFETY DATA SHEET

5．FIRE-FIGHTING MEASURES
Suitable extinguishing media:
Dry chemical powder, carbon dioxide, foam, sand, and water.
Specific hazards:
Intense heat from fires may cause thermal decomposition, harmful gases or irritation gases.
Fire-Fighting procedures:
Product itself will not ignite.
Always place yourself upwind.
In case of peripheral fires promptly move containers to safe area.
If containers are immobile, cool down the peripheral surrounding area with cold water as to prevent
rupture of container.
Put localized primary fires out using appropriate fire-extinguisher.

6．ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment, and emergency procedures:
Workers must wear appropriate protection equipment (8. Exposure Prevention and Protection Measures
referenced) and work from upwind.
Unauthorized personnel must stay away from large spills. Ventilate enclosed areas.
Environmental precautions:
Barricade larger spills with gravel and the like to avoid runoff of spilled material and prevent its contact
with soil, waterways, drains and sewers.
Waste water from washing/rinsing area should not be released into the environment.
Methods and materials for containment and clean up:
For small spills, use chemical absorbent or wipe up with waste cloth.
For larger spills, collect it in a PE container as much as possible.
Subsequently neutralize with Soda ash solution or Caustic soda solution, then rinse liberally with water.

7．HANDLING AND STORAGE

Handling:
Must use proper PPE (8. Exposure Prevention and Protection Measure referenced), and must be
handled in well ventilated areas.
Handle only in well ventilated area. Must use PPE. Follow exposure prevention measure 8.
Avoid breathing vapor/mist, do not get in eyes, skin, clothes, wear appropriate PPE, to minimize
exposure.
Seal container after each use.
Collect all empty containers in one designated area.
Do not contact with oxidizing agents.
Storage:
Store in secure area to avoid theft.
Avoid direct sunlight, high temperatures, and high humidity.
Ideal storage conditions include cool, dark areas at 5 to 35C.
Use containers provided with product.
Use containers specified by the UN transport regulations.

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 DIPSOL CHEMICALS CO., LTD. Ref. No. MS04911 Issued: 07/07/1995
PROD NAME: DIPSOL L-800 Revised: 01/31/2012

MATERIAL SAFETY DATA SHEET

8．EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure limits:
Concentration to Maintain Concentration Allowance
Component Ministry of health, labour Japan Society for Occupational ACGIH
and welfare (Japan) Health

Sodium Metabisulfite Not available Not available TWA 5 mg/m3

Appropriate engineering controls:

Storage and handling areas must be equipped with eye wash station and shower, and there should be
signs clearly indicating location of each.
Prevent generated mist from contaminating air in work environment seal the origin, place localized
exhaust system, or total ventilation system.
Personal Protective Equipment (PPE):
Respiratory protection
Wear respiratory protection if ventilation is not sufficient.
Hand protection
Protective gloves.
Eye protection
Protective glasses, goggles.
Skin and body protection
Protective clothing, rubber boots.
Hygiene measures:
Wash hands thoroughly after handling. Avoid taking contaminated clothing out of work place.

9．PHYSICAL AND CHEMICAL PROPERTIES

Physical state Liquid
Color Light yellow - Yellow
Odor Odorless
pH 3-6
Melting point Not available
Freezing point Not available
Initial boiling point / Range Not available
Flash point / Method No flash point
Evaporation rate (Water=1) Not available
Flammability (solid, gas) Not available
Flammability / Explosion limits Not available
Vapor / Vapour pressure Not available
Vapor / Vapour density (Air=1) Not available
Specific gravity 1.08 - 1.10 (25°C)
Specific weight / Weight density Not available
% Solubility in water Not available
n-Octanol / Water partition coefficient Not available
Auto-ignition temperature Not available
Decomposition temperature Not available

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 DIPSOL CHEMICALS CO., LTD. Ref. No. MS04911 Issued: 07/07/1995
PROD NAME: DIPSOL L-800 Revised: 01/31/2012

MATERIAL SAFETY DATA SHEET

10．STABILITY AND REACTIVITY
Stability:
Stable under recommended handling and storage conditions.
Precipitation, decline in pH may occur, when time pass for long time. Substances in this product might
precipitate readily, when the concentration of the solution is more than their usual saturated
concentration at a certain condition.
Possiblility of Hazardous Reactions:
Reacts violently when exposed to oxidizing agents.
Incompatible Materials:
Oxidizing agents.

11．TOXICOLOGICAL INFORMATION
Acute toxicity:
Estimates Oral Not available
[Sodium Metabisulfite]
Oral LD50 1,310mg/kg (rat)
Skin corrosion / Irritation:
Irritates the skin.
Serious eye damage / Eye irritation:
Irritates the eyes upon contact, may cause conjunctivitis.
Respiratory sensitizer:
May cause respiratory anaphylaxis.
Skin sensitizer:
May cause allergic reaction.

12．ECOLOGICAL INFORMATION
Ecotoxicity:
Not available
Other:
[Sodium Metabisulfite]
Daphnia magna LC50 89 ppm (48h)
Caution:
Since there is a possibility of affecting environment, in the case of a leak and disposal be careful of
handling.

13．DISPOSAL CONSIDERATIONS
Residual waste method:
Treatment process
Treatment of contents/container in accordance with local/regional/national/international regulations.
Disposal method
Disposal of contents/container in accordance with local/regional/national/international regulations.
Used containers and packaging:
Clean containers out, waste solution after washing must be disposed of in accordance to standards
of the local municipality.
Cleaned out empty containers shall be disposed of by those appointed by local, regional, state
government.
Caution:
Waste disposals should be treated to meet local laws.

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 DIPSOL CHEMICALS CO., LTD. Ref. No. MS04911 Issued: 07/07/1995
PROD NAME: DIPSOL L-800 Revised: 01/31/2012

MATERIAL SAFETY DATA SHEET

14．TRANSPORT INFORMATION
International regulation:
UN Class Not applicable
UN Number Not applicable
UN Proper shipping name Not applicable
Packing group Not applicable

15．REGULATORY INFORMATION
The product should be used, handled, stored, and disposed under the local laws.
Ship safety law Not applicable
Aviation law Not applicable

16．OTHER INFORMATION
References:
Raw material supplier's MSDS
Disclaimer:
This MSDS is in compliance with JIS Z 7250：2005 and follows the law of Japan accordingly.
It is not meant to conform to the laws of any other country.
Contents of this MSDS is accurate to the best of our knowledge, however, the accuracy of information,
hazard evaluation may not be most current, and therefore cannot be guaranteed to be safe.
Contents of the product with regards to physical/chemical property values are not guaranteed values.
This MSDS can be updated without warning upon discovery of new information.
All chemical products may have unknown, potentially hazardous/toxic characteristics.
It is recommended that handling be done with caution. Each individual handler shall establish his/her
own criteria to prioritize safety.
No guarantee other than product description use in section 1.

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