MD 1
MD 1
MD 1
Minerals shows isomorphism (atomic structure do not change )(with the same atomic
structure but different chemical formulas).Example- olivine [(Mg,Fe)2SiO4 ]At the
high temperatures and pressures found at depth within the Earth the olivine structure
is no longer stable. Below depths of about 410 km (250 mi) olivine undergoes an
exothermic phase transition to the sorosilicate, wadsleyite and, at about 520 km
(320 mi) depth, wadsleyite transforms exothermically into ringwoodite, which has
the spinel structure. At a depth of about 660 km (410 mi), ringwoodite decomposes
into silicate perovskite ((Mg,Fe)SiO3) and ferropericlase ((Mg,Fe)O) in an
endothermic reaction. The pressure at which these phase transitions occur depends on
temperature and iron content.
Rock vs mineral:
Chalk, clay, granite(igneous rock),coal are rocks there are not come under
definition of minerals because they are not physically and chemically
homogeneous.
Rocks generally consists of variety of minerals.
The minimum metal content required for a deposit to qualify as an ore
varies from metal to metal:
Many non ferrous ore contains only 1% metals or some times less then
it.
Gold can be recovered profitable from an ore containing 1 ppm level of
metals.
Iron containing less then 45 % percent in an ore is said to be low grade.
Every ton of material deposited have Contained value – depend upon
metal content and current price of the contained metal.
Ore types : on the basis of nature of valuable mineral
native ore – metal is present in native form
sulphide ore- metal is present in sulphide form
oxide ore- metal is in form of oxide
sulphate ore- metal is in form of sulphate
Silicate ore – metal is in form of silicate
carbonate ore- metal is in form of carbonate
hydrated form
Hydroxide
complex ore- those ore which contains profitable amount of more than one
valuable mineral.
Ore types : on the basis of nature of their gangues
Calcareous or basic – lime rich
Siliceous or acidic – silica rich
What constitutes mineral beneficiation?
Ore is an aggregate of minerals and contains valuable and gangue minerals .
The mineral beneficiation involves separation of gangue minerals from ore.
It has three steps
Liberation ,
Separation,
Concentration.
1) Liberation of valuable mineral by size reduction.
2) Separation of coarse and fine particles.
3) Concentration to separate the gangue minerals to increase the metal grade.
If the first step is not done correctly, the second step will be incomplete.
Liberation by size reduction
Consider a cube ( 10 cm dia. )of the ore having MINERAL and
GANGUE.
Suppose it has cubic grains of 10 mm.
Assumptions
1.crushing is conducted to yield grains of same size.
2.crystals in the ore are intimately joined with each other.
Till the ore lump is crushed to 10 mm dia., all grains are locked.
It cannot be assumed that all particles are free since they are of 5
mm dia. ( smaller than 10 mm dia.).
Minerals of equal abundance
The cube is sectioned along a vertical plane. Visualize that lattices with
parameters 10mm and 5 mm are superimposed with their axes parallel.
It appears that , in the plane of section, alternate rows ‘A’ and ‘C’ only
have “free looking” particles. Other alternate rows ‘B’ and ‘D’ do not
have them.
The free particles are 1,3,5,13,15,17. ( They may be locked in other planes
). Free particles of mineral and gangue – 6 out of 48 (1/8) ( and not 6 out
of 24).
Bauxite
LIBERATION BY DETACHMENT.
If the ore lump is made of mineral grains bonded loosely, fracturing to the grain size
results in complete liberation.
Eg: Pebble phosphate rock