Stream In

Stream 18

ΔHH2SO4
(l, 25˚C, 1atm) (l, 142.8 ˚C, 15atm)

ΔH1 ΔH2
(l, 142.8˚C, 1atm)

ΔHH2SO4
REF: (l, 25˚C, 1atm)
142.8 ˚C
H H 2 SO 4=∆ Ĥ f ( l ) + ∫ Cp H 2 SO 4 dT + ṽΔP
25 ˚C

142.8˚ C
1
H H 2 SO 4=−811.32+ ∫ Cp H 2 SO 4 dT +( ) ΔP
25˚ C ρ@ 25˚ C
142.8˚ C
1 kg 1 kJ
H H 2 SO 4=−811.32+ ∫
25˚ C
−3 −5
139.1 x 10 + ( 15.59 x 10 T ) dT +
1830.2
kg ( 98.08
mol ) (1519.88−101.32 )
( 1 kPa .
m3
kJ kJ kJ
H H 2 SO 4=−811.32 +17.9268 +76.0203
kmol kmol kmol
kmol kJ
n¿ H ¿ =567.41 x−717.3729
hr kmol
kJ
n¿ H ¿ =−407044.5572
hr

Stream 8

ΔHO2
(g, 25˚C, 1atm) (g, 410˚C, 2 atm)

ΔH1 ΔH2
(g, 410˚C, 1atm)
 T
Δ H oxygen= ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H oxygen= ∫ Cp dT + ΔP
Tref P
410 ˚C
( 0.0815 kPa . m3 kg . K ) ( 683 K ) kg 1
Δ H oxygen= ∫
25˚ C
−3 −5
29.10 x 10 +1.158 x 10 T +(
202.65 kPa
)(32
kmol (
) ( 202.65−101.32 )
1 kP
Δ H oxygen=12.1732+890.6760

Δ H oxygen=902.8491 kJ /kmol

kmol kJ
n oxygen H oxygen=130.84 x 902.8491
hr kmol

n oxygen H oxygen=117550.9592 kJ / hr

ΔHnitrogen
(l, 25˚C, 1atm) (l, 410˚C, 2atm)

ΔH1 ΔH2
(l, 410˚C, 1atm)

T
Δ H nitrogen = ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H nitrogen = ∫ Cp dT + ΔP
Tref P
410 ˚C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 683 K ) kg
Δ H nitrogen = ∫ 29.00 x 10 +0.2199 x 10 T +( )(28.02 ) ( 202.65−101.32 )
25˚ C 202.65 kPa kmol

Δ H nitrogen =11.3491+779.8981

Δ H nitrogen =779.8981 kJ /kmol

kmol kJ
n nitrogen H nitrogen =939.69 x 779.8981
hr kmol
n nitrogen H nitrogen =732862.4456 kJ /hr
 ΔHSO2
(g, 25˚C, 1atm) (g, 140˚C, 2 atm)

ΔH1 ΔH2
(g, 140˚C, 1atm)

T
Δ H SO 2=∆ Ĥ f ( g ) + ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H SO 2=∆ Ĥ f ( g ) + ∫ Cp dT + ΔP
Tref P
410 ˚C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 683 K ) kg
Δ H SO 2=−296.90+ ∫ 38.91 x 10 +3.904 x 10 T +( )(64.07 ) ( 202.65−1
25˚ C 202.65 kPa kmol

Δ H SO 2=−296.90+18.2495+1783.3003

Δ H SO 2=1504.6498 kJ /kmol

kmol kJ
n SO 2 H SO 2 =118.95 x 1504.6498
hr kmol
n SO 2 H SO 2 =178978.0937 kJ /hr

Stream 10

ΔHO2
(g, 25˚C, 1atm) (g, 438˚C, 2 atm)

ΔH1 ΔH2
(g, 438˚C, 1atm)

T
Δ H oxygen= ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H oxygen= ∫ Cp dT + ΔP
Tref P
438 ˚C
( 0.0815 kPa . m3 kg . K ) ( 711 K ) kg 1
Δ H oxygen= ∫
25˚ C
−3 −5
29.10 x 10 +1.158 x 10 T +(
202.65 kPa
)(32
kmol
) ( 202.65−101.32 )
(1 kP
Δ H oxygen=13.1254+ 927.1898

Δ H oxygen=940.3152 kJ /kmol

kmol kJ
n oxygen H oxygen=93.84 x 940.3152
hr kmol

n oxygen H oxygen=88239.1784 kJ /hr

ΔHN2
(g, 25˚C, 1atm) (g, 438˚C, 2 atm)

ΔH1 ΔH2
(g, 438˚C, 1atm)

T
Δ H nitrogen = ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H nitrogen = ∫ Cp dT + ΔP
Tref P
438 ˚C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 711 K ) kg
Δ H nitrogen = ∫ 29.00 x 10 +0.2199 x 10 T +( )(28.02 ) ( 202.65−101.32 )
25˚ C 202.65 kPa kmol

Δ H nitrogen =12.1872+811.8705

Δ H nitrogen =824.0577 kJ /kmol

kmol kJ
n nitrogen H nitrogen =939.69 x 824.0577
hr kmol
n nitrogen H nitrogen =771960.8146 kJ /hr

ΔHSO2
(g, 25˚C, 1atm) (g, 438˚C, 2 atm)

ΔH1 ΔH2
(g, 438˚C, 1atm)

T
Δ H SO 2=∆ Ĥ f ( g ) + ∫ Cp dT + ṽΔP
Tref
 T
RT
Δ H SO 2=∆ Ĥ f ( g ) + ∫ Cp dT + ΔP
Tref P
438 ˚C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 711 K ) kg
Δ H SO 2=−296.90+ ∫ 38.91 x 10 +3.904 x 10 T +( )(64.07 ) ( 202.65−1
25˚ C 202.65 kPa kmol

Δ H SO 2=−296.90+19.8024+ 1856.4077

Δ H SO 2=1579.3101 kJ /kmol

kmol kJ
n SO 2 H SO 2 =30.93 x 1579.3101
hr kmol
n SO 2 H SO 2 =48848.0614 kJ /hr

ΔHSO3
(g, 25˚C, 1atm) (g, 438˚C, 2 atm)

ΔH1 ΔH2
(g, 438˚C, 1atm)

T
Δ H SO 3=∆ Ĥ f ( g ) + ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H SO 3=∆ Ĥ f ( g ) + ∫ Cp dT + ΔP
Tref P
438 ˚C
−3 −5 ( 0.0815 kPa. m3 kg . K ) (711 K ) kg
Δ H SO 3=−395.18+ ∫ 48.50 x 10 + 9.188 x 10 T +( )(80.07 ) ( 202.65−1
25˚ C 202.65 kPa kmol

Δ H SO 3=−395.18+28.8151+2320.0026

Δ H SO 3=1953.6377 kJ /kmol

kmol kJ
n SO 3 H SO3 =88.02 x 1953.6377
hr kmol
n SO 3 H SO3 =171959.1904 kJ /hr

Stream 12
 ΔHO2
(g, 25˚C, 1atm) (g, 432˚C, 2 atm)

ΔH1 ΔH2
(g, 432˚C, 1atm)

T
Δ H oxygen= ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H oxygen= ∫ Cp dT + ΔP
Tref P
432 ˚C
( 0.0815 kPa .m3 kg . K ) ( 705 K ) kg 1
Δ H oxygen= ∫
25˚ C
−3 −5
29.10 x 10 +1.158 x 10 T +(
202.65 kPa
)(32
kmol (
) ( 202.65−101.32 )
1kP
Δ H oxygen=12.9206+ 919.3664

Δ H oxygen=932.2870 kJ /kmol

kmol kJ
n oxygen H oxygen=84.64 x 932.2870
hr kmol

n oxygen H oxygen=78908.7717 kJ /hr

ΔHN2
(g, 25˚C, 1atm) (g, 432˚C, 2 atm)

ΔH1 ΔH2
(g, 432˚C, 1atm)

T
Δ H nitrogen = ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H nitrogen = ∫ Cp dT + ΔP
Tref P
432 ˚C
−3 −5 ( 0.0815 kPa .m3 kg . K ) ( 705 K ) kg
Δ H nitrogen = ∫ 29.00 x 10 +0.2199 x 10 T +( )(28.02 ) (202.65−101.32 )
25˚ C 202.65 kPa kmol

Δ H nitrogen =12.0075+805.0193

Δ H nitrogen =817.0194 kJ /kmol

 kmol kJ
n nitrogen H nitrogen =939.69 x 817.0194
hr kmol
n nitrogen H nitrogen =767744.9258 kJ /hr

ΔHSO2
(g, 25˚C, 1atm) (g, 432˚C, 2 atm)

ΔH1 ΔH2
(g, 432˚C, 1atm)

T
Δ H SO 2=∆ Ĥ f ( g ) + ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H SO 2=∆ Ĥ f ( g ) + ∫ Cp dT + ΔP
Tref P
432 ˚C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 705 K ) kg
Δ H SO 2=−296.90+ ∫ 38.91 x 10 + 3.904 x 10 T +( )(64.07 ) ( 202.65−1
25˚ C 202.65 kPa kmol

Δ H SO 2=−296.90+19.4671+1840.7418

Δ H SO 2=1563.3089 kJ /kmol

kmol kJ
n SO 2 H SO 2 =9.4 x 1563.3089
hr kmol
n SO 2 H SO 2 =14695.1037 kJ /hr

ΔHSO3
(g, 25˚C, 1atm) (g, 432˚C, 2 atm)

ΔH1 ΔH2
(g, 432˚C, 1atm)

T
Δ H SO 3=∆ Ĥ f ( g ) + ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H SO 3=∆ Ĥ f ( g ) + ∫ Cp dT + ΔP
Tref P
 432 ˚C
−3 −5 ( 0.0815 kPa. m3 kg . K ) ( 705 K ) kg
Δ H SO 3=−395.18+ ∫ 48.50 x 10 + 9.188 x 10 T +( )( 80.07 ) ( 202.65−1
25˚ C 202.65 kPa kmol

Δ H SO 3=−395.18+28.2843+2300.4245

Δ H SO 3=1933.5288 kJ /kmol

kmol kJ
n SO 3 H SO3 =109.91 x 1933.5288
hr kmol
n SO 3 H SO3 =212514.1504 kJ /hr

Stream 16

ΔHO2
(g, 25˚C, 1atm) (g, 444˚C, 2 atm)

ΔH1 ΔH2
(g, 444˚C, 1atm)

T
Δ H oxygen= ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H oxygen= ∫ Cp dT + ΔP
Tref P
444 ˚ C
( 0.0815 kPa . m3 kg . K ) ( 717 K ) kg 1
Δ H oxygen= ∫
25˚ C
−3 −5
29.10 x 10 +1.158 x 10 T +(
202.65 kPa
)(32
kmol
) ( 202.65−101.32 )
(
1 kP
Δ H oxygen=13.3307+ 935.0141

Δ H oxygen=948.3448 kJ /kmol

kmol kJ
n oxygen H oxygen=82.49 x 948.3448
hr kmol

n oxygen H oxygen=78228.9626 kJ /hr

ΔHN2
(g, 25˚C, 1atm) (g, 444˚C, 2 atm)

ΔH1 ΔH2
(g, 444˚C, 1atm)
 T
Δ H nitrogen = ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H nitrogen = ∫ Cp dT + ΔP
Tref P
444 ˚ C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 717 K ) kg
Δ H nitrogen = ∫ 29.00 x 10 +0.2199 x 10 T +( )(28.02 ) ( 202.65−101.32 )
25˚ C 202.65 kPa kmol

Δ H nitrogen =12.3671+818.7218

Δ H nitrogen =831.0889 kJ /kmol

kmol kJ
n nitrogen H nitrogen =939.69 x 831.0889
hr kmol
n nitrogen H nitrogen =778547.4259 kJ /hr

ΔHSO2
(g, 25˚C, 1atm) (g, 444˚C, 2 atm)

ΔH1 ΔH2
(g, 444˚C, 1atm)

T
Δ H SO 2=∆ Ĥ f ( g ) + ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H SO 2=∆ Ĥ f ( g ) + ∫ Cp dT + ΔP
Tref P
444 ˚ C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 717 K ) kg
Δ H SO 2=−296.90+ ∫ 38.91 x 10 +3.904 x 10 T +( )(64.07 ) (202.65−1
25˚ C 202.65 kPa kmol

Δ H SO 2=−296.90+20.1392+1872.0736

Δ H SO 2=1595.3128 kJ /kmol

kmol kJ
n SO 2 H SO 2 =4.29 x 1595.3128
hr kmol
n SO 2 H SO 2 =6843.8919 kJ /hr

ΔHSO3
(g, 25˚C, 1atm) (g, 444˚C, 2 atm)

ΔH1 ΔH2
(g, 444˚C, 1atm)
 T
Δ H SO 3=∆ Ĥ f ( g ) + ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H SO 3=∆ Ĥ f ( g ) + ∫ Cp dT + ΔP
Tref P
444 ˚ C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 717 K ) kg
Δ H SO 3=−395.18+ ∫ 48.50 x 10 + 9.188 x 10 T +( )(80.07 ) ( 202.65−1
25˚ C 202.65 kPa kmol

Δ H SO 3=−395.18+29.3492+2339.5807

Δ H SO 3=1973.7499 kJ / kmol

kmol kJ
n SO 3 H SO3 =115 x 1973.7499
hr kmol
n SO 3 H SO3 =226981.2385 kJ /hr

Stream Out
Stream 9

ΔHO2
(g, 25˚C, 1atm) (g, 601.8˚C, 15 atm)

ΔH1 ΔH2
(g, 601.8˚C, 1atm)

T
Δ H oxygen= ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H oxygen= ∫ Cp dT + ΔP
Tref P
601.8 ˚C
( 0.0815 kPa . m3 kg . K ) ( 874.8 K ) kg
Δ H oxygen= ∫
25 ˚C
−3
29.10 x 10 +1.158 x 10 T +(
−5
1519.88 kPa
)(32
kmol
) ( 1519.88−101.32 )
(
Δ H oxygen=18.8782+2129.388

Δ H oxygen=2148.2662 kJ /kmol
 kmol kJ
n oxygen H oxygen=93.84 x 2148.2662
hr kmol

n oxygen H oxygen=201593.6568 kJ /hr

ΔHN2
(g, 25˚C, 1atm) (g, 601.8˚C, 15 atm)

ΔH1 ΔH2
(g, 601.8˚C, 1atm)

T
Δ H nitrogen = ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H nitrogen = ∫ Cp dT + ΔP
Tref P
601.8 ˚C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 874.8 K ) kg
Δ H nitrogen = ∫ 29.00 x 10 +0.2199 x 10 T +( )(28.02 ) ( 1519.88−101
25 ˚C 1519.88 kPa kmol

Δ H nitrogen =17.1247+1864.545

Δ H nitrogen =1881.6697 kJ / kmol

kmol kJ
n nitrogen H nitrogen =939.69 x 1881.6697
hr kmol
n nitrogen H nitrogen =1762710.542 kJ /hr

ΔHSO2
(g, 25˚C, 1atm) (g, 601.8˚C, 15 atm)

ΔH1 ΔH2
(g, 601.8˚C, 1atm)
 T
Δ H SO 2=∆ Ĥ f ( g ) + ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H SO 2=∆ Ĥ f ( g ) + ∫ Cp dT + ΔP
Tref P
601.8 ˚C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 874.8 K ) kg
Δ H SO 2=−296.90+ ∫ 38.91 x 10 +3.904 x 10 T +( )(64.07 ) ( 1519.8
25 ˚C 1519.88 kPa kmol

Δ H SO 2=−296.90+29.5005+ 4263.434

Δ H SO 2=3996.0345 kJ / kmol

kmol kJ
n SO 2 H SO 2 =30.93 x 3996.0345
hr kmol
n SO 2 H SO 2 =123597.3471kJ /hr

ΔHSO3
(g, 25˚C, 1atm) (g, 601.8˚C, 15atm)

ΔH1 ΔH2
(g, 601.8˚C, 1atm)

T
Δ H SO 3=∆ Ĥ f ( g ) + ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H SO 3=∆ Ĥ f ( g ) + ∫ Cp dT + ΔP
Tref P
601.8 ˚C
−3 −5 ( 0.0815 kPa. m3 kg . K ) ( 874.8 K ) kg
Δ H SO 3=−395.18+ ∫ 48.50 x 10 + 9.188 x 10 T +( )(80.07 ) ( 1519.8
25 ˚C 1519.88 kPa kmol

Δ H SO 3=−395.18+ 44.5839+5328.128

Δ H SO 3=4977.5319 kJ /kmol

kmol kJ
n SO 3 H SO3 =88 x 4977.5319
hr kmol
n SO 3 H SO3 =438022.8072 kJ /hr

Stream 11

ΔHO2
(g, 25˚C, 1atm) (g, 485.3˚C, 15 atm)

ΔH1 ΔH2
(g, 485.3˚C, 1atm)
 T
Δ H oxygen= ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H oxygen= ∫ Cp dT + ΔP
Tref P
485.3 ˚ C
( 0.0815 kPa . m3 kg . K ) ( 758.3 K ) kg
Δ H oxygen= ∫
25 ˚C
−3 −5
29.10 x 10 +1.158 x 10 T +(
1519.88 kPa
)(32
kmol
) ( 1519.88−101.32 )
(
Δ H oxygen=14.7547+1845.81

Δ H oxygen=1860.5647 kJ /kmol

kmol kJ
n oxygen H oxygen=84.64 x 1860.5647
hr kmol

n oxygen H oxygen=157478.1962 kJ /hr

ΔHN2
(g, 25˚C, 1atm) (g, 485.3˚C, 15 atm)

ΔH1 ΔH2
(g, 485.3˚C, 1atm)

T
Δ H nitrogen = ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H nitrogen = ∫ Cp dT + ΔP
Tref P
485.3 ˚C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 758.3 K ) kg
Δ H nitrogen = ∫ 29.00 x 10 +0.2199 x 10 T +( )(28.02 ) ( 1519.88−101
25 ˚C 1519.88 kPa kmol

Δ H nitrogen =13.6070+1616.238

Δ H nitrogen =1629.8450 kJ /kmol

 kmol kJ
n nitrogen H nitrogen =939.69 x 1629.8450
hr kmol
n nitrogen H nitrogen =1526806.164 kJ /hr

ΔHSO2
(g, 25˚C, 1atm) (g, 485.3˚C, 15 atm)

ΔH1 ΔH2
(g, 485.3˚C, 1atm)

T
Δ H SO 2=∆ Ĥ f ( g ) + ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H SO 2=∆ Ĥ f ( g ) + ∫ Cp dT + ΔP
Tref P
485.3 ˚ C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 758.3 K ) kg
Δ H SO 2=−296.90+ ∫ 38.91 x 10 +3.904 x 10 T +( )(64.07 ) ( 1519.8
25 ˚C 1519.88 kPa kmol

Δ H SO 2=−296.90+22.4953+3695.658

Δ H SO 2=3421.2533 kJ / kmol

kmol kJ
n SO 2 H SO 2 =9.4 x 3421.2533
hr kmol
n SO 2 H SO 2 =32159.7810 kJ /hr

ΔHSO3
(g, 25˚C, 1atm) (g, 485.3˚C, 15atm)

ΔH1 ΔH2
(g, 485.3˚C, 1atm)
 T
Δ H SO 3=∆ Ĥ f ( g ) + ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H SO 3=∆ Ĥ f ( g ) + ∫ Cp dT + ΔP
Tref P
485.3 ˚ C
−3 −5 ( 0.0815 kPa .m3 kg . K ) ( 758.3 K ) kg
Δ H SO 3=−395.18+ ∫ 48.50 x 10 + 9.188 x 10 T +( )(80.07 ) ( 1519.8
25 ˚C 1519.88 kPa kmol

Δ H SO 3=−395.18+33.1154 + 4618.563

Δ H SO 3=4256.4984 kJ /kmol

kmol kJ
n SO 3 H SO3 =109.88 x 4256.4984
hr kmol
n SO 3 H SO3 =467704.0442 kJ /hr

Stream 13

ΔHO2
(g, 25˚C, 1atm) (g, 444˚C, 15 atm)

ΔH1 ΔH2
(g, 444˚C, 1atm)

T
Δ H oxygen= ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H oxygen= ∫ Cp dT + ΔP
Tref P
444 ˚ C
( 0.0815 kPa . m3 kg . K ) ( 717 K ) kg
Δ H oxygen= ∫
25˚ C
−3
29.10 x 10 +1.158 x 10 T +(
−5
1519.88 kPa
)(32
kmol
) ( 1519.88−101.32 )
(
1k
Δ H oxygen=13.3307+1745.28

Δ H oxygen=1758.6107 kJ /kmol

kmol kJ
n oxygen H oxygen=82.49 x 1758.6107
hr kmol

n oxygen H oxygen=145067.7966 kJ / hr

ΔHN2
(g, 25˚C, 1atm) (g, 444˚C, 15 atm)

ΔH1 ΔH2
(g, 444˚C, 1atm)
 T
Δ H nitrogen = ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H nitrogen = ∫ Cp dT + ΔP
Tref P
444 ˚ C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 717 K ) kg
Δ H nitrogen = ∫ 29.00 x 10 +0.2199 x 10 T +( )(28.02 ) ( 1519.88−101.32
25˚ C 1519.88 kPa kmol

Δ H nitrogen =12.3671+1528.211

Δ H nitrogen =1540.5781 kJ /kmol

kmol kJ
n nitrogen H nitrogen =939.69 x 1540.5781
hr kmol
n nitrogen H nitrogen =1443182.719 kJ /hr

ΔHSO2
(g, 25˚C, 1atm) (g, 444˚C, 15 atm)

ΔH1 ΔH2
(g, 444˚C, 1atm)

T
Δ H SO 2=∆ Ĥ f ( g ) + ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H SO 2=∆ Ĥ f ( g ) + ∫ Cp dT + ΔP
Tref P
444 ˚ C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 717 K ) kg
Δ H SO 2=−296.90+ ∫ 38.91 x 10 +3.904 x 10 T +( )(64.07 ) (1519.88−
25˚ C 1519.88 kPa kmol

Δ H SO 2=−296.90+20.1392+3494.378

Δ H SO 2=3217.6172 kJ /kmol
 kmol kJ
n SO 2 H SO 2 =4.29 x 3217.6172
hr kmol
n SO 2 H SO 2 =13803.5778 kJ /hr

ΔHSO3
(g, 25˚C, 1atm) (g, 444˚C, 15atm)

ΔH1 ΔH2
(g, 444˚C, 1atm)

T
Δ H SO 3=∆ Ĥ f ( g ) + ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H SO 3=∆ Ĥ f ( g ) + ∫ Cp dT + ΔP
Tref P
444 ˚ C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 717 K ) kg
Δ H SO 3=−395.18+ ∫ 48.50 x 10 + 9.188 x 10 T +( )(80.07 ) ( 1519.88−
25˚ C 1519.88 kPa kmol

Δ H SO 3=−395.18+29.3492+ 4367.018

Δ H SO 3=4001.1872 kJ /kmol

kmol kJ
n SO 3 H SO3 =115 x 4001.1872
hr kmol
n SO 3 H SO3 =460136.5280 kJ /hr

Stream 17

ΔHO2
(g, 25˚C, 1atm) (g, 135˚C, 15 atm)

ΔH1 ΔH2
(g, 135˚C, 1atm)
 T
Δ H oxygen= ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H oxygen= ∫ Cp dT + ΔP
Tref P
135 ˚C
( 0.0815 kPa. m3 kg . K ) ( 408 K ) kg
Δ H oxygen= ∫
25˚ C
−3 −5
29.10 x 10 +1.158 x 10 T +(
1519.88 kPa
)(32
kmol (
) ( 1519.88−101.32 )
1k
Δ H oxygen=3.3029+993.1301

Δ H oxygen=996.4330 kJ /kmol

kmol kJ
n oxygen H oxygen=80.94 x 996.4330
hr kmol

n oxygen H oxygen=80651.2870 kJ /hr

ΔHN2
(g, 25˚C, 1atm) (g, 135˚C, 15 atm)

ΔH1 ΔH2
(g, 135˚C, 1atm)

T
Δ H nitrogen = ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H nitrogen = ∫ Cp dT + ΔP
Tref P
135˚ C
−3 −5 ( 0.0815 kPa .m3 kg . K ) ( 408 K ) kg
Δ H nitrogen = ∫ 29.00 x 10 + 0.2199 x 10 T +( )(28.02 ) ( 1519.88−101.32
25 ˚ C 1519.88 kPa kmol

Δ H nitrogen =3.2094+ 869.6096

Δ H nitrogen =872.8190 kJ /kmol

kmol kJ
n nitrogen H nitrogen =939.69 x 872.8190
hr kmol
n nitrogen H nitrogen =817639.3371 kJ /hr

ΔHSO2
(g, 25˚C, 1atm) (g, 135˚C, 15 atm)

ΔH1 ΔH2
(g, 135˚C, 1atm)
 T
Δ H SO 2=∆ Ĥ f ( g ) + ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H SO 2=∆ Ĥ f ( g ) + ∫ Cp dT + ΔP
Tref P
135 ˚C
−3 −5 ( 0.0815 kPa .m 3 kg . K ) ( 408 K ) kg
Δ H SO 2=−296.90+ ∫ 38.91 x 10 +3.904 x 10 T +( )(64.07 ) ( 1519.88−
25˚ C 1519.88 kPa kmol

Δ H SO 2=−296.90+ 4.6237+1988.433

Δ H SO 2=1696.1567 kJ /kmol

kmol kJ
n SO 2 H SO 2 =0.6 x 1696.1567
hr kmol
n SO 2 H SO 2 =1017.6940 kJ /hr

ΔHSO3
(g, 25˚C, 1atm) (g, 135˚C, 15atm)

ΔH1 ΔH2
(g, 135˚C, 1atm)

T
Δ H SO 3=∆ Ĥ f ( g ) + ∫ Cp dT + ṽΔP
Tref

T
RT
Δ H SO 3=∆ Ĥ f ( g ) + ∫ Cp dT + ΔP
Tref P
135 ˚C
−3 −5 ( 0.0815 kPa . m3 kg . K ) ( 408 K ) kg
Δ H SO 3=−395.18+ ∫ 48.50 x 10 +9.188 x 10 T +( )(80.07 ) ( 1519.88−
25˚ C 1519.88 kPa kmol

Δ H SO 3=−395.18+6.1435+2484.998

Δ H SO 3=2095.9615 kJ /kmol
 kmol kJ
n SO 3 H SO3 =56.55 x 2095.9615
hr kmol
n SO 3 H SO3 =118526.6228 kJ /hr