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Photoelectric Absorption

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Photoelectric absorption[edit]

The probability of a photoelectric absorption per unit mass is approximately proportional


to Z3/E3, where Z is the atomic number and E is the energy of the incident photon.[72] This rule
is not valid close to inner shell electron binding energies where there are abrupt changes in
interaction probability, so called absorption edges. However, the general trend of
high absorption coefficients and thus short penetration depths for low photon energies and
high atomic numbers is very strong. For soft tissue, photoabsorption dominates up to about
26 keV photon energy where Compton scattering takes over. For higher atomic number
substances this limit is higher. The high amount of calcium (Z = 20) in bones, together with
their high density, is what makes them show up so clearly on medical radiographs.
A photoabsorbed photon transfers all its energy to the electron with which it interacts, thus
ionizing the atom to which the electron was bound and producing a photoelectron that is
likely to ionize more atoms in its path. An outer electron will fill the vacant electron position
and produce either a characteristic X-ray or an Auger electron. These effects can be used for
elemental detection through X-ray spectroscopy or Auger electron spectroscopy.

Compton scattering[edit]
Compton scattering is the predominant interaction between X-rays and soft tissue in medical
imaging.[73] Compton scattering is an inelastic scattering of the X-ray photon by an outer shell
electron. Part of the energy of the photon is transferred to the scattering electron, thereby
ionizing the atom and increasing the wavelength of the X-ray. The scattered photon can go
in any direction, but a direction similar to the original direction is more likely, especially for
high-energy X-rays. The probability for different scattering angles are described by the Klein–
Nishina formula. The transferred energy can be directly obtained from the scattering angle
from the conservation of energy and momentum.

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